| Common Name: | PUR FILL NF16, CODE BF16 |
| Manufacturer: | HAGO CHEMOTECHNIK GERMANY |
| SDS Revision Date: | 6/3/2014 |
| SDS Format: | GHS-EU |
| Item Number(s): | 45TP90 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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TODOL PRODUCTS
SAFETY DATA SHEET
ACCORDING TO REGULATION (EC) NO 1907/2006
PUR FILL NF16, CODE BF16
PRINT DATE: 03.06.2014
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER: PUR FILL NF16, CODE BF16
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: ADHESIVES, SEALANTS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME: HAGO CHEMOTECHNIK GMBH & CO. KG
STREET: BODENSEESTR. 217
PLACE: D-81243 MUNCHEN
TELEPHONE: +49 (0)89 897702-0
E-MAIL: MSDS@HAGO.DE
CONTACT PERSON: CLAUDIA MEYER-PUNDSACK
TELEPHONE: -58
E-MAIL: CLAUDIA.MEYER-PUNDSACK@HAGO.DE
INTERNET: WWW.HAGO.DE
RESPONSIBLE DEPARTMENT: DEPT. DEVELOPMENT AND APPLICATION
1.4. EMERGENCY TELEPHONE NUMBER:
PUBLIC EMERGENCY NUMBER:
GIFTNOTRUF BERLIN: 030-30686-790 (24 H)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
INDICATIONS OF DANGER:
F+ - EXTREMELY FLAMMABLE
XN - HARMFUL
XI - IRRITANT
R PHRASES:
EXTREMELY FLAMMABLE.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
LIMITED EVIDENCE OF A CARCINOGENIC EFFECT.
MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
GHS CLASSIFICATION:
HAZARD CATEGORIES:
AEROSOL: AEROSOL 1
SKIN CORROSION/IRRITATION: SKIN IRRIT. 2
SERIOUS EYE DAMAGE/EYE IRRITATION: EYE IRRIT. 2
RESPIRATORY/SKIN SENSITIZATION: RESP. SENS. 1
RESPIRATORY/SKIN SENSITIZATION: SKIN SENS. 1
CARCINOGENICITY: CARC. 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: STOT SE 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: STOT RE 2
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
PRESSURISED CONTAINER: MAY BURST IF HEATED.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF CAUSING CANCER.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
2.2. LABEL ELEMENTS:
HAZARDOUS COMPONENTS WHICH MUST BE LISTED ON THE LABEL:
DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
SIGNAL WORD: DANGER
PICTOGRAMS:
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
P410+P412:
PROTECT FROM SUNLIGHT. DO NO EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/
122 DEG. F.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P260: DO NOT BREATHE VAPOUR/AEROSOL.
P251: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P102: KEEP OUT OF REACH OF CHILDREN.
SPECIAL LABELLING OF CERTAIN MIXTURES:
EUH204: CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
2.3. OTHER HAZARDS:
IN CASE OF INSUFFICIENT VENTILATION AND/OR THROUGH USE, EXPLOSIVE/HIGHLY
FLAMMABLE MIXTURES MAY DEVELOP.
PERSONS ALREADY SENSITISED TO DIISOCYANATES MAY DEVELOP ALLERGIC REACTIONS
WHEN USING THIS PRODUCT. PERSONS SUFFERING FROM ASTHMA, ECZEMA OR SKIN
PROBLEMS SHOULD AVOID CONTACT, INCLUDING DERMAL CONTACT, WITH THIS PRODUCT.
THIS PRODUCT SHOULD NOT BE USED UNDER CONDITIONS OF POOR VENTILATION UNLESS
A PROTECTIVE MASK WITH AN APPROPRIATE GAS FILTER (I.E. TYPE A1 ACCORDING TO
STANDARD EN 14387) IS USED.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
HAZARDOUS COMPONENTS:
EC NO CHEMICAL NAME QUANTITY
CAS NO CLASSIFICATION
INDEX NO GHS CLASSIFICATION
REACH NO
DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND 5 - <20%
HOMOLOGUES
9016-87-9 CARC. CAT. 3, XN - HARMFUL, XI - IRRITANT
R40-20-48/20-36/37/38-42/43
615-005-01-6 ACUTE TO X . 4, SKIN IRRIT. 2, EYE IRRIT.
2, RESP. SENS. 1, SKIN SENS. 1, CARC. 2,
STOT SE 3, STOT RE 2; H332 H315 H319 H334
H317 H351 H335 H373
237-158-7 TRIS (2-CHLOROISOPROPYL) PHOSPHATE 10 - <25%
13674-84-5 XN - HARMFUL R22
ACUTE TOX. 4; H302
01-2119486772-26
204-065-8 DIMETHYL ETHER 2.5 - <10%
115-10-6 F+ - EXTREMELY FLAMMABLE R12
603-019-00-8 FLAM. GAS 1; H220
01-2119472128-37
200-857-2 ISOBUTANE 2.5 - <10%
75-28-5 F+ - EXTREMELY FLAMMABLE R12
601-004-00-0 FLAM. GAS 1; H220
200-827-9 PROPANE 1 - <10%
74-98-6 F+ - EXTREMELY FLAMMABLE R12
601-003-00-5 FLAM. GAS 1; H220
FULL TEXT OF R AND H PHRASES: SEE SECTION 16.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
MOVE VICTIM OUT OF DANGER ZONE. IN CASE OF ACCIDENT OR UNWELLNESS, SEEK
MEDICAL ADVICE IMMEDIATELY (SHOW DIRECTIONS FOR USE OR SAFETY DATA SHEET IF
POSSIBLE).
AFTER INHALATION:
PROVIDE FRESH AIR. IN CASE OF IRREGULAR BREATHING OR RESPIRATORY ARREST
PROVIDE ARTIFICIAL RESPIRATION.
AFTER CONTACT WITH SKIN:
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH:
WATER AND SOAP. IN CASE OF SKIN IRRITATION, SEEK MEDICAL TREATMENT.
AFTER CONTACT WITH EYES:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF FLOWING
WATER FOR 10 TO 15 MINUTES HOLDING EYELIDS APART. SUBSEQUENTLY CONSULT AN
OPHTHALMOLOGIST.
AFTER INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN IMMEDIATELY.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ALLERGIC REACTIONS. MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
DANGER OF STICKING EYES AND SKIN DUE TO CURING FOAM.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: FIRST AID, DECONTAMINATION, TREATMENT OF SYMPTOMS.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2). FOAM. EXTINGUISHING POWDER.
UNSUITABLE EXTINGUISHING MEDIA: HIGH POWER WATER JET.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IN CASE OF FIRE MAY BE LIBERATED:
CARBON MONOXIDE. CARBON DIOXIDE (CO2). NITROGEN OXIDES (NOX).
HYDROGEN CHLORIDE (HCl). HYDROCYANIC ACID (HYDROCYANIC ACID).
VAPOURS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
5.3. ADVICE FOR FIREFIGHTERS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. WEAR A
SELF-CONTAINED BREATHING APPARATUS AND CHEMICAL PROTECTIVE CLOTHING.
ADDITIONAL INFORMATION:
USE WATER SPRAY JET TO PROTECT PERSONNEL AND TO COOL ENDANGERED CONTAINERS.
COLLECT CONTAMINATED FIRE EXTINGUISHING WATER SEPARATELY. DO NOT ALLOW
ENTERING DRAINS OR SURFACE WATER.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PROVIDE ADEQUATE VENTILATION. REMOVE ALL SOURCES OF IGNITION.
AVOID CONTACT WITH SKIN, EYES AND CLOTHES. DO NOT BREATHE VAPOUR/AEROSOL.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS.
DO NOT ALLOW TO ENTER INTO SOIL/SUBSOIL.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
PROVIDE ADEQUATE VENTILATION. ALLOW STIFFENING. TAKE UP MECHANICALLY.
6.4. REFERENCE TO OTHER SECTIONS:
TREAT THE RECOVERED MATERIAL AS PRESCRIBED IN THE SECTION ON WASTE
DISPOSAL.
HANDLING, PERSONAL PROTECTION EQUIPMENT:
SEE PROTECTIVE MEASURES UNDER POINT 7 AND 8.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
PROVIDE ADEQUATE VENTILATION AS WELL AS LOCAL EXHAUSTION AT CRITICAL
LOCATIONS. DO NOT USE IN ENCLOSED ROOMS.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50
DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT SPRAY ON A NAKED
FLAME OR ANY INCANDESCENT MATERIAL. KEEP AWAY FROM SOURCES OF IGNITION - NO
SMOKING. KEEP OUT OF THE REACH OF CHILDREN. VAPOURS MAY FORM EXPLOSIVE
MIXTURES WITH AIR. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS FOR STORAGE ROOMS AND VESSELS:
KEEP IN A COOL, WELL-VENTILATED PLACE.
ADVICE ON STORAGE COMPATIBILITY:
DO NOT STORE TOGETHER WITH: OXIDIZING AGENTS.
FURTHER INFORMATION ON STORAGE CONDITIONS:
PROTECT FROM SUNLIGHT. DO NO EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/
122 DEG. F.
RECOMMENDED STORAGE TEMPERATURE:
15 - 23 DEG. C. STORAGE ABOVE 23 DEG. C WILL REDUCE SHELF LIFE
SIGNIFICANTLY, DEPENDING ON TEMPERATURE AND DURATION.
7.3. SPECIFIC END USE(S): NOT APPLICABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE LIMITS (EH40):
CAS NO SUBSTANCE PPM MG/M3 FIBRES/ML CATEGORY ORIGIN
9016-87-9 DIPHENYLMETHANEDI- 0,05 TWA (8 H) AGW
ISOCYANATE,
ISOMERS AND STEL (15 AGW
HOMOLOGUES MIN)
115-10-6 DIMETHYL ETHER 400 766 TWA (8 H) WEL
500 958 STEL (15 WEL
MIN)
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT HAS TO BE CHOSEN IN ACCORDANCE WITH WORKPLACE
SPECIFIC CONDITIONS, E. G. CONCENTRATION OF THE PRODUCT. CHEMICAL
RESISTANCE HAS TO BE CLARIFIED WITH THE SUPPLIER OF PROTECTIVE EQUIPMENT.
PROTECTIVE AND HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AFTER WORK. DO NOT EAT, DRINK, SMOKE OR SNEEZE
AT THE WORKPLACE. TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
EYE/FACE PROTECTION: TIGHTLY SEALED SAFETY GLASSES.
HAND PROTECTION:
SUITABLE MATERIAL: BUTYL RUBBER.
THE QUALITY OF THE PROTECTIVE GLOVES RESISTANT TO CHEMICALS MUST BE CHOSEN
AS A FUNCTION OF THE SPECIFIC WORKING PLACE CONCENTRATION AND QUANTITY OF
HAZARDOUS SUBSTANCES.
SKIN PROTECTION:
FOR THE PROTECTION AGAINST DIRECT SKIN CONTACT, BODY PROTECTIVE CLOTHING IS
ESSENTIAL (IN ADDITION TO THE USUAL WORKING CLOTHES).
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NECESSARY AT: INSUFFICIENT VENTILATION.
SUITABLE RESPIRATORY PROTECTIVE EQUIPMENT:
GAS FILTERING EQUIPMENT (EN 141).
ENVIRONMENTAL EXPOSURE CONTROLS:
REFER TO CHAPTER 7. NO FURTHER ACTION IS NECESSARY.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: AEROSOL
COLOUR: DEPENDING ON TYPE
ODOUR: CHARACTERISTIC
TEST METHOD:
PH-VALUE: NOT APPLICABLE
CHANGES IN THE PHYSICAL STATE:
MELTING POINT: NOT APPLICABLE
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
EXPLOSIVE PROPERTIES:
IN USE, MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
LOWER EXPLOSION LIMITS: 1,5 VOL. %
UPPER EXPLOSION LIMITS: 26,2 VOL. %
IGNITION TEMPERATURE: >230 DEG. C
VAPOUR PRESSURE: 5500 - 6000 HPA
DENSITY: NOT DETERMINED
WATER SOLUBILITY: PRACTICALLY INSOLUBLE
PARTITION COEFFICIENT: NOT DETERMINED
VISCOSITY / DYNAMIC: NOT APPLICABLE
VISCOSITY / KINEMATIC: NOT APPLICABLE
VAPOUR DENSITY: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
9.2. OTHER INFORMATION: NONE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
10.2. CHEMICAL STABILITY:
THE PRODUCT IS STABLE UNDER STORAGE AT NORMAL AMBIENT TEMPERATURES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
EXOTHERMIC REACTIONS WITH: OXIDIZING AGENTS, STRONG.
IN USE, MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
10.4. CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT EXPOSE TO TEMPERATURES ABOVE 50 DEG. C. HEATING CAUSES RISE IN
PRESSURE WITH RISK OF BURSTING.
10.5. INCOMPATIBLE MATERIALS:
EXOTHERMIC REACTIONS WITH: OXIDIZING AGENTS, STRONG.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. NITROGEN OXIDES (NOX).
HYDROGEN CHLORIDE (HCl). HYDROCYANIC ACID (HYDROCYANIC ACID).
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
TOXICOCINETICS, METABOLISM AND DISTRIBUTION:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ACUTE TOXICITY:
CAS NO CHEMICAL NAME
EXPOSURE ROUTES METHOD DOSE SPECIES SOURCE
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
ORAL LD50 >10000 MG/KG RAT
DERMAL LD50 >10000 MG/KG RABBIT
INHALATIVE VAPOUR ATE 11 MG/L
INHALATIVE AEROSOL ATE 1,5 MG/L
13674-84-5 TRIS (2-CHLOROISOPROPYL) PHOSPHATE
ORAL LD50 630 - 2000 MG/KG RAT
DERMAL LD50 >5000 MG/KG RABBIT
INHALATIVE (4 H) LC50 >7 MG/L RAT
VAPOUR
115-10-6 DIMETHYL ETHER
INHALATIVE (4 H) LC50 309 PPM RAT
GAS
IRRITATION AND CORROSIVITY:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
SENSITISING EFFECTS:
MAY CAUSE AN ALLERGIC SKIN REACTION. (DIPHENYLMETHANEDIISOCYANATE, ISOMERS
AND HOMOLOGUES)
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
(DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES)
DO NOT APPLY TO THE CURED FOAM.
STOT-SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION. (DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND
HOMOLOGUES)
SEVERE EFFECTS AFTER REPEATED OR PROLONGED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
(DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES)
CARCINOGENIC/MUTAGENIC/TOXIC EFFECTS FOR REPRODUCTION:
SUSPECTED OF CAUSING CANCER. (DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND
HOMOLOGUES)
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CAS NO CHEMICAL NAME
AQUATIC TOXICITY METHOD DOSE [H]/ SPECIES SOURCE
[D]
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
ACUTE FISH LC50 >1000 96 H BRACHYDANIO
TOXICITY MG/L RERIO
(ZEBRA-FISH)
13674-84-5 TRIS (2-CHLOROISOPROPYL) PHOSPHATE
ACUTE FISH LC50 56,2 96 H
TOXICITY MG/L
ACUTE ALGAE ERC50 82 MG/L 72 H
TOXICITY
ACUTE CRUSTACEA EC50 131 48 H DAPHNIA
TOXICITY MG/L MAGNA
115-10-6 DIMETHYL ETHER
ACUTE FISH LC50 >4,1 96 H POECILIA
TOXICITY MG/L RETICULATA
(GUPPY)
ACUTE ALGAE ERC50 154,9 96 H
TOXICITY MG/L
ACUTE EC50 >4,4 48 H DAPHNIA
CRUSTACEA MG/L MAGNA (BIG
TOXICITY WATER FLEA)
12.2. PERSISTENCE AND DEGRADABILITY:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CAS NO CHEMICAL NAME
METHOD VALUE D SOURCE
EVALUATION
9016-87-9 DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES
OECD 302C <10% 28
POORLY BIODEGRADABLE.
12.3. BIOACCUMULATIVE POTENTIAL:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
PARTITION COEFFICIENT N-OCTANOL/WATER:
CAS NO CHEMICAL NAME LOG POW
13674-84-5 TRIS (2-CHLOROISOPROPYL) PHOSPHATE -2,68
115-10-6 DIMETHYL ETHER 0,1
75-28-5 ISOBUTANE 2,8
74-98-6 PROPANE 2,36
12.4. MOBILITY IN SOIL: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
12.6. OTHER ADVERSE EFFECTS: NONE
FURTHER INFORMATION:
ACCORDING TO THE CRITERIA OF THE EUROPEAN CLASSIFICATION AND LABELLING
SYSTEM, THE SUBSTANCE/THE PRODUCT HAS NOT TO BE LABELLED AS "DANGEROUS FOR
THE ENVIRONMENT".
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
ADVICE ON DISPOSAL: DISPOSE OF WASTE ACCORDING TO APPLICABLE LEGISLATION.
WASTE DISPOSAL NUMBER OF WASTE FROM RESIDUES/UNUSED PRODUCTS:
160504:
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; GASES IN PRESSURE CONTAINERS
AND DISCARDED CHEMICALS; GASES IN PRESSURE CONTAINERS (INCLUDING HALONS)
CONTAINING DANGEROUS SUBSTANCES CLASSIFIED AS HAZARDOUS WASTE.
WASTE DISPOSAL NUMBER OF USED PRODUCT:
170203:
CONSTRUCTION AND DEMOLITION WASTES (INCLUDING EXCAVATED SOIL FROM
CONTAMINATED SITES); WOOD, GLASS AND PLASTIC; PLASTIC
WASTE DISPOSAL NUMBER OF CONTAMINATED PACKAGING:
080409:
WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING
INKS; WASTES FROM MFSU OF ADHESIVES AND SEALANTS (INCLUDING WATERPROOFING
PRODUCTS); WASTE ADHESIVES AND SEALANTS CONTAINING ORGANIC SOLVENTS OR
OTHER DANGEROUS SUBSTANCES CLASSIFIED AS HAZARDOUS WASTE.
CONTAMINATED PACKAGING:
IN GERMANY:
TAKING BACK WITHOUT ADDITIONAL COSTS BY PU-DOSEN-RECYCLING GMBH & CO.
BETRIEBSKG (PDR), AM ALTEN SAGEWERK 3, D-95349 THURNAU.
ORDER AND PICKUP: PHONE 0800-7836736 OR FAX 0800-7836737.
| SECTION 14: TRANSPORT INFORMATION | |
LAND TRANSPORT (ADR/RID):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS
14.3. TRANSPORT HAZARD CLASS(ES): 2
14.4. PACKING GROUP:
HAZARD LABEL: 2.1
CLASS 2.1, FLAMMABLE GASES
CLASSIFICATION CODE: 5F
LIMITED QUANTITY: 1 L
TRANSPORT CATEGORY: 2
TUNNEL RESTRICTION CODE: D
OTHER APPLICABLE INFORMATION (LAND TRANSPORT):
TRANSPORT AS "LIMITED QUANTITY" ACCORDING TO CHAPTER 3.4 ADR/RID.
INLAND WATERWAYS TRANSPORT (ADN):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS
14.3. TRANSPORT HAZARD CLASS(ES): 2
14.4. PACKING GROUP:
HAZARD LABEL: 2.1
CLASS 2.1, FLAMMABLE GASES
CLASSIFICATION CODE: 5F
LIMITED QUANTITY: 1 L
MARINE TRANSPORT (IMDG):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS
14.3. TRANSPORT HAZARD CLASS(ES): 2.1
14.4. PACKING GROUP:
HAZARD LABEL: 2.1
CLASS 2.1 - FLAMMABLE GASES
MARINE POLLUTANT:
LIMITED QUANTITY: SEE SP277
EMS: F-D, S-U
AIR TRANSPORT (ICAO):
14.1. UN NUMBER: UN 1950
14.2. UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
14.3. TRANSPORT HAZARD CLASS(ES): 2.1
HAZARD LABEL: 2.1
CLASS 2.1, FLAMMABLE GASES
LIMITED QUANTITY PASSENGER: 30 KG G
14.5. ENVIRONMENTAL HAZARDS:
ENVIRONMENTALLY HAZARDOUS: NO
14.6. SPECIAL PRECAUTIONS FOR USER: SEE CHAPTER 6 - 8
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT RELEVANT
| SECTION 15: REGULATORY INFORMATION | |
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATORY INFORMATION:
1999/13/EC (VOC): (PLEASE REFER TO THE MANUFACTURER)
NATIONAL REGULATORY INFORMATION:
EMPLOYMENT RESTRICTIONS:
OBSERVE EMPLOYMENT RESTRICTIONS FOR YOUNG PEOPLE.
OBSERVE EMPLOYMENT RESTRICTIONS FOR CHILD BEARING MOTHERS AND NURSING.
WATER CONTAMINATING CLASS (D): NOT WATER CONTAMINATING
SKIN RESORPTION/SENSITIZATION: CAUSES ALLERGIC HYPERSENSITIVITY REACTIONS.
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY ASSESSMENTS FOR SUBSTANCES IN THIS MIXTURE WERE NOT CARRIED
OUT.
| SECTION 16: OTHER INFORMATION | |
CHANGES:
SECTION: 2, 11, 12, 13
FULL TEXT OF R PHRASES REFERRED TO UNDER SECTIONS 2 AND 3:
12: EXTREMELY FLAMMABLE.
20: HARMFUL BY INHALATION.
22: HARMFUL IF SWALLOWED.
36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
40: LIMITED EVIDENCE OF A CARCINOGENIC EFFECT.
42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
FULL TEXT OF H STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3:
H220: EXTREMELY FLAMMABLE GAS.
H222: EXTREMELY FLAMMABLE AEROSOL.
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
FURTHER INFORMATION:
DATA SOURCES: DATA ARISE FROM REFERENCE WORKS AND LITERATURE.
THE ABOVE INFORMATION DESCRIBES EXCLUSIVELY THE SAFETY REQUIREMENTS OF THE
PRODUCT AND IS BASED ON OUR PRESENT-DAY KNOWLEDGE. THE INFORMATION IS
INTENDED TO GIVE YOU ADVICE ABOUT THE SAFE HANDLING OF THE PRODUCT NAMED IN
THIS SAFETY DATA SHEET, FOR STORAGE, PROCESSING, TRANSPORT AND DISPOSAL.
THE INFORMATION CANNOT BE TRANSFERRED TO OTHER PRODUCTS. IN THE CASE OF
MIXING THE PRODUCT WITH OTHER PRODUCTS OR IN THE CASE OF PROCESSING, THE
INFORMATION ON THIS SAFETY DATA SHEET IS NOT NECESSARILY VALID
FOR THE NEW MADE-UP MATERIAL.
(THE DATA FOR THE HAZARDOUS INGREDIENTS WERE TAKEN RESPECTIVELY FROM THE
LAST VERSION OF THE SUB-CONTRACTOR'S SAFETY DATA SHEET.)
REVISION NO: 7,01
REVISION DATE: 03.06.2014
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