| Common Name: | SCOTCH-WELD HYDRAULIC PNEUMATIC SEALANT HP45, PURPLE |
| Manufacturer: | 3M |
| SDS Revision Date: | 9/11/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2XLL9, 2XLN1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) HYDRAULIC PNEUMATIC SEALANT HP45, PURPLE
09/11/14
3M
SAFETY DATA SHEET
COPYRIGHT,2014,3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 33-8419-5
VERSION NUMBER: 1.00
ISSUE DATE: 09/11/14
SUPERCEDES DATE: INITIAL ISSUE
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) HYDRAULIC PNEUMATIC SEALANT HP45, PURPLE
PRODUCT IDENTIFICATION NUMBERS:
62-3477-3960-9, 62-3477-5060-6, 62-3477-5065-5
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER,
ST. PAUL, MN 55144-1000,
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1A.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
25% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYESTER RESIN (NJTS REG. NO. TRADE SECRET* 20 - 40 TRADE
04499600-7087) SECRET *
POLYGLYCOL DIOCTANOATE 18268-70-7 20 - 40 TRADE
SECRET *
POLYETHYLENEGLYCOL DIMETHACRYLATE 25852-47-5 10 - 30 TRADE
SECRET *
HYDROXYPROPYL METHACRYLATE 27813-02-1 10 - 30 TRADE
SECRET *
AMORPHOUS SILICA 112945-52-5 1 - 10 TRADE
SECRET *
2-HYDROXYETHYL METHACRYLATE 868-77-9 1 - 5 TRADE
SECRET *
CUMENE HYDROPEROXIDE 80-15-9 1 - 5 TRADE
SECRET *
1-ACETYL-2-PHENYLHYDRAZINE 114-83-0 <=1 TRADE
SECRET *
METHANOL 67-56-1 <=0.7 TRADE
SECRET *
MALEIC ANHYDRIDE 108-31-6 <=0.5 TRADE
SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE: USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY
COMBUSTIBLE MATERIAL SUCH AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS
(EG. CHLORINE, CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT
(GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
PROTECT FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
MALEIC 108-31-6 OSHA TWA: 1 MG/M3
ANHYDRIDE (0.25 PPM)
MALEIC 108-31-6 ACGIH TWA(INHALABLE A4: NOT
ANHYDRIDE FRACTION AND CLASS. AS
VAPOR): 0.01 HUMAN
MG/M3; TWA: CARCIN,
0.01 MG/M3 DERMAL/
RESPIRATORY
SENSITIZER,
SENSITIZER
SILICA, 112945-52-5 OSHA TWA
AMORPHOUS CONCENTRATION:
0.8 MG/M3; TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
HYDROXYPROPYL 27813-02-1 CMRG CEIL: 3 PPM
METHACRYLATE
METHANOL 67-56-1 ACGIH TWA: 200 PPM; SKIN
STEL: 250 PPM NOTATION
METHANOL 67-56-1 OSHA TWA: 260 MG/M3
(200 PPM)
CUMENE 80-15-9 AIHA TWA: 6 MG/M3 SKIN
HYDROPEROXIDE (1 PPM) NOTATION
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY
AND DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND
OTHER USE CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE
CLOTHING MANUFACTURER FOR SELECTION OF APPROPRIATE COMPATIBLE
GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS
REQUIRED. IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A
FULL RESPIRATORY PROTECTION PROGRAM. BASED ON THE RESULTS OF THE
EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING RESPIRATOR TYPE(S)
TO REDUCE INHALATION EXPOSURE:
FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ORGANIC VAPORS
AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT
WITH YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: THIXOTROPIC LIQUID
ODOR, COLOR, GRADE: BROWN LIQUID SLIGHTLY SWEET ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=300 DEG. F [@ 760 MMHg]
FLASH POINT: >=212 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
EVAPORATION RATE: NEGLIGIBLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: 13.3 PA [@ 20 DEG. C]
DENSITY: 1.05 G/ML [@ 20 DEG. C]
SPECIFIC GRAVITY: 1.05 [@ 20 DEG. C] [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 500 CENTIPOISE [@ 20 DEG. C] [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: <1 % WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
<10 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
LIGHT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST. MAY CAUSE TARGET ORGAN EFFECTS AFTER INHALATION.
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE TARGET ORGAN EFFECTS AFTER INGESTION.
TARGET ORGAN EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE:
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE >5,000
MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE >5,000
MG/KG
POLYGLYCOL DERMAL RABBIT LD50 >20,000 MG/KG
DIOCTANOATE
POLYGLYCOL INGESTION RAT LD50 18,000 MG/KG
DIOCTANOATE
POLYETHYLENEGLYCOL DERMAL LD50 ESTIMATED TO BE
DIMETHACRYLATE >5,000 MG/KG
POLYETHYLENEGLYCOL INGESTION RAT LD50 >5,000 MG/KG
DIMETHACRYLATE
HYDROXYPROPYL DERMAL RABBIT LD50 >5,000 MG/KG
METHACRYLATE
HYDROXYPROPYL INGESTION RAT LD50 11,200 MG/KG
METHACRYLATE
AMORPHOUS SILICA DERMAL RABBIT LD50 >5,000 MG/KG
AMORPHOUS SILICA INHALATION- RAT LC50 >0.691 MG/L
DUST/MIST
(4 HOURS)
AMORPHOUS SILICA INGESTION RAT LD50 >5,110 MG/KG
2-HYDROXYETHYL DERMAL RABBIT LD50 >5,000 MG/KG
METHACRYLATE
2-HYDROXYETHYL INGESTION RAT LD50 5,564 MG/KG
METHACRYLATE
CUMENE DERMAL RAT LD50 500 MG/KG
HYDROPEROXIDE
CUMENE INHALATION- RAT LC50 1.4 MG/L
HYDROPEROXIDE VAPOR (4
HOURS)
CUMENE INGESTION RAT LD50 382 MG/KG
HYDROPEROXIDE
1-ACETYL-2- DERMAL LD50 ESTIMATED TO BE
PHENYLHYDRAZINE 200 - 1,000 MG/KG
1-ACETYL-2- INGESTION MOUSE LD50 270 MG/KG
PHENYLHYDRAZINE
METHANOL DERMAL LD50 ESTIMATED TO BE
1,000 - 2,000 MG/KG
METHANOL INHALATION- LC50 ESTIMATED TO BE
VAPOR 10 - 20 MG/L
METHANOL INGESTION LD50 ESTIMATED TO BE
50 - 300 MG/KG
MALEIC ANHYDRIDE DERMAL RABBIT LD50 2,620 MG/KG
MALEIC ANHYDRIDE INGESTION RAT LD50 400 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
AMORPHOUS SILICA RABBIT NO SIGNIFICANT
IRRITATION
2-HYDROXYETHYL METHACRYLATE RABBIT MINIMAL IRRITATION
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
METHANOL RABBIT MILD IRRITANT
MALEIC ANHYDRIDE RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
2-HYDROXYETHYL METHACRYLATE RABBIT MODERATE IRRITANT
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
METHANOL RABBIT MODERATE IRRITANT
MALEIC ANHYDRIDE RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
AMORPHOUS SILICA HUMAN AND ANIMAL NOT SENSITIZING
2-HYDROXYETHYL METHACRYLATE HUMAN AND ANIMAL SENSITIZING
METHANOL GUINEA PIG NOT SENSITIZING
MALEIC ANHYDRIDE MULTIPLE ANIMAL SENSITIZING
SPECIES
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
MALEIC ANHYDRIDE HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
AMORPHOUS SILICA IN VITRO NOT MUTAGENIC
2-HYDROXYETHYL METHACRYLATE IN VIVO NOT MUTAGENIC
2-HYDROXYETHYL METHACRYLATE IN VITRO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CUMENE HYDROPEROXIDE IN VIVO NOT MUTAGENIC
CUMENE HYDROPEROXIDE IN VITRO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHANOL IN VITRO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHANOL IN VIVO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
AMORPHOUS SILICA NOT MOUSE SOME POSITIVE DATA EXIST,
SPECIFIED BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHANOL INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
AMORPHOUS SILICA INGESTION NOT TOXIC TO FEMALE REPRODUCTION
AMORPHOUS SILICA INGESTION NOT TOXIC TO MALE REPRODUCTION
AMORPHOUS SILICA INGESTION NOT TOXIC TO DEVELOPMENT
2-HYDROXYETHYL INGESTION NOT TOXIC TO FEMALE REPRODUCTION
METHACRYLATE
2-HYDROXYETHYL INGESTION NOT TOXIC TO MALE REPRODUCTION
METHACRYLATE
2-HYDROXYETHYL INGESTION NOT TOXIC TO DEVELOPMENT
METHACRYLATE
METHANOL INGESTION SOME POSITIVE MALE REPRODUCTIVE
DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
METHANOL INGESTION TOXIC TO DEVELOPMENT
METHANOL INHALATION TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
AMORPHOUS SILICA RAT NOAEL 509 MG/KG/DAY 1 GENERATION
AMORPHOUS SILICA RAT NOAEL 497 MG/KG/DAY 1 GENERATION
AMORPHOUS SILICA RAT NOAEL 1,350 DURING ORGANOGENESIS
MG/KG/DAY
2-HYDROXYETHYL RAT NOAEL 1,000 PREMATING &
METHACRYLATE MG/KG/DAY DURING GESTATION
2-HYDROXYETHYL RAT NOAEL 1,000 49 DAYS
METHACRYLATE MG/KG/DAY
2-HYDROXYETHYL RAT NOAEL 1,000 PREMATING &
METHACRYLATE MG/KG/DAY DURING GESTATION
METHANOL RAT NOAEL 1,600 21 DAYS
MG/KG/DAY
METHANOL MOUSE LOAEL 4,000 DURING ORGANOGENESIS
MG/KG/DAY
METHANOL MOUSE NOAEL 1.3 MG/L DURING ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CUMENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
HYDROPEROXIDE SYSTEM DEPRESSION DIZZINESS
CUMENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
HYDROPEROXIDE IRRITATION IRRITATION
METHANOL INHALATION BLINDNESS CAUSES DAMAGE TO ORGANS
METHANOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
METHANOL INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHANOL INGESTION BLINDNESS CAUSES DAMAGE TO ORGANS
METHANOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
MALEIC INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
ANHYDRIDE IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
CUMENE HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL
HYDROPEROXIDE EXPOSURE
CUMENE HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL
HYDROPEROXIDE EXPOSURE
METHANOL HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL
EXPOSURE
METHANOL HUMAN NOAEL NOT AVAILABLE NOT AVAILABLE
METHANOL RAT NOAEL NOT AVAILABLE 6 HOURS
METHANOL HUMAN NOAEL NOT AVAILABLE POISONING
AND/OR ABUSE
METHANOL HUMAN NOAEL NOT AVAILABLE POISONING
AND/OR ABUSE
MALEIC ANHYDRIDE HUMAN LOAEL 0.001 MG/L OCCUPATIONAL
EXPOSURE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
AMORPHOUS INHALATION RESPIRATORY ALL DATA ARE NEGATIVE
SILICA SYSTEM |
SILICOSIS
CUMENE INHALATION NERVOUS SYSTEM | CAUSES DAMAGE TO ORGANS
HYDROPEROXIDE RESPIRATORY THROUGH PROLONGED OR
SYSTEM REPEATED EXPOSURE
CUMENE INHALATION HEART | LIVER | SOME POSITIVE DATA EXIST,
HYDROPEROXIDE KIDNEY AND/OR BUT THE DATA ARE NOT
BLADDER SUFFICIENT FOR
CLASSIFICATION
METHANOL INHALATION LIVER ALL DATA ARE NEGATIVE
METHANOL INHALATION RESPIRATORY ALL DATA ARE NEGATIVE
SYSTEM
METHANOL INGESTION LIVER | NERVOUS SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
AMORPHOUS SILICA HUMAN NOAEL NOT AVAILABLE OCCUPATIONAL
EXPOSURE
CUMENE RAT LOAEL 0.2 MG/L 7 DAYS
HYDROPEROXIDE
CUMENE RAT NOAEL 0.03 MG/L 90 DAYS
HYDROPEROXIDE
METHANOL RAT NOAEL 6.55 MG/L 4 WEEKS
METHANOL RAT NOAEL 13.1 MG/L 6 WEEKS
METHANOL RAT NOAEL 2,500 MG/KG/DAY 90 DAYS
ASPIRATION HAZARD:
NAME VALUE
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF
ADDITIONAL FUEL DURING INCINERATION PROCESSES. AS A DISPOSAL ALTERNATIVE,
UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED
BY APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
CUMENE HYDROPEROXIDE 80-15-9 1 - 5
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS
OF FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY
BASED ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT
ALSO INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS
THAT ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 33-8419-5
VERSION NUMBER: 1.00
ISSUE DATE: 09/11/14
SUPERCEDES DATE: INITIAL ISSUE
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
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FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
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PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
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INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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