| Common Name: | CD 887 COIL & FIN CLEANER AEROSOL |
| Manufacturer: | SPRAYON PRODUCTS |
| SDS Revision Date: | 5/22/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 1MEU7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
S00887000
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: CD(TM)887 COIL & FIN CLEANER AEROSOL
PRODUCT CODE: S00887000
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
SPRAYON PRODUCTS
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: (800)247-3266
REGULATORY INFORMATION TELEPHONE NUMBER: (216)566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800)424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN CORROSION/IRRITATION: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
1.6%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
CORROSION
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION. WEAR PROTECTIVE
CLOTHING. KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER
IGNITION SOURCES. NO SMOKING.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT SPRAY ON AN OPEN FLAME OR
OTHER IGNITION SOURCE. DO NOT BREATHE DUST OR MIST. WASH HANDS THOROUGHLY
AFTER HANDLING.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. RINSE MOUTH. DO NOT INDUCE
VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR PHYSICIAN.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP UPRIGHT IN A COOL,
DRY PLACE. DO NOT DISCARD EMPTY CAN IN TRASH COMPACTOR.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
BUTANE 3.4 106-97-8
2-BUTOXYETHANOL 2.0 111-76-2
2-(2-ETHOXYETHOXY)-ETHANOL 2.0 111-90-0
PROPANE 1.6 74-98-6
TETRASODIUM ETHYLENEDIAMINETETRAACETATE 1.6 64-02-8
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE
TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS MUST BE TREATED PROMPTLY
BY A PHYSICIAN.
INHALATION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF INHALATION OF DECOMPOSITION
PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED. THE EXPOSED PERSON MAY NEED TO
BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. FLUSH
CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND
SHOES. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT,
OR WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS
MUST BE TREATED PROMPTLY BY A PHYSICIAN. WASH CLOTHING BEFORE REUSE. CLEAN
SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH AIR
AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS
BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES
OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE
DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT
DOES NOT ENTER THE LUNGS. CHEMICAL BURNS MUST BE TREATED PROMPTLY BY A
PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
MAY GIVE OFF GAS, VAPOR OR DUST THAT IS VERY IRRITATING OR CORROSIVE TO THE
RESPIRATORY SYSTEM. EXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH
HAZARD. SERIOUS EFFECTS MAY BE DELAYED FOLLOWING EXPOSURE.
SKIN CONTACT: CAUSES SEVERE BURNS.
INGESTION: MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. IN A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT
EXPLOSION. GAS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE
OR EXPLOSION. BURSTING AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT
HIGH SPEED. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION. DO
NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL IGNITION SOURCES.
NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. DO NOT BREATHE VAPOR OR MIST.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT GET IN EYES OR
ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST. AVOID
BREATHING GAS. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. STORE AND USE AWAY FROM HEAT,
SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF
ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE
ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE HAZARDOUS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE AWAY FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. PROTECT FROM SUNLIGHT. STORE LOCKED
UP. ELIMINATE ALL IGNITION SOURCES. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
BUTANE NIOSH REL (UNITED STATES, 10/2013).
TWA: 800 PPM 10 HOURS.
TWA: 1900 MG/M3 10 HOURS.
ACGIH TLV (UNITED STATES, 4/2014).
STEL: 1000 PPM 15 MINUTES.
2-BUTOXYETHANOL ACGIH TLV (UNITED STATES, 4/2014).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
ABSORBED THROUGH SKIN.
TWA: 5 PPM 10 HOURS.
TWA: 24 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 8 HOURS.
TWA: 240 MG/M3 8 HOURS.
2-(2-ETHOXYETHOXY)-ETHANOL AIHA WEEL (UNITED STATES, 10/2011).
TWA: 25 PPM 8 HOURS.
PROPANE NIOSH REL (UNITED STATES, 10/2013).
TWA: 1000 PPM 10 HOURS.
TWA: 1800 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 1000 PPM 8 HOURS.
TWA: 1800 MG/M3 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. IF USER OPERATIONS GENERATE DUST,
FUMES, GAS, VAPOR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS.
IF CONTACT IS POSSIBLE, THE FOLLOWING PROTECTION SHOULD BE WORN, UNLESS
THE ASSESSMENT INDICATES A HIGHER DEGREE OF PROTECTION:
CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD. IF INHALATION HAZARDS EXIST, A
FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 13
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: -29 DEG. C (-20.2 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 0.09 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1.1%
UPPER: 23.5%
VAPOR PRESSURE: 13.5 KPA (101.325 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 1 [AIR = 1]
RELATIVE DENSITY: 0.97
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (ROOM TEMPERATURE): >0.205 CM2/S (>20.5 CST)
KINEMATIC (40 DEG. C (104 DEG. F)): >0.205 CM2/S (>20.5 CST)
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 0.000004589 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME).
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
BUTANE LC50 INHALATION RAT 658000 MG/M3 4 HOURS
VAPOR
2-BUTOXYETHANOL LCLO INHALATION GUINEA PIG >3.1 MG/L 1 HOURS
VAPOR
LD50 DERMAL GUINEA PIG >2000 MG/KG
LD50 ORAL RAT 1300 MG/KG
2-(2-ETHOXY- LD50 ORAL RAT 7500 MG/KG
ETHOXY)-ETHANOL
TETRASODIUM LD50 ORAL RAT 10 G/KG
ETHYLENE DIAMINE
TETRAACETATE
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
2-BUTOXY- EYES: RABBIT 24 HOURS
ETHANOL MODERATE 100 MILLIGRAMS
IRRITANT
EYES: RABBIT 100 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 500 MILLIGRAMS
MILD IRRITANT
2-(2-ETHOXY- EYES: RABBIT 125 MILLIGRAMS
ETHOXY)- MILD IRRITANT
ETHANOL
EYES: RABBIT 500 MILLIGRAMS
MODERATE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 500 MILLIGRAMS
TETRASODIUM EYES: RABBIT: 24 HOURS
ETHYLENE MODERATE 100 MILLIGRAMS
DIAMINE IRRITANT
TETRAACETATE
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
2-BUTOXYETHANOL 3
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
BUTANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
2-BUTOXYETHANOL CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
2-(2-ETHOXYETHOXY)- CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
ETHANOL IRRITATION AND
NARCOTIC EFFECTS
PROPANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
BUTANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
2-BUTOXYETHANOL CATEGORY 2 NOT DETERMINED NOT DETERMINED
2-(2-ETHOXYETHOXY)- CATEGORY 2 NOT DETERMINED NOT DETERMINED
ETHANOL
PROPANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
BUTANE ASPIRATION HAZARD - CATEGORY 1
PROPANE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
MAY GIVE OFF GAS, VAPOR OR DUST THAT IS VERY IRRITATING OR CORROSIVE TO THE
RESPIRATORY SYSTEM. EXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH
HAZARD. SERIOUS EFFECTS MAY BE DELAYED FOLLOWING EXPOSURE.
SKIN CONTACT: CAUSES SEVERE BURNS.
INGESTION: MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 21502.3 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
2-BUTOXYETHANOL ACUTE EC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
>1000 MG/L
FRESH WATER
ACUTE LC50: CRUSTACEANS - CRANGON 48 HOURS
800000 (MICRO)G/L CRANGON
MARINE WATER
ACUTE LC50: FISH - MENIDIA 96 HOURS
1250000 (MICRO)G/L BERYLLINA
MARINE WATER
2-(2-ETHOXY- ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
ETHOXY)-ETHANOL 3340000 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ICTALURUS 96 HOURS
6010000 (MICRO)G/L PUNCTATUS
FRESH WATER
TETRASODIUM ACUTE LC50: FISH - LEPOMIS 96 HOURS
ETHYLENE DIAMINE 486000 (MICRO)G/L MACROCHIRUS
TETRAACETATE FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
2-BUTOXYETHANOL READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
TETRASODIUM ETHYLENE DIAMINE 1.8 LOW
TETRAACETATE
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. DO NOT PUNCTURE OR INCINERATE CONTAINER.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1950 UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS AEROSOLS AEROSOLS
TRANSPORT HAZARD CLASS(ES) 2.2 2.2 2.2
NON-FLAMMABLE CLASS 2.2, CLASS 2.2,
GAS, CLASS/ NON-FLAMMABLE NON-FLAMMABLE
DIVISION 2.2 AND NON-TOXIC AND NON-TOXIC
GASES GASES
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION SPECIAL SPECIAL SPECIAL
PROVISIONS: PROVISIONS: PROVISIONS:
LIMITED LIMITED (ERG#126)
QUANTITY QUANTITY
IATA IMDG
UN NUMBER UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS, AEROSOLS
NON-FLAMMABLE
TRANSPORT HAZARD CLASS(ES) 2.2 2.2
CLASS 2.2, CLASS 2.2 -
NON-FLAMMABLE NON-FLAMMABLE GASES
AND NON-TOXIC GASES
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION SPECIAL PROVISIONS: EMERGENCY SCHEDULES
LIMITED QUANTITY (EMS):
LIMITED QUANTITY,
F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON ALL
ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
STATE REGULATIONS:
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2
FLAMMABILITY 2
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK
OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS
MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA SHEET
(SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.
DATE OF ISSUE/DATE OF REVISION: 5/22/2015.
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION.
VERSION: 1