| Common Name: | COOLER GUARD |
| Manufacturer: | CONTROLLED RELEASE TECHNOLOGIES |
| SDS Revision Date: | 9/19/2013 |
| SDS Format: | GHS-US |
| Item Number(s): | 22D152, 4MH76 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CRT
SAFETY DATA SHEET
| SECTION 1 PRODUCT AND COMPANY INFORMATION |  |
PRODUCT NAME(S): COOLER GUARD
PRODUCT CODE(S): MK47, E2000, E4000, E10000
USES:
THIS PRODUCT IS INTENDED FOR SCALE CONTROL IN EVAPORATIVE COOLERS AND
RELATED APPLICATIONS.
COMPANY: CONTROLLED RELEASE TECHNOLOGIES, INC.
ADDRESS:
1016 INDUSTRY DRIVE
SHELBY, NC 28152
USA
TELEPHONE NUMBER: (704) 487-0878
FAX NUMBER: (704) 487-0877
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.: 1- (800) 255-3924; + 01 (813) 248-0585 (INTERNATIONAL)
DATE ISSUED: SEPTEMBER 19, 2013
DATE REVISED: SEPTEMBER 19, 2013
THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD
29CFR1910.1200 AS REVISED IN MAY 2012 (GHS). IT MAY NOT MEET REQUIREMENTS
IN OTHER COUNTRIES.
| SECTION 2 HAZARDS IDENTIFICATION | |
HEALTH HAZARD
EXCLAMATION MARK
GHS CLASSIFICATION:
WARNING
CARCINOGEN (CATEGORY 2)
EYE IRRITANT (CATEGORY 2A)
SKIN IRRITATION (CATEGORY 2)
REPEATED EXPOSURE (CATEGORY 2)
ACUTE AQUATIC TOXICITY (CATEGORY 3)
GHS HAZARD STATEMENTS:
SUSPECTED OF CAUSING CANCER
CAUSES SERIOUS EYE IRRITATION
CAUSES SKIN IRRITATION
MAY CAUSE DAMAGE TO ORGANS (LIVER AND KIDNEYS) THROUGH PROLONGED OR
REPEATED EXPOSURE
HARMFUL TO AQUATIC LIFE
GHS PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
WASH HANDS/SKIN THOROUGHLY AFTER HANDLING.
DO NOT BREATHE DUST.
AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER/SOAP.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
COLLECT SPILLAGE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
GHS ASSESSMENT:
APPROXIMATELY 1% OF THIS MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY.
APPROXIMATELY 3-7% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN
HAZARDS TO THE AQUATIC ENVIRONMENT.
| SECTION 3 COMPOSITION / INGREDIENTS | |
COMPONENT CAS NUMBER EC NUMBER CONCENTRATION
FUNCTIONAL POLYMERS PROPRIETARY 55 - 75%
ORGANIC PHOSPHONATE PROPRIETARY 10 - 20%
COCAMIDE 68603-42-9 271-657-0 10 - 25%
DIETHANOLAMINE
SURFACTANT PROPRIETARY 3 - 7%
DIETHANOLAMINE 111-42-2 203-868-0 1 - 3%
TRADE SECRET CLAIMS:
SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF COMPONENTS HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4 FIRST AID MEASURES | |
FIRST AID - EYES:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION, IF IRRITATION DEVELOPS.
FIRST AID - SKIN:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF SOAP AND WATER
FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION OR RASH DEVELOPS AND/OR
PERSISTS. WASH CONTAMINATED CLOTHING BEFORE REUSE.
FIRST AID - INGESTION:
IF SWALLOWED AND FEEL UNWELL, CALL A PHYSICIAN OR POISON CONTROL CENTER. DO
NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY A PHYSICIAN OR POISON
CONTROL CENTER. IF VICTIM IS FULLY CONSCIOUS, GIVE A CUPFUL OF WATER. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
FIRST AID - INHALATION:
IF RESPIRATORY SYMPTOMS OR OTHER SYMPTOMS OF EXPOSURE DEVELOP, MOVE VICTIM
AWAY FROM SOURCE OF EXPOSURE AND INTO FRESH AIR. IF SYMPTOMS PERSIST, SEEK
IMMEDIATE MEDICAL ATTENTION. IF VICTIM IS NOT BREATHING, CLEAR AIRWAY AND
IMMEDIATELY BEGIN ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULTIES
DEVELOP, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. SEEK
IMMEDIATE MEDICAL ATTENTION.
IMPORTANT SYMPTOMS / EFFECTS - ACUTE AND DELAYED:
RASH, TISSUE REDNESS/IRRITATION.
ADVICE TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| SECTION 5 FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
TREAT SURROUNDING MATERIAL. WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, OR
FOAM IS RECOMMENDED. CARBON DIOXIDE CAN DISPLACE OXYGEN. USE CAUTION WHEN
APPLYING CARBON DIOXIDE IN CONFINED SPACES.
SPECIFIC HAZARDS:
THIS PRODUCT IS NOT COMBUSTIBLE. THIS PRODUCT MAY GIVE RISE TO HAZARDOUS
VAPORS IN A FIRE. VAPORS/FUMES MAY BE IRRITATING, CORROSIVE AND/OR TOXIC.
PROTECTIVE EQUIPMENT AND PROCEDURES FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS.
ADDITIONAL ADVICE: NONE.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
SPILL PROCEDURES:
SWEEP UP SPILLED MATERIAL AND TRANSFER INTO SUITABLE CONTAINERS FOR
RECOVERY OR DISPOSAL. FINALLY FLUSH AREA WITH WATER.
PERSONAL PRECAUTIONS: WEAR SUITABLE PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT THE MATERIAL FROM ENTERING DRAINS OR WATER COURSES. DO NOT
DISCHARGE DIRECTLY TO A WATER SOURCE. ADVISE AUTHORITIES IF SPILLAGE HAS
ENTERED WATERCOURSE OR SEWER OR HAS CONTAMINATED SOIL OR VEGETATION.
| SECTION 7 HANDLING AND STORAGE | |
HANDLING:
WEAR APPROPRIATE PERSONAL PROTECTION (SEE SECTION 8) WHEN HANDLING THIS
MATERIAL. THE WORK AREA MUST BE EQUIPPED WITH A SAFETY SHOWER AND EYE WASH
STATION. IF EXPOSED TO THE SOLUTION, AVOID CONTACT WITH SKIN AND EYES. WASH
THOROUGHLY AFTER HANDLING SOLUTION.
STORAGE:
KEEP CONTAINER(S) TIGHTLY CLOSED. USE AND STORE THIS MATERIAL AT
TEMPERATURES BELOW 60 DEG. C (140 DEG. F) AWAY FROM HEAT, DIRECT SUNLIGHT
AND HOT METAL SURFACES. KEEP FROM FREEZING. KEEP AWAY FROM ANY INCOMPATIBLE
MATERIALS (SEE SECTION 10).
ADDITIONAL ADVICE:
STORE IN ORIGINAL CONTAINER. STORE AS DIRECTED BY THE MANUFACTURER.
| SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE STANDARDS:
EXPOSURE LIMITS ARE LISTED BELOW, IF THEY EXIST.
FUNCTIONAL POLYMERS: (AS PARTICULATES NOT OTHERWISE REGULATED)
OSHA PEL: 15 MG/M3 TWA (TOTAL).
OSHA PEL: 5 MG/M3 TWA (RESPIRABLE FRACTION).
ORGANIC PHOSPHONATE: NONE.
COCAMIDE DIETHANOLAMINE: NONE.
SURFACTANT: NONE.
DIETHANOLAMINE:
ACGIH: 2MG/M3 TWA TLV.
NIOSH REL: 3 PPM TWA.
ENGINEERING CONTROL MEASURES:
ENGINEERING METHODS TO PREVENT OR CONTROL EXPOSURE ARE PREFERRED. METHODS
INCLUDE PROCESS OR PERSONNEL ENCLOSURE, MECHANICAL VENTILATION (LOCAL
EXHAUST), AND CONTROL OF PROCESS CONDITIONS.
RESPIRATORY PROTECTION:
A NIOSH CERTIFIED AIR PURIFYING RESPIRATOR WITH SUITABLE PARTICULATE
FILTERING CAPABILITY MAY BE USED UNDER CONDITIONS WHERE AIRBORNE
CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS.
HAND PROTECTION:
THE USE OF GLOVES IMPERVIOUS TO THE SPECIFIC MATERIAL HANDLED IS ADVISED
TO PREVENT SKIN CONTACT, POSSIBLE IRRITATION AND SKIN DAMAGE (SEE GLOVE
MANUFACTURER LITERATURE FOR INFORMATION ON PERMEABILITY).
EYE PROTECTION:
APPROVED EYE PROTECTION (SAFETY GLASSES WITH SIDE-SHIELDS OR GOGGLES)
TO SAFEGUARD AGAINST POTENTIAL EYE CONTACT, IRRITATION, OR INJURY IS
RECOMMENDED. DEPENDING ON CONDITIONS OF USE, A FACE SHIELD MAY BE
NECESSARY.
BODY PROTECTION:
IMPERVIOUS CLOTHING SHOULD BE WORN AS NEEDED TO PREVENT SKIN CONTACT.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
COLOR: PALE BROWN
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/RANGE (DEG. C/DEG. F): NOT AVAILABLE.
BOILING POINT/RANGE (DEG. C/DEG. F): >100 DEG. C / >212 DEG. F
FLASH POINT (PMCC) (DEG. C/DEG. F): >134 DEG. C / >273.2 DEG. F
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY / EXPLOSIVITY LIMITS IN AIR (%): NOT AVAILABLE.
VAPOR PRESSURE: NEGLIGIBLE (<1 MMHg)
VAPOR DENSITY (AIR = 1): NOT AVAILABLE.
RELATIVE DENSITY: 1.2 G/CM3 (25 DEG. C)
SOLUBILITY IN WATER: PARTLY SOLUBLE (>45%)
PARTITION COEFFICIENT: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NOT AVAILABLE.
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
EXPLOSIVE PROPERTIES: NONE.
OXIDIZING PROPERTIES: NONE.
VOLATILE ORGANIC CONTENT (VOC) (G/L):
CA. 150-240 G/L (AS DEFINED BY 40CFR51.100)
| SECTION 10 STABILITY AND REACTIVITY | |
REACTIVITY: PRODUCT WILL NOT UNDERGO ADDITIONAL REACTION.
STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: CONTACT WITH INCOMPATIBLE MATERIALS, EXCESSIVE HEAT.
INCOMPATIBILITIES: OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES, HALIDES.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, OXIDES OF SULFUR, OXIDES OF
PHOSPHORUS, OXIDES OF SILICON, AMINES, TOXIC BY-PRODUCTS.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
IF AVAILABLE, TOXICITY DATA FOR THE PRODUCT IS GIVEN; OTHERWISE COMPONENT
DATA IS LISTED.
ACUTE TOXICITY: THIS PRODUCT IS NOT EXPECTED TO BE APPRECIABLY TOXIC.
(FUNCTIONAL POLYMERS):
ORAL LD50 (RAT): >2000 MG/KG
DERMAL LD50 (RABBIT):
>1000 MG/KG (ESTIMATED BASED ON DATA AND ANALOGOUS POLYMER)
(ORGANIC PHOSPHONATE):
ORAL LD50 (RAT): >1000 MG/KG
DERMAL LD50 (RABBIT): >1000 MG/KG
(COCAMIDE DIETHANOLAMINE):
ORAL LD50 (RAT): 12.2 G/KG
DERMAL LD50 (RABBIT): >2 G/KG
(SURFACTANT):
ORAL LD50 (RAT): >5000 MG/KG
DERMAL LD50 (RABBIT) >2000 MG/KG
(DIETHANOLAMINE):
ORAL LD50 (RAT): 710-1800 MG/KG
DERMAL LD50 (RABBIT): 13 G/KG
SKIN CORROSION / IRRITATION:
THE PRODUCT IS EXPECTED TO BE IRRITATING TO THE SKIN.
(FUNCTIONAL POLYMERS):
MODERATELY IRRITATING TO SKIN (ESTIMATED FROM RABBIT DATA AND DATA FOR
ANALOGOUS POLYMER).
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE): MODERATELY IRRITATING TO SKIN (RABBIT).
(SURFACTANT): NOT IRRITATING TO SKIN (RABBIT).
(DIETHANOLAMINE): IRRITATING TO SKIN (RABBIT).
SERIOUS EYE DAMAGE / IRRITATION:
THE PRODUCT IS EXPECTED TO BE SEVERELY IRRITATING TO THE EYES WITH POSSIBLE
DAMAGE UPON PROLONGED OR REPEATED EXPOSURES.
(FUNCTIONAL POLYMERS):
IRRITATING TO EