| Common Name: | ZEREX HD NITRITE FREE EXTENDED LIFE RTU ANTIFREEZE COOLANT |
| Manufacturer: | ASHLAND CHEMICAL |
| SDS Revision Date: | 5/22/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 46KK36, 46KK37, 46KK38, 46KK39 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
ASHLAND(R*)
SAFETY DATA SHEET
REVISION DATE: 05/22/2015
PRINT DATE: 1/4/2016
SDS NUMBER: 000000248245
VERSION: 1.0
ZEREX(TM) HD NITRITE FREE EXTENDED LIFE RTU ANTIFREEZE COOLANT
(TM) TRADEMARK, ASHLAND OR ITS SUBSIDIARIES, REGISTERED IN VARIOUS
COUNTRIES
846438
29 CFR 1910.1200 (OSHA HAZCOM 2012)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: ZEREX(TM) HD NITRITE FREE EXTENDED LIFE RTU ANTIFREEZE COOLANT
(TM) TRADEMARK, ASHLAND OR ITS SUBSIDIARIES, REGISTERED IN VARIOUS
COUNTRIES
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
ASHLAND
P.O. BOX 2219
COLUMBUS, OH 43216
UNITED STATES OF AMERICA
EHS CUSTOMER REQUESTS@ASHLAND.COM
EMERGENCY TELEPHONE NUMBER: 1-800-ASHLAND (1-800-274-5263)
REGULATORY INFORMATION NUMBER: 1-800-325-3751
PRODUCT INFORMATION: 614-790-3333
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - REPEATED EXPOSURE (ORAL):
CATEGORY 2 (KIDNEY, LIVER)
GHS LABEL ELEMENT:
HAZARD PICTOGRAMS: HEALTH HAZARD
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
MAY CAUSE DAMAGE TO ORGANS (KIDNEY, LIVER) THROUGH PROLONGED OR REPEATED
EXPOSURE IF SWALLOWED.
PRECAUTIONARY STATEMENTS:
PREVENTION: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
RESPONSE: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%)
ETHYLENE GLYCOL 107-21-1 ACUTE TOX. 4; H302 46.53
STOT RE 2; H373
DIETHYLENE GLYCOL 111-46-6 ACUTE TOX. 4; H302 2.32
STOT RE 2; H373
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
CALL A POISON CENTRE OR DOCTOR/PHYSICIAN IF EXPOSED OR YOU FEEL UNWELL.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR.
IF UNCONSCIOUS PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
FIRST AID IS NOT NORMALLY REQUIRED. HOWEVER, IT IS RECOMMENDED THAT EXPOSED
AREAS BE CLEANED BY WASHING WITH SOAP AND WATER.
IN CASE OF EYE CONTACT:
FLUSH EYES WITH WATER AS A PRECAUTION.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
OBTAIN MEDICAL ATTENTION.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
EFFECTS OF ACUTE ETHYLENE GLYCOL POISONING APPEAR IN THREE FAIRLY DISTINCT
STAGES. THE INITIAL STAGE OCCURS SHORTLY AFTER EXPOSURE, LASTS 6-12 HOURS,
AND IS CHARACTERIZED BY CENTRAL NERVOUS SYSTEM EFFECTS (TRANSIENT
EXHILARATION, NAUSEA, VOMITING, AND IN SEVERE CASES, COMA, CONVULSIONS, AND
POSSIBLE DEATH). THE SECOND STAGE LASTS FROM 12-36 HOURS AFTER EXPOSURE AND
IS INITIATED BY THE ONSET OF COMA. THIS PHASE IS CHARACTERIZED BY
TACHYPNIA, TACHYCARDIA, MILD HYPOTENSION, CYANOSIS, AND IN SEVERE CASES,
PULMONARY EDEMA, BRONCHOPNEUMONIA, CARDIAC ENLARGEMENT, AND CONGESTIVE
FAILURE. THE FINAL STAGE OCCURS 24-72 POST-EXPOSURE AND IS CHARACTERIZED BY
RENAL FAILURE, RANGING FROM A MILD INCREASE IN BLOOD UREA NITROGEN AND
CREATININE FOLLOWED BY RECOVERY, TO COMPLETE ANURIA WITH ACUTE TUBULAR
NECROSIS THAT CAN LEAD TO DEATH. OXALURIA IS FOUND IN MOST CASES. THE MOST
SIGNIFICANT LABORATORY FINDING IN ETHYLENE GLYCOL INTOXICATION IS SEVERE
METABOLIC ACIDOSIS.
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA) IRRITATION (NOSE,
THROAT, AIRWAYS) COUGH PAIN IN THE ABDOMEN AND LOWER BACK CYANOSIS (CAUSES
BLUE COLORING OF THE SKIN AND NAILS FROM LACK OF OXYGEN) LUNG EDEMA (FLUID
BUILDUP IN THE LUNG TISSUE) ACUTE KIDNEY FAILURE (SUDDEN SLOWING OR
STOPPING OF URINE PRODUCTION) CONVULSIONS MAY CAUSE DAMAGE TO ORGANS
THROUGH PROLONGED OR REPEATED EXPOSURE IF SWALLOWED.
NOTES TO PHYSICIAN:
THIS PRODUCT CONTAINS ETHYLENE GLYCOL. ETHANOL DECREASES THE METABOLISM OF
ETHYLENE GLYCOL TO TOXIC METABOLITES. ETHANOL SHOULD BE ADMINISTERED AS
SOON AS POSSIBLE IN CASES OF SEVERE POISONING SINCE THE ELIMINATION
HALF-LIFE OF ETHYLENE GLYCOL IS 3 HOURS. IF MEDICAL CARE WILL BE DELAYED
SEVERAL HOURS, GIVE THE PATIENT THREE TO FOUR 1-OUNCE ORAL "SHOTS" OF
86-PROOF OR HIGHER WHISKEY BEFORE OR DURING TRANSPORT TO THE HOSPITAL.
FOMEPIZOLE (4-METHYLPYRAZOLE) IS AN EFFECTIVE ANTAGONIST OF ALCOHOL
DEHYDROGENASE, AND AS SUCH, MAY BE USED AS AN ANTIDOTE IN THE TREATMENT OF
ETHYLENE GLYCOL POISONING. HEMODIALYSIS EFFECTIVELY REMOVES ETHYLENE GLYCOL
AND ITS METABOLITES FROM THE BODY.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
WATER SPRAY
FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
ALCOHOLS
ALDEHYDES
CARBON DIOXIDE AND CARBON MONOXIDE
ETHERS
TOXIC FUMES
SODIUM OXIDES
HYDROCARBONS
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION: STANDARD PROCEDURE FOR CHEMICAL FIRES.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
OTHER INFORMATION:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
CONTAINER HAZARDOUS WHEN EMPTY.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
ELECTRICAL INSTALLATIONS / WORKING MATERIALS MUST COMPLY WITH THE
TECHNOLOGICAL SAFETY STANDARDS.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
ETHYLENE GLYCOL 107-21-1 CEILING 100 MG/M3 ACGIH
AEROSOL.
TWA 10 MG/M3 ACGIHLIS_P
INHALABLE
FRACTION AND
VAPOR
DIETHYLENE 111-46-6 TWA 10 MG/M3 WEEL
GLYCOL
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS
THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
HAND PROTECTION:
REMARKS:
THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE
PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. WEAR SPLASH-PROOF SAFETY
GOGGLES IF MATERIAL COULD BE MISTED OR SPLASHED INTO EYES.
SKIN AND BODY PROTECTION:
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
SAFETY SHOES
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER).
HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
WHEN USING DO NOT EAT OR DRINK.
WHEN USING DO NOT SMOKE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
ODOUR: NO DATA AVAILABLE
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 9.0
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE: NO DATA AVAILABLE
FLASH POINT: >250 DEG. F / >121 DEG. C
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: 1.076 G/CM3 (15.6 DEG. C)
SOLUBILITY(IES):
WATER SOLUBILITY: SOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
CONDITIONS TO AVOID: EXCESSIVE HEAT
INCOMPATIBLE MATERIALS:
ACIDS
ALDEHYDES
ALKALI METALS
ALKALINE EARTH METALS
BASES
STRONG ALKALIS
STRONG OXIDIZING AGENTS
SULPHUR COMPOUNDS
HAZARDOUS DECOMPOSITION PRODUCTS:
ALCOHOLS
ALDEHYDES
CARBON DIOXIDE AND CARBON MONOXIDE
ETHERS
HYDROCARBONS
ORGANIC ACIDS
KETONES
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
EYE CONTACT
INGESTION
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ACUTE ORAL TOXICITY:
REMARKS:
INGESTION OF MEDICATIONS CONTAMINATED WITH DIETHYLENE GLYCOL HAS CAUSED
KIDNEY FAILURE AND DEATH IN HUMANS. PRODUCTS CONTAINING DIETHYLENE GLYCOL
SHOULD BE CONSIDERED TOXIC BY INGESTION.
ACUTE DERMAL TOXICITY:
REMARKS:
SKIN ABSORPTION OF THIS MATERIAL (OR A COMPONENT) MAY BE INCREASED THROUGH
INJURED SKIN.
COMPONENTS:
ETHYLENE GLYCOL:
ACUTE ORAL TOXICITY:
LD50 (RAT): 6,140 MG/KG
LD50 (HUMAN): ESTIMATED 1.56 G/KG
ASSESSMENT:
THE COMPONENT/MIXTURE IS CLASSIFIED AS ACUTE ORAL TOXICITY, CATEGORY 4.
ACUTE INHALATION TOXICITY:
LC50 (RAT): 10.9 MG/L
EXPOSURE TIME: 1 H
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE INHALATION TOXICITY TESTS.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 9,530 MG/KG
DIETHYLENE GLYCOL:
ACUTE ORAL TOXICITY:
LD50 (HUMAN): EXPECTED 1,120 MG/KG
TARGET ORGANS: KIDNEY
ACUTE INHALATION TOXICITY:
LC50 (RAT): >4.6 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE INHALATION TOXICITY TESTS.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 13,300 MG/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENE GLYCOL:
RESULT: MILDLY IRRITATING TO SKIN
DIETHYLENE GLYCOL:
SPECIES: HUMAN
RESULT: SLIGHTLY IRRITATING TO SKIN
SERIOUS EYE DAMAGE/EYE IRRITATION:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
REMARKS: UNLIKELY TO CAUSE EYE IRRITATION OR INJURY.
COMPONENTS:
ETHYLENE GLYCOL:
RESULT: POSSIBLY IRRITATING TO EYES
DIETHYLENE GLYCOL:
SPECIES: RABBIT
RESULT: SLIGHTLY IRRITATING TO EYES
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
DIETHYLENE GLYCOL:
TEST TYPE: MAXIMIZATION TEST (GPMT)
SPECIES: GUINEA PIG
METHOD: DIRECTIVE 67/548/EEC, ANNEX V, B.6.
RESULT: DID NOT CAUSE SENSITIZATION ON LABORATORY ANIMALS.
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
DIETHYLENE GLYCOL:
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
GLP: YES
TEST SPECIES: CHINESE HAMSTER OVARY CELLS
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 479
RESULT: NEGATIVE
GLP: YES
GENOTOXICITY IN VIVO:
TEST TYPE: IN VIVO MICRONUCLEUS TEST
TEST SPECIES: MOUSE
METHOD: OECD TEST GUIDELINE 474
RESULT: NEGATIVE
GLP: YES
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (KIDNEY, LIVER) THROUGH PROLONGED OR REPEATED
EXPOSURE IF SWALLOWED.
COMPONENTS:
ETHYLENE GLYCOL:
EXPOSURE ROUTES: INGESTION
TARGET ORGANS: KIDNEY, LIVER
ASSESSMENT:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
DIETHYLENE GLYCOL:
EXPOSURE ROUTES: INGESTION
TARGET ORGANS: KIDNEY
ASSESSMENT:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
EXPERIENCE WITH HUMAN EXPOSURE:
COMPONENTS:
DIETHYLENE GLYCOL: LIVER
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
COMPONENTS:
ETHYLENE GLYCOL:
TOXICITY TO FISH:
LC50 (BLUEGILL (LEPOMIS MACROCHIRUS)): 27,540 MG/L
EXPOSURE TIME: 96 H
METHOD: STATIC
REMARKS: MORTALITY
LC50 (FATHEAD MINNOW (PIMEPHALES PROMELAS)): 8,050 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
LC50 (WATER FLEA (DAPHNIA MAGNA)): >10,000 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
DIETHYLENE GLYCOL:
TOXICITY TO FISH:
LC50 (FATHEAD MINNOW (PIMEPHALES PROMELAS)): 75,210 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: FLOW-THROUGH TEST
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
LC50 (WATER FLEA (DAPHNIA MAGNA)): >10,000 MG/L
EXPOSURE TIME: 24 H
TEST TYPE: STATIC TEST
METHOD: DIN 38412
PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
DIETHYLENE GLYCOL:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE
BIODEGRADATION: 70 - 80%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301B
BIOACCUMULATIVE POTENTIAL:
COMPONENTS:
ETHYLENE GLYCOL:
BIOACCUMULATION:
SPECIES: CRAYFISH (PROCAMBARUS)
BIOCONCENTRATION FACTOR (BCF): 0.27
EXPOSURE TIME: 61 D
CONCENTRATION: 1000 MG/L
METHOD: FLOW THROUGH
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: -1.36
DIETHYLENE GLYCOL:
BIOACCUMULATION:
SPECIES: LEUCISCUS IDUS (GOLDEN ORFE)
BIOCONCENTRATION FACTOR (BCF): 100
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: -1.47
MOBILITY IN SOIL:
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE
COMPONENTS:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
GENERAL ADVICE:
DO NOT DISPOSE OF WASTE INTO SEWER.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
SEND TO A LICENSED WASTE MANAGEMENT COMPANY.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATION:
ID NUMBER PROPER SHIPPING *HAZARD SUBSIDIARY PACKING MARINE POLLUTANT
NAME CLASS HAZARDS GROUP / LTD. QTY.
U.S. DOT - ROAD: NOT DANGEROUS GOODS
U.S. DOT - RAIL: NOT DANGEROUS GOODS
U.S. DOT - INLAND WATERWAYS: NOT DANGEROUS GOODS
TRANSPORT CANADA - ROAD: NOT DANGEROUS GOODS
TRANSPORT CANADA - RAIL: NOT DANGEROUS GOODS
TRANSPORT CANADA - INLAND WATERWAYS: NOT DANGEROUS GOODS
INTERNATIONAL MARITIME DANGEROUS GOODS: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: NOT DANGEROUS GOODS
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES: NOT DANGEROUS GOODS
*ORM = ORM-D
CBL = COMBUSTIBLE LIQUID
MARINE POLLUTANT: NO
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY,
END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING
DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ (LBS)
ETHYLENE GLYCOL 107-21-1 5000 10744.25451
SARA 311/312 HAZARDS: CHRONIC HEALTH HAZARD
SARA 313 COMPONENT(S):
ETHYLENE GLYCOL 107-21-1 46.53%
PENNSYLVANIA RIGHT TO KNOW:
WATER 7732-18-5 50.00 - 70.00%
ETHYLENE GLYCOL 107-21-1 30.00 - 50.00%
DIETHYLENE GLYCOL 111-46-6 1.00 - 5.00%
NEW JERSEY RIGHT TO KNOW:
WATER 7732-18-5 50.00 - 70.00%
ETHYLENE GLYCOL 107-21-1 30.00 - 50.00%
DECANEDIOIC ACID, DISODIUM SALT 17265-14-4 1.00 - 5.00%
DIETHYLENE GLYCOL 111-46-6 1.00 - 5.00%
CALIFORNIA PROP 65:
PROPOSITION 65 WARNINGS ARE NOT REQUIRED FOR THIS PRODUCT BASED ON THE
RESULTS OF A RISK ASSESSMENT.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA: ON TSCA INVENTORY
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL.
AUSTR: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
ENCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
KECL: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION), ENCS
(JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
REVISION DATE: 05/22/2015
NFPA:
HEALTH 1
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT,
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION:
COMBUSTIBLE LIQUID CLASS IIIB
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.:
H302: HARMFUL IF SWALLOWED.
H373:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
SWALLOWED.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET
ASHLAND INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS
THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONIZED
CLASSIFICATION FOR LABELING (GHS) AND TRANSPORT.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE
ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN PREPARED
BY ASHLAND'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT (1-800-325-3751).
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE,
USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT ASSOCIATION"
(IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT , BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM