| Common Name: | TOUGH GUY MASTIC AND ADHESIVE REMOVER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 4/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 36MV84 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
DATE PREPARED: 04/28/2015
SDS NO: W.W. GRAINGER INC. MASTIC AND ADHESIVE REMOVER
TOUGH GUY MASTIC AND ADHESIVE REMOVER
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY MASTIC AND ADHESIVE REMOVER
GENERAL USE: REMOVES GRAFFITI FROM MULTIPLE SUBSTRATES.
PRODUCT DESCRIPTION: CLINGING BIO GEL BASED GRAFFITI REMOVER
CHEMICAL FAMILY: SOLVENT/DETERGENT BLEND
MANUFACTURED FOR:
W.W. GRAINGER INC.
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
CUSTOMER SERVICE: 800-472-4643
24 HR. EMERGENCY TELEPHONE NUMBERS:
CHEM-TEL (MEDICAL AND TRANSPORTATION): 800-255-3924
POISON CONTROL CENTER (MEDICAL): 800-222-1222
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATIONS:
HEALTH:
SKIN IRRITATION: CATEGORY 2
EYE CORROSION: CATEGORY 1
TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
CATEGORY 3, RESPIRATORY TRACT IRRITATION
CARCINOGENICITY: CATEGORY 2
PHYSICAL:
FLAMMABLE LIQUIDS: CATEGORY 3
GHS LABEL:
CORROSION
HEALTH HAZARD
FLAME
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H318: CAUSES SERIOUS EYE DAMAGE.
H315: CAUSES SKIN IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H351: SUSPECTED OF CAUSING CANCER THROUGH DERMAL CONTACT.
PRECAUTIONARY STATEMENT(S):
PREVENTION:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P261: AVOID BREATHING FUME, GAS, MIST, VAPORS, OR SPRAY.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
RESPONSE:
P305+P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P370+P378:
IN CASE OF FIRE: USE DRY CHEMICAL, FOAM OR WATER MIST TO EXTINGUISH.
STORAGE:
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER ACCORDING TO ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
EMERGENCY OVERVIEW:
PHYSICAL APPEARANCE: AMBER LIQUID
IMMEDIATE CONCERNS: CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS.
POTENTIAL HEALTH EFFECTS:
EYES: CORROSIVE, CONTACT CAUSES SEVERE EYE BURNS.
SKIN: CONTACT MAY CAUSE MODERATE TO SEVERE IRRITATION.
SKIN ABSORPTION: HARMFUL IF ABSORBED THROUGH SKIN.
INGESTION: HARMFUL IF SWALLOWED.
INHALATION: VAPORS ARE IRRITATING TO RESPIRATORY TRACT.
REPRODUCTIVE TOXICITY:
TERATOGENIC EFFECTS: NO LISTED SUBSTANCE
CARCINOGENICITY: CONTAINS AN INGREDIENT LISTED UNDER IARC GROUP 2B STATUS.
MUTAGENICITY: NO LISTED SUBSTANCE
ROUTES OF ENTRY: EYE, SKIN, INGESTION, INHALATION.
TARGET ORGAN STATEMENT: BLOOD, KIDNEY, LIVER, CENTRAL NERVOUS SYSTEM
CANCER STATEMENT:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
WARNING CAUTION LABELS: CORROSIVE
PHYSICAL HAZARDS: COMBUSTIBLE MATERIAL.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME WT.% CAS
METHYL ETHER, SOYBEAN OIL 50 - 55 67784-80-9
ETHYL 2-HYDROXYPROPIONATE, ETHYL-(S)-LACTATE 25 - 30 97-64-3
COCAMIDE DEA 0 - 2 8051-30-7
ETHOXYLATE ALCOHOL C9-11 0 - 5 68439-46-3
PRIMARY ALCOHOL ETHOXYLATE C11 0 - 5 34398-01-1
PROPYLENE GLYCOL PHENYL ETHER 5 - 10 770-35-4
| 4. FIRST AID MEASURES | |
EYES:
IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES, WHILE HOLDING
EYELIDS OPEN. REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES,
THEN CONTINUE RINSING EYE. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN:
REMOVE CONTAMINATED CLOTHING. IMMEDIATELY FLUSH WITH WATER FOLLOWED BY
WASHING WITH MILD SOAP. SEEK MEDICAL ATTENTION.
INGESTION:
GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS INSTRUCTED
TO DO SO BY POISON CENTER OR PHYSICIAN.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND MONITOR. SEEK MEDICAL ADVISE IF IRRITATION
PERSISTS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
EYES: SEVERE BURNING SENSATION, DAMAGE MARKED BY BURNS.
SKIN: BURNING SENSATION, REDNESS.
INGESTION: IRRITATION OF MOUTH, THROAT, ALONG WITH STOMACH UPSET, VOMITING.
INHALATION:
IRRITATION OF NOSE, THROAT AND LUNGS WITH COUGHING, SNEEZING, POSSIBLE
DIFFICULTY BREATHING.
ACUTE TOXICITY:
CORROSIVE TO EYES. CAUSES MODERATE TO SEVERE SKIN IRRITATION. HARMFUL IF
INHALED.
CHRONIC EFFECTS: NOT ESTABLISHED
| 5. FIRE FIGHTING MEASURES | |
FLAMMABLE CLASS: II (100-140 F)
GENERAL HAZARD: COMBUSTIBLE LIQUID
EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CARBON DIOXIDE, OR WATER SPRAY WHEN FIGHTING FIRES
INVOLVING THIS MATERIAL.
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE FROM COMBUSTION
EXPLOSION HAZARDS:
FIRE EXPOSED CONTAINERS MAY BURST DUE TO INCREASED PRESSURE FROM HEAT.
FIRE FIGHTING PROCEDURES:
USE AN EXTINGUISHING AGENT SUITABLE FOR SURROUNDING FIRE.
FIRE FIGHTING EQUIPMENT:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT ANS
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
HAZARDOUS DECOMPOSITION PRODUCTS: NOT ESTABLISHED
| 6. ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS.
LARGE SPILL:
AVOID WALKING IN MATERIAL. PREVENT PRODUCT FROM ENTERING INTO STREAM, SOIL,
STORM SEWER OR OTHER BODIES OF WATER.
ENVIRONMENTAL PRECAUTIONS:
WATER SPILL: AVOID DISCHARGES INTO OPEN WATERWAYS.
LAND SPILL: AVOID DISCHARGE TO SOIL.
AIR SPILL:
NA = NOT APPLICABLE
GENERAL PROCEDURES:
ISOLATE SPILL OR LEAK AREA IMMEDIATELY. KEEP UNAUTHORIZED PERSONNEL AWAY.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. PREVENT ENTRY INTO
WATERWAYS, SEWERS, OR CONFINED AREAS. ABSORB WITH DRY EARTH, SAND OR OTHER
NON-COMBUSTIBLE MATERIAL AND TRANSFER TO CONTAINERS.
RELEASE NOTES: ELIMINATE ALL IGNITION SOURCES. VENTILATE AREA WELL.
SPECIAL PROTECTIVE EQUIPMENT:
EYE PROTECTION, RUBBER GLOVES, RUBBER BOOTS TO PROTECT FEET.
| 7. HANDLING AND STORAGE | |
GENERAL PROCEDURES: CLOSE CONTAINER AFTER USE.
HANDLING:
AVOID CONTACT WITH SKIN AND EYES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES.
STORAGE: STORE IN CLOSED CONTAINER AWAY FROM HEAT, SPARK OR OPEN FLAME.
STORAGE TEMPERATURE: (40 DEG. F) MINIMUM TO (110 DEG. F) MAXIMUM
STORAGE PRESSURE: STORE AT AMBIENT ATMOSPHERIC PRESSURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PROVIDE MECHANICAL VENTILATION WHEN USED IN CONFINED AREAS, OR AREAS WITH
POOR VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
EYES AND FACE: CHEMICAL SPLASH GOGGLES AND FULL FACE-SHIELD.
SKIN: RUBBER OR OTHER CHEMICAL RESISTANT GLOVES.
RESPIRATORY:
A RESPIRATOR IS NOT NEEDED UNDER NORMAL AND INTENDED CONDITIONS OF PRODUCT
USE.
