| Common Name: | COMET DEODORIZING CLEANSER WITH CHLORINOL |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 4/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G PROFESSIONAL(TM)
SAFETY DATA SHEET
ISSUING DATE: 09-JAN-2015
REVISION DATE: 07-APR-2015
VERSION: 2
| 1. IDENTIFICATION |  |
PRODUCT NAME: COMET(R*) DEODORIZING CLEANSER WITH CHLORINOL(R*)
PRODUCT CODE(S): 3-10
PRODUCT ID: 15885959_PROF_NG
PRODUCT TYPE: FINISHED PRODUCT - PROFESSIONAL USE ONLY
RECOMMENDED USE: HARD SURFACE CLEANER
RESTRICTIONS ON USE:
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED.
MANUFACTURER:
PROCTER & GAMBLE PROFESSIONAL
2 P&G PLAZA
CINCINNATI, OHIO 45202
PROCTER & GAMBLE INC.
P.O. BOX 355, STATION A
TORONTO, ON M5W 1C5
1-800-332-7787
E-MAIL ADDRESS: PGSDS.IM@PG.COM
EMERGENCY TELEPHONE:
TRANSPORTATION (24 HR):
CHEMTREC: 1-800-424-9300 (U.S./ CANADA) OR 1-703-527-3887
MEXICO TOLL FREE IN COUNTRY: 800-681-9531
| 2. HAZARD IDENTIFICATION | |
THIS PRODUCT IS CLASSIFIED UNDER 29CFR 1910.1200(D) AND THE CANADIAN
HAZARDOUS PRODUCTS REGULATION AS FOLLOWS:
HAZARD CATEGORY:
EYE DAMAGE / IRRITATION: CATEGORY 2B
SIGNAL WORD: WARNING
HAZARD STATEMENTS: CAUSES EYE IRRITATION
HAZARD PICTOGRAMS: NONE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH HANDS THOROUGHLY AFTER HANDLING
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SWALLOWED:
DRINK 1 OR 2 GLASSES OF WATER
PRECAUTIONARY STATEMENTS -STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS ARE LISTED ACCORDING TO 29CFR 1910.1200 APPENDIX D AND THE
CANADIAN HAZARDOUS PRODUCTS REGULATION:
CHEMICAL NAME SYNONYMS TRADE SECRET CAS-NO WEIGHT %
LIMESTONE NO 1317-65-3 40 - 100
SODIUM CARBONATE NO 497-19-8 5 - 10
CALCIUM HYDROXIDE NO 1305-62-0 1 - 5
(Ca(OH)2)
TROCLOSENE SODIUM, NO 51580-86-0 1 - 5
DIHYDRATE
BENZENESULFONIC ACID, NO 68081-81-2 1 - 5
MONO-C10-16-ALKYL
DERIVS., SODIUM SALTS
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION
PERSISTS.
SKIN CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INGESTION:
DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NONE UNDER NORMAL USE CONDITIONS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIAL HAZARD: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
ADVICE FOR EMERGENCY RESPONDERS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT DUST CLOUD. PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. DISPOSE OF IN
ACCORDANCE WITH LOCAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED WHEN
NOT IN USE.NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE.
KEEP OUT OF THE REACH OF CHILDREN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS:
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME CAS-NO ACGIH TLV OSHA PEL MEXICO PEL
LIMESTONE 1317-65-3 TWA: MEXICO:
15 MG/M3 TWA: 10 MG/M3
TOTAL DUST
MEXICO:
TWA: STEL: 20 MG/M3
5 MG/M3
RESPIRABLE
FRACTION
(VACATED) TWA:
15 MG/M3
TOTAL DUST
(VACATED) TWA:
5 MG/M3
RESPIRABLE
FRACTION
CALCIUM 1305-62-0 TWA: TWA: MEXICO:
HYDROXIDE 5 MG/M3 15 MG/M3 TWA: 5 MG/M3
(Ca(OH)2) TOTAL DUST
TWA:
5 MG/M3
RESPIRABLE
FRACTION
(VACATED) TWA:
5 MG/M3
NOT IN EFFECT
AS A RESULT OF
RECONSIDERATION
CHEMICAL NAME CAS-NO ALBERTA QUEBEC ONTARIO BRITISH
TWAEV COLUMBIA
LIMESTONE 1317-65-3 TWA: TWA: TWA: 10 MG/M3
10 MG/M3 10 MG/M3 TWA: 3 MG/M3
STEL: 20 MG/M3
CALCIUM 1305-62-0 TWA: TWA: TWA: TWA: 5 MG/M3
HYDROXIDE 5 MG/M3 5 MG/M3 5 MG/M3
(Ca(OH)2)
NO RELEVANT EXPOSURE GUIDELINES FOR OTHER INGREDIENTS
EXPOSURE CONTROLS:
ENGINEERING MEASURES:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS: ENSURE ADEQUATE VENTILATION
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
USE APPROPRIATE EYE PROTECTION
HAND PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
PROTECTIVE GLOVES
SKIN AND BODY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE @20 DEG. C: SOLID
APPEARANCE: WHITE
ODOR: PINE
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES NOTE
PH VALUE 12.3 (AS 1% SOLUTION)
MELTING/FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT/BOILING RANGE NO INFORMATION AVAILABLE
FLASH POINT NO INFORMATION AVAILABLE
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
RELATIVE DENSITY NO INFORMATION AVAILABLE
WATER SOLUBILITY 15%
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE.
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE.
VISCOSITY OF PRODUCT NO INFORMATION AVAILABLE
VOC CONTENT (%) PRODUCTS COMPLY WITH US
STATE AND FEDERAL
REGULATIONS FOR VOC CONTENT
IN CONSUMER PRODUCTS.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
STABILITY: STABLE UNDER NORMAL CONDITIONS.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE UNDER NORMAL PROCESSING.
MATERIALS TO AVOID:
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL USE.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO KNOWN EFFECT.
SKIN CONTACT: NO KNOWN EFFECT.
INGESTION: NO KNOWN EFFECT.
EYE CONTACT: IRRITATING TO EYES.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
ACUTE TOXICITY: NO KNOWN EFFECT.
SKIN CORROSION/IRRITATION: NO KNOWN EFFECT.
SERIOUS EYE DAMAGE/EYE IRRITATION: IRRITATING TO EYES.
SKIN SENSITIZATION: NO KNOWN EFFECT.
RESPIRATORY SENSITIZATION: NO KNOWN EFFECT.
GERM CELL MUTAGENICITY: NO KNOWN EFFECT.
NEUROLOGICAL EFFECTS: NO KNOWN EFFECT.
REPRODUCTIVE TOXICITY: NO KNOWN EFFECT.
DEVELOPMENTAL TOXICITY: NO KNOWN EFFECT.
TERATOGENICITY: NO KNOWN EFFECT.
STOT - SINGLE EXPOSURE: NO KNOWN EFFECT.
STOT - REPEATED EXPOSURE: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: NO KNOWN EFFECT.
ASPIRATION HAZARD: NO KNOWN EFFECT.
CARCINOGENICITY: NO KNOWN EFFECT.
COMPONENT INFORMATION:
CHEMICAL NAME CAS-NO LD50 ORAL LD50 DERMAL LC50
INHALATION
SODIUM 497-19-8 2800 MG/KG BW >2000 MG/KG BW
CARBONATE (GUIDELINE NOT (EPA 16 CFR
INDICATED; RAT) 1500.40; RABBIT)
CALCIUM 1305-62-0 >2000 MG/KG BW >2500 MG/KG BW
HYDROXIDE (OECD 425; RAT) (EU METHOD B.3
(Ca(OH)2) AND OECD 402;
RABBIT)
BENZENESULFONIC 68081-81-2 1090.00 MG/KG
ACID, (RAT)
MONO-C10-16-
ALKYL DERIVS.,
SODIUM SALTS
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES (NON-HOUSEHOLD SETTING): 331
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
IMDG: NOT REGULATED
IATA: NOT REGULATED
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS HAZARDOUS AIR
POLLUTANTS (HAPS) UNDER SECTION 112 OF THE CLEAN AIR ACT AMENDMENTS
OF 1990.
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
U.S. STATE REGULATIONS (RTK):
CHEMICAL NAME CAS-NO NEW JERSEY
LIMESTONE 1317-65-3 X
CALCIUM HYDROXIDE (Ca(OH)2) 1305-62-0 X
TROCLOSENE SODIUM, DIHYDRATE 51580-86-0 X
CHEMICAL NAME CAS-NO MASSACHUSETTS
LIMESTONE 1317-65-3 X
CALCIUM HYDROXIDE (Ca(OH)2) 1305-62-0 X
TROCLOSENE SODIUM, DIHYDRATE 51580-86-0 X
CHEMICAL NAME CAS-NO PENNSYLVANIA
LIMESTONE 1317-65-3 X
CALCIUM HYDROXIDE (Ca(OH)2) 1305-62-0 X
TROCLOSENE SODIUM, DIHYDRATE 51580-86-0 X
INTERNATIONAL INVENTORIES:
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT(S) ARE LISTED ON THE US
TSCA INVENTORY.
CANADA: THIS PRODUCT IS IN COMPLIANCE WITH CEPA FOR IMPORT BY P&G.
LEGEND:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
CEPA - CANADIAN ENVIRONMENTAL PROTECTION ACT
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH HAZARD 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH HAZARD 2
FLAMMABILITY 0
INSTABILITY 0
ISSUING DATE: 09-JAN-2015
REVISION DATE: 07-APR-2015
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT