| Common Name: | RAID WASP & HORNET KILLER 33 |
| Manufacturer: | S.C. JOHNSON |
| SDS Revision Date: | 2/23/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 392C77, 4HK60 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SC JOHNSON
A FAMILY COMPANY
SAFETY DATA SHEET
ACCORDING TO HAZARD COMMUNICATION STANDARD; 29 CFR 1910.1200
RAID(R*) WASP & HORNET KILLER 33
VERSION: 1.1
PRINT DATE: 03/04/2015
REVISION DATE: 02/23/2015
SDS NUMBER: 350000010778
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT INFORMATION:
PRODUCT NAME: RAID(R*) WASP & HORNET KILLER 33
RECOMMENDED USE: INSECTICIDE
MANUFACTURER, IMPORTER, SUPPLIER:
S.C. JOHNSON & SON, INC.
1525 HOWE STREET
RACINE WI 53403-2236
TELEPHONE: +18005585252
EMERGENCY TELEPHONE NUMBER:
24 HOUR MEDICAL EMERGENCY PHONE: (866) 231-5406
24 HOUR INTERNATIONAL EMERGENCY PHONE: (703) 527-3887
24 HOUR TRANSPORT EMERGENCY PHONE: (800) 424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GLOBALLY HARMONIZED SYSTEM (GHS) CLASSIFICATION:
HAZARD CLASSIFICATION HAZARD CATEGORY HAZARDS IDENTIFICATION
AEROSOL CATEGORY 1 EXTREMELY FLAMMABLE AEROSOL.
ASPIRATION HAZARD CATEGORY 1 MAY BE FATAL IF SWALLOWED AND
ENTERS AIRWAYS.
GASES UNDER PRESSURE COMPRESSED GAS CONTAINS GAS UNDER PRESSURE;
MAY EXPLODE IF HEATED.
LABELLING:
HAZARD SYMBOLS:
FLAME
GAS CYLINDER
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
PRECAUTIONARY STATEMENTS:
IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
KEEP OUT OF REACH OF CHILDREN.
READ LABEL BEFORE USE.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
DO NOT INDUCE VOMITING.
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSE OF CONTENTS / CONTAINER TO AN APPROVED INCINERATION PLANT.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
DO NOT PIERCE OR BURN, EVEN AFTER USE.
OTHER HAZARDS: NONE IDENTIFIED
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WEIGHT PERCENT
DISTILLATES (PETROLEUM), HYDROTREATED 64742-47-8 60.00 - 100.00
LIGHT
CARBON DIOXIDE 124-38-9 1.00 - 5.00
ISOPROPANOL 67-63-0 1.00 - 5.00
CYPERMETHRIN 52315-07-8 0.0001 - 0.10
PRALLETHRIN 23031-36-9 0.0001 - 0.10
THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
FOR ADDITIONAL INFORMATION ON PRODUCT INGREDIENTS, SEE
WWW.WHATSINSIDESCJOHNSON.COM.
| 4. FIRST AID MEASURES | |
EYE CONTACT: NO SPECIAL REQUIREMENTS
SKIN CONTACT: NO SPECIAL REQUIREMENTS
INHALATION: NO SPECIAL REQUIREMENTS.
INGESTION:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. DO NOT INDUCE
VOMITING.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE. AEROSOL
PRODUCT - CONTAINERS MAY ROCKET OR EXPLODE IN HEAT OF FIRE. DO NOT ALLOW
RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
FURTHER INFORMATION:
FIGHT FIRE FROM MAXIMUM DISTANCE OR PROTECTED AREA. COOL AND USE CAUTION
WHEN APPROACHING OR HANDLING FIRE-EXPOSED CONTAINERS. WEAR FULL PROTECTIVE
CLOTHING AND POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CASE
OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
NFPA CLASSIFICATION: NFPA LEVEL 3 AEROSOL
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION.
WEAR PERSONAL PROTECTIVE EQUIPMENT.
WASH THOROUGHLY AFTER HANDLING.
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
OUTSIDE OF NORMAL USE, AVOID RELEASE TO THE ENVIRONMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
IF DAMAGE OCCURS TO AEROSOL CAN:
CONTAIN SPILLAGE, SOAK UP WITH NON-COMBUSTIBLE ABSORBENT MATERIAL, (E.G.
SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND TRANSFER TO A CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
USE ONLY NON-SPARKING EQUIPMENT.
DIKE LARGE SPILLS.
CLEAN RESIDUE FROM SPILL SITE.
| 7. HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
DO NOT ENTER PLACES WHERE USED OR STORED UNTIL ADEQUATELY VENTILATED.
FOR PERSONAL PROTECTION SEE SECTION 8.
USE ONLY AS DIRECTED.
KEEP OUT OF REACH OF CHILDREN AND PETS.
PRESSURIZED CONTAINER.
DO NOT PIERCE OR BURN, EVEN AFTER USE.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
STORAGE:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
KEEP IN A DRY, COOL AND WELL-VENTILATED PLACE.
STORE LOCKED UP.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. MG/M3 PPM NON- BASIS
STANDARD
UNITS
DISTILLATES 64742-47-8 1,200 MG/M3 152 PPM SUPPLIER
(PETROLEUM),
HYDROTREATED
LIGHT
CARBON DIOXIDE 124-38-9 9,000 MG/M3 5,000 PPM OSHA TWA
CARBON DIOXIDE 124-38-9 30,000 PPM ACGIH
STEL
CARBON DIOXIDE 124-38-9 5,000 PPM ACGIH
TWA
ISOPROPANOL 67-63-0 980 MG/M3 400 PPM OSHA TWA
ISOPROPANOL 67-63-0 400 PPM ACGIH
STEL
ISOPROPANOL 67-63-0 200 PPM ACGIH
TWA
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION: DO NOT SPRAY IN ENCLOSED AREAS.
HAND PROTECTION: NO SPECIAL REQUIREMENTS.
EYE PROTECTION: NO SPECIAL REQUIREMENTS.
SKIN AND BODY PROTECTION: NO SPECIAL REQUIREMENTS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WASH THOROUGHLY AFTER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM: AEROSOL
FORM: COMPRESSED GAS
COLOR: CLEAR
ODOR: CHARACTERISTIC
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
FLASH POINT:
22 DEG. C
71.6 DEG. F
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): SUSTAINS COMBUSTION
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY:
0.81 G/CM3 AT 21 DEG. CGLP: YES
SOLUBILITY(IES): NEGLIGIBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS TOTAL VOC (WT.%)*:
3 % - ADDITIONAL EXEMPTIONS MAY APPLY
*AS DEFINED BY US FEDERAL AND STATE CONSUMER PRODUCT REGULATIONS
OTHER INFORMATION: NONE IDENTIFIED
| 10. STABILITY AND REACTIVITY | |
POSSIBILITY OF HAZARDOUS REACTIONS:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPOURS.
| 11. TOXICOLOGICAL INFORMATION | |
EMERGENCY OVERVIEW: DANGER
ACUTE ORAL TOXICITY:
NA GHS LD50 ESTIMATED: >5,000 MG/KG
ACUTE INHALATION TOXICITY:
NA GHS LC50 (DUST AND MIST) ESTIMATED: >5.47 MG/L
ACUTE DERMAL TOXICITY:
NA GHS LD50 ESTIMATED: >5,000 MG/KG
GHS PROPERTIES CLASSIFICATION ROUTES OF ENTRY
ACUTE TOXICITY NO CLASSIFICATION PROPOSED
SKIN CORROSION/IRRITATION NO CLASSIFICATION PROPOSED
SERIOUS EYE NO CLASSIFICATION PROPOSED
DAMAGE/EYE IRRITATION
SKIN SENSITISATION NO CLASSIFICATION PROPOSED
RESPIRATORY SENSITISATION NO CLASSIFICATION PROPOSED
GERM CELL MUTAGENICITY NO CLASSIFICATION PROPOSED
CARCINOGENICITY NO CLASSIFICATION PROPOSED
REPRODUCTIVE TOXICITY NO CLASSIFICATION PROPOSED
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - SINGLE
EXPOSURE
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - REPEATED
EXPOSURE
ASPIRATION HAZARD CATEGORY 1
AGGRAVATED MEDICAL CONDITION: NONE KNOWN.
| 12. ECOLOGICAL INFORMATION | |
PRODUCT: THE PRODUCT ITSELF HAS NOT BEEN TESTED.
TOXICITY:
THE INGREDIENTS IN THIS FORMULA HAVE BEEN REVIEWED AND NO ADVERSE IMPACT
TO THE ENVIRONMENT IS EXPECTED WHEN USED ACCORDING TO LABEL DIRECTIONS.
TOXICITY TO FISH:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
DISTILLATES (PETROLEUM), STATIC TEST LEPOMIS 2.2 MG/L 96 H
HYDROTREATED LIGHT LC50 MACROCHIRUS
CARBON DIOXIDE NO DATA
AVAILABLE
ISOPROPANOL LC50 PIMEPHALES 9,640 MG/L 96 H
PROMELAS
(FATHEAD
MINNOW)
CYPERMETHRIN LC50 ONCORHYNCHUS 0.00283 MG/L 96 H
MYKISS
(RAINBOW
TROUT)
NOEC PIMEPHALES 0.00001 MG/L 28 D
PROMELAS
(FATHEAD
MINNOW)
PRALLETHRIN LC50 ONCORHYNCHUS 0.012 MG/L 96 H
MYKISS
(RAINBOW
TROUT)
TOXICITY TO AQUATIC INVERTEBRATES:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
DISTILLATES (PETROLEUM), NO DATA
HYDROTREATED LIGHT AVAILABLE
CARBON DIOXIDE NO DATA
AVAILABLE
ISOPROPANOL EC50 DAPHNIA MAGNA 13,299 MG/L 48 H
(WATER FLEA)
CYPERMETHRIN EC50 DAPHNIA MAGNA 0.00471 48 H
(WATER FLEA) MG/L
NOEC DAPHNIA MAGNA 0.00004 21 D
(WATER FLEA) MG/L
PRALLETHRIN EC50 DAPHNIA MAGNA 0.0062 48 H
(WATER FLEA) MG/L
TOXICITY TO AQUATIC PLANTS:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
DISTILLATES (PETROLEUM), NO DATA
HYDROTREATED LIGHT AVAILABLE
CARBON DIOXIDE NO DATA
AVAILABLE
ISOPROPANOL EC50 DESMODESMUS >1,000 MG/L 72 H
SUBSPICATUS
(GREEN ALGAE)
CYPERMETHRIN ERC50 >0.0033 72 H
NO DATA MG/L
AVAILABLE
PRALLETHRIN NO DATA PSEUDOKIRCH- 2 MG/L 96 H
AVAILABLE NERIELLA
SUBCAPITATA
(GREEN ALGAE)
PERSISTENCE AND DEGRADABILITY:
COMPONENT BIODEGRADATION EXPOSURE TIME SUMMARY
DISTILLATES (PETROLEUM), NO DATA AVAILABLE
HYDROTREATED LIGHT
CARBON DIOXIDE NO DATA AVAILABLE
ISOPROPANOL 53 % 5 D READILY
BIODEGRADABLE
CYPERMETHRIN 0.6 - 1.4 % 33 D NOT READILY
BIODEGRADABLE.
PRALLETHRIN NO DATA AVAILABLE NOT READILY
BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
COMPONENT BIOCONCENTRATION PARTITION COEFFICIENT
FACTOR (BCF) N-OCTANOL/WATER (LOG)
DISTILLATES (PETROLEUM), 61 - 159 NO DATA AVAILABLE
HYDROTREATED LIGHT
CARBON DIOXIDE NO DATA AVAILABLE NO DATA AVAILABLE
ISOPROPANOL 0.96 ESTIMATED 0.05
CYPERMETHRIN 373.4 MEASURED 5.3 - 5.6
PRALLETHRIN NO DATA AVAILABLE 4.49
MOBILITY:
COMPONENT END POINT VALUE
DISTILLATES (PETROLEUM), NO DATA AVAILABLE
HYDROTREATED LIGHT
CARBON DIOXIDE NO DATA AVAILABLE
ISOPROPANOL NO DATA AVAILABLE
CYPERMETHRIN KOC 80653 - 574360
PRALLETHRIN NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT:
COMPONENT RESULTS
DISTILLATES (PETROLEUM), NOT FULFILLING PBT AND VPVB CRITERIA
HYDROTREATED LIGHT
ISOPROPANOL NOT FULFILLING PBT AND VPVB CRITERIA
CYPERMETHRIN NOT FULFILLING PBT AND VPVB CRITERIA
PRALLETHRIN NOT FULFILLING PBT AND VPVB CRITERIA
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
PESTICIDAL WASTE:
FOR DISPOSAL INFORMATION, PLEASE READ AND FOLLOW DISPOSAL INSTRUCTIONS ON
THE PESTICIDE LABEL.
CONSUMER MAY DISCARD EMPTY CONTAINER IN TRASH, OR RECYCLE WHERE FACILITIES
EXIST.
| 14. TRANSPORT INFORMATION | |
PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP-TO-DATE
SHIPPING INFORMATION.
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT
UN NUMBER 1950 1950 1950
UN PROPER SHIPPING AEROSOLS, AEROSOLS, AEROSOLS,
NAME FLAMMABLE, 2.1 FLAMMABLE, 2.1 FLAMMABLE, 2.1
TRANSPORT HAZARD 2.1 2 2.1
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL
HAZARDS
SPECIAL LIMITED LIMITED LIMITED
PRECAUTIONS FOR QUANTITIES QUANTITIES QUANTITIES
USER DEROGATION MAY DEROGATION MAY DEROGATION MAY
BE APPLICABLE TO BE APPLICABLE BE APPLICABLE
THIS PRODUCT, TO THIS PRODUCT, TO THIS PRODUCT,
PLEASE CHECK PLEASE CHECK PLEASE CHECK
TRANSPORT TRANSPORT TRANSPORT
DOCUMENTS. DOCUMENTS. DOCUMENTS.
| 15. REGULATORY INFORMATION | |
FIFRA LABELING:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS, AND FOR
WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS.
FOLLOWING IS THE HAZARD INFORMATION AS REQUIRED ON THE PESTICIDE LABEL:
CAUTION:
EXTREMELY FLAMMABLE.
CONTENTS UNDER PRESSURE.
EXPOSURE TO TEMPERATURES ABOVE 130 DEG. F MAY CAUSE BURSTING.
THIS PRODUCT IS EXTREMELY TOXIC TO FISH AND AQUATIC INVERTEBRATES.
DRIFT AND RUNOFF MAY BE HAZARDOUS TO FISH IN WATER ADJACENT TO TREATED
AREAS.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA
TO CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE HARM.
REGISTRATION # / AGENCY: 4822-553/US/EPA
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
NFPA RATINGS:
HEALTH 2
FIRE 3
REACTIVITY 0
SPECIAL
THIS INFORMATION IS BEING PROVIDED IN ACCORDANCE WITH THE OCCUPATIONAL
SAFETY AND HEALTH ADMINISTRATION (OSHA) REGULATION (29 CFR 1910.1200). THE
INFORMATION SUPPLIED IS DESIGNED FOR WORKPLACES WHERE PRODUCT USE AND
FREQUENCY OF EXPOSURE EXCEEDS THAT ESTABLISHED FOR THE LABELED CONSUMER
USE.
FURTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TO BE
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESSED OR
IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED HEREIN. ACTUAL
CONDITIONS OF USE ARE BEYOND THE SELLER'S CONTROL. USER IS RESPONSIBLE TO
EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR
USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND
REGULATIONS.
PREPARED BY:
SC JOHNSON GLOBAL SAFETY ASSESSMENT & REGULATORY AFFAIRS (GSARA)