| Common Name: | LOCTITE PC 5070 TAPE KNOWN AS PIPE REPAIR KIT TAPE, 96321_314086, LOCTITE EA 346 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 10/3/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 4KM86 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.0
ISSUE DATE: 10/03/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE PC 5070 TAPE KNOWN AS PIPE REPAIR KIT TAPE
IDH NUMBER: 702198
PRODUCT TYPE: POLYURETHANE ADHESIVE
ITEM NUMBER: 96321_314086
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
HARMFUL IF SWALLOWED.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
FATAL IF INHALED.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY ORAL 4
ACUTE TOXICITY INHALATION 2
SKIN IRRITATION 2
EYE IRRITATION 2A
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
PICTOGRAM(S):
SKULLS AND CROSSBONES
HEALTH HAZARD
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST OR FUMES. WASH THOROUGHLY AFTER HANDLING. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WEAR EYE AND FACE PROTECTION. WEAR PROTECTIVE GLOVES.
WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL POISON CONTROL OR PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CONTROL CENTER OR PHYSICIAN. RINSE MOUTH.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
GLASS, OXIDE, CHEMICALS 65997-17-3 60 - 100
MDI PREPOLYMER PROPRIETARY 10 - 30
METHYLENEBIS(PHENYLISOCYANATE) 101-68-8 5 - 10
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 1 - 5
TITANIUM DIOXIDE 13463-67-7 0.1 - 1
*EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. ASTHMATIC-TYPE
SYMPTOMS MAY DEVELOP AND MAY BE IMMEDIATE OR DELAYED UP TO SEVERAL HOURS.
CONSULT A PHYSICIAN SHOULD THIS DEVELOPMENT OCCUR.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE. FOR
SEVERE EXPOSURES, GET UNDER SAFETY SHOWER AFTER REMOVING CLOTHING, THEN GET
MEDICAL ATTENTION. FOR LESSER EXPOSURE, SEEK MEDICAL ATTENTION IF
IRRITATION DEVELOPS OR PERSISTS AFTER AREA IS WASHED.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN:
EYES:
STAIN FOR EVIDENCE OF CORNEAL INJURY. IF CORNEA IS BURNED, INSTILL
ANTIBIOTIC STEROID PREPARATION FREQUENTLY. WORKPLACE VAPORS HAVE PRODUCED
REVERSIBLE CORNEAL EPITHELIAL EDEMA IMPAIRING VISION.
SKIN:
THIS COMPOUND IS A KNOWN SKIN SENSITIZER. TREAT SYMPTOMATICALLY AS FOR
CONTACT DERMATITIS OR THERMAL BURNS.
INGESTION:
TREAT SYMPTOMATICALLY. THERE IS NO SPECIFIC ANTIDOTE. INDUCING VOMITING IS
CONTRAINDICATED BECAUSE OF THE IRRITATING NATURE OF THIS COMPOUND.
RESPIRATORY:
THIS COMPOUND IS A KNOWN PULMONARY SENSITIZER. TREAT SYMPTOMATICALLY AND
SUPPORTIVELY.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. DURING A FIRE, MDI VAPORS AND OTHER IRRITATING, HIGHLY
TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR COMBUSTION. AT
TEMPERATURES ABOVE 204.4 DEG. C (400 DEG. F), POLYMERIC MDI CAN POLYMERIZE
AND DECOMPOSE WHICH CAN CAUSE PRESSURE BUILD-UP IN CLOSED CONTAINERS.
EXPLOSIVE RUPTURE IS POSSIBLE. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH
WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
SEALED CONTAINERS AT ELEVATED TEMPERATURES OR CONTAMINATED WITH WATER MAY
RUPTURE EXPLOSIVELY. WATER OR FOG MAY CAUSE FROTHING WHICH CAN BE VIOLENT
ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT OR BURNING LIQUID. DO NOT
ALLOW RUNOFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. HYDROGEN CYANIDE. IRRITATING ORGANIC
VAPOURS. ISOCYANATES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. IF TEMPORARY CONTROL OF ISOCYANATE VAPOR IS REQUIRED, A
BLANKET OF PROTEIN FOAM (AVAILABLE AT MOST FIRE DEPARTMENTS) MAY BE PLACED
OVER SPILL. LARGE QUANTITIES MAY BE PUMPED INTO CLOSED, BUT NOT SEALED
CONTAINERS FOR DISPOSAL. FOR MINOR SPILLS, ABSORB ISOCYANATES WITH SAWDUST
OR OTHER ABSORBENT, SHOVEL INTO SUITABLE UNSEALED CONTAINERS, TRANSPORT TO
WELL VENTILATED AREA (OUTSIDE) AND TREAT WITH NEUTRALIZING SOLUTION:
MIXTURE OF 80% WATER AND 20% NON-IONIC SURFACTANT TERGITOL TMN-10; OR 90%
WATER, 3-8% CONCENTRATED AMMONIA AND 2% DETERGENT. ADD ABOUT TEN PARTS OF
NEUTRALIZER PER PART OF ISOCYANATE, WITH MIXING. ALLOW TO STAND UNCOVERED
FOR 48 HOURS TO LET CARBON DIOXIDE ESCAPE. DECONTAMINATE FLOOR WITH
DECONTAMINATION SOLUTION LETTING STAND FOR AT LEAST 15 MINUTES. REFER TO
SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
EXPOSURE TO VAPORS OF HEATED MDI CAN BE EXTREMELY DANGEROUS. EMPLOYEE
EDUCATION AND TRAINING IN THE SAFE USE AND HANDLING OF THIS COMPOUND ARE
REQUIRED UNDER THE OSHA HAZARD COMMUNICATION STANDARD. DO NOT TASTE OR
SWALLOW. PROTECT FROM MOISTURE. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 40 DEG. C
(104 DEG. F)
STORE IN TIGHTLY CLOSED CONTAINERS TO PREVENT MOISTURE CONTAMINATION. KEEP
CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM
INCOMPATIBLE MATERIALS. STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER
SOURCES OF IGNITION. DO NOT RESEAL IF CONTAMINATION IS SUSPECTED. IF
CONTAINER IS EXPOSED TO HIGH HEAT (204.4 DEG. C (400 DEG. F)), IT CAN BE
PRESSURIZED AND POSSIBLY RUPTURE. MDI REACTS SLOWLY WITH WATER TO FORM
CARBON DIOXIDE GAS. THIS GAS CAN CAUSE SEALED CONTAINERS TO EXPAND AND
POSSIBLY RUPTURE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
GLASS, OXIDE, CHEMICALS NONE NONE NONE NONE
MDI PREPOLYMER NONE NONE NONE NONE
METHYLENEBIS 0.005 PPM TWA 0.02 PPM NONE NONE
(PHENYLISOCYANATE) (0.2 MG/M3)
CEILING
POLYMERIC DIPHENYLMETHANE 0.005 PPM TWA 0.02 PPM NONE NONE
DIISOCYANATE (0.2 MG/M3)
CEILING
TITANIUM DIOXIDE 10 MG/M3 TWA 15 MG/M3 PEL NONE NONE
TOTAL DUST.
ENGINEERING CONTROLS:
LOCAL EXHAUST SHOULD BE USED TO MAINTAIN LEVELS BELOW THE TLV WHENEVER MDI
IS PROCESSED, HEATED OR SPRAY APPLIED. STANDARD REFERENCE SOURCES REGARDING
INDUSTRIAL VENTILATION (I.E., ACGIH INDUSTRIAL VENTILATION) SHOULD BE
CONSULTED FOR GUIDANCE ABOUT ADEQUATE VENTILATION.
AIR MONITORING:
ISOCYANATE EXPOSURE LEVELS MUST BE MONITORED. MONITORING OF AIRBORNE
ISOCYANATES IN THE BREATHING ZONE OF INDIVIDUALS SHOULD BECOME PART OF THE
OVERALL EMPLOYEE EXPOSURE CHARACTERIZATION PROGRAM. MONITORING TECHNIQUES
HAVE BEEN DEVELOPED BY NIOSH AND OSHA.
MEDICAL SURVEILLANCE:
MEDICAL SUPERVISION OF ALL EMPLOYEES WHO HANDLE OR COME IN CONTACT WITH
ISOCYANATES IS RECOMMENDED. THESE SHOULD INCLUDE PREEMPLOYMENT AND PERIODIC
MEDICAL EXAMINATIONS WITH PULMONARY FUNCTION TESTS (FEV, FVC AS A MINIMUM).
PERSONS WITH ASTHMATIC-TYPE CONDITIONS, CHRONIC BRONCHITIS, OTHER CHRONIC
RESPIRATORY DISEASES OR RECURRENT SKIN ECZEMA OR SENSITIZATION SHOULD BE
EXCLUDED FROM WORKING WITH ISOCYANATES. ONCE A PERSON IS DIAGNOSED AS
SENSITIZED TO AN ISOCYANATE, NO FURTHER EXPOSURE CAN BE PERMITTED.
RESPIRATORY PROTECTION:
CONCENTRATIONS GREATER THAN THE TLV CAN OCCUR WHEN MDI IS SPRAYED, HEATED
OR USED IN A POORLY VENTILATED AREA. IN SUCH CASES, OR WHENEVER
CONCENTRATIONS OF MDI EXCEED THE TLV, RESPIRATORY PROTECTION MUST BE WORN.
A POSITIVE PRESSURE, SUPPLIED-AIR RESPIRATOR OR A SELF-CONTAINED BREATHING
APPARATUS IS RECOMMENDED. IN SITUATIONS WHERE MDI IS NOT SPRAYED, HEATED,
OR USED IN A POORLY VENTILATED AREA, AND A SUPPLIED-AIR OR SELF-CONTAINED
BREATHING APPARATUS IS UNAVAILABLE OR ITS USE IMPRACTICAL, AT LEAST AN
AIR-PURIFYING CARTRIDGE AND PARTICULATE PRE-FILTERS MUST BE WORN.
HOWEVER, THIS SHOULD BE PERMITTED ONLY FOR SHORT PERIODS OF TIME (LESS
THAN ONE HOUR) AT RELATIVELY LOW CONCENTRATIONS (AT OR NEAR THE TLV).
HOWEVER, DUE TO THE POOR WARNING PROPERTIES OF MDI, PROPER FIT AND TIMELY
REPLACEMENT OF FILTER ELEMENTS MUST BE ENSURED. OBSERVE OSHA REGULATIONS
FOR RESPIRATOR USE (29 CFR 1910.134).
EYE/FACE PROTECTION:
SAFETY GLASSES WITH SIDESHIELDS OR CHEMICAL SAFETY GOGGLES SHOULD BE WORN
IF THERE IS A RISK OF SPLASHING. VAPOR RESISTANT GOGGLES SHOULD BE WORN
WHEN CONTACT LENSES ARE IN USE. FULL FACE PROTECTION SHOULD BE USED IF THE
POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS. SAFETY SHOWERS AND
EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
PERMEATION RESISTANT GLOVES (BUTYL RUBBER, NITRILE RUBBER, POLYVINYL
ALCOHOL). HOWEVER, PLEASE NOTE THAT POLYVINYL ALCOHOL DEGRADES IN WATER.
COVER AS MUCH OF THE EXPOSED SKIN AREA AS POSSIBLE WITH APPROPRIATE
CLOTHING. IF SKIN CREAMS ARE USED, KEEP THE AREA COVERED BY THE CREAM TO A
MINIMUM. USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND
EITHER AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. EDUCATE AND TRAIN
EMPLOYEES IN SAFE USE OF PRODUCT. FOLLOW ALL LABEL INSTRUCTIONS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: FIBERGLASS CLOTH COATED WITH VISCOUS WHITE RESIN
COLOR: WHITE
ODOR: ODORLESS
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: 0.003 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: 648.9 DEG. C (1,200 DEG. F)
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.22
VAPOR DENSITY: 8.5
FLASH POINT: 188 DEG. C (370.4 DEG. F) PENSKY MARTENS CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
HAZARDOUS REACTIONS:
CONTACT WITH MOISTURE, OTHER MATERIALS WHICH CAN REACT WITH ISOCYANATES,
OR TEMPERATURES ABOVE 204.4 DEG. C (400 DEG. F), MAY CAUSE POLYMERIZATION.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. HYDROGEN CYANIDE. IRRITATING ORGANIC
VAPOURS.
INCOMPATIBLE MATERIALS:
WILL CAUSE SOME CORROSION OF COPPER ALLOYS AND ALUMINUM. WATER AMINES.
STRONG BASES. ALCOHOLS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
CONTAMINATION WITH WATER. ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND
OTHER SOURCES OF IGNITION. STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT TOXICITY DATA:
TOXICITY DATA FOR MONOMERIC AND POLYMERIC METHYLENE BISPHENYL ISOCYANATE:
INHALATION LC50:
APPROXIMATELY 370-490 MG/ML FOR AN AEROSOL OF POLYMERIC MDI
(RATS 4 HOURS)., A TWO HOUR LC50 OF GREATER THAN 400 MG/ML WAS DETERMINED
ON A DUST OF MONOMERIC MDI (RATS).
EYE EFFECTS:
SLIGHTLY IRRITATING. A MAXIMUM PRIMARY EYE IRRITATION SCORE FOR A POLYMERIC
MDI OF 12.0/110 (24 HOURS) WAS OBTAINED. THIS SCORE IS FAIRLY TYPICAL FOR A
NUMBER OF MDI PRODUCTS.
SKIN EFFECTS:
SIGHT TO MODERATE IRRITANT. PRIMARY DERMAL IRRITATION SCORES ARE TYPICALLY
BELOW 3.4/8.0 (DRAIZE).
SENSITIZATION:
MDI HAS BEEN SHOWN TO PRODUCE DERMAL SENSITIZATION IN SEVERAL SPECIES
(GUINEA PIGS, MICE, RABBITS, AND DOGS). INTRADERMAL OR TOPICAL APPLICATION
FOLLOWED BY INHALATION CHALLENGE HAVE RESULTED IN A RESPIRATION
SENSITIZATION RESPONSE IN GUINEA PIGS. IN ADDITION, THERE IS SOME EVIDENCE
TO SUGGEST THAT CROSS-SENSITIZATION BETWEEN DIFFERENT TYPES OF
DIISOCYANATES MAY OCCUR.
CHRONIC TOXICITY:
IN A CHRONIC INHALATION STUDY, RATS WERE EXPOSED TO AN AEROSOL OF
POLYMERIC MDI FOR SIX HOURS PER DAY, FIVE DAYS PER WEEK FOR A PERIOD OF TWO
YEARS. THE EXPOSURE CONCENTRATIONS WERE 0, 0.2, 1.0 AND 6.0 MG/M3. THE NO
OBSERVABLE EFFECTS LEVEL (NOEL) WAS 0.2 MG/M3.
CARCINOGENICITY:
IN THE SAME TWO YEAR STUDY DESCRIBED IN "CHRONIC TOXICITY" ABOVE, THE
OCCURRENCE OF PULMONARY ADENOMAS (BENIGN TUMORS) AND A SINGLE PULMONARY
ADENOCARCINOMA (MALIGNANT TUMOR) WAS CONSIDERED TO BE RELATED TO EXPOSURE.
THESE TUMORS WERE OBSERVED ONLY IN RATS EXPOSED TO THE HIGH CONCENTRATION
OF 6.0 MG/M3.
MUTAGENICITY:
MONOMERIC MDI IS POSITIVE IN THE AMES ASSAY (WITH HEPATIC MICROSOMAL
ACTIVATION). HOWEVER, IT WAS NEGATIVE IN AN INVIVO-INVITRO MICRONUCLEOUS
ASSAY. MDI HAS BEEN REPORTED BY NIOSH TO BE MUTAGENIC TO SALMONELLA
TYPHEMURIUM BACTERIA IN PRESENCE OF A MAMMALIAN ACTIVATING SYSTEM. RECENT
WORK DONE BY M. ANDERSON, AT THE DANISH SCHOOL OF PHARMACY IN DENMARK AND
PUBLISHED IN THE SCANDINAVIAN JOURNAL OF WORK AND ENVIRONMENTAL HEALTH,
ALSO SHOWS A POSITIVE RESULT. THERE IS NOT FULL AGREEMENT IN THE SCIENTIFIC
COMMUNITY ON THE SIGNIFICANCE OF THESE AMES TEST RESULTS AND THEIR
RELATIONSHIP TO HUMAN SAFETY IN THE RISK OF CANCER IN MAN.
OTHER TOXICITY DATA:
NO CONCLUSIVE EVIDENCE HAS BEEN DEVELOPED TO INDICATE THAT EITHER MDI OR A
SIMILAR PRODUCT (A SOLUTION OF MDI AND A POLYISOCYANATE PREPOLYMER BASED ON
MDI) IS CARCINOGENIC, TERATOGENIC OR THAT IT CAUSES REPRODUCTIVE EFFECTS IN
ANIMALS OR IN HUMANS.
RELEVANT ROUTES OF EXPOSURE: SKIN, EYES, INHALATION, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: THIS PRODUCT IS HARMFUL OR FATAL BY INHALATION.
ACUTE:
METHYLENE BISPHENYL ISOCYANATE (MDI) VAPORS OR MIST AT CONCENTRATIONS ABOVE
THE TLV CAN IRRITATE THE MUCOUS MEMBRANES IN THE RESPIRATORY TRACT (NOSE,
THROAT, LUNGS) CAUSING RUNNY NOSE, SORE THROAT, COUGHING, CHEST DISCOMFORT,
SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION (BREATHING OBSTRUCTION).
PERSONS WITH PREEXISTING, NONSPECIFIC BRONCHIAL HYPER-REACTIVITY CAN
RESPOND TO CONCENTRATIONS BELOW THE TLV WITH SIMILAR SYMPTOMS AS WELL AS
LEAD TO BRONCHITIS, BRONCHIAL SPASM AND PULMONARY EDEMA (FLUID IN LUNGS).
CHEMICAL OR HYPERSENSITIVE PNEUMONITIS WITH FLU-LIKE SYMPTOMS (E.G. FEVER,
CHILLS) HAVE ALSO BEEN REPORTED. THESE SYMPTOMS CAN BE DELAYED UP TO
SEVERAL HOURS AFTER EXPOSURE.
CHRONIC:
AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURES OR A SINGLE LARGE DOSE,
CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION (CHEMICAL ASTHMA)
WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE TO ISOCYANATE AT LEVELS
WELL BELOW THE TLV. CHRONIC OVEREXPOSURE TO ISOCYANATES HAS BEEN REPORTED
TO CAUSE LUNG DAMAGE. MAY CAUSE ALLERGIC RESPIRATORY REACTION. THESE
SYMPTOMS, WHICH CAN INCLUDE CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF
BREATH OR ASTHMA ATTACK, COULD BE IMMEDIATE OR DELAYED (UP TO SEVERAL HOURS
AFTER EXPOSURE). SIMILAR TO MANY NON-SPECIFIC ASTHMATIC RESPONSES, THERE
ARE REPORTS THAT ONCE SENSITIZED AN INDIVIDUAL CAN EXPERIENCE THESE
SYMPTOMS UPON EXPOSURE TO DUST, COLD AIR, OR OTHER IRRITANTS. THIS
INCREASED LUNG SENSITIVITY CAN PERSIST FOR WEEKS AND IN SEVERE CASES FOR
SEVERAL YEARS. OVER EXPOSURE TO ISOCYANATES HAS ALSO BEEN REPORTED TO
CAUSE LUNG DAMAGE (INCLUDING DECREASE IN LUNG FUNCTION) WHICH MAY BE
PERMANENT. SENSITIZATION CAN EITHER BE TEMPORARY OR PERMANENT.
SKIN CONTACT:
ACUTE:
CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. ISOCYANATES REACT
WITH SKIN PROTEIN AND MOISTURE AND CAN CAUSE IRRITATION WHICH MAY INCLUDE
THE FOLLOWING SYMPTOMS:
REDDENING, SWELLING, RASH, SCALING OR BLISTERING. CURED MATERIAL IS
DIFFICULT TO REMOVE.
CHRONIC:
PROLONGED CONTACT CAN CAUSE REDDENING, SWELLING, RASH, SCALING, BLISTERING
AND IN SOME CASES, SKIN SENSITIZATION. INDIVIDUALS WHO HAVE SKIN
SENSITIZATION CAN DEVELOP THESE SYMPTOMS FROM CONTACT WITH LIQUID OR VAPOR.
ONCE SENSITIZED, AN INDIVIDUAL MAY REACT EVEN TO AIRBORNE LEVELS BELOW THE
TLV WITH THE FOLLOWING SYMPTOMS:
ITCHING AND TINGLING OF THE EARLOBES AND NECK, RASH, HIVES, SWELLING OF THE
ARMS AND LEGS OR OTHER SYMPTOMS COMMON TO ALLERGIC DERMATITIS. ANIMAL TESTS
HAVE INDICATED THAT RESPIRATORY SENSITIZATION CAN RESULT FROM SKIN CONTACT
WITH MDI. THESE DATA REINFORCE THE NEED TO PREVENT DIRECT SKIN CONTACT
WITH MDI.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. LIQUID, AEROSOLS OR VAPOR ARE IRRITATING AND
CAN CAUSE TEARING, REDDENING AND SWELLING. IF LEFT UNTREATED, CORNEAL
DAMAGE CAN OCCUR AND INJURY IS SLOW TO HEAL. THESE EFFECTS ARE USUALLY
REVERSIBLE. SEE SECTION 4 FOR FIRST AID MEASURES.
INGESTION:
HARMFUL IF SWALLOWED. IRRITATION AND CORROSIVE ACTION CAN OCCUR IN THE
MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT IF SWALLOWED. SYMPTOMS CAN
INCLUDE SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
GLASS, OXIDE, CHEMICALS NONE ALLERGEN, RESPIRATORY
MDI PREPOLYMER NONE NO RECORDS
METHYLENEBIS INHALATION LC50 IRRITANT, RESPIRATORY,
(PHENYLISOCYANATE) (RAT, 4 H): ALLERGEN
0.38 MG/L
INHALATION LC50
(RAT, 4 H):
0.369 MG/L
POLYMERIC DIPHENYLMETHANE NONE ALLERGEN, IRRITANT,
DIISOCYANATE KIDNEY, LIVER, RESPIRATORY
TITANIUM DIOXIDE NONE IRRITANT, RESPIRATORY,
SOME EVIDENCE OF
CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
GLASS, OXIDE, CHEMICALS NO NO NO
MDI PREPOLYMER NO NO NO
METHYLENEBIS NO NO NO
(PHENYLISOCYANATE)
POLYMERIC DIPHENYLMETHANE NO NO NO
DIISOCYANATE
TITANIUM DIOXIDE NO GROUP 2B NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH, REACTIVE
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
METHYLENEBIS(PHENYLISOCYANATE) (CAS# 101-68-8). POLYMERIC DIPHENYLMETHANE
DIISOCYANATE (CAS# 9016-87-9).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 10/03/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.0
ISSUE DATE: 08/20/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE EA 3463 KNOWN AS PIPE REPAIR KIT EPOXY STICK
IDH NUMBER: 702199
PRODUCT TYPE: EPOXY STICK
ITEM NUMBER: 96321_314111
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
EYE AND FACE PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
TALC 14807-96-6 30 - 60
IRON 7439-89-6 10 - 30
EPOXY RESIN PROPRIETARY 10 - 30
GLASS, OXIDE, CHEMICALS 65997-17-3 10 - 30
POLYETHER POLYMERCAPTAN UNKNOWN 5 - 10
SUBSTITUTED AMINOPHENOL PROPRIETARY 5 - 10
TREATED FUMED SILICA 67762-90-7 1 - 5
QUARTZ (SiO2) 14808-60-7 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. CLOSED CONTAINERS
MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. HALOGENATED COMPOUNDS. METAL OXIDE
FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL
PROTECTION" PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL
(E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP
AS MUCH MATERIAL AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER
UNTIL DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 32 DEG. C (89.6 DEG. F)
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER
SOURCES OF IGNITION. PROTECT FROM DIRECT SUNLIGHT.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
TALC 2 MG/M3 TWA 20 MPPCF TWA NONE 50 PPM
RESPIRABLE
FRACTION. 2.4 MPPCF TWA
RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
0.3 MG/M3 TWA
TOTAL DUST.
IRON NONE NONE NONE NONE
EPOXY RESIN NONE NONE NONE NONE
GLASS, OXIDE, CHEMICALS 10 MG/M3 TWA 15 MG/M3 TWA NONE NONE
INHALABLE TOTAL DUST.
DUST.
5 MG/M3 TWA
3 MG/M3 TWA RESPIRABLE
RESPIRABLE FRACTION.
FRACTION.
5 MG/M3 TWA
INHALABLE
FRACTION.
1 FIBERS/CM3
TWA FIBER.
POLYETHER POLYMERCAPTAN NONE NONE NONE NONE
SUBSTITUTED AMINOPHENOL NONE NONE NONE NONE
TREATED FUMED SILICA 10 MG/M3 TWA 15 MG/M3 TWA NONE NONE
INHALABLE TOTAL DUST.
DUST.
5 MG/M3 TWA
3 MG/M3 TWA RESPIRABLE
RESPIRABLE FRACTION.
FRACTION.
QUARTZ (SiO2) 0.025 MG/M3 2.4 MPPCF TWA NONE NONE
TWA RESPIRABLE.
RESPIRABLE
FRACTION. 0.1 MG/M3 TWA
RESPIRABLE.
0.3 MG/M3 TWA
TOTAL DUST.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR IF THE POTENTIAL TO EXCEED
ESTABLISHED EXPOSURE LIMITS EXISTS.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE, BUTYL-RUBBER, OR
NITRILE-RUBBER GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PUTTY
COLOR: METALLIC, BLACK
ODOR: MERCAPTAN, SULFUR
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT DETERMINED
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT APPLICABLE
SPECIFIC GRAVITY: 2.247
VAPOR DENSITY: NOT APPLICABLE
FLASH POINT: >93.3 DEG. C (>199.94 DEG. F) SETAFLASH CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT APPLICABLE
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <1 %
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. HALOGENATED COMPOUNDS. METAL OXIDE
FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS: NONE IDENTIFIED.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
ELEVATED TEMPERATURES. PROTECT FROM DIRECT SUNLIGHT. HEAT, FLAMES, SPARKS
AND OTHER SOURCES OF IGNITION. STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM. CONTAINS CRYSTALLINE SILICA (QUARTZ), WHICH IS
CLASSIFIED AS A POSSIBLE CARCINOGEN. HOWEVER, THE CRYSTALLINE SILICA
PRESENT IN THIS PRODUCT IS ENCAPSULATED IN THE LIQUID AND WILL ONLY BE
LIBERATED IF THE PRODUCT IS SANDED OR ABRADED, AND EVEN THEN WHAT IS
LIBERATED WILL NOT BE PURE CRYSTALLINE SILICA. APPROPRIATE PRECAUTIONS,
HOWEVER, SHOULD BE TAKEN IF THE PRODUCT IS SANDED OR ABRADED TO PREVENT
PERSONNEL FROM BREATHING THE DUST.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
TALC NONE IRRITANT, LUNG, SOME
EVIDENCE OF CARCINOGENICITY
IRON NONE EYES, LUNG
EPOXY RESIN NONE ALLERGEN, IRRITANT
GLASS, OXIDE, CHEMICALS NONE ALLERGEN, RESPIRATORY
POLYETHER POLYMERCAPTAN NONE NO DATA
SUBSTITUTED AMINOPHENOL NONE IRRITANT, ALLERGEN
TREATED FUMED SILICA NONE IRRITANT
QUARTZ (SiO2) NONE IMMUNE SYSTEM, LUNG, SOME
EVIDENCE OF CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
TALC NO GROUP 2B NO
IRON NO NO NO
EPOXY RESIN NO NO NO
GLASS, OXIDE, CHEMICALS NO GROUP 2B NO
POLYETHER POLYMERCAPTAN NO NO NO
SUBSTITUTED AMINOPHENOL NO NO NO
TREATED FUMED SILICA NO NO NO
QUARTZ (SiO2) KNOWN TO BE GROUP 1 NO
HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/20/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.