| Common Name: | ICE MACHINE CLEANER |
| Manufacturer: | PARKER HANNIFIN |
| SDS Revision Date: | 4/10/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4E310, 4E838 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PARKER
PARKER HANNIFIN CORPORATION
SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO 63090
U.S.A.
ICE MACHINE CLEANER
H418-16OZ; H419
SDS REVISION DATE (MM/DD/YYYY): 04/10/2015
SAFETY DATA SHEET
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER USED ON THE LABEL: ICE MACHINE CLEANER
PRODUCT CODE(S): H418-16OZ (P/N 475060); H419 (P/N 475063)
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
PROFESSIONAL USE ONLY: ICE MACHINE CLEANING.
CHEMICAL FAMILY: AQUEOUS ACID SOLUTION
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE SUPPLIER:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO 63090
U.S.A.
SUPPLIER'S TELEPHONE #: (636)-239-1111
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE MANUFACTURER: REFER TO SUPPLIER
24 HR. EMERGENCY TEL #:
CHEMTREC: 1-800-424-9300 (WITHIN CONTINENTAL U.S.)
CHEMTREC: 703-527-3887 (OUTSIDE U.S.).
| SECTION 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL:
WHMIS INFORMATION:
THIS PRODUCT IS A WHMIS CONTROLLED PRODUCT. IT MEETS ONE OR MORE OF THE
CRITERIA FOR A CONTROLLED PRODUCT PROVIDED IN PART IV OF THE CANADIAN
CONTROLLED PRODUCTS REGULATIONS (CPR).
WHMIS CLASSIFICATION: CLASS E (CORROSIVE MATERIAL)
OSHA:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
OSHA CLASSIFICATION:
CORROSIVE TO METALS: CATEGORY 1
EYE DAMAGE/IRRITATION: CATEGORY 1
SKIN CORROSION/IRRITATION: CATEGORY 1
LABEL ELEMENTS:
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO THE UNITED STATES
ACCORDING TO OSHA REGULATIONS (29 CFR 1910.1200) (HAZCOM 2012):
SIGNAL WORD: DANGER!
HAZARD STATEMENT(S):
MAY BE CORROSIVE TO METALS. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
PRECAUTIONARY STATEMENT(S):
WASH THOROUGHLY AFTER HANDLING. KEEP ONLY IN ORIGINAL CONTAINER. DO NOT
BREATHE MISTS. WEAR PROTECTIVE GLOVES/CLOTHING AND EYE/FACE PROTECTION.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/
SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN. ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE. STORE IN
CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER. STORE LOCKED
UP. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/
NATIONAL/INTERNATIONAL REGULATIONS.
CORROSION
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO CANADA ACCORDING TO
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR/WHMIS):
DANGER!
MAY BE CORROSIVE TO METALS. CONTACT WITH METALS MAY RELEASE SMALL AMOUNTS
OF FLAMMABLE HYDROGEN GAS. CORROSIVE MATERIAL. MAY CAUSE SEVERE BURNS TO
ALL ROUTES OF EXPOSURE.
USE IN A WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES/CLOTHING AND EYE/FACE
PROTECTION. DO NOT INGEST. DO NOT BREATHE VAPOURS OR SPRAY MIST. KEEP AWAY
FROM BASES, METALS AND OTHER INCOMPATIBLES. KEEP CONTAINERS TIGHTLY CLOSED
WHEN NOT IN USE. WASH THOROUGHLY AFTER HANDLING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IF BREATHING
STOPPED, BEGIN ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. IMMEDIATELY CALL A POISON CENTRE OR DOCTOR/PHYSICIAN.
E - CORROSIVE MATERIAL
OTHER HAZARDS:
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
INGESTION MAY CAUSE SEVERE IRRITATION TO THE MOUTH, THROAT AND STOMACH.
CONTACT WITH METALS MAY RELEASE SMALL AMOUNTS OF FLAMMABLE HYDROGEN GAS.
