| Common Name: | RESOLVE SPRAY 'N WASH GOLD LAUNDRY STAIN REMOVER |
| Manufacturer: | RECKITT BENCKISER |
| SDS Revision Date: | 3/12/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 24L287 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CONFORMS TO USDOL OSHA 29 CFR 1910.1200 HAZCOM
RB
HEALTH - HYGIENE - HOME
SAFETY DATA SHEET
RESOLVE(R*) SPRAY 'N WASH(R*) GOLD LAUNDRY STAIN REMOVER
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: RESOLVE(R*) SPRAY 'N WASH(R*) GOLD LAUNDRY STAIN REMOVER
DISTRIBUTED BY:
RECKITT BENCKISER LLC.
MORRIS CORPORATE CENTER IV
399 INTERPACE PARKWAY (P.O. BOX 225)
PARSIPPANY, NEW JERSEY 07054-0225
+1 973 404 2600
EMERGENCY TELEPHONE NUMBER (MEDICAL): 1-800-338-6167
EMERGENCY TELEPHONE NUMBER (TRANSPORT):
1-800-424-9300 (U.S. & CANADA) CHEMTREC
OUTSIDE U.S. AND CANADA (NORTH AMERICA), CALL CHEMTREC: 703-527-3887
WEBSITE: HTTP://WWW.RBNAINFO.COM
THIS SDS IS DESIGNED FOR WORKPLACE EMPLOYEES, EMERGENCY PERSONNEL AND FOR
OTHER CONDITIONS AND SITUATIONS WHERE THERE IS GREATER POTENTIAL FOR
LARGE-SCALE OR PROLONGED EXPOSURE, IN ACCORDANCE WITH THE REQUIREMENTS OF
USDOL OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
THIS SDS IS NOT APPLICABLE FOR CONSUMER USE OF OUR PRODUCTS. FOR CONSUMER
USE, ALL PRECAUTIONARY AND FIRST AID LANGUAGE IS PROVIDED ON THE PRODUCT
LABEL IN ACCORDANCE WITH THE APPLICABLE GOVERNMENT REGULATIONS, AND SHOWN
IN SECTION 15 OF THIS SDS.
SDS #: D8156366
FORMULATION #: 8153106
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENTS: CAUSES SERIOUS EYE DAMAGE.
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
WEAR EYE OR FACE PROTECTION. WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR PHYSICIAN.
STORAGE: NOT APPLICABLE.
DISPOSAL: NOT APPLICABLE.
SUPPLEMENTAL LABEL ELEMENTS: NONE KNOWN.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
INGREDIENT NAME % CAS NUMBER
ALCOHOLS, C12-16, ETHOXYLATED 3EO 5 - 10 68551-12-2
HYDROGEN PEROXIDE 2.5 - 5 7722-84-1
ALCOHOLS, C12-16, ETHOXYLATED 7EO 2.5 - 5 68551-12-2
PROPYLENE GLYCOL 1.5 - 2.5 57-55-6
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS MUST BE TREATED PROMPTLY BY
A PHYSICIAN.
INHALATION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY.
SKIN CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. FLUSH
CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND
SHOES. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT,
OR WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS
MUST BE TREATED PROMPTLY BY A PHYSICIAN.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. MOVE TO FRESH AIR. IF
MATERIAL HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. CHEMICAL BURNS MUST BE TREATED
PROMPTLY BY A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL
ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
MAY GIVE OFF GAS, VAPOR OR DUST THAT IS VERY IRRITATING OR CORROSIVE TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. DO
NOT BREATHE VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS
OR CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR
PROCEED AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE,
ABSORBENT MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH
AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS
(SEE SECTION 13). DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
CONTAMINATED ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED
PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT
INGEST. IF DURING NORMAL USE THE MATERIAL PRESENTS A RESPIRATORY HAZARD,
USE ONLY WITH ADEQUATE VENTILATION OR WEAR APPROPRIATE RESPIRATOR. KEEP IN
THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. STORE
LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE.
CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
HYDROGEN PEROXIDE ACGIH TLV (UNITED STATES, 6/2013).
TWA: 1 PPM 8 HOURS.
TWA: 1.4 MG/M3 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 1 PPM 8 HOURS.
TWA: 1.4 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 1 PPM 10 HOURS.
TWA: 1.4 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 1 PPM 8 HOURS.
TWA: 1.4 MG/M3 8 HOURS.
PROPYLENE GLYCOL AIHA WEEL (UNITED STATES, 10/2011).
TWA: 10 MG/M3 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP
WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY
LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION:
CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD. IF INHALATION HAZARDS EXIST, A
FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: OPAQUE WHITE.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 3.5 (NEAT SOLUTION)
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1 TO 1.02
SOLUBILITY:
EASILY SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
DYNAMIC (ROOM TEMPERATURE): <50 MPA.S (<50 CP)
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
POLYMERIZATION.: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CONDITIONS TO AVOID:
DO NOT MIX WITH: ACIDS OR OXIDIZING AGENTS
INCOMPATIBLE MATERIALS: DO NOT MIX WITH HOUSEHOLD CHEMICALS
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES, VARIOUS ORGANIC CHEMICALS.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
ALCOHOLS, C12-16, LD50 ORAL RAT 500 TO 2000 MG/KG
ETHOXYLATED
HYDROGEN PEROXIDE LD50 ORAL RAT - MALE, 805 MG/KG
FEMALE (70% H2O2 W/W)
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
ALCOHOLS, EYES: RABBIT 24 HOURS
C12-16, MODERATE 100 MICROLITERS
ETHOXYLATED IRRITANT
HYDROGEN EYES: RABBIT 1 MILLIGRAMS
PEROXIDE SEVERE IRRITANT
ALCOHOLS, EYES: RABBIT 24 HOURS
C12-16, MODERATE 100 MICROLITERS
ETHOXYLATED IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
HYDROGEN PEROXIDE 3
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
MAY GIVE OFF GAS, VAPOR OR DUST THAT IS VERY IRRITATING OR CORROSIVE TO
THE RESPIRATORY SYSTEM.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 8843.4 MG/KG
| 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
HYDROGEN PEROXIDE ACUTE EC50: ALGAE - DUNALIELLA 72 HOURS
1.2 MG/L TERTIOLECTA -
MARINE WATER EXPONENTIAL GROWTH
PHASE
ACUTE EC50: ALGAE - 96 HOURS
5.38 MG/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2320 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - SILURIFORMES - 96 HOURS
30 MG/L FINGERLING
FRESH WATER
CHRONIC NOEC: FISH - ONCORHYNCHUS 43 DAYS
989.7 PPM TSHAWYTSCHA - EGG
FRESH WATER
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
HYDROGEN PEROXIDE -1.36 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE PACKAGING SHOULD BE RECYCLED. WASTE MUST BE DISPOSED OF IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
NOT A DOT CONTROLLED MATERIAL (UNITED STATES). NOT A TDG-CONTROLLED
MATERIAL. THIS PREPARATION IS NOT CLASSIFIED AS DANGEROUS ACCORDING TO
INTERNATIONAL TRANSPORT REGULATIONS (ADR/RID, IMDG OR ICAO/IATA).
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
UNITED STATES INVENTORY (TSCA 8B): NOT DETERMINED.
CLEAN AIR ACT SECTION 112(B) HAZARDOUS AIR POLLUTANTS (HAPS): NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % EHS SARA 302 TPQ SARA 304 RQ
(LBS) (GALLONS) (LBS) (GALLONS)
HYDROGEN PEROXIDE 2.5 - 5 YES. 1000 106.1 1000 106.1
SARA 304 RQ: 28571.4 LBS / 12971.4 KG [3392.8 GAL / 12843 L]
SARA 311/312:
CLASSIFICATION: IMMEDIATE (ACUTE) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
ALCOHOLS, 5 - 10 NO. NO. NO. YES. NO.
C12-16,
ETHOXYLATED
HYDROGEN 2.5 - 5 NO. NO. NO. YES. NO.
PEROXIDE
ALCOHOLS, 2.5 - 5 NO. NO. NO. YES. NO.
C12-16,
ETHOXYLATED
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: HYDROGEN PEROXIDE
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: HYDROGEN PEROXIDE
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
PROPYLENE GLYCOL; 1,2-PROPANEDIOL; HYDROGEN PEROXIDE
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
1,2-PROPANEDIOL; HYDROGEN PEROXIDE (CONC >52 PERCENT)
LABEL ELEMENTS:
SIGNAL WORD: CAUTION
HAZARD STATEMENTS:
CAUSES EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED.
PRECAUTIONARY MEASURES:
KEEP OUT OF THE REACH OF CHILDREN. DO NOT GET IN EYES. DO NOT GET ON SKIN.
DO NOT INGEST. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR
USE. WASH THOROUGHLY AFTER HANDLING.
ADDITIONAL INFORMATION:
SHORT TERM SKIN BLEACHING AGENT.
IF ON SKIN: RINSE SKIN WITH WATER.
| 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2
FLAMMABILITY 0
PHYSICAL HAZARDS 0
PERSONAL PROTECTION B
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 2
FLAMMABILITY 0
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE
HAZARDS OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL
FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS
NOT THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
DATE OF ISSUE: 12/03/2015.
DATE OF PREVIOUS ISSUE: 16/10/2014.
VERSION: 1
PREPARED BY:
RECKITT BENCKISER ITALY
VIA SANT'ANTONIO, 5
30034 MIRA, VENICE
ITALY
++39 041 5629211
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
CSPA
PRODUCT CARE(R*)
RB IS A MEMBER OF THE CSPA PRODUCT CARE PRODUCT STEWARDSHIP PROGRAM.
CODE #: D8156366