| Common Name: | MOLY DRY FILM LUBRICANT |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/7/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 5E202 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 006.0
ISSUE DATE: 08/07/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: MOLY DRY FILM LUBRICANT
PRODUCT TYPE: LUBRICANT
IDH NUMBER: 226675
ITEM NUMBER: 39895
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CONTENTS UNDER PRESSURE.
FLAMMABLE AEROSOL.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE AEROSOL. 2
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
FLAME
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. PRESSURIZED CONTAINER: DO
NOT PIERCE OR BURN, EVEN AFTER USE. AVOID BREATHING MIST OR SPRAY. WASH
THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR EYE AND FACE PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. IF INHALED: REMOVE PERSON TO FRESH AIR
AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
ACETONE 67-64-1 30 - 60
METHYL ETHYL KETONE 78-93-3 10 - 30
BUTANE 106-97-8 10 - 30
PROPANE 74-98-6 10 - 30
1,2,4-TRIMETHYLBENZENE 95-63-6 1 - 5
SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM. 64742-95-6 1 - 5
GRAPHITE 7782-42-5 1 - 5
CUMENE 98-82-8 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH WITH SOAP AND WATER. IF
SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION. WASH CLOTHING BEFORE
REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
RINSE OUT MOUTH, DRINK 1-2 GLASSES OF WATER, DO NOT INDUCE VOMITING. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, POWDER
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
COOL AEROSOL CONTAINERS WITH JET OF WATER. CONTAINERS MAY EXPLODE. DO NOT
HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES OF IGNITION.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, IRRITATING ORGANIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS: DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. FOR SMALL SPILLS WIPE UP WITH PAPER TOWEL AND
PLACE IN CONTAINER FOR DISPOSAL. FOR LARGE SPILLS ABSORB ONTO INERT
ABSORBENT MATERIAL AND PLACE IN SEALED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY IN WELL-VENTILATED AREAS. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
REMOVE ALL SOURCES OF IGNITION. KEEP AWAY FROM HEAT, SPARK AND FLAME. REFER
TO SECTION 8.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
ACETONE 750 PPM STEL 1,000 PPM (2,400 NONE NONE
500 PPM TWA MG/M3) PEL
METHYL ETHYL KETONE 200 PPM TWA 200 PPM (590 NONE NONE
300 PPM STEL MG/M3) PEL
BUTANE 1,000 PPM STEL NONE NONE NONE
PROPANE INCLUDED IN THE 1,000 PPM (1,800 NONE NONE
REGULATION BUT MG/M3) PEL
WITH NO DATA
VALUES. SEE
REGULATION FOR
FURTHER DETAILS
1,2,4-TRIMETHYLBENZENE 25 PPM TWA NONE NONE NONE
SOLVENT NAPHTHA NONE NONE NONE 50 PPM
(PETROLEUM), LIGHT
AROM.
GRAPHITE 2 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
15 MG/M3 PEL
TOTAL DUST.
15 MPPCF TWA
CUMENE 50 PPM TWA 50 PPM (245 NONE NONE
MG/M3) PEL
(SKIN)
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR
CARTRIDGE.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS.
SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL, LIQUID
COLOR: DARK GREY
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: -42.00 DEG. C (-43.6 DEG. F); ESTIMATED
FLASHBACK: THIS PRODUCT EXHIBITS FLASHBACK WHEN TESTED FOR FLAME EXTENSION.
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 47.92% (CALCULATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON.
INCOMPATIBLE MATERIALS: ACIDS AND BASES. OXIDIZING AGENTS. HEAT.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
SKIN CONTACT:
CAUSES SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. SOLVENT
ACTION CAN DRY AND DEFAT THE SKIN, CAUSING THE SKIN TO CRACK, LEADING TO
DERMATITIS.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
ACETONE ORAL LD50 (RABBIT): BLOOD, CENTRAL NERVOUS SYSTEM,
5,340 MG/KG IRRITANT, REPRODUCTIVE
ORAL LD50 (RAT):
5,800 MG/KG
ORAL LD50 (RAT):
9,800 MG/KG
DERMAL LD50 (RABBIT):
20,000 MG/KG
INHALATION LC50 (RAT,
8 H): 50.1 MG/L
INHALATION LC50 (RAT,
4 H): 76 MG/L
METHYL ETHYL KETONE ORAL LD50 (RAT): IRRITANT, CENTRAL NERVOUS SYSTEM
2,300 - 3,500 MG/KG
ORAL LD50 (RAT):
4,500 - 6,800 MG/KG
DERMAL LD50 (RABBIT):
>8,000 MG/KG
INHALATION LC50
(RAT, 4 H): 11700 PPM
BUTANE INHALATION LC50 (RAT, CARDIAC, CENTRAL NERVOUS
4 H): 658 MG/L SYSTEM, IRRITANT
PROPANE INHALATION LC50 (RAT, CARDIAC, CENTRAL NERVOUS
15 MIN): SYSTEM,IRRITANT
>1,442.847 MG/L
INHALATION LC50 (RAT,
15 MIN): >1,464 MG/L
1,2,4-TRIMETHYLBENZENE ORAL LD50 (RAT): CENTRAL NERVOUS SYSTEM,
6.0 G/KG IRRITANT, RESPIRATORY
DERMAL LD50 (RABBIT):
>3,160 MG/KG
INHALATION LC50 (RAT,
48 H): >2000 PPM
SOLVENT NAPHTHA NONE IRRITANT
(PETROLEUM), LIGHT
AROM.
GRAPHITE NONE LUNG
CUMENE ORAL LD50 (RAT): CENTRAL NERVOUS SYSTEM,
2.91 G/KG IRRITANT, LUNG
ORAL LD50 (RAT):
1,400 MG/KG
INHALATION LC50 (RAT,
4 H): 8000 PPM
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
ACETONE NO NO NO
METHYL ETHYL KETONE NO NO NO
BUTANE NO NO NO
PROPANE NO NO NO
1,2,4-TRIMETHYLBENZENE NO NO NO
SOLVENT NAPHTHA NO NO NO
(PETROLEUM), LIGHT
AROM.
GRAPHITE NO NO NO
CUMENE NO GROUP 2B NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
DOT HAZARDOUS SUBSTANCE(S): ACETONE, METHYL ETHYL KETONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA)
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH, FIRE,
PRESSURE
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). METHYL ETHYL KETONE
(CAS# 78-93-3). 1,2,4-TRIMETHYLBENZENE (CAS# 95-63-6).
CERCLA REPORTABLE QUANTITY:
ACETONE (CAS# 67-64-1): 5,000 LBS. (2,270 KG)
METHYL ETHYL KETONE (CAS# 78-93-3): 5,000 LBS. (2,270 KG)
BUTANE (CAS# 106-97-8): 100 LBS. (45.4 KG)
PROPANE (CAS# 74-98-6): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: CATHERINE BIMLER, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/07/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.