PROLONGED SKIN CONTACT MAY CAUSE DERMATITIS (RASH), CHARACTERIZED BY RED,
DRY, ITCHING SKIN. MAY CAUSE RESPIRATORY TRACT IRRITATION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS # CONCENTRATION
PHOSPHORIC ACID 7664-38-2 70.0 - 80.0
| SECTION 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INGESTION:
DO NOT INDUCE VOMITING. HAVE VICTIM RINSE MOUTH WITH WATER, THEN GIVE ONE
TO TWO GLASSES OF WATER TO DRINK. SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE.
NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS UNCONSCIOUS.
INHALATION:
IMMEDIATELY REMOVE PERSON TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN BY QUALIFIED
MEDICAL PERSONNEL ONLY. SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE.
SKIN CONTACT:
TAKE OFF ALL CONTAMINATED CLOTHING IMMEDIATELY. IMMEDIATELY FLUSH SKIN WITH
GENTLY FLOWING, RUNNING WATER FOR AT LEAST 20 MINUTES. DO NOT RUB AREA OF
CONTACT. SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT LEAST 20 MINUTES.
SEEK IMMEDIATE MEDICAL ATTENTION/ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MAY CAUSE SERIOUS EYE IRRITATION OR DAMAGE. SYMPTOMS MAY INCLUDE REDNESS,
PAIN, TEARING AND CONJUNCTIVITIS. DIRECT SKIN CONTACT MAY CAUSE CORROSIVE
SKIN BURNS, DEEP ULCERATIONS AND POSSIBLY PERMANENT SCARRING. MAY CAUSE
SEVERE IRRITATION AND CORROSIVE DAMAGE IN THE MOUTH, THROAT AND STOMACH.
SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, VOMITING, BURNS, PERFORATIONS,
BLEEDING AND EVENTUALLY DEATH. MAY CAUSE SEVERE IRRITATION TO THE NOSE,
THROAT AND RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE COUGHING, CHOKING AND
WHEEZING.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CAUSES BURNS. TREAT
SYMPTOMATICALLY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT. WATER SPRAY MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE DIRECT STREAM OF WATER, WHICH CAN RESULT IN A DUST CLOUD AND
EXPLOSION HAZARD.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE / CONDITIONS OF
FLAMMABILITY:
NOT CONSIDERED FLAMMABLE. BURNING PRODUCES OBNOXIOUS AND TOXIC FUMES.
FLAMMABILITY CLASSIFICATION (OSHA 29 CFR 1910.106): NON-FLAMMABLE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT / STATIC DISCHARGE:
NOT EXPECTED TO BE SENSITIVE TO MECHANICAL IMPACT OR STATIC DISCHARGE.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE. PHOSPHORUS OXIDES
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
SPECIAL FIRE-FIGHTING PROCEDURES:
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN POSITIVE PRESSURE
MODE. A FULL-BODY CHEMICAL RESISTANT SUIT SHOULD BE WORN. MOVE CONTAINERS
FROM FIRE AREA IF SAFE TO DO SO. WATER SPRAY MAY BE USEFUL IN COOLING
EQUIPMENT EXPOSED TO HEAT AND FLAME. DIKE FOR WATER CONTROL. DO NOT ALLOW
RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ALL PERSONS DEALING WITH CLEAN-UP SHOULD WEAR THE APPROPRIATE PROTECTIVE
EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS. KEEP ALL OTHER
PERSONNEL UPWIND AND AWAY FROM THE SPILL/RELEASE. RESTRICT ACCESS TO AREA
UNTIL COMPLETION OF CLEAN-UP. REFER TO SECTION 8, EXPOSURE CONTROLS AND
PERSONAL PROTECTION, FOR ADDITIONAL INFORMATION ON ACCEPTABLE PERSONAL
PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
ENSURE SPILLED PRODUCT DOES NOT ENTER DRAINS, SEWERS, WATERWAYS, OR
CONFINED SPACES. FOR LARGE SPILLS, DIKE THE AREA TO PREVENT SPREADING.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA OF RELEASE. STOP SPILL OR
LEAK AT SOURCE IF SAFELY POSSIBLE. DIKE FOR WATER CONTROL. NEUTRALIZE WITH
SODIUM BICARBONATE OR A MIXTURE OF SODA ASH/SLAKED LIME. SOAK UP WITH INERT
ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER,
SAWDUST). REFER TO SECTION 13 FOR DISPOSAL OF CONTAMINATED MATERIAL.
SPECIAL SPILL RESPONSE PROCEDURES:
IF A SPILL/RELEASE IN EXCESS OF THE EPA REPORTABLE QUANTITY IS MADE INTO
THE ENVIRONMENT, IMMEDIATELY NOTIFY THE NATIONAL RESPONSE CENTER IN THE
UNITED STATES (PHONE: 1-800-424-8802).
US CERCLA REPORTABLE QUANTITY (RQ): PHOSPHORIC ACID (5000 LBS / 2270 KG)
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
USE IN A WELL-VENTILATED AREA. WEAR CHEMICALLY RESISTANT PROTECTIVE
EQUIPMENT DURING HANDLING. SEE SECTION 8 FOR ADDITIONAL PERSONAL PROTECTION
ADVICE WHEN HANDLING THIS PRODUCT. DO NOT INGEST. AVOID BREATHING VAPOUR OR
MIST. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. TRANSFER ONLY REQUIRED
AMOUNTS TO WORK AREA. WHEN MIXING WITH WATER, STIR SMALL AMOUNTS IN SLOWLY.
DURING PREPARATION OR DILUTION, ALWAYS ADD LIQUID SLOWLY TO WATER AND WITH
CONSTANT STIRRING. WHEN DILUTING, ALWAYS ADD THE PRODUCT TO WATER. NEVER
ADD WATER TO THE PRODUCT. KEEP AWAY FROM EXTREME HEAT AND FLAME. KEEP AWAY
FROM BASES, METALS AND OTHER INCOMPATIBLES. KEEP CONTAINER TIGHTLY CLOSED
WHEN NOT IN USE. WASH THOROUGHLY AFTER HANDLING.
CONDITIONS FOR SAFE STORAGE:
STORE IN A COOL, DRY, WELL-VENTILATED AREA. STORE AWAY FROM INCOMPATIBLES
AND OUT OF DIRECT SUNLIGHT. STORAGE AREA SHOULD BE CLEARLY IDENTIFIED,
CLEAR OF OBSTRUCTION AND ACCESSIBLE ONLY TO TRAINED AND AUTHORIZED
PERSONNEL. INSPECT PERIODICALLY FOR DAMAGE OR LEAKS. STORE IN
CORROSION-RESISTANT CONTAINERS. CORROSIVE TO METALS (TYPE 1100 AND 3003
ALUMINUM ALLOYS, TYPE 1020 CARBON STEEL, 400 SERIES STAINLESS STEELS,
UNALLOYED CAST IRONS AND COPPER ALLOYS). ATTACKS PORCELAIN, EARTHENWARE AND
GLASS ABOVE 200 DEG. C / 390 DEG. F. MAY ATTACK SOME PLASTICS (E.G. NYLON,
CHLORINATED POLYETHYLENE).
INCOMPATIBLE MATERIALS:
STRONG BASES; STRONG OXIDIZING AGENTS; STRONG REDUCING AGENTS; METALS.
| SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV OSHA PEL
TWA STEL PEL STEL
PHOSPHORIC ACID 1 MG/M3 3 MG/M3 1 MG/M3 N/AV
EXPOSURE CONTROLS:
VENTILATION AND ENGINEERING MEASURES:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MAINTAIN AIR CONCENTRATIONS
BELOW RECOMMENDED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
IF THE TLV IS EXCEEDED, A NIOSH/MSHA-APPROVED RESPIRATOR IS ADVISED.
CONFIRMATION OF WHICH TYPE OF RESPIRATOR IS MOST SUITABLE FOR THE INTENDED
APPLICATION SHOULD BE OBTAINED FROM RESPIRATORY PROTECTION SUPPLIERS.
RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION OF
CONTAMINANTS IN AIR, AND IN ACCORDANCE WITH OSHA (29 CFR 1910.134) OR
CSA Z94.4-02.
SKIN PROTECTION:
WEAR CHEMICALLY PROTECTIVE GLOVES (IMPERVIOUS), BOOTS, APRONS, AND
GAUNTLETS TO PREVENT PROLONGED OR REPEATED SKIN CONTACT. WEAR IMPERVIOUS
GLOVES, SUCH AS BUTYL RUBBER.
UNSUITABLE MATERIAL:
POLYVINYL ALCOHOL. ADVICE SHOULD BE SOUGHT FROM GLOVE SUPPLIERS.
EYE / FACE PROTECTION:
CHEMICAL SPLASH GOGGLES MUST BE WORN WHEN HANDLING THIS MATERIAL. A FULL
FACE SHIELD MAY ALSO BE NECESSARY.
OTHER PROTECTIVE EQUIPMENT:
OTHER EQUIPMENT MAY BE REQUIRED DEPENDING ON WORKPLACE STANDARDS. AN
EYEWASH STATION AND SAFETY SHOWER SHOULD BE MADE AVAILABLE IN THE IMMEDIATE
WORKING AREA.
GENERAL HYGIENE CONSIDERATIONS:
AVOID BREATHING VAPOUR OR MIST. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
DO NOT EAT, DRINK, SMOKE OR USE COSMETICS WHILE WORKING WITH THIS PRODUCT.
UPON COMPLETION OF WORK, WASH HANDS BEFORE EATING, DRINKING, SMOKING OR USE
OF TOILET FACILITIES. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE.
DO NOT TAKE CONTAMINATED CLOTHING HOME.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR LIQUID.
ODOUR: ODORLESS.
ODOUR THRESHOLD: N/AV
PH: 1 - 2
MELTING/FREEZING POINT: -17.5 DEG. C (0.5 DEG. F) (75%)
INITIAL BOILING POINT AND BOILING RANGE: 135 DEG. C (275 DEG. F) (75%)
FLASH POINT: N/AP
FLASHPOINT (METHOD): N/AP
EVAPORATION RATE (BUAE = 1): NEGLIGIBLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
LOWER FLAMMABLE LIMIT (% BY VOL.): N/AP
UPPER FLAMMABLE LIMIT (% BY VOL.): N/AP
OXIDIZING PROPERTIES: NONE KNOWN.
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
VAPOUR PRESSURE: 5.63 (75%)
VAPOUR DENSITY: N/AV
RELATIVE DENSITY / SPECIFIC GRAVITY: 1.573 (75%)
SOLUBILITY IN WATER: SOLUBLE
OTHER SOLUBILITY(IES): NONE KNOWN.
PARTITION COEFFICIENT N-OCTANOL/WATER OR COEFFICIENT OF WATER/OIL
DISTRIBUTION: N/AV
AUTO-IGNITION TEMPERATURE: N/AP
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: 18 CST @ 20 DEG. C (68 DEG. F) (75%)
VOLATILES (% BY WEIGHT): NOT AVAILABLE.
VOLATILE ORGANIC COMPOUNDS (VOC'S): 42 G/L (0.351 LBS/GAL)
ABSOLUTE PRESSURE OF CONTAINER: N/AP
FLAME PROJECTION LENGTH: N/AP
OTHER PHYSICAL/CHEMICAL COMMENTS:
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT NORMALLY REACTIVE. CONTACT WITH METALS MAY RELEASE SMALL AMOUNTS OF
FLAMMABLE HYDROGEN GAS. CORROSIVE IN CONTACT WITH METALS
CHEMICAL STABILITY:
STABLE UNDER THE RECOMMENDED STORAGE AND HANDLING CONDITIONS PRESCRIBED.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR. CONTACT WITH METALS MAY RELEASE
SMALL AMOUNTS OF FLAMMABLE HYDROGEN GAS.
CONDITIONS TO AVOID:
AVOID HEAT AND OPEN FLAME. ENSURE ADEQUATE VENTILATION, ESPECIALLY IN
CONFINED AREAS. AVOID CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG BASES; STRONG OXIDIZING AGENTS; STRONG REDUCING AGENTS; METALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NONE KNOWN, REFER TO HAZARDOUS COMBUSTION PRODUCTS IN SECTION 5.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY INHALATION: YES
ROUTES OF ENTRY SKIN & EYE: YES
ROUTES OF ENTRY INGESTION: YES
ROUTES OF EXPOSURE SKIN ABSORPTION: NO
POTENTIAL HEALTH EFFECTS:
SIGNS AND SYMPTOMS OF SHORT-TERM (ACUTE) EXPOSURE:
SIGN AND SYMPTOMS INHALATION:
INHALATION OF HIGH CONCENTRATIONS OF FUMES OR MISTS MAY CAUSE SEVERE
IRRITATION AND CORROSIVE DAMAGE TO THE NOSE, THROAT AND UPPER RESPIRATORY
TRACT. SYMPTOMS MAY INCLUDE COUGHING, CHOKING AND WHEEZING.
SIGN AND SYMPTOMS INGESTION:
MAY CAUSE SEVERE IRRITATION AND CORROSIVE DAMAGE IN THE MOUTH, THROAT AND
STOMACH. SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, VOMITING, BURNS,
PERFORATIONS, BLEEDING AND EVENTUALLY DEATH.
SIGN AND SYMPTOMS SKIN:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS (29CFR
1910.1200) (HAZCOM 2012).
CLASSIFICATION:
SKIN CORROSION/IRRITATION: CATEGORY 1
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. DIRECT SKIN CONTACT MAY CAUSE
CORROSIVE SKIN BURNS, DEEP ULCERATIONS AND POSSIBLY PERMANENT SCARRING.
SIGN AND SYMPTOMS EYES:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS (29CFR
1910.1200) (HAZCOM 2012).
CLASSIFICATION:
EYE DAMAGE/IRRITATION: CATEGORY 1
CAUSES SERIOUS EYE DAMAGE.
POTENTIAL CHRONIC HEALTH EFFECTS:
CHRONIC SKIN CONTACT WITH LOW CONCENTRATIONS MAY CAUSE DERMATITIS.
MUTAGENICITY: NOT EXPECTED TO BE MUTAGENIC IN HUMANS.
CARCINOGENICITY:
NO COMPONENTS ARE LISTED AS CARCINOGENS BY ACGIH, IARC, OSHA OR NTP.
REPRODUCTIVE EFFECTS & TERATOGENICITY:
NOT EXPECTED TO CAUSE REPRODUCTIVE EFFECTS.
SENSITIZATION TO MATERIAL:
NOT EXPECTED TO BE A SKIN OR RESPIRATORY SENSITIZER.
SPECIFIC TARGET ORGAN EFFECTS:
TARGET ORGANS: EYES, SKIN, RESPIRATORY SYSTEM AND DIGESTIVE SYSTEM.
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS SPECIFIC TARGET ORGAN
TOXICANT, SINGLE EXPOSURE.
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS SPECIFIC TARGET ORGAN
TOXICANT, REPEATED EXPOSURE.
IRRITANCY: CORROSIVE.
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE:
PRE-EXISTING SKIN, EYE AND RESPIRATORY DISORDERS.
SYNERGISTIC MATERIALS: NOT AVAILABLE.
TOXICOLOGICAL DATA:
CHEMICAL NAME LC50 (4HR) LD50
INH, RAT (ORAL, RAT) (RABBIT, DERMAL)
PHOSPHORIC ACID N/AV 4400 MG/KG (75%) >1260 MG/KG (85%)
OTHER IMPORTANT TOXICOLOGICAL HAZARDS:
NONE KNOWN OR REPORTED BY THE MANUFACTURER.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT SHOULD NOT BE ALLOWED TO ENTER DRAINS OR WATER COURSES, OR BE
DEPOSITED WHERE IT CAN AFFECT GROUND OR SURFACE WATERS. HARMFUL TO AQUATIC
LIFE.
ECOTOXICITY DATA:
INGREDIENTS CAS NO TOXICITY TO FISH
LC50 / 96H NOEC / 21 DAY M FACTOR
PHOSPHORIC ACID 7664-38-2 75.1 MG/L (JAPANESE N/AV NONE.
RICEFISH)
INGREDIENTS CAS NO TOXICITY TO DAPHNIA
EC50 48H NOEC / 21 DAY M FACTOR
PHOSPHORIC ACID 7664-38-2 376 MG/L (WATER N/AV NONE.
FLEA)
INGREDIENTS CAS NO TOXICITY TO ALGAE
EC50 96H OR 72H NOEC / 96H OR 72H M FACTOR
PHOSPHORIC ACID 7664-38-2 32 MG/L (GREEN N/AV NONE.
ALGAE)
PERSISTENCE AND DEGRADABILITY:
BIODEGRADATION IS NOT APPLICABLE TO INORGANIC MATERIALS.
BIOACCUMULATION POTENTIAL: NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
MOBILITY IN SOIL: NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
OTHER ADVERSE ENVIRONMENTAL EFFECTS: NO ADDITIONAL INFORMATION.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
HANDLING FOR DISPOSAL:
HANDLE WASTE ACCORDING TO RECOMMENDATIONS IN SECTION 7. EMPTY CONTAINERS
RETAIN RESIDUE (LIQUID AND/OR VAPOUR) AND CAN BE DANGEROUS.
METHODS OF DISPOSAL:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, PROVINCIAL AND
LOCAL REGULATIONS.
RCRA:
IF THIS PRODUCT, AS SUPPLIED, BECOMES A WASTE IN THE UNITED STATES, IT MAY
MEET THE CRITERIA OF A HAZARDOUS WASTE AS DEFINED UNDER RCRA, TITLE 40 CFR
261. IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR TO DETERMINE THE
PROPER WASTE IDENTIFICATION AND DISPOSAL METHOD. FOR DISPOSAL OF UNUSED OR
WASTE MATERIAL, CHECK WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL AGENCIES.
| SECTION 14. TRANSPORTATION INFORMATION | |
REGULATORY UN NUMBER UN PROPER TRANSPORT PACKING LABEL
INFORMATION SHIPPING NAME HAZARD GROUP
CLASS(ES)
49CFR/DOT UN1805 PHOSPHORIC 8 III CORROSIVE,
ACID SOLUTION CLASS/
DIVISION 8
49CFR/DOT MAY BE SHIPPED AS LIMITED QUANTITY WHEN TRANSPORTED IN
ADDITIONAL CONTAINERS NO LARGER THAN 5.0 LITRES; IN PACKAGES NOT
INFORMATION EXCEEDING 30 KG GROSS MASS. REFER TO 49 CFR SECTION 173.154.
US CERCLA REPORTABLE QUANTITY (RQ): (5000 LBS / 2270 KG)
TDG UN1805 PHOSPHORIC 8 III CLASS 8,
ACID, LIQUID CORROSIVES
TDG MAY BE SHIPPED AS LIMITED QUANTITY WHEN TRANSPORTED IN
ADDITIONAL CONTAINERS NO LARGER THAN 5.0 LITRES; IN PACKAGES NOT
INFORMATION EXCEEDING 30 KG GROSS MASS. UNDER THE TDGR, REFER TO SECTION
1.17 FOR ADDITIONAL EXEMPTION INFORMATION, IF SHIPPING
UNDER THIS EXEMPTION.
ICAO/IATA UN1805 PHOSPHORIC 8 III CLASS 8,
ACID, SOLUTION CORROSIVES
ICAO/IATA REFER TO THE APPROPRIATE PACKING INSTRUCTION, PRIOR TO
ADDITIONAL SHIPPING THIS MATERIAL. REVIEW ALL STATE AND OPERATOR
INFORMATION VARIATIONS, PRIOR TO SHIPPING THIS MATERIAL.
SPECIAL PRECAUTIONS FOR USER: NONE KNOWN.
ENVIRONMENTAL HAZARDS: SEE ECOLOGICAL INFORMATION, SECTION 12.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
| SECTION 15. REGULATORY INFORMATION | |
US FEDERAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING U.S. FEDERAL CHEMICAL
LISTS:
INGREDIENTS CAS # TSCA INVENTORY CERCLA REPORTABLE
QUANTITY (RQ)
(40 CFR 117.302)
PHOSPHORIC ACID 7664-38-2 YES 5000 LB/2270 KG
INGREDIENTS SARA TITLE III: SARA TITLE III:
SEC. 302, SEC. 313, 40 CFR 372,
EXTREMELY SPECIFIC TOXIC CHEMICAL
HAZARDOUS TOXIC CHEMICAL DE MINIMUS
SUBSTANCE, CONCENTRATION
40 CFR 355
PHOSPHORIC ACID N/AV NO N/AP
SARA TITLE III:
SEC. 311 AND 312, MSDS REQUIREMENTS, 40 CFR 370 HAZARD CLASSES:
ACUTE HEALTH HAZARD. UNDER SARA SECTIONS 311 AND 312, THE EPA HAS
ESTABLISHED THRESHOLD QUANTITIES FOR THE REPORTING OF HAZARDOUS CHEMICALS.
THE CURRENT THRESHOLDS ARE 500 POUNDS FOR THE THRESHOLD PLANNING QUANTITY
(TPQ), WHICHEVER IS LOWER, FOR EXTREMELY HAZARDOUS SUBSTANCES AND 10,000
POUNDS FOR ALL OTHER HAZARDOUS CHEMICALS.
US STATE RIGHT TO KNOW LAWS:
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES:
INGREDIENTS CAS # CALIFORNIA STATE "RIGHT TO KNOW" LISTS
PROPOSITION 65 CA MA MN NJ PA RI
LISTED TYPE OF
TOXICITY
PHOSPHORIC 7664-38-2 NO N/AP YES YES YES YES YES YES
ACID
CANADIAN INFORMATION:
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) INFORMATION:
ALL INGREDIENTS LISTED APPEAR ON THE DOMESTIC SUBSTANCES LIST (DSL).
WHMIS INFORMATION:
REFER TO SECTION 2 FOR A WHMIS CLASSIFICATION FOR THIS PRODUCT.
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
INTERNATIONAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING INTERNATIONAL
INVENTORY LIST:
INGREDIENTS CAS # EUROPEAN AUSTRALIA PHILIPPINES
EINECS AICS PICCS
PHOSPHORIC ACID 7664-38-2 231-633-2 PRESENT PRESENT
INGREDIENTS JAPAN ENCS KOREA CHINA NEWZEALAND
KECI/KECL IECSC IOC
PHOSPHORIC ACID (1)-422 KE-27427 PRESENT HSR001545,
HSR001571
(DILUTION)
| SECTION 16. OTHER INFORMATION | |
LEGEND:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CA: CALIFORNIA
CAS: CHEMICAL ABSTRACT SERVICES
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF
1980
CFR: CODE OF FEDERAL REGULATIONS
DOT: DEPARTMENT OF TRANSPORTATION
EPA: ENVIRONMENTAL PROTECTION AGENCY
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
HSDB: HAZARDOUS SUBSTANCES DATA BANK
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
INH: INHALATION
IUCLID: INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE
MA: MASSACHUSETTS
MN: MINNESOTA
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N/AP: NOT APPLICABLE
N/AV: NOT AVAILABLE
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
NJ: NEW JERSEY
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PA: PENNSYLVANIA
PEL: PERMISSIBLE EXPOSURE LIMIT
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
RI: RHODE ISLAND
RTECS: REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
STEL: SHORT TERM EXPOSURE LIMIT
TDG: CANADIAN TRANSPORTATION OF DANGEROUS GOODS ACT & REGULATIONS
TLV: THRESHOLD LIMIT VALUES
TWA: TIME WEIGHTED AVERAGE
WHMIS: WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
REFERENCES:
CANADIAN CENTRE FOR OCCUPATIONAL HEALTH AND SAFETY, CCINFOWEB DATABASES,
2015 (CHEMPENDIUM, RTECS, HSDB, INCHEM).
EUROPEAN CHEMICALS AGENCY, CLASSIFICATION LEGISLATION, 2015
MATERIAL SAFETY DATA SHEET FROM MANUFACTURER
OECD:
THE GLOBAL PORTAL TO INFORMATION ON CHEMICAL SUBSTANCES - ECHEMPORTAL, 2015
PREPARATION DATE (MM/DD/YYYY): 05/29/2012
REVIEWED DATE SDS (DD/MM/YYYY): 10/04/2015
REVISION NO.: 2
REVISION INFORMATION: ALL (FORMAT CHANGE)
OTHER SPECIAL CONSIDERATIONS FOR HANDLING:
PROVIDE ADEQUATE INFORMATION, INSTRUCTION AND TRAINING FOR OPERATORS.
HMIS RATING:
HEALTH 3
FLAMMABILITY 0
REACTIVITY 0
* - CHRONIC HAZARD
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
NFPA RATING:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS NONE
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
PREPARED FOR:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO, 63090
U.S.A.
TELEPHONE: (636) 239-1111
WWW.PARKER.COM
DIRECT ALL ENQUIRIES TO: PARKER HANNIFIN CORP. - SPORLAN DIVISION.
PARKER
PREPARED BY:
ICC THE COMPLIANCE CENTER INC.
TELEPHONE:
(888) 442-9628 (U.S.)
(888) 977-4834 (CANADA)
HTTP://WWW.THECOMPLIANCECENTER.COM
ICC COMPLIANCE CENTER
DISCLAIMER:
THIS MATERIAL SAFETY DATA SHEET WAS PREPARED BY ICC THE COMPLIANCE CENTER
INC. USING INFORMATION PROVIDED BY / OBTAINED FROM PARKER HANNIFIN CORP AND
CCOHS' WEB INFORMATION SERVICE. THE INFORMATION IN THE MATERIAL SAFETY DATA
SHEET IS OFFERED FOR YOUR CONSIDERATION AND GUIDANCE WHEN EXPOSED TO THIS
PRODUCT. ICC THE COMPLIANCE CENTER INC AND PARKER HANNIFIN CORP EXPRESSLY
DISCLAIM ALL EXPRESSED OR IMPLIED WARRANTIES AND ASSUME NO RESPONSIBILITIES
FOR THE ACCURACY OR COMPLETENESS OF THE DATA CONTAINED HEREIN. THE DATA IN
THIS MSDS DOES NOT APPLY TO USE WITH ANY OTHER PRODUCT OR IN ANY OTHER
PROCESS.
THIS MATERIAL SAFETY DATA SHEET MAY NOT BE CHANGED, OR ALTERED IN ANY WAY
WITHOUT THE EXPRESSED KNOWLEDGE AND PERMISSION OF ICC THE COMPLIANCE CENTER
INC. AND PARKER HANNIFIN CORP.