| Common Name: | SPRAY NINE GREZ-OFF 32 FL.OZ, 22732 |
| Manufacturer: | ITW PERMATEX |
| SDS Revision Date: | 3/25/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 36P452 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
PERMATEX(R*)
REVISION DATE: 25-MAR-2015
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: SPRAY NINE GREZ-OFF(R*) 32 FL.OZ
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 22732
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: DEGREASER - GENERAL PURPOSE - NON-AEROSOL
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER ADDRESS:
ITW PERMATEX
10 COLUMBUS BLVD.
HARTFORD, CT 06106
USA
DISTRIBUTOR:
ITW PERMATEX CANADA
35 BROWNRIDGE ROAD, UNIT 1
HALTON HILLS, ON L7G 0C6
CANADA
TELEPHONE: (800) 924-6994
COMPANY PHONE NUMBER:
1-87-PERMATEX
(877) 376-2839
24 HOUR EMERGENCY PHONE NUMBER:
CHEM-TEL: 800-255-3924
INTERNATIONAL EMERGENCY: 00+1+ 813-248-0585
CONTRACT NUMBER: MIS0003453
E-MAIL ADDRESS: MAIL@PERMATEX.COM
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
OSHA REGULATORY STATUS:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
LABEL ELEMENTS:
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: ORANGE
PHYSICAL STATE: LIQUID
ODOR: CITRUS
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL)
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE
PRECAUTIONARY STATEMENTS - STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: NOT APPLICABLE
UNKNOWN ACUTE TOXICITY:
1.4708% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE:
CHEMICAL NAME CAS NO WEIGHT-% TRADE SECRET
WATER 7732-18-5 60 - 100 *
DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 1 - 5 *
ETHOXYLATED C9-C11 ALCOHOLS 68439-46-3 1 - 5 *
SODIUM METASILICATE 6834-92-0 1 - 5 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
SKIN CONTACT:
IF ON SKIN:
WASH SKIN WITH SOAP AND WATER. IF SKIN IRRITATION PERSISTS, CALL A
PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
INGESTION:
IF SWALLOWED. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. CALL A PHYSICIAN.
SELF-PROTECTION OF THE FIRST AIDER:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS: SEE SECTION 2 FOR MORE INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY (FOG), DRY CHEMICAL, CARBON DIOXIDE (CO2), FOAM
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE IN PARTICULAR.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. AVOID CONTACT
WITH EYES AND SKIN. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. SEE SECTION 12
FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
ENSURE ADEQUATE VENTILATION. SOAK UP WITH INERT ABSORBENT MATERIAL. SWEEP
UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL.
PREVENTION OF SECONDARY HAZARDS:
CLEAN CONTAMINATED OBJECTS AND AREAS THOROUGHLY OBSERVING ENVIRONMENTAL
REGULATIONS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID BREATHING VAPORS OR MISTS. AVOID CONTACT WITH SKIN, EYES OR CLOTHING.
WASH THOROUGHLY AFTER HANDLING. WASH CONTAMINATED CLOTHING BEFORE REUSE.
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. KEEP FROM
FREEZING.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN AND BODY PROTECTION: WEAR PROTECTIVE GLOVES AND PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
USE NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR
CANISTER, AS APPROPRIATE.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
REGULAR CLEANING OF EQUIPMENT, WORK AREA AND CLOTHING IS RECOMMENDED.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: ORANGE
ODOR: CITRUS
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS-METHOD
PH 8-11
MELTING POINT / FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT / BOILING RANGE 100 DEG. C / 212 DEG. F
FLASH POINT >93 DEG. C / >200 DEG. F TAG CLOSED CUP
EVAPORATION RATE <1 BUTYL ACETATE = 1
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE 18 MM Hg
VAPOR DENSITY >1 AIR = 1
RELATIVE DENSITY APPROX. 1.013 G/ML
WATER SOLUBILITY SOLUBLE IN WATER
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
KINEMATIC VISCOSITY NO INFORMATION AVAILABLE
DYNAMIC VISCOSITY NO INFORMATION AVAILABLE
EXPLOSIVE PROPERTIES NO INFORMATION AVAILABLE
OXIDIZING PROPERTIES NO INFORMATION AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO INFORMATION AVAILABLE
MOLECULAR WEIGHT NO INFORMATION AVAILABLE
VOC CONTENT (%) <1%
DENSITY NO INFORMATION AVAILABLE
BULK DENSITY NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: EXCESSIVE HEAT. KEEP FROM FREEZING.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES
NITROGEN OXIDES (NOX)
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: MAY CAUSE IRRITATION OF RESPIRATORY TRACT.
EYE CONTACT:
CONTACT WITH EYES MAY CAUSE IRRITATION. MAY CAUSE REDNESS AND TEARING OF
THE EYES.
SKIN CONTACT: MAY CAUSE SKIN IRRITATION AND/OR DERMATITIS.
INGESTION: INGESTION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES.
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
WATER >90 ML/KG (RAT)
7732-18-5
DIPROPYLENE = 1620 (MICRO)L/KG = 5860 (MICRO)L/KG = 42.1 PPM (RAT) 4 H
GLYCOL (RAT) (RABBIT)
MONONBUTYL
ETHER
29911-28-2
ETHOXYLATED = 1378 MG/KG (RAT) >2 G/KG (RABBIT)
C9-C11 = 1400 MG/KG (RAT)
ALCOHOLS
68439-46-3
SODIUM = 600 MG/KG (RAT)
METASILICATE
6834-92-0
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
GERM CELL MUTAGENICITY: NO INFORMATION AVAILABLE.
CARCINOGENICITY: NO INFORMATION AVAILABLE.
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.
ATEMIX (ORAL): 17322 MG/KG
ATEMIX (DERMAL): 75518 MG/KG
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
3.2241% OF THE MIXTURE CONSISTS OF COMPONENTS(S) OF UNKNOWN HAZARDS TO THE
AQUATIC ENVIRONMENT
CHEMICAL NAME ALGAE/AQUATIC FISH CRUSTACEA
PLANTS
DIPROPYLENE GLYCOL 841:
MONONBUTYL ETHER 96 H POECILIA
29911-28-2 RETICULATA MG/L
LC50 STATIC
SODIUM METASILICATE 210: 216:
6834-92-0 96 H BRACHYDANIO 96 H DAPHNIA MAGNA
RERIO MG/L LC50 MG/L EC50
210:
96 H BRACHYDANIO
RERIO MG/L LC50
SEMI-STATIC
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING: DO NOT REUSE CONTAINER.
US EPA WASTE NUMBER: NOT APPLICABLE
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME: NOT REGULATED
IATA:
PROPER SHIPPING NAME: NOT REGULATED
IMDG:
PROPER SHIPPING NAME: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL/NDSL: COMPLIES
EINECS/ELINCS: NOT LISTED
ENCS: NOT LISTED
IECSC: COMPLIES
KECL: COMPLIES
PICCS: NOT LISTED
AICS: COMPLIES
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
REACTIVE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
NFPA:
HEALTH HAZARDS 1
FLAMMABILITY 1
INSTABILITY 0
HMIS:
HEALTH HAZARDS 1
FLAMMABILITY 1
PHYSICAL HAZARDS 0
PERSONAL PROTECTION B
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION)
HMIS (HAZARDOUS MATERIAL INFORMATION SYSTEM)
REVISION DATE: 25-MAR-2015
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET IS CORRECT TO
THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE
VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.