WORK HYGIENIC PRACTICES:
WASH WITH SOAP AND WATER AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHILE
USING PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: HIGH VISCOSITY GEL
ODOR: SOLVENT, CHARACTERISTIC
ODOR THRESHOLD: NOT ESTABLISHED
COLOR: AMBER
PH:
NA = NOT APPLICABLE
PERCENT VOLATILE: <30
FLASH POINT AND METHOD: 46 DEG. C (115 DEG. F) TAG CLOSED CUP (TCC)
FLAMMABLE LIMITS: 1.5 TO 11.4
AUTOIGNITION TEMPERATURE:
NA = NOT APPLICABLE
VAPOR PRESSURE: NOT ESTABLISHED
VAPOR DENSITY: >1 AIR = 1
BOILING POINT: NOT ESTABLISHED
FREEZING POINT: NOT ESTABLISHED
MELTING POINT:
NA = NOT APPLICABLE
THERMAL DECOMPOSITION: NOT AVAILABLE
SOLUBILITY IN WATER: DISPERSABLE
EVAPORATION RATE: (WATER =1) <1.0
DENSITY: 7.90 AT 20 DEG. C (68 DEG. F)
SPECIFIC GRAVITY: APPROX. 0.947 GRAMS/ML.
VISCOSITY: THICK RINGING GEL
(VOC): 27.120 % BY WEIGHT
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: YES
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
STABILITY: STABLE UNDER NORMAL STORAGE AND USE CONDITIONS.
CONDITIONS TO AVOID: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
INCOMPATIBLE MATERIALS: STRONG ACIDS, OXIDIZERS.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION
(RAT) (RABBIT) LC50 (RAT)
ETHYL 2-HYDROXYPROPIONATE, 8200 MG/KG >5000 MG/KG NO DATA
ETHYL-(S)-LACTATE (RAT) (RABBIT) AVAILABLE
ETHOXYLATE ALCOHOL C9-11 1400 MG/KG >5000 MG/KG NO DATA
(RAT) (RAT) AVAILABLE
PRIMARY ALCOHOL ETHOXYLATE C11 >2000 MG/KG >2000 MG/KG
(RAT) (RABBIT)
PROPYLENE GLYCOL PHENYL ETHER 2830 TO 3730 >2000 MG/KG
MG/KG (RAT) (RABBIT)
EYES: CORROSIVE
DERMAL LD50: NOT ESTABLISHED
SKIN ABSORPTION: NOT ESTABLISHED
ORAL LD50: NOT ESTABLISHED
INHALATION LC50: NOT ESTABLISHED
EYE EFFECTS: CORROSIVE TO EYES. PERMANENT DAMAGE MAY OCCUR.
SKIN EFFECTS: SEVERE SKIN IRRITANT. MAY CAUSE BURNS TO SKIN.
CARCINOGENICITY:
CHEMICAL NAME IARC STATUS
COCAMIDE DEA GROUP 2B - LIMITED EVIDENCE OF CARCINOGENICITY
IN HUMANS.
IARC: NO LISTED SUBSTANCE
IRRITATION: IRRITANT
CORROSIVITY: CORROSIVE
SENSITIZATION: NO PRODUCTS WERE FOUND.
NEUROTOXICITY: NOT ESTABLISHED
GENETIC EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
REPRODUCTIVE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TARGET ORGANS: VAPORS MAY HARM RESPIRATORY TRACT.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL DATA: NOT ESTABLISHED
ECOTOXICOLOGICAL INFORMATION: NOT ESTABLISHED
AQUATIC TOXICITY (ACUTE): NOT ESTABLISHED
96-HOUR LC50: NOT ESTABLISHED
96-HOUR EC50: NOT ESTABLISHED
NOTES: PRACTICALLY NONTOXIC
CHEMICAL FATE INFORMATION: THIS PRODUCT IS BIODEGRADABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
ANY METHOD IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL LAWS. BEST METHOD IS
TO RECYCLE OR REUSE FOR INTENDED PURPOSE. IF DISCARDED, THIS MATERIAL AND
ITS CONTAINERS SHOULD BE TREATED AS HAZARDOUS WASTE BASED ON THE
CHARACTERISTICS OF IGNITIBILITY AS DEFINED UNDER FEDERAL RCRA REGULATIONS
(40 CFR 261). CONSULT LOCAL AUTHORITIES FOR DISPOSAL INTO PUBLIC SEWER.
FOR LARGE SPILLS:
CONSULT WITH LOCAL AND STATE AUTHORITIES FOR LARGE VOLUME DISPOSAL.
PRODUCT DISPOSAL:
ANY METHOD IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL LAWS. BEST METHOD
IS TO RECYCLE OR REUSE FOR INTENDED PURPOSE.
EMPTY CONTAINER:
RINSE CONTAINER WITH CLEAR WATER. OFFER CONTAINER FOR RECYCLING, OR DISPOSE
OF IN TRASH.
RCRA/EPA WASTE INFORMATION: HAZARDOUS WASTE
RCRA HAZARD CLASS: IGNITABILITY
| 14. TRANSPORT INFORMATION | |
DOT (DEPARTMENT OF TRANSPORTATION):
PROPER SHIPPING NAME:
CLEANING COMPOUND, NOT REGULATED (FOR US DOMESTIC SHIPMENT ONLY)
PLACARDS: NO SPECIAL REQUIREMENTS.
LABEL:
CERTAIN PACKAGE SIZES DETERMINE THE PROPER LABELING OF CONTAINERS. CONSULT
MANUFACTURER FOR SPECIFIC INFORMATION REGARDING PROPER LABELING.
OTHER SHIPPING INFORMATION:
CERTAIN SHIPPING MODES AND PACKAGING SIZES MAY HAVE EXCEPTIONS FROM THE
TRANSPORT REGULATIONS. THE CLASSIFICATIONS/INFORMATION PROVIDED ABOVE MAY
NOT REFLECT APPLICABLE EXCEPTIONS. CONTACT THE MANUFACTURER FOR MORE
SPECIFIC INFORMATION ON THE PROPER SHIPPING OF THIS MATERIAL.
SPECIAL SHIPPING NOTES:
QUANTITIES LESS THAN OR EQUAL TO ONE (1) GALLON:
LIMITED QUANTITY NOT REGULATED.
AIR (ICAO/IATA):
SHIPPING NAME: CONTACT MANUFACTURER FOR MORE INFORMATION.
VESSEL (IMO/IMDG):
SHIPPING NAME: CONTACT MANUFACTURER FOR MORE INFORMATION.
| 15. REGULATORY INFORMATION | |
UNITED STATES:
DOT LABEL SYMBOL AND HAZARD CLASSIFICATION:
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
311/312 HAZARD CATEGORIES:
HEALTH HAZARD: ACUTE; FIRE HAZARD
FIRE: YES
PRESSURE GENERATING: NO
REACTIVITY: NO
ACUTE: YES
CHRONIC: YES
313 REPORTABLE INGREDIENTS: NO LISTED SUBSTANCE
302/304 EMERGENCY PLANNING:
EMERGENCY PLAN: NO LISTED SUBSTANCE
TSCA (TOXIC SUBSTANCE CONTROL ACT):
TSCA REGULATORY: ALL INGREDIENTS ARE LISTED ON THE TSCA CHEMICAL INVENTORY.
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CHEMICAL NAME WT.% LISTED
COCAMIDE DEA 0 - 2 CANCER
CARCINOGEN: CONTAINS AN INGREDIENT LISTED UNDER IARC GROUP 2B.
| 16. OTHER INFORMATION | |
PREPARED BY: REGULATORY AFFAIRS DEPARTMENT
DATE PREPARED: 04/28/2015
HMIS RATING:
HEALTH 3
FLAMMABILITY 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION C
NFPA CODES:
3
2
0
MANUFACTURER DISCLAIMER:
THIS COMPANY CANNOT ANTICIPATE ALL CONDITIONS OF HANDLING AND USE OF THIS
PRODUCT. THEREFORE, THIS COMPANY ACCEPTS NO RESPONSIBILITY FOR RESULTS
OBTAINED BY THE APPLICATION OF THIS INFORMATION, OR THE SAFETY AND
SUITABILITY OF THE PRODUCT EITHER ALONE OR IN COMBINATION WITH OTHER
PRODUCTS. IT IS THE RESPONSIBILITY OF THE EMPLOYER AND/OR USER TO PROVIDE A
SAFE WORKPLACE, USING HEALTH AND SAFETY INFORMATION CONTAINED HEREIN AS A
GUIDE. THIS COMPANY WILL ACCEPT NO LIABILITY FOR DAMAGES OR LOSSES INCURRED
FROM THE IMPROPER HANDLING AND USE OF THIS PRODUCT.