| Common Name: | THERMAL BLOCK |
| Manufacturer: | PARKER HANNIFIN |
| SDS Revision Date: | 1/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4E846 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PARKER
PARKER HANNIFIN CORPORATION
SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO 63090
USA
THERMAL BLOCK
TB2 (P/N 475322)
SDS REVISION DATE (MM/DD/YYYY): 01/28/2015
SAFETY DATA SHEET
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER USED ON THE LABEL: THERMAL BLOCK
PRODUCT CODE(S): TB2 (P/N 475322)
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
PROFESSIONAL USE ONLY; ABSORBS HEAT GENERATED BY WELDING, BRAZING OR
SOLDERING.
CHEMICAL FAMILY: MIXTURE.
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE SUPPLIER:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO, 63090
U.S.A.
SUPPLIER'S TELEPHONE #: (636) 239-1111
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE MANUFACTURER: REFER TO SUPPLIER
24 HR. EMERGENCY TEL #:
CHEMTREC: 1-800-424-9300 (WITHIN CONTINENTAL U.S.)
CHEMTREC: 703-527-3887 (OUTSIDE U.S.).
| SECTION 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL:
WHMIS INFORMATION:
THIS PRODUCT IS A WHMIS CONTROLLED PRODUCT. IT MEETS ONE OR MORE OF THE
CRITERIA FOR A CONTROLLED PRODUCT PROVIDED IN PART IV OF THE CANADIAN
CONTROLLED PRODUCTS REGULATIONS (CPR).
WHMIS CLASSIFICATION: CLASS E (CORROSIVE MATERIAL)
OSHA:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
HAZARDOUS CLASSIFICATION:
SKIN IRRITANT: CATEGORY 2
SERIOUS EYE DAMAGE: CATEGORY 1
LABEL ELEMENTS:
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO THE UNITED STATES
ACCORDING TO OSHA REGULATIONS (29 CFR 1910.1200) (HAZCOM 2012):
SIGNAL WORD:
DANGER!
HAZARD STATEMENT(S):
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE DAMAGE.
PRECAUTIONARY STATEMENT(S):
WASH HANDS AND FACE THOROUGHLY AFTER HANDLING.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
SPECIFIC TREATMENT (SEE THIS LABEL).
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS, GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
HAZARD PICTOGRAMS: CORROSION
THE FOLLOWING LABEL INFORMATION IS APPLICABLE ONLY TO CANADA ACCORDING TO
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR/WHMIS):
DANGER!
SEVERELY IRRITATING OR CORROSIVE. CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE
SKIN IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. MAY CAUSE
RESPIRATORY IRRITATION.
PRECAUTIONS:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR SUITABLE PROTECTIVE
EQUIPMENT DURING HANDLING. AVOID BREATHING VAPOUR OR MIST. AVOID CONTACT
WITH EYES, SKIN AND CLOTHING. KEEP AWAY FROM INCOMPATIBLES. KEEP AWAY FROM
HEAT, SPARKS AND OPEN FLAME. - NO SMOKING. STORE IN A COOL, DRY, WELL
VENTILATED AREA.
FIRST AID:
FOR SKIN CONTACT, IMMEDIATELY REMOVE ALL CONTAMINATED CLOTHING. FLUSH SKIN
THOROUGHLY WITH RUNNING WATER FOR AT LEAST 15 TO 20 MINUTES. IF SKIN
IRRITATION OCCURS, SEEK MEDICAL ADVICE/ATTENTION. IF IN CONTACT WITH EYES,
IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT LEAST 20 MINUTES.
IMMEDIATELY CALL A POISON CENTRE OR DOCTOR/PHYSICIAN. IF INHALED, MOVE TO
FRESH AIR. IF INGESTED, DO NOT INDUCE VOMITING. WHEN SYMPTOMS PERSIST OR
IN ALL CASES OF DOUBT SEEK MEDICAL ADVICE.
REFER TO MATERIAL SAFETY DATA SHEET FOR FURTHER INFORMATION.
WHMIS SYMBOLS REQUIRED ON A SUPPLIER LABEL: E - CORROSIVE MATERIAL
OTHER HAZARDS:
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
BURNING PRODUCES OBNOXIOUS AND TOXIC FUMES. INGESTION MAY CAUSE IRRITATION
OF THE MOUTH, THROAT AND STOMACH. MAY CAUSE IRRITATION TO THE NOSE, THROAT
AND UPPER RESPIRATORY TRACT. WHEN HEATED ABOVE 150 DEG. C IN AIR, MAY
RELEASE FORMALDEHYDE GAS. PRODUCT EVOLVES ACETIC ACID WHEN EXPOSED TO WATER
OR HUMID AIR.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. SEE ECOLOGICAL INFORMATION, SECTION 12.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS # CONCENTRATION
METHYLTRIACETOXYSILANE 4253-34-3 1.0 - 5.0
ETHYLTRIACETOXYSILANE 17689-77-9 1.0 - 5.0
POSSIBLE DECOMPOSITION PRODUCTS IN CASE OF HYDROLYSIS ARE:
ACETIC ACID 64-19-7 NOT KNOWN.
THE FOLLOWING INGREDIENT IS RELEASED FROM THE PRODUCT ONLY WHEN HEATED
ABOVE 150 DEG. C:
FORMALDEHYDE 50-00-0 NOT KNOWN.
NOTE:
ACETIC ACID AND FORMALDEHYDE ARE NOT INTENTIONALLY ADDED TO THIS PRODUCT.
THE EXACT CONCENTRATIONS OF THE ABOVE LISTED CHEMICALS ARE BEING WITHHELD
AS A TRADE SECRET.
| SECTION 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INGESTION:
IF INGESTED, DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
INHALATION:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF BREATHING IS IRREGULAR OR
STOPPED, ADMINISTER ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN BY QUALIFIED MEDICAL PERSONNEL ONLY. CONSULT A PHYSICIAN.
SKIN CONTACT:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. IF SKIN IRRITATION OCCURS, GET MEDICAL
ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. DURATION OF RINSING SHOULD BE AT
LEAST 20 MINUTES. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE SKIN IRRITATION. INGESTION MAY
CAUSE IRRITATION OF THE MOUTH, THROAT AND STOMACH. MAY CAUSE IRRITATION TO
THE NOSE, THROAT AND UPPER RESPIRATORY TRACT.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREAT SYMPTOMATICALLY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER FOG OR FINE SPRAY, FOAMS, CARBON DIOXIDE OR DRY CHEMICAL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET, AS THIS MAY SPREAD BURNING MATERIAL.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE / CONDITIONS OF
FLAMMABILITY:
NOT FLAMMABLE UNDER NORMAL CONDITIONS OF USE. WHEN HEATED ABOVE
150 DEG. C IN AIR, MAY RELEASE FORMALDEHYDE GAS. CLOSED CONTAINERS MAY
RUPTURE IF EXPOSED TO EXCESS HEAT OR FLAME DUE TO A BUILD-UP OF INTERNAL
PRESSURE. PRODUCT EVOLVES ACETIC ACID WHEN EXPOSED TO WATER OR HUMID AIR.
FLAMMABILITY CLASSIFICATION (OSHA 29 CFR 1910.106): NON-FLAMMABLE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT / STATIC DISCHARGE:
NOT EXPECTED TO BE SENSITIVE TO MECHANICAL IMPACT OR STATIC DISCHARGE.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON OXIDES; FORMALDEHYDE; SILICON OXIDES; SILICA; FORMIC ACID; ACETIC
ACID; OTHER UNIDENTIFIED ORGANIC COMPOUNDS.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN POSITIVE PRESSURE
MODE.
SPECIAL FIRE-FIGHTING PROCEDURES:
MOVE CONTAINERS FROM FIRE AREA IF SAFE TO DO SO. WATER SPRAY MAY BE USEFUL
IN COOLING EQUIPMENT EXPOSED TO HEAT AND FLAME. AVOID SPREADING BURNING
LIQUID WITH WATER SPRAY USED FOR COOLING PURPOSES.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
RESTRICT ACCESS TO AREA UNTIL COMPLETION OF CLEAN-UP. ENSURE CLEAN-UP IS
CONDUCTED BY TRAINED PERSONNEL ONLY. ALL PERSONS DEALING WITH THE CLEAN-UP
SHOULD WEAR THE APPROPRIATE CHEMICALLY PROTECTIVE EQUIPMENT. REFER TO
PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
ENSURE SPILLED PRODUCT DOES NOT ENTER DRAINS, SEWERS, WATERWAYS, OR
CONFINED SPACES. IF NECESSARY, DIKE WELL AHEAD OF THE SPILL TO PREVENT
RUNOFF INTO DRAINS, SEWERS, OR ANY NATURAL WATERWAY OR DRINKING SUPPLY.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA OF RELEASE. STOP THE SPILL
AT SOURCE IF IT IS SAFE TO DO SO. COVER ANY SPILLED MATERIAL WITH
NON-COMBUSTIBLE ABSORBENT MATERIAL, SUCH AS VERMICULITE OR SAND, THEN
PLACE ABSORBENT MATERIAL INTO A CONTAINER FOR LATER DISPOSAL (SEE
SECTION 13). NOTIFY THE APPROPRIATE AUTHORITIES AS REQUIRED.
SPECIAL SPILL RESPONSE PROCEDURES:
IF A SPILL/RELEASE IN EXCESS OF THE EPA REPORTABLE QUANTITY IS MADE INTO
THE ENVIRONMENT, IMMEDIATELY NOTIFY THE NATIONAL RESPONSE CENTER IN THE
UNITED STATES (PHONE: 1-800-424-8802).
US CERCLA REPORTABLE QUANTITY (RQ): NONE REPORTED.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
USE ONLY IN WELL-VENTILATED AREAS. WEAR PROTECTIVE EQUIPMENT DURING
HANDLING. IMPERVIOUS GLOVES MUST BE WORN WHEN USING THIS PRODUCT. AVOID
BREATHING VAPORS, FUMES OR DUST. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP AWAY FROM HEAT AND SOURCES OF IGNITION. PROTECT FROM
MOISTURE. KEEP CONTAINER TIGHTLY CLOSED. EMPTY CONTAINERS RETAIN RESIDUE
(LIQUID AND/OR VAPOUR) AND CAN BE DANGEROUS. WASH THOROUGHLY AFTER
HANDLING.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE. KEEP
AWAY FROM INCOMPATIBLES. INSPECT PERIODICALLY FOR DAMAGE OR LEAKS. STORE
OUT OF DIRECT SUNLIGHT. KEEP CONTAINERS DRY AND TIGHTLY CLOSED TO AVOID
MOISTURE ABSORPTION AND CONTAMINATION.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS; STRONG ACIDS; BASES; WATER.
| SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV OSHA PEL
TWA STEL PEL STEL
METHYLTRIACETOXYSILANE N/AV N/AV N/AV N/AV
ETHYLTRIACETOXYSILANE N/AV N/AV N/AV N/AV
ACETIC ACID 10 PPM 15 PPM 10 PPM
25 MG/M3 N/AV
FORMALDEHYDE 0.3 PPM N/AV 0.75 PPM 2 PPM
(CEILING)
ACETIC ACID AND FORMALDEHYDE ARE NOT INTENTIONALLY ADDED TO THIS PRODUCT.
THE ABOVE EXPOSURE LIMITS ARE PROVIDED FOR SAFETY REASONS.
EXPOSURE CONTROLS:
VENTILATION AND ENGINEERING MEASURES:
USE ONLY IN WELL-VENTILATED AREAS. PROVIDE SUFFICIENT VENTILATION TO KEEP
VAPOUR CONCENTRATION BELOW THE GIVEN TLV AND/OR PEL.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS REQUIRED IF THE CONCENTRATIONS EXCEED THE TLV.
USE NIOSH/MSHA APPROVED EQUIPMENT. ADVICE SHOULD BE SOUGHT FROM RESPIRATORY
PROTECTION SPECIALISTS.
SKIN PROTECTION:
IMPERVIOUS GLOVES MUST BE WORN WHEN USING THIS PRODUCT. ADVICE SHOULD BE
SOUGHT FROM GLOVE SUPPLIERS.
EYE / FACE PROTECTION:
CHEMICAL SPLASH GOGGLES MUST BE WORN WHEN HANDLING THIS MATERIAL.
OTHER PROTECTIVE EQUIPMENT:
WHERE EXTENSIVE EXPOSURE TO PRODUCT IS POSSIBLE, USE RESISTANT COVERALLS,
APRON AND BOOTS TO PREVENT CONTACT. ENSURE THAT EYEWASH STATIONS AND SAFETY
SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
GENERAL HYGIENE CONSIDERATIONS:
AVOID BREATHING VAPORS OR MISTS. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. UPON
COMPLETION OF WORK, WASH HANDS BEFORE EATING, DRINKING, SMOKING OR USE OF
TOILET FACILITIES. REMOVE SOILED CLOTHING AND WASH IT THOROUGHLY BEFORE
REUSE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: TRANSLUCENT GEL.
ODOUR: MILD ODOR.
ODOUR THRESHOLD: N/AV
PH: N/AV
MELTING/FREEZING POINT: N/AV
INITIAL BOILING POINT AND BOILING RANGE: N/AV
FLASH POINT: >100 DEG. C (>212 DEG. F)
FLASHPOINT (METHOD): SETA CLOSED CUP
EVAPORATION RATE (BUAE = 1): <1
FLAMMABILITY (SOLID, GAS): N/AP
LOWER FLAMMABLE LIMIT (% BY VOL.): N/AV
UPPER FLAMMABLE LIMIT (% BY VOL.): N/AV
OXIDIZING PROPERTIES: NONE KNOWN.
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
VAPOUR PRESSURE: N/AV
VAPOUR DENSITY: N/AV
RELATIVE DENSITY / SPECIFIC GRAVITY: 1.0
SOLUBILITY IN WATER: MAY REACT WITH WATER.
OTHER SOLUBILITY(IES): N/AV
PARTITION COEFFICIENT N-OCTANOL/WATER OR COEFFICIENT OF WATER/OIL
DISTRIBUTION: N/AV
AUTO-IGNITION TEMPERATURE: N/AV
DECOMPOSITION TEMPERATURE: N/AV
VISCOSITY: APPROXIMATELY 10000 CPS
VOLATILES (% BY WEIGHT): N/AV
VOLATILE ORGANIC COMPOUNDS (VOC'S): N/AV
ABSOLUTE PRESSURE OF CONTAINER: N/AP
FLAME PROJECTION LENGTH: N/AP
OTHER PHYSICAL/CHEMICAL COMMENTS: NO ADDITIONAL INFORMATION.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: PRODUCT EVOLVES ACETIC ACID WHEN EXPOSED TO WATER OR HUMID AIR.
CHEMICAL STABILITY:
STABLE UNDER THE RECOMMENDED STORAGE AND HANDLING CONDITIONS PRESCRIBED.
WHEN HEATED ABOVE 150 DEG. C IN AIR, MAY RELEASE FORMALDEHYDE GAS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: DIRECT SOURCES OF HEAT. AVOID MOISTURE.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS; STRONG ACIDS; BASES; WATER.
HAZARDOUS DECOMPOSITION PRODUCTS:
FORMALDEHYDE GAS. REFER ALSO TO HAZARDOUS COMBUSTION PRODUCTS, SECTION 5.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY INHALATION: YES
ROUTES OF ENTRY SKIN & EYE: YES
ROUTES OF ENTRY INGESTION: YES
ROUTES OF EXPOSURE SKIN ABSORPTION: NO
POTENTIAL HEALTH EFFECTS:
SIGNS AND SYMPTOMS OF SHORT-TERM (ACUTE) EXPOSURE:
SIGN AND SYMPTOMS INHALATION:
MAY CAUSE IRRITATION OF THE NOSE, THROAT, MUCOUS MEMBRANES, AND RESPIRATORY
TRACT. AVOID HEATING, WHICH WILL RESULT IN THE LIBERATION OF FORMALDEHYDE
GAS. FORMALDEHYDE CAUSES SEVERE RESPIRATORY IRRITATION, LUNG INFLAMMATION
AND PULMONARY EDEMA. SYMPTOMS OF PULMONARY EDEMA (CHEST PAIN, SHORTNESS OF
BREATH) MAY BE DELAYED.
SIGN AND SYMPTOMS INGESTION:
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND
DIARRHEA.
SIGN AND SYMPTOMS SKIN:
CAUSES SEVERE SKIN IRRITATION. AVOID CONTACT WITH WATER, WHICH WILL RESULT
IN THE LIBERATION OF ACETIC ACID. ACETIC ACID CAN BE SEVERELY IRRITATING OR
CORROSIVE.
SIGN AND SYMPTOMS EYES:
CAUSES SERIOUS EYE DAMAGE. AVOID HEATING, WHICH WILL RESULT IN THE
LIBERATION OF FORMALDEHYDE GAS. FORMALDEHYDE GAS CAUSES MODERATE TO SEVERE
EYE IRRITATION. AVOID CONTACT WITH WATER, WHICH WILL RESULT IN THE
LIBERATION OF ACETIC ACID. ACETIC ACID CAN BE SEVERELY IRRITATING OR
CORROSIVE.
POTENTIAL CHRONIC HEALTH EFFECTS: NONE EXPECTED, WHEN USED AS INTENDED.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC. THIS PRODUCT DOES NOT MEET THE
CRITERIA FOR GERM CELL MUTAGENS UNDER OSHA REGULATIONS (29 CFR 1910.1200)
(HAZCOM 2012). AVOID HEATING, WHICH WILL RESULT IN THE LIBERATION OF
FORMALDEHYDE GAS. FORMALDEHYDE MAY CAUSE MUTATIONS TO NON-REPRODUCTIVE
(SOMATIC) CELLS, BASED ON ANIMAL DATA.
CARCINOGENICITY:
NO COMPONENTS ARE LISTED AS CARCINOGENS BY ACGIH, IARC, OSHA OR NTP. THIS
PRODUCT DOES NOT MEET THE CRITERIA FOR CARCINOGENS UNDER OSHA REGULATIONS
(29 CFR 1910.1200) (HAZCOM 2012).
AVOID HEATING, WHICH WILL RESULT IN THE LIBERATION OF FORMALDEHYDE GAS.
FORMALDEHYDE IS CLASSIFIED AS CARCINOGENIC BY IARC (GROUP 1), ACGIH
(GROUP A2) AND NTP (GROUP 2).
REPRODUCTIVE EFFECTS & TERATOGENICITY:
THIS MATERIAL IS NOT CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS (29CFR
1910.1200) (HAZCOM 2012).
SENSITIZATION TO MATERIAL:
NOT EXPECTED TO BE A SKIN OR RESPIRATORY SENSITIZER. THIS MATERIAL IS NOT
CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS (29CFR 1910.1200)
(HAZCOM 2012).
AVOID HEATING, WHICH WILL RESULT IN THE LIBERATION OF FORMALDEHYDE GAS.
FORMALDEHYDE MAY CAUSE SENSITISATION BY SKIN CONTACT.
SPECIFIC TARGET ORGAN EFFECTS:
THIS MATERIAL IS NOT CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS (29CFR
1910.1200) (HAZCOM 2012).
IRRITANCY: CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE SKIN IRRITATION.
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE:
PRE-EXISTING SKIN, EYE AND RESPIRATORY DISORDERS.
SYNERGISTIC MATERIALS: NO INFORMATION AVAILABLE.
TOXICOLOGICAL DATA:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF.
THE CALCULATED ATE VALUES FOR THIS MIXTURE ARE:
ATE ORAL: 18386 MG/KG
SEE BELOW FOR INDIVIDUAL INGREDIENT ACUTE TOXICITY DATA.
CHEMICAL NAME LC50 (4HR) LD50
INH, RAT (ORAL, RAT) (RABBIT, DERMAL)
METHYLTRIACETOXYSILANE N/AV 1062 MG/KG N/AV
ETHYLTRIACETOXYSILANE N/AV 1462 MG/KG N/AV
POSSIBLE DECOMPOSITION PRODUCTS IN CASE OF HYDROLYSIS ARE:
ACETIC ACID 11400 MG/M3 3310 MG/KG 1060 MG/KG
(11.4 MG/L)
2810 PPM
(6.95 MG/L)
(MOUSE)
THE FOLLOWING INGREDIENT IS RELEASED FROM THE PRODUCT ONLY WHEN HEATED
ABOVE 150 DEG. C:
FORMALDEHYDE 287 PPM 800 MG/KG 300 MG/KG
OTHER IMPORTANT TOXICOLOGICAL HAZARDS:
AVOID CONTACT WITH WATER, WHICH WILL RESULT IN THE LIBERATION OF ACETIC
ACID. ACETIC ACID CAN BE SEVERELY IRRITATING OR CORROSIVE.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
NO DATA IS AVAILABLE ON THE PRODUCT ITSELF. THE PRODUCT SHOULD NOT BE
ALLOWED TO ENTER DRAINS OR WATER COURSES, OR BE DEPOSITED WHERE IT CAN
AFFECT GROUND OR SURFACE WATERS. SEE THE FOLLOWING TABLES FOR INDIVIDUAL
INGREDIENT ECOTOXICITY DATA.
ECOTOXICITY DATA:
INGREDIENTS CAS NO TOXICITY TO FISH
LC50 / 96H NOEC / M FACTOR
21 DAY
METHYLTRIACETOXYSILANE 4253-34-3 N/AV N/AV N/AV
ETHYLTRIACETOXYSILANE 17689-77-9 251 MG/L N/AV NONE.
(ZEBRA FISH)
ACETIC ACID 64-19-7 N/AV N/AV N/AV
FORMALDEHYDE 50-00-0 6.7 MG/L N/AV NONE.
(STRIPED BASS)
INGREDIENTS CAS NO TOXICITY TO DAPHNIA
EC50 48H NOEC / 21 DAY M FACTOR
METHYLTRIACETOXYSILANE 4253-34-3 N/AV N/AV N/AV
ETHYLTRIACETOXYSILANE 17689-77-9 62 MG/L N/AV NONE.
(WATER FLEA)
ACETIC ACID 64-19-7 65 MG/L 37.9 MG/L N/AP
(WATER FLEA) (WATER FLEA)
FORMALDEHYDE 50-00-0 5.8 MG/L N/AV NONE.
INGREDIENTS CAS NO TOXICITY TO ALGAE
EC50 96H NOEC / 96H M FACTOR
OR 72H OR 72H
METHYLTRIACETOXYSILANE 4253-34-3 N/AV N/AV N/AV
ETHYLTRIACETOXYSILANE 17689-77-9 N/AV N/AV N/AV
ACETIC ACID 64-19-7 N/AV N/AV N/AV
FORMALDEHYDE 50-00-0 14.7 MG/L/24HR N/AV NONE.
PERSISTENCE AND DEGRADABILITY: THE PRODUCT ITSELF HAS NOT BEEN TESTED.
BIOACCUMULATION POTENTIAL: THE PRODUCT ITSELF HAS NOT BEEN TESTED.
MOBILITY IN SOIL: THE PRODUCT ITSELF HAS NOT BEEN TESTED.
OTHER ADVERSE ENVIRONMENTAL EFFECTS: NONE KNOWN.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
HANDLING FOR DISPOSAL:
HANDLE WASTE ACCORDING TO RECOMMENDATIONS IN SECTION 7. EMPTY CONTAINERS
RETAIN RESIDUE (LIQUID AND/OR VAPOUR) AND CAN BE DANGEROUS.
METHODS OF DISPOSAL:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, PROVINCIAL AND
LOCAL REGULATIONS.
RCRA:
IF THIS PRODUCT, AS SUPPLIED, BECOMES A WASTE IN THE UNITED STATES, IT MAY
MEET THE CRITERIA OF A HAZARDOUS WASTE AS DEFINED UNDER RCRA, TITLE 40 CFR
261. IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR TO DETERMINE THE
PROPER WASTE IDENTIFICATION AND DISPOSAL METHOD. FOR DISPOSAL OF UNUSED OR
WASTE MATERIAL, CHECK WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL AGENCIES.
| SECTION 14. TRANSPORTATION INFORMATION | |
REGULATORY UN NUMBER UN PROPER TRANSPORT PACKING LABEL
INFORMATION SHIPPING NAME HAZARD GROUP
CLASS(ES)
49CFR/DOT NONE NOT REGULATED. NOT NONE NO PLACARD
REGULATED REQUIRED
49CFR/DOT NONE.
ADDITIONAL
INFORMATION
TDG NONE NOT REGULATED. NOT NONE NO PLACARD
REGULATED REQUIRED
TDG NONE.
ADDITIONAL
INFORMATION
ICAO/IATA NONE NOT REGULATED. NOT NONE NO PLACARD
REGULATED REQUIRED
ICAO/IATA NONE.
ADDITIONAL
INFORMATION
SPECIAL PRECAUTIONS FOR USER:
APPROPRIATE ADVICE ON SAFETY MUST ACCOMPANY THE PACKAGE.
ENVIRONMENTAL HAZARDS:
THIS PRODUCT DOES NOT MEET THE CRITERIA FOR AN ENVIRONMENTALLY HAZARDOUS
MIXTURE, ACCORDING TO THE IMDG CODE. SEE ECOLOGICAL INFORMATION,
SECTION 12.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
THIS INFORMATION IS NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
US FEDERAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING U.S. FEDERAL CHEMICAL
LISTS:
INGREDIENTS CAS # TSCA CERCLA REPORTABLE
INVENTORY QUANTITY (RQ)
(40 CFR 117.302)
METHYLTRIACETOXYSILANE 4253-34-3 YES N/AP
ETHYLTRIACETOXYSILANE 17689-77-9 YES N/AP
ACETIC ACID 64-19-7 YES 5000 LB / 2270 KG
FORMALDEHYDE 50-00-0 YES 100 LBS / 45.4 KG
INGREDIENTS SARA TITLE III: SARA TITLE III:
SEC. 302, EXTREMELY SEC. 313, 40 CFR 372,
HAZARDOUS SUBSTANCE, SPECIFIC TOXIC CHEMICAL
40 CFR 355 TOXIC CHEMICAL DE MINIMUS
CONCENTRATION
METHYLTRIACETOXYSILANE N/AP NO N/AP
ETHYLTRIACETOXYSILANE N/AP NO N/AP
ACETIC ACID N/AP NO N/AP
FORMALDEHYDE 500 LB TPQ YES 1%
SARA TITLE III:
SEC. 311 AND 312, MSDS REQUIREMENTS, 40 CFR 370 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD. UNDER SARA SECTIONS 311 AND 312, THE EPA
HAS ESTABLISHED THRESHOLD QUANTITIES FOR THE REPORTING OF HAZARDOUS
CHEMICALS. THE CURRENT THRESHOLDS ARE 500 POUNDS FOR THE THRESHOLD PLANNING
QUANTITY (TPQ), WHICHEVER IS LOWER, FOR EXTREMELY HAZARDOUS SUBSTANCES AND
10,000 POUNDS FOR ALL OTHER HAZARDOUS CHEMICALS.
SARA TITLE III:
SEC. 313, TOXIC CHEMICALS NOTIFICATION, 40 CFR 372:
US STATE RIGHT TO KNOW LAWS:
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES:
INGREDIENTS CAS # CALIFORNIA STATE "RIGHT TO KNOW" LISTS
PROPOSITION 65
LISTED TYPE OF CA MA MN NJ PA RI
TOXICITY
METHYLTRI- 4253-34-3 NO N/AP NO NO NO NO NO NO
ACETOXYSILANE
ETHYLTRIACE- 17689-77-9 NO N/AP NO NO NO NO NO NO
TOXYSILANE
ACETIC ACID 64-19-7 NO N/AP YES YES YES YES YES YES
FORMALDEHYDE 50-00-0 YES CARCINOGEN YES YES YES YES YES YES
(GAS)
CANADIAN INFORMATION:
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) INFORMATION:
ALL INGREDIENTS LISTED APPEAR ON THE DOMESTIC SUBSTANCES LIST (DSL).
WHMIS INFORMATION:
REFER TO SECTION 2 FOR A WHMIS CLASSIFICATION FOR THIS PRODUCT.
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
INTERNATIONAL INFORMATION:
COMPONENTS LISTED BELOW ARE PRESENT ON THE FOLLOWING INTERNATIONAL
INVENTORY LIST:
INGREDIENTS CAS # EUROPEAN AUSTRALIA PHILIPPINES
EINECS AICS PICCS
METHYLTRIACETOXYSILANE 4253-34-3 224-221-9 PRESENT PRESENT
ETHYLTRIACETOXYSILANE 17689-77-9 241-677-4 PRESENT PRESENT
ACETIC ACID 64-19-7 200-580-7 PRESENT PRESENT
FORMALDEHYDE 50-00-0 200-001-8 PRESENT PRESENT
INGREDIENTS JAPAN ENCS KOREA CHINA NEWZEALAND
KECI/KECL IECSC IOC
METHYLTRIACETOXYSILANE (9)-1939 KE-25331 PRESENT HSR007291
ETHYLTRIACETOXYSILANE (9)-1939 KE-14056 PRESENT NO INFORMATION
AVAILABLE.
ACETIC ACID (2)-688 KE-00013 PRESENT HSR000975,
HSR001580,
HSR001581,
HSR001582
(DILUTION)
FORMALDEHYDE (2)-482 KE-17074 PRESENT HSR001584,
HSR001162,
HSR001518,
HSR001583
(DILUTION)
| SECTION 16. OTHER INFORMATION | |
LEGEND:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
ATE: ACUTE TOXICITY ESTIMATE
CA: CALIFORNIA
CAS: CHEMICAL ABSTRACT SERVICES
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF
1980
CFR: CODE OF FEDERAL REGULATIONS
DOT: DEPARTMENT OF TRANSPORTATION
EPA: ENVIRONMENTAL PROTECTION AGENCY
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
HSDB: HAZARDOUS SUBSTANCES DATA BANK
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANISATION
INH: INHALATION
LC: LETHAL CONCENTRATION
LD: LETHAL DOSE
MA: MASSACHUSETTS
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N/AP: NOT APPLICABLE
N/AV: NOT AVAILABLE
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PA: PENNSYLVANIA
PEL: PERMISSIBLE EXPOSURE LIMIT
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
RTECS: REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
STEL: SHORT TERM EXPOSURE LIMIT
TDG: CANADIAN TRANSPORTATION OF DANGEROUS GOODS ACT & REGULATIONS
TLV: THRESHOLD LIMIT VALUES
TWA: TIME WEIGHTED AVERAGE
WHMIS: WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
REFERENCES:
1. ACGIH, THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL
AGENTS & BIOLOGICAL EXPOSURE INDICES FOR 2014.
2. INTERNATIONAL AGENCY FOR RESEARCH ON CANCER MONOGRAPHS, SEARCHED 2014.
3. CANADIAN CENTRE FOR OCCUPATIONAL HEALTH AND SAFETY, CCINFOWEB DATABASES,
2015 (CHEMPENDIUM, HSDB AND RTECS).
4. MATERIAL SAFETY DATA SHEETS FROM MANUFACTURER.
5. US EPA TITLE III LIST OF LISTS - OCTOBER 2012
6. CALIFORNIA PROPOSITION 65 LIST - 26 DECEMBER 2014
PREPARATION DATE (MM/DD/YYYY): 06/18/2012
REVIEWED DATE SDS (DD/MM/YYYY): 28/01/2015
REVISION NO.: 3
REVISION INFORMATION:
(M)SDS SECTIONS UPDATED: ALL
OTHER SPECIAL CONSIDERATIONS FOR HANDLING:
PROVIDE ADEQUATE INFORMATION, INSTRUCTION AND TRAINING FOR OPERATORS.
HMIS RATING:
HEALTH 3
FLAMMABILITY 1
REACTIVITY 1
* - CHRONIC HAZARD
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
NFPA RATING:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
0 - MINIMAL
1 - SLIGHT
2 - MODERATE
3 - SERIOUS
4 - SEVERE
PREPARED FOR:
PARKER HANNIFIN CORPORATION - SPORLAN DIVISION
206 LANGE DRIVE
WASHINGTON, MO 63090
U.S.A.
TELEPHONE: (636) 239-1111
DIRECT ALL ENQUIRIES TO: PARKER HANNIFIN CORP. - SPORLAN DIVISION.
PARKER
PREPARED BY:
ICC THE COMPLIANCE CENTER INC.
TELEPHONE:
(888) 442-9628 (U.S.)
(888) 977-4834 (CANADA)
HTTP://WWW.THECOMPLIANCECENTER.COM
ICC COMPLIANCE CENTER
DISCLAIMER:
THIS SAFETY DATA SHEET WAS PREPARED BY ICC THE COMPLIANCE CENTER INC.
USING INFORMATION PROVIDED BY PARKER HANNIFIN CORPORATION AND CCOHS' WEB
INFORMATION SERVICE. THE INFORMATION IN THE SAFETY DATA SHEET IS OFFERED
FOR YOUR CONSIDERATION AND GUIDANCE WHEN EXPOSED TO THIS PRODUCT. ICC THE
COMPLIANCE CENTER INC AND PARKER HANNIFIN CORPORATION EXPRESSLY DISCLAIM
ALL EXPRESSED OR IMPLIED WARRANTIES AND ASSUME NO RESPONSIBILITIES FOR THE
ACCURACY OR COMPLETENESS OF THE DATA CONTAINED HEREIN. THE DATA IN THIS SDS
DOES NOT APPLY TO USE WITH ANY OTHER PRODUCT OR IN ANY OTHER PROCESS.
THIS SAFETY DATA SHEET MAY NOT BE CHANGED, OR ALTERED IN ANY WAY WITHOUT
THE EXPRESSED KNOWLEDGE AND PERMISSION OF ICC THE COMPLIANCE CENTER INC.
AND PARKER HANNIFIN CORPORATION.