| Common Name: | LOCTITE LB 8065 COPPER ANTI-SEIZE STICK KNOWN AS C5-A COPPER ANTI-SEIZE , 37229 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/28/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 3UU54 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.0
ISSUE DATE: 08/28/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE LB 8065 COPPER ANTI-SEIZE STICK KNOWN AS C5-A(R*) COPPER ANTI-SEIZE
STICK
IDH NUMBER: 466863
PRODUCT TYPE: LUBRICANT
ITEM NUMBER: 37229
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST OR FUMES. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED
WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR EYE AND FACE
PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY 64742-52-5 30 - 60
NAPHTHENIC
COPPER 7440-50-8 10 - 30
GRAPHITE 7782-42-5 10 - 30
PETROLEUM DISTILLATES, HYDROTREATED, LIGHT 64742-53-6 10 - 30
NAPHTHENIC
QUARTZ (SiO2) 14808-60-7 1 - 5
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS DEVELOP AND PERSIST, GET
MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. ASPIRATION MAY CAUSE PULMONARY EDEMA AND
PNEUMONITIS. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: DRY CHEMICAL. CARBON DIOXIDE. FOAM
SPECIAL FIREFIGHTING PROCEDURES: NONE
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS: NO SPECIAL ENVIRONMENTAL PRECAUTIONS REQUIRED.
CLEAN-UP METHODS:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. CLEAN RESIDUE WITH SOAP AND WATER.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
KEEP CONTAINER CLOSED.
STORAGE: KEEP IN A COOL, WELL VENTILATED AREA.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 5 MG/M3 TWA NONE NONE
HYDROTREATED HEAVY MIST MIST
NAPHTHENIC
10 MG/M3 STEL 500 PPM
MIST (2,000 MG/M3)
PEL
5 MG/M3 PEL
MIST.
COPPER 0.2 MG/M3 TWA 1 MG/M3 PEL NONE NONE
(AS Cu) (AS Cu)
FUME. DUST AND MIST.
1 MG/M3 TWA 0.1 MG/M3 PEL
(AS Cu) (AS Cu)
DUST AND MIST. FUME.
GRAPHITE 2 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
15 MG/M3 PEL
TOTAL DUST.
15 MPPCF TWA
PETROLEUM DISTILLATES, NONE 500 PPM NONE NONE
HYDROTREATED, LIGHT (2,000 MG/M3)
NAPHTHENIC PEL
5 MG/M3 PEL
MIST.
QUARTZ (SiO2) 0.025 MG/M3 2.4 MPPCF TWA NONE NONE
TWA RESPIRABLE.
RESPIRABLE
FRACTION. 0.1 MG/M3 TWA
RESPIRABLE.
0.3 MG/M3 TWA
TOTAL DUST.
ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION IS
RECOMMENDED WHEN GENERAL VENTILATION IS NOT SUFFICIENT TO CONTROL AIRBORNE
CONTAMINATION BELOW OCCUPATIONAL EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S). OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR 1910.134).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
COLOR: COPPER
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT DETERMINED
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.18
VAPOR DENSITY: NOT DETERMINED
FLASH POINT: PRODUCT IS A SOLID.
BURN RATE: APPROX 14 MM/2 MINUTES
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED
VOC CONTENT: 0%
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: NONE KNOWN
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: EYES, SKIN
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF COPPER FUMES MAY RESULT IN METAL FUME FEVER. SYMPTOMS INCLUDE
METALLIC TASTE, DISCOLORATION OF SKIN OR HAIR. THIS PRODUCT HAS LOW
VOLATILITY AND IS NOT EXPECTED TO CAUSE RESPIRATORY TRACT IRRITATION
DURING NORMAL CONDITIONS OF USE. MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND
DIARRHEA. PRINCIPAL HAZARD OF INGESTION IS ASPIRATION INTO THE LUNGS AND
SUBSEQUENT PNEUMONITIS.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED HEAVY
NAPHTHENIC
COPPER NONE ALLERGEN, BLOOD, CENTRAL
NERVOUS SYSTEM, DEVELOPMENTAL,
GASTROINTESTINAL, IMMUNE
SYSTEM, IRRITANT, KIDNEY,
LIVER, MUTAGEN, SENSORY, SKIN
GRAPHITE NONE LUNG
PETROLEUM DISTILLATES, NONE IRRITANT
HYDROTREATED, LIGHT
NAPHTHENIC
QUARTZ (SiO2) NONE IMMUNE SYSTEM, LUNG, SOME
EVIDENCE OF CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED HEAVY
NAPHTHENIC
COPPER NO NO NO
GRAPHITE NO NO NO
PETROLEUM DISTILLATES, NO NO NO
HYDROTREATED, LIGHT
NAPHTHENIC
QUARTZ (SiO2) KNOWN TO BE GROUP 1 NO
HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (COPPER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3077
PACKING GROUP: III
MARINE POLLUTANT: COPPER
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). COPPER (CAS# 7440-50-8).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: CATHERINE BIMLER, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/28/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.