| Common Name: | LAUNDRY DETERGENT |
| Manufacturer: | TOTAL SOLUTIONS |
| SDS Revision Date: | 5/27/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3WGD2, 3WGD4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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TOTAL SOLUTIONS(TM)
LAUNDRY DETERGENT
SAFETY DATA SHEET
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LAUNDRY DETERGENT
USE OF THE SUBSTANCE/MIXTURE: CLEANER
PRODUCT CODE: 0666
COMPANY:
TOTAL SOLUTIONS
P.O. BOX 240014
MILWAUKEE, WI 53224
USA
T: (414) 354-6417
EMERGENCY NUMBER:
CHEMTREC: (800) 424-9300
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
SKIN IRRIT. 2: H315
EYE DAM. 1: H318
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE DAMAGE
PRECAUTIONARY STATEMENTS (GHS-US):
WASH THOROUGHLY AFTER HANDLING
WEAR EYE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE GLOVES
IF ON SKIN: WASH WITH PLENTY OF WATER
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IMMEDIATELY CALL A DOCTOR
SPECIFIC TREATMENT (SEE FIRST AID MEASURES ON THIS LABEL)
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION
(GHS-US)
SODIUM CARBONATE (CAS NO): 497-19-8 60.0 - 100.0 EYE IRRIT. 2A, H319
SODIUM CARBONATE (CAS NO): 15630-89-4 5.0 - 10.0 ACUTE TOX. 4 (ORAL),
PEROXYHYDRATE H302
EYE DAM. 1, H318
ALCOHOL (CAS NO): 68439-46-3 1.0 - 5.0 ACUTE TOX. 4 (ORAL),
ETHOXYLATE H302
SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
DISODIUM (CAS NO): 6834-92-0 3.0 - 7.0 SKIN CORR. 1B, H314
METASILICATE STOT SE 3, H335
BENZENESULFONIC (CAS NO): 68584-22-5 1.0 - 5.0 ACUTE TOX. 4 (ORAL),
ACID, H302
C10-16-ALKYL SKIN CORR. 1A, H314
DERIVATIVES
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION: REMOVE THE VICTIM INTO FRESH AIR.
FIRST-AID MEASURES AFTER SKIN CONTACT:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
RINSE SKIN WITH WATER/SHOWER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING. GET IMMEDIATE MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. DO NOT INDUCE VOMITING.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
CAUSES SERIOUS EYE DAMAGE. CORROSION OF THE EYE TISSUE. PERMANENT EYE
DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
GASTROINTESTINAL COMPLAINTS. BURNS TO THE GASTRIC/INTESTINAL MUCOSA.
DIARRHEA. CRAMPS. NAUSEA.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: TREAT SYMPTOMATICALLY.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: ALL EXTINGUISHING MEDIA ALLOWED.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
REACTIVITY:
UPON COMBUSTION: CO AND CO2 ARE FORMED.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. USE WATER SPRAY OR FOG
FOR COOLING EXPOSED CONTAINERS. TAKE ACCOUNT OF ENVIRONMENTALLY HAZARDOUS
FIREFIGHTING WATER.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES: ISOLATE FROM FIRE, IF POSSIBLE, WITHOUT UNNECESSARY RISK.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: PROTECTIVE GOGGLES. GLOVES. PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
EVACUATE UNNECESSARY PERSONNEL. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
VENTILATE SPILLAGE AREA.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
STOP LEAK IF SAFE TO DO SO. STOP RELEASE. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT ENTRY TO SEWERS AND PUBLIC
WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS.
METHODS FOR CLEANING UP:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY, AND AS
PER LOCAL LEGISLATION.
6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
COMPLY WITH THE LEGAL REQUIREMENTS. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
HYGIENE MEASURES:
WASH THOROUGHLY AFTER HANDLING. WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: ACIDS.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM: (STRONG) ACIDS.
STORAGE AREA:
MEET THE LEGAL REQUIREMENTS. STORE IN A COOL AREA. STORE IN A DRY AREA.
SPECIAL RULES ON PACKAGING: MEET THE LEGAL REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS: NO ADDITIONAL INFORMATION AVAILABLE
8.2. EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT WHEN RISK ASSESSMENT
INDICATES THIS IS NECESSARY. GLOVES. PROTECTIVE GOGGLES. PROTECTIVE
CLOTHING.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: FINE WHITE POWDER.
ODOR: NO ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VOC CONTENT: 0%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
UPON COMBUSTION: CO AND CO2 ARE FORMED.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REFER TO SECTION 10.1 ON REACTIVITY.
10.4. CONDITIONS TO AVOID: NO ADDITIONAL INFORMATION AVAILABLE
10.5. INCOMPATIBLE MATERIALS: ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
BENZENESULFONIC ACID, C10-16-ALKYL DERIVATIVES (68584-22-5):
LD50 ORAL RAT: 530 MG/KG
SODIUM CARBONATE (497-19-8):
LD50 ORAL RAT: 2800 MG/KG (RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT: >2000 MG/KG (RABBIT; EXPERIMENTAL VALUE)
ATE CLP (ORAL): 2800.000 MG/KG BODY WEIGHT
ALCOHOL ETHOXYLATE (68439-46-3):
LD50 ORAL RAT: 1400 MG/KG ESTIMATED
LD50 DERMAL RABBIT: >5000 MG/KG
ATE CLP (ORAL): 1400.000 MG/KG BODY WEIGHT
SODIUM CARBONATE PEROXYHYDRATE (15630-89-4):
LD50 ORAL RAT: 1034 MG/KG (RAT)
LD50 DERMAL RABBIT: >2000 MG/KG (RABBIT)
ATE CLP (ORAL): 1034.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
CAUSES SERIOUS EYE DAMAGE. CORROSION OF THE EYE TISSUE. PERMANENT EYE
DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
GASTROINTESTINAL COMPLAINTS. BURNS TO THE GASTRIC/INTESTINAL MUCOSA.
DIARRHEA. CRAMPS. NAUSEA.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
SODIUM CARBONATE (497-19-8):
LC50 FISH 1: 300 MG/L (96 H; LEPOMIS MACROCHIRUS)
EC50 DAPHNIA 1: <424 MG/L (48 H; DAPHNIA MAGNA)
EC50 OTHER AQUATIC ORGANISMS 1: 14 MG/L (168 H; PLANKTON)
LC50 FISH 2: 740 MG/L (96 H; GAMBUSIA AFFINIS)
EC50 DAPHNIA: 2 265 MG/L (48 H; DAPHNIA MAGNA)
TLM FISH 1: 300 PPM (96 H; LEPOMIS MACROCHIRUS)
TLM OTHER AQUATIC ORGANISMS 1: 500 PPM (96 H; DAPHNIA MAGNA)
THRESHOLD LIMIT ALGAE 1: 242 MG/L (5 DAYS; ALGAE)
12.2. PERSISTENCE AND DEGRADABILITY:
SODIUM CARBONATE (497-19-8):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE. LOW POTENTIAL FOR ADSORPTION IN SOIL.
THOD: NOT APPLICABLE (INORGANIC)
SODIUM CARBONATE PEROXYHYDRATE (15630-89-4):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE. HYDROLYSIS IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
12.3. BIOACCUMULATIVE POTENTIAL:
SODIUM CARBONATE (497-19-8):
LOG POW: -6.19 (ESTIMATED VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
SODIUM CARBONATE PEROXYHYDRATE (15630-89-4):
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NOT APPLICABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT: NOT REGULATED FOR TRANSPORT
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
ADR: NO ADDITIONAL INFORMATION AVAILABLE
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY.
THIS PRODUCT OR MIXTURE DOES NOT CONTAIN A TOXIC CHEMICAL OR CHEMICALS IN
EXCESS OF THE APPLICABLE DE MINIMIS CONCENTRATION AS SPECIFIED IN 40 CFR
SUBSECTION 372.38(A) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313
OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
AND 40 CFR PART 372.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS, OR MAY CONTAIN, TRACE QUANTITIES OF A SUBSTANCE(S)
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE
TOXICITY.
| SECTION 16: OTHER INFORMATION | |
TRAINING ADVICE:
NORMAL USE OF THIS PRODUCT SHALL IMPLY USE IN ACCORDANCE WITH THE
INSTRUCTIONS ON THE PACKAGING.
FULL TEXT OF H-PHRASES:
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL) CATEGORY 4
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A
SKIN CORR. 1A: SKIN CORROSION/IRRITATION CATEGORY 1A
SKIN CORR. 1B: SKIN CORROSION/IRRITATION CATEGORY 1B
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H315: CAUSES SKIN IRRITATION
H318: CAUSES SERIOUS EYE DAMAGE
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
PREPARED BY: TECHNICAL DEPARTMENT
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT. NO WARRANTY IS EXPRESSED OR IMPLIED
REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS OBTAINED FROM THE USE
THEREOF. OUR COMPANY ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR
PROPERTY DAMAGE TO THE VENDEE, USERS OR THIRD PARTIES CAUSED BY THE
MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF
THIS MATERIAL.
DATE OF ISSUE: 7/21/2015
REVISION DATE: 05/27/2015
VERSION: 1.0
P GHS SDS