| Common Name: | HEET WINDSHIELD WASHER CONCENTRATE |
| Manufacturer: | GOLD EAGLE |
| SDS Revision Date: | 9/9/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2AER1, 2AER2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HEET WINDSHIELD WASHER CONCENTRATE
SAFETY DATA SHEET
GOLD EAGLE(R*)
| SECTION 1 - IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: HEET WINDSHIELD WASHER CONCENTRATE
SYNONYMS: 588933
PRODUCT CODE: KL16; KLQ-C
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RECOMMENDED USE: USE PER LABEL DIRECTIONS
RESTRICTIONS ON USE:
SEE PRODUCT LABEL DIRECTIONS AND WARNINGS FOR PRODUCT USE RESTRICTIONS
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
GOLD EAGLE CO.
4400 S. KILDARE AVENUE
CHICAGO, IL 60632-4372
UNITED STATES
HTTP://WWW.GOLDEAGLE.COM/
TELEPHONE (GENERAL): 773-376-4400
EMERGENCY TELEPHONE NUMBER:
MANUFACTURER: 1-800-535-5053 - (INFOTRAC #22283)
| SECTION 2 - HAZARD IDENTIFICATION | |
UNITED STATES (US):
ACCORDING TO: OSHA 29 CFR 1910.1200 HCS
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
FLAMMABLE LIQUIDS 2
SKIN IRRITATION 2 EYE IRRITATION 2
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE 3: NARCOTIC EFFECTS
REPRODUCTIVE TOXICITY 2
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE 1
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 1
LABEL ELEMENTS:
OSHA HCS 2012:
DANGER:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOUR
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE DROWSINESS OR DIZZINESS
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS - EYES
CAUSES DAMAGE TO ORGANS - EYES THROUGH PROLONGED OR REPEATED EXPOSURE
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND/OR HOT SURFACES. - NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED.
GROUND AND/OR BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE MIST/VAPOURS/SPRAY.
WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION
RESPONSE:
IN CASE OF FIRE: USE APPROPRIATE MEDIA FOR EXTINCTION.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
SPECIFIC TREATMENT, SEE SUPPLEMENTAL FIRST AID INFORMATION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED: CALL POISON CENTER OR DOCTOR/PHYSICIAN.
STORAGE/DISPOSAL:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
OTHER INFORMATION:
NFPA:
HEALTH 1
FIRE 3
INSTABILITY 0
SPECIAL
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCES: MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE.
MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS %
METHANOL CAS: 67-56-1 >=95%
WATER CAS: 7732-18-5 BALANCE
CHEMICAL NAME LD50/LC50 CLASSIFICATIONS ACCORDING TO
REGULATION/DIRECTIVE
METHANOL INGESTION/ORAL-RABBIT OSHA HCS 2012:
LD50: 14200 MG/KG FLAM. LIQ. 2; EYE IRRIT. 2;
SKIN IRRIT. 2; STOT SE 1
SKIN-RABBIT LD50: (EYES)
15800 MG/KG
STOT SE 3:
INGESTION/ORAL-RAT LD50: NARC.; STOT RE 1 (EYES);
5600 MG/KG REPR. 2
WATER
| SECTION 4 - FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
MOVE VICTIM TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GIVE
ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING.
SKIN:
IN CASE OF BURNS, IMMEDIATELY COOL AFFECTED SKIN FOR AS LONG AS POSSIBLE
WITH COLD WATER. DO NOT REMOVE CLOTHING IF ADHERING TO SKIN. IN CASE OF
CONTACT WITH SUBSTANCE, IMMEDIATELY FLUSH SKIN WITH RUNNING WATER FOR AT
LEAST 20 MINUTES. REMOVE AND ISOLATE CONTAMINATED CLOTHING. WASH SKIN WITH
SOAP AND WATER.
EYE:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST FIVE MINUTES, THEN
CONTINUE RINSING EYE. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
INDUCE VOMITING (ONLY IN CONSCIOUS PERSONS) THEN GIVE 2 TEASPOONS OF BAKING
SODA IN A GLASS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED.
| SECTION 5 - FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE HALON REPLACEMENT OR CARBON DIOXIDE EXTINGUISHERS OR ALCOHOL FOAM FOR
SMALL FIRES.
LARGE FIRES SHOULD BE EXTINGUISHED WITH ALCOHOL FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
WATER SPRAY OR FOG CAN COOL FIRE BUT MAY NOT BE EFFECTIVE IN EXTINGUISHING
FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN HEATED.
VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS OR IN SEWERS.
HIGHLY FLAMMABLE: WILL BE EASILY IGNITED BY HEAT, SPARKS OR FLAMES.
MANY LIQUIDS ARE LIGHTER THAN WATER.
MOST VAPORS ARE HEAVIER THAN AIR. THEY WILL SPREAD ALONG GROUND AND COLLECT
IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS).
RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND FLASH BACK.
HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE
ADVICE FOR FIREFIGHTERS:
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
LARGE FIRES:
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS
OUT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
VENTILATE THE AREA. DO NOT WALK THROUGH SPILLED MATERIAL. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT (PPE) DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. DO NOT
BREATHE MIST, VAPOURS AND/OR SPRAY. AVOID CONTACT WITH SKIN, EYES, AND
CLOTHING.
EMERGENCY PROCEDURES:
AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE SPILL OR LEAK AREA FOR AT
LEAST 50 METERS (150 FEET) IN ALL DIRECTIONS. IF TANK, RAIL CAR OR TANK
TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR 800 METERS (1/2 MILE) IN ALL
DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION FOR 800 METERS (1/2 MILE) IN
ALL DIRECTIONS. LARGE SPILL: CONSIDER INITIAL DOWNWIND EVACUATION FOR AT
LEAST 300 METERS (1000 FEET) ELIMINATE ALL IGNITION SOURCES (NO SMOKING,
FLARES, SPARKS OR FLAMES IN IMMEDIATE AREA). KEEP UNAUTHORIZED PERSONNEL
AWAY. STAY UPWIND. KEEP OUT OF LOW AREAS. VENTILATE CLOSED SPACES BEFORE
ENTERING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
ABSORB OR COVER WITH DRY EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND
TRANSFER TO CONTAINERS.
USE CLEAN NON-SPARKING TOOLS TO COLLECT ABSORBED MATERIAL.
A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS.
ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED.
LARGE SPILLS: DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
LARGE SPILLS:
WATER SPRAY MAY REDUCE VAPOR; BUT MAY NOT PREVENT IGNITION IN CLOSED
SPACES.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARKS, AND FLAME.
ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC CHARGES. DO NOT USE SPARKING TOOLS.
CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS CHEMICAL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT, AVOID DIRECT CONTACT. DO NOT
BREATHE MIST, VAPOURS AND/OR SPRAY. AVOID CONTACT WITH SKIN, EYES, AND
CLOTHING. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE
EATING, DRINKING, OR USING TOBACCO.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM SOURCES OF IGNITION - NO
SMOKING.
STORE IN A COOL, DRY, WELL-VENTILATED PLACE. EMPTY CONTAINERS CONTAIN
PRODUCT RESIDUES, ASSUME EMPTIED CONTAINERS TO HAVE SAME HAZARDS AS FULL
CONTAINERS.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH NIOSH OSHA
METHANOL TWAS 200 PPM TWA 200 PPM TWA 200 PPM TWA
(67-56-1) 260 MG/M3 TWA 260 MG/M3 TWA
STELS 250 PPM STEL 250 PPM STEL NOT ESTABLISHED
325 MG/M3 STEL
EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS
BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. USE ONLY
APPROPRIATELY CLASSIFIED ELECTRICAL EQUIPMENT.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. USE A
NIOSH/MSHA APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS
ARE EXPERIENCED.
EYE/FACE: WEAR CHEMICAL SPLASH SAFETY GOGGLES.
SKIN/BODY: WEAR APPROPRIATE GLOVES. WEAR PROTECTIVE CLOTHING
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO
WATERWAYS. FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE.
KEY TO ABBREVIATIONS:
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
STEL = SHORT TERM EXPOSURE LIMITS ARE BASED ON 15-MINUTE EXPOSURES
TWA = TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: LIQUID
APPEARANCE/DESCRIPTION: NO DATA AVAILABLE.
COLOR: BLUE
ODOR: NO DATA AVAILABLE
ODOR THRESHOLD: NO DATA AVAILABLE
GENERAL PROPERTIES:
BOILING POINT: 147 F(63.8889 C)
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
SPECIFIC GRAVITY/RELATIVE DENSITY: = 0.791 WATER=1
WATER SOLUBILITY: SOLUBLE 100%
VISCOSITY: 3 TO 5 CENTISTOKE (CST, CS) OR MM2/SEC @ 40 C(104 F)
VOLATILITY:
VAPOR PRESSURE: 96 MMHg (TORR)
VAPOR DENSITY: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
VOC (VOL.): 100%
VOLATILES (VOL.): 100%
FLAMMABILITY:
FLASH POINT: 56 F(13.3333 C)
UEL:12.7%
LEL: 2%
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT RELEVANT.
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: NO DATA AVAILABLE
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, SPARKS, AND FLAME.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS, ALUMINUM, ZINC, OR METALS THAT DISPLACE HYDROGEN,
RUBBER AND RUBBER BASED COATINGS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE AND
PERCHLORIC ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
EXCESSIVE HEATING AND/OR INCOMPLETE COMBUSTION WILL PRODUCE CARBON
MONOXIDE.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENTS:
METHANOL (>=95%) 67-56-1:
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: 5600 MG/KG
INHALATION-RAT LC50: 64000 PPM 4 HOUR(S)
SKIN-RABBIT LD50: 15800 MG/KG
IRRITATION:
EYE-RABBIT: 100 MG 24 HOUR(S) MODERATE IRRITATION
SKIN-RABBIT: 20 MG 24 HOUR(S) MODERATE IRRITATION
MUTAGEN:
CYTOGENETIC ANALYSIS:
INGESTION/ORAL-MOUSE: 1 G/KG
DNA DAMAGE:
INGESTION/ORAL-RAT: 10 (MICRO)MOL/KG
REPRODUCTIVE:
INHALATION-MOUSE TCLO: 5000 PPM 7 HOUR(S)(6-15D PREG)
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES: CENTRAL NERVOUS SYSTEM
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES:
CRANIOFACIAL (INCLUDING NOSE AND TONGUE)
INHALATION-MOUSE TCLO: 2000 PPM 7 HOUR(S)(6-15D PREG)
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES: MUSCULOSKELETAL SYSTEM
GHS PROPERTIES CLASSIFICATION
RESPIRATORY SENSITIZATION OSHA HCS 2012: DATA LACKING
SERIOUS EYE DAMAGE/IRRITATION OSHA HCS 2012: EYE IRRITATION 2
ACUTE TOXICITY OSHA HCS 2012: DATA LACKING
ASPIRATION HAZARD OSHA HCS 2012: DATA LACKING
CARCINOGENICITY OSHA HCS 2012: DATA LACKING
SKIN CORROSION/IRRITATION OSHA HCS 2012: SKIN IRRITATION 2
SKIN SENSITIZATION OSHA HCS 2012: DATA LACKING
STOT-RE OSHA HCS 2012:
SPECIFIC TARGET ORGAN TOXICITY
REPEATED EXPOSURE 1
STOT-SE OSHA HCS 2012:
SPECIFIC TARGET ORGAN TOXICITY SINGLE
EXPOSURE 1
SPECIFIC TARGET ORGAN TOXICITY SINGLE
EXPOSURE 3: NARCOTIC EFFECTS
TOXICITY FOR REPRODUCTION OSHA HCS 2012: TOXIC TO REPRODUCTION 2
GERM CELL MUTAGENICITY OSHA HCS 2012: DATA LACKING
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE):
MAY AFFECT THE CENTRAL NERVOUS SYSTEM. SYMPTOMS MAY INCLUDE DIZZINESS,
DROWSINESS, LETHARGY, COMA AND DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE.
SKIN:
ACUTE (IMMEDIATE): CAUSES SKIN IRRITATION.
CHRONIC (DELAYED): NO DATA AVAILABLE.
EYE:
ACUTE (IMMEDIATE): CAUSES SERIOUS EYE IRRITATION.
CHRONIC (DELAYED): NO DATA AVAILABLE.
INGESTION:
ACUTE (IMMEDIATE):
MAY CAUSE HEADACHE, DIZZINESS, WEAKNESS, EUPHORIA, DROWSINESS, SHORTNESS
OF BREATH, VOMITING, AND LOSS OF VOLUNTARY MUSCLE CONTROL. CAN ALSO CAUSE
BLINDNESS AND DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE.
OTHER:
CHRONIC (DELAYED):
CHRONIC POISONING FROM REPEATED EXPOSURE TO METHANOL VAPOR WERE MANIFESTED
BY CONJUNCTIVITIS, HEADACHE, GIDDINESS, INSOMNIA, GASTRIC DISTURBANCES, AND
BILATERAL BLINDNESS.
CARCINOGENIC EFFECTS:
THIS PRODUCT DOES NOT CONTAIN ANY COMPONENTS ABOVE DE MINIMUS
CONCENTRATIONS THAT ARE CONSIDERED CARCINOGENIC BY OSHA, IARC OR NTP.
REPRODUCTIVE EFFECTS:
ANIMAL TESTS FOR COMPONENTS HAVE SHOWN ADVERSE REPRODUCTIVE EFFECTS.
KEY TO ABBREVIATIONS:
LD = LETHAL DOSE
TC = TOXIC CONCENTRATION
| SECTION 12 - ECOLOGICAL INFORMATION | |
TOXICITY:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
PERSISTENCE AND DEGRADABILITY:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
BIOACCUMULATIVE POTENTIAL:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
MOBILITY IN SOIL:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
OTHER ADVERSE EFFECTS:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
UN NUMBER UN PROPER TRANSPORT PACKING ENVIRONMENTAL
SHIPPING NAME HAZARD CLASS(ES) GROUP HAZARDS
DOT ORM-D CONSUMER NDA NDA NDA
COMMODITY
SPECIAL PRECAUTIONS FOR USER: NONE SPECIFIED.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NO DATA AVAILABLE
| SECTION 15 - REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: ACUTE, CHRONIC, FIRE
INVENTORY:
COMPONENT CAS TSCA
METHANOL 67-56-1 YES
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
METHANOL 67-56-1 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
METHANOL 67-56-1 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
METHANOL 67-56-1
U.S. - CAA (CLEAN AIR ACT) - ACCIDENTAL RELEASE PREVENTION - FLAMMABLE
SUBSTANCES:
METHANOL 67-56-1 NOT LISTED
U.S. - CAA (CLEAN AIR ACT) - ACCIDENTAL RELEASE PREVENTION - TOXIC
SUBSTANCES:
METHANOL 67-56-1 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
METHANOL 67-56-1 5000 LB FINAL RQ
2270 KG FINAL RQ
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
METHANOL 67-56-1 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
METHANOL 67-56-1 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
METHANOL 67-56-1 1.0% DE MINIMIS CONCENTRATION
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
METHANOL 67-56-1 NOT LISTED
U.S. - CWA (CLEAN WATER ACT) - HAZARDOUS SUBSTANCES:
METHANOL 67-56-1 NOT LISTED
U.S. - CWA (CLEAN WATER ACT) - TOXIC POLLUTANTS:
METHANOL 67-56-1 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
METHANOL 67-56-1 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
METHANOL 67-56-1 DEVELOPMENTAL TOXICITY,
INITIAL DATE 3/16/12
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
METHANOL 67-56-1 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
METHANOL 67-56-1 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
METHANOL 67-56-1 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
METHANOL 67-56-1 NOT LISTED
OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
REVISION DATE: 09/SEPTEMBER/2015
PREPARATION DATE: 09/SEPTEMBER/2015
OTHER INFORMATION:
SCHEDULE B NUMBER: 3820.00.0000.
DISCLAIMER/STATEMENT OF LIABILITY:
INFORMATION PRESENTED HEREIN IS BELIEVED TO BE FACTUAL, AS IT HAS BEEN
DERIVED FROM THE WORKS AND OPINIONS OF PERSONS BELIEVED TO BE QUALIFIED
EXPERTS. HOWEVER, NOTHING CONTAINED IN THIS INFORMATION IS TO BE TAKEN AS
WARRANTY OR REPRESENTATION FOR WHICH THE GOLD EAGLE CO. BEARS LEGAL
RESPONSIBILITY. THE USER SHOULD REVIEW ANY RECOMMENDATIONS IN THE SPECIFIC
CONTEXT OF THE INTENDED USE TO DETERMINE WHETHER THEY ARE APPROPRIATE.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
FORMAT: GHS
LANGUAGE: ENGLISH (US)
OSHA HCS 2012