| Common Name: | SCRUBS NATURAL FORCE CITRUS DEGREASER TOWELS |
| Manufacturer: | ITW PRO BRANDS |
| SDS Revision Date: | 1/11/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 48KT03, 48KT04 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ITW PRO BRANDS
SAFETY DATA SHEET
ISSUING DATE: 25-FEB-2014
REVISION DATE: 11-JAN-2016
REVISION NUMBER: 2
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND THE COMPANY/UNDERTAKING
GHS PRODUCT IDENTIFIER:
PRODUCT NAME: SCRUBS(R*) NATURAL FORCE(R*) CITRUS DEGREASER TOWELS
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE(S): 90630, 90656
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: DEGREASER
USES ADVISED AGAINST: NONE REASONABLY FORESEEABLE
SUPPLIER'S DETAILS:
SUPPLIER ADDRESS:
ITW PRO BRANDS
805 E. OLD 56 HIGHWAY
OLATHE, KS 66061
TEL: 1-800-443-9536
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE NUMBER: 800-535-5053 INFOTRAC
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE OSHA HAZARD
COMMUNICATION STANDARD 2012 (29 CFR 1910.1200)
SKIN SENSITIZATION: CATEGORY 1
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: WARNING
HAZARD STATEMENTS: MAY CAUSE AN ALLERGIC SKIN REACTION
EXCLAMATION MARK
APPEARANCE: COLORLESS TO LIGHT YELLOW
PHYSICAL STATE: LIQUID.
ODOR: ORANGE
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES.
GENERAL ADVICE:
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL)
SKIN:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: NONE
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
8.69591% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO WEIGHT % TRADE SECRET
ALCOHOLS, ETHOXYLATED 68439-46-3 5-10 *
D-LIMONENE 5989-27-5 0.1-1 *
THE SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET. *THE EXACT PERCENTAGE (CONCENTRATION) OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST-AID MEASURES:
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF IRRITATION PERSISTS, CALL A PHYSICIAN.
SKIN CONTACT:
MAY CAUSE AN ALLERGIC SKIN REACTION. WASH OFF IMMEDIATELY WITH SOAP AND
PLENTY OF WATER REMOVING ALL CONTAMINATED CLOTHES AND SHOES. IN THE CASE
OF SKIN IRRITATION OR ALLERGIC REACTIONS SEE A PHYSICIAN.
INHALATION:
NOT AN EXPECTED ROUTE OF EXPOSURE. IN CASE OF OVEREXPOSURE: MOVE TO FRESH
AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
INGESTION:
NOT AN EXPECTED ROUTE OF EXPOSURE. IF SWALLOWED: DO NOT INDUCE VOMITING
WITHOUT MEDICAL ADVICE. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS/EFFECTS: MAY CAUSE ALLERGIC SKIN REACTION.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA: NONE
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NO INFORMATION AVAILABLE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
USE WATER SPRAY TO COOL SURROUNDING CONTAINERS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS. AVOID
RELEASE TO THE ENVIRONMENT. SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL
INFORMATION. DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL
PLANT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
SMALL SPILLAGE: WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE).
LARGE SPILLAGE:
USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP
THE PRODUCT AND PLACE INTO A CONTAINER FOR LATER DISPOSAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WEAR PERSONAL PROTECTIVE
EQUIPMENT. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE. WASH
THOROUGHLY AFTER HANDLING.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN COOL/WELL-VENTILATED PLACE. KEEP OUT OF THE REACH OF CHILDREN.
KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT CONTAMINATE FOOD OR FEED
STUFFS. KEEP FROM FREEZING. KEEP IN ORIGINAL CONTAINER.
INCOMPATIBLE PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS MATERIALS WITH OCCUPATIONAL
EXPOSURE LIMITS ESTABLISHED BY THE REGION SPECIFIC REGULATORY BODIES.
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NONE REQUIRED UNDER NORMAL USAGE. AVOID CONTACT WITH EYES.
SKIN AND BODY PROTECTION: NONE REQUIRED UNDER NORMAL USAGE.
REPEATED OR PROLONGED CONTACT: IMPERVIOUS GLOVES.
RESPIRATORY PROTECTION:
NONE REQUIRED UNDER NORMAL USAGE. IF EXPOSURE LIMITS ARE EXCEEDED OR
IRRITATION IS EXPERIENCED, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION
SHOULD BE WORN.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID.
APPEARANCE: COLORLESS TO LIGHT YELLOW.
ODOR: ORANGE.
ODOR THRESHOLD: NO INFORMATION AVAILABLE.
PROPERTY VALUES REMARKS/ - METHOD
PH 11.0 +/-0.5
MELTING POINT/RANGE NO DATA AVAILABLE NONE KNOWN
BOILING POINT/BOILING RANGE 100 DEG. C / 212 DEG. F NONE KNOWN
FLASH POINT NONE. NONE KNOWN
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY >1 NONE KNOWN
SPECIFIC GRAVITY 1.005 NONE KNOWN
WATER SOLUBILITY COMPLETELY SOLUBLE NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT NO DATA AVAILABLE NONE KNOWN
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
VISCOSITY NO DATA AVAILABLE NONE KNOWN
FLAMMABLE PROPERTIES NOT FLAMMABLE
EXPLOSIVE PROPERTIES NO DATA AVAILABLE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
VOC CONTENT (%) 0.5
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID: NONE KNOWN BASED ON INFORMATION SUPPLIED.
INCOMPATIBLE MATERIALS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES. NITROGEN OXIDES (NOX).
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION: NOT AN EXPECTED ROUTE OF EXPOSURE
EYE CONTACT: CONTACT WITH EYES MAY CAUSE IRRITATION.
SKIN CONTACT:
MAY CAUSE MILD SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION
INGESTION: NOT AN EXPECTED ROUTE OF EXPOSURE.
CHEMICAL NAME LD50 ORAL LD50 DERMAL LC50 INHALATION
D-LIMONENE 5000 MG/KG (RAT) >5000 MG/KG (RABBIT)
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SENSITIZATION:
MAY CAUSE SENSITIZATION OF SUSCEPTIBLE PERSONS. MAY CAUSE SENSITIZATION BY
SKIN CONTACT.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
THE TABLE BELOW INDICATES WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT AS
A CARCINOGEN.
CHEMICAL NAME ACGIH IARC NTP OSHA
D-LIMONENE GROUP 3
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 3: NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT:
ACUTE TOXICITY:
8.69591% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE ENVIRONMENTAL IMPACT OF THIS PRODUCT HAS NOT BEEN FULLY INVESTIGATED.
CHEMICAL NAME TOXICITY TO TOXICITY TO FISH TOXICITY TO DAPHNIA
ALGAE MICROORGANISMS MAGNA (WATER
FLEA)
D-LIMONENE LC50 96 H:
5989-27-5 0.619 - 0.796
MG/L FLOW-
THROUGH
(PIMEPHALES
PROMELAS)
LC50 96 H:
=35 MG/L
(ONCORHYNCHUS
MYKISS)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS
CONTAMINATED PACKAGING: DO NOT RE-USE EMPTY CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
LEGEND:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL - CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
U.S. FEDERAL REGULATIONS:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372.
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42).
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL.
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
"X" DESIGNATES THAT THE INGREDIENTS ARE LISTED ON THE STATE RIGHT TO KNOW
LIST.
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA ILLINOIS RHODE
ISLAND
D-LIMONENE X X
2-PHENOXYETHANOL X X X
IODOPROPYNYL X
BUTYLCARBAMATE
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARD 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
PREPARED BY:
PRODUCT STEWARDSHIP
23 BRITISH AMERICAN BLVD.
LATHAM, NY 12110
1-800-572-6501
ISSUING DATE: 25-FEB-2014
REVISION DATE: 11-JAN-2016
REVISION NOTE: CHANGE TO COMPOSITION.
GENERAL DISCLAIMER:
THE INFORMATION PROVIDED ON THIS SDS IS CORRECT TO THE BEST OF OUR
KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION. THE
INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT TO BE
CONSIDERED AS A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH
MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS,
UNLESS SPECIFIED IN THE TEXT.
WPS-ITW-004 - SCRUBS(R*) NATURAL FORCE(R*) CITRUS DEGREASER TOWELS