| Common Name: | TIDE ORIGINAL PLUS BLEACH ALTERNATIVE |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 2/26/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 24L310 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
SAFETY DATA SHEET
ISSUING DATE: 26-FEB-2015
REVISION DATE: 26-FEB-2015
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT NAME: TIDE ORIGINAL PLUS BLEACH ALTERNATIVE
PRODUCT ID: 97202526_RET_NG
PRODUCT TYPE: FINISHED PRODUCT - CONSUMER (RETAIL) USE ONLY
RECOMMENDED USE: LAUNDRY CARE
RESTRICTIONS ON USE: USE ONLY AS DIRECTED ON LABEL.
SYNONYMS:
TIDE CLEAN BREEZE PLUS BLEACH ALTERNATIVE (97202527_RET_NG)
TIDE MOUNTAIN SPRINGS PLUS BLEACH ALTERNATIVE (97202528_RET_NG)
MANUFACTURER:
PROCTER & GAMBLE - FABRIC AND HOME CARE DIVISION. IVORYDALE TECHNICAL
CENTRE.
5289 SPRING GROVE AVENUE
CINCINNATI, OHIO 45217-1087
USA
E-MAIL ADDRESS: PGSDS.IM@PG.COM
EMERGENCY TELEPHONE:
TRANSPORTATION (24 HR):
CHEMTREC: 1-800-424-9300 (U.S./ CANADA) OR 1-703-527-3887
MEXICO TOLL FREE IN COUNTRY: 800-681-9531
| 2. HAZARD IDENTIFICATION | |
"CONSUMER PRODUCTS", AS DEFINED BY THE US CONSUMER PRODUCT SAFETY ACT AND
WHICH ARE USED AS INTENDED (TYPICAL CONSUMER DURATION AND FREQUENCY), ARE
EXEMPT FROM THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). THIS
SDS IS BEING PROVIDED AS A COURTESY TO HELP ASSIST IN THE SAFE HANDLING AND
PROPER USE OF THE PRODUCT.
THIS PRODUCT IS CLASSIFIED UNDER 29CFR 1910.1200(D) AND THE CANADIAN
HAZARDOUS PRODUCTS REGULATION AS FOLLOWS:
HAZARD CATEGORY:
ACUTE TOXICITY - ORAL: CATEGORY 4
EYE DAMAGE / IRRITATION: CATEGORY 2B
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES EYE IRRITATION
HARMFUL IF SWALLOWED
HAZARD PICTOGRAMS: EXCLAMATION MARK
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH HANDS THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SWALLOWED:
RINSE WITH PLENTY OF WATER
DRINK 1 OR 2 GLASSES OF WATER
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS ARE LISTED ACCORDING TO 29CFR 1910.1200 APPENDIX D AND THE
CANADIAN HAZARDOUS PRODUCTS REGULATION:
CHEMICAL NAME SYNONYMS TRADE SECRET CAS-NO WEIGHT %
POLY(OXY-1,2-ETHANEDIYL), NO 68585-34-2 10 - 15
ALPHA-SULFO-OMEGA-
HYDROXY-, C10-16-ALKYL
ETHERS, SODIUM SALTS
BENZENESULFONIC ACID, NO 68081-81-2 5 - 10
MONO-C10-16-ALKYL
DERIVS., SODIUM SALTS
PROPYLENE GLYCOL NO 57-55-6 1 - 5
ETHANOL, 2-AMINO-, NO 17863-38-6 1 - 5
2-HYDROXY-1,2,3-
PROPANETRICARBOXYLATE
(1:?)
MEA- NO 68910-32-7 1 - 5
DODECYLBENZENESULFONATE
2,2'-OXYBISETHANOL NO 111-46-6 1 - 5
ETHANOL NO 64-17-5 1 - 5
SULFURIC ACID, NO 68585-47-7 1 - 5
MONO-C10-16-ALKYL
ESTERS, SODIUM SALTS
DISODIUM TETRABORATE NO 12179-04-3 0.5 - 1.5
PENTAHYDRATE
GLYCINE, N,N-BIS[2- NO 140-01-2 0.1 - 1.0
[BIS(CARBOXYMETHYL)
AMINO]ETHYL]-,
SODIUM SALT (1:5)
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION
PERSISTS.
SKIN CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INGESTION:
RINSE MOUTH. DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. GET
MEDICAL ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NONE UNDER NORMAL USE CONDITIONS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIAL HAZARD: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
ADVICE FOR EMERGENCY RESPONDERS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED WHEN
NOT IN USE.
NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE. KEEP OUT OF THE
REACH OF CHILDREN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME CAS-NO ACGIH TLV OSHA PEL MEXICO PEL
ETHANOL 64-17-5 STEL: 1000 PPM TWA: 1000 PPM MEXICO:
TWA: 1000 PPM
TWA:
1900 MG/M3 MEXICO:
TWA:
(VACATED) TWA: 1900 MG/M3
1000 PPM
(VACATED) TWA:
1900 MG/M3
DISODIUM 12179-04-3 STEL: (VACATED) TWA: MEXICO:
TETRABORATE 6 MG/M3 10 MG/M3 TWA: 1 MG/M3
PENTAHYDRATE INHALABLE
FRACTION
TWA:
2 MG/M3
INHALABLE
FRACTION
CHEMICAL NAME CAS-NO ALBERTA QUEBEC ONTARIO BRITISH
TWAEV COLUMBIA
PROPYLENE 57-55-6 TWA:
GLYCOL 10 MG/M3
TWA:
50 PPM
TWA:
155 MG/M3
ETHANOL 64-17-5 TWA: TWA: STEL: STEL:
1000 PPM 1000 PPM 1000 PPM 1000 PPM
TWA: TWA:
1880 MG/M3 1880 MG/M3
DISODIUM 12179-04-3 TWA: TWA: TWA: TWA:
TETRABORATE 1 MG/M3 1 MG/M3 2 MG/M3 2 MG/M3
PENTAHYDRATE
STEL: 3 PPM STEL: STEL:
6 MG/M3 6 MG/M3
NO RELEVANT EXPOSURE GUIDELINES FOR OTHER INGREDIENTS
EXPOSURE CONTROLS:
ENGINEERING MEASURES:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS: ENSURE ADEQUATE VENTILATION
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
USE APPROPRIATE EYE PROTECTION
HAND PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
PROTECTIVE GLOVES
SKIN AND BODY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE @20 DEG. C: LIQUID
APPEARANCE: BLUE
ODOR: FLORAL
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES NOTE
PH VALUE 7.7 - 8.6 10% AQUEOUS SOLUTION
MELTING/FREEZING POINT NO INFORMATION
AVAILABLE
BOILING POINT/BOILING RANGE NO INFORMATION
AVAILABLE
FLASH POINT >65.5 DEG. C /
>150 DEG. F
EVAPORATION RATE NO INFORMATION
AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION
AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION
AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION
AVAILABLE
VAPOR PRESSURE NO INFORMATION
AVAILABLE
VAPOR DENSITY NO INFORMATION
AVAILABLE
RELATIVE DENSITY 1.0000 - 1.0980
WATER SOLUBILITY 100%
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION
AVAILABLE
PARTITION COEFFICIENT NO INFORMATION
N-OCTANOL/WATER AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION
AVAILABLE.
DECOMPOSITION TEMPERATURE NO INFORMATION
AVAILABLE.
VISCOSITY OF PRODUCT 100 - 1100 CPS
VOC CONTENT (%) PRODUCTS COMPLY WITH
US STATE AND FEDERAL
REGULATIONS FOR VOC
CONTENT IN CONSUMER
PRODUCTS.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
STABILITY: STABLE UNDER NORMAL CONDITIONS.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE UNDER NORMAL PROCESSING.
MATERIALS TO AVOID: NONE IN PARTICULAR.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL USE.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO KNOWN EFFECT.
SKIN CONTACT: NO KNOWN EFFECT.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
EYE CONTACT: IRRITATING TO EYES.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
ACUTE TOXICITY: MAY BE HARMFUL IF SWALLOWED.
SKIN CORROSION/IRRITATION: NO KNOWN EFFECT.
SERIOUS EYE DAMAGE/EYE IRRITATION: IRRITATING TO EYES.
SKIN SENSITIZATION: NO KNOWN EFFECT.
RESPIRATORY SENSITIZATION: NO KNOWN EFFECT.
GERM CELL MUTAGENICITY: NO KNOWN EFFECT.
NEUROLOGICAL EFFECTS: NO KNOWN EFFECT.
REPRODUCTIVE TOXICITY: NO KNOWN EFFECT.
DEVELOPMENTAL TOXICITY: NO KNOWN EFFECT.
TERATOGENICITY: NO KNOWN EFFECT.
STOT - SINGLE EXPOSURE: NO KNOWN EFFECT.
STOT - REPEATED EXPOSURE: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: NO KNOWN EFFECT.
ASPIRATION HAZARD: NO KNOWN EFFECT.
CARCINOGENICITY: NO KNOWN EFFECT.
COMPONENT INFORMATION:
CHEMICAL NAME CAS-NO LD50 ORAL LD50 DERMAL LC50
INHALATION
POLY(OXY- 68585-34-2 >2001 MG/KG
1,2-ETHANEDIYL),
ALPHA-SULFO-
OMEGA-HYDROXY-,
C10-16-ALKYL
ETHERS, SODIUM
SALTS
BENZENESULFONIC 68081-81-2 1090.00 MG/KG
ACID, MONO-C10- (RAT)
16-ALKYL
DERIVS., SODIUM
SALTS
PROPYLENE GLYCOL 57-55-6 22000 MG/KG 2000 MG/KG >317.042 MG/L
(RAT) (RABBIT) (GUIDELINE
NOT
INDICATED;
RABBIT; 2 H)
2,2'-OXYBISETHANOL 111-46-6 12000.00 MG/KG
(RAT)
GLYCINE, 140-01-2 >5000 MG/KG >2000 MG/KG
N,N-BIS[2-[BIS BW (READ BW (OECD
(CARBOXYMETHYL) ACROSS DATA 402 AND EU
AMINO]ETHYL]-, (TEST SUBSTANCE METHOD B.3;
SODIUM SALT (1:5) NAME NOT STANDARD
INDICATED); ACUTE
OECD 401; METHOD;
STANDARD ACUTE RAT)
METHOD; RAT)
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES (NON-HOUSEHOLD SETTING): 331
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
IMDG: NOT REGULATED
IATA: NOT REGULATED
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS HAZARDOUS AIR
POLLUTANTS (HAPS) UNDER SECTION 112 OF THE CLEAN AIR ACT AMENDMENTS OF
1990.
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
U.S. STATE REGULATIONS (RTK):
CHEMICAL NAME CAS-NO NEW JERSEY
PROPYLENE GLYCOL 57-55-6 X
ETHANOL 64-17-5 X
CHEMICAL NAME CAS-NO MASSACHUSETTS
ETHANOL 64-17-5 X
CHEMICAL NAME CAS-NO PENNSYLVANIA
PROPYLENE GLYCOL 57-55-6 X
2,2'-OXYBISETHANOL 111-46-6 X
ETHANOL 64-17-5 X
DISODIUM TETRABORATE PENTAHYDRATE 12179-04-3 X
INTERNATIONAL INVENTORIES:
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT(S) ARE LISTED ON THE US
TSCA INVENTORY.
CANADA: THIS PRODUCT IS IN COMPLIANCE WITH CEPA FOR IMPORT BY P&G.
LEGEND:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
CEPA - CANADIAN ENVIRONMENTAL PROTECTION ACT
| 16. OTHER INFORMATION | |
ISSUING DATE: 26-FEB-2015
REVISION DATE: 26-FEB-2015
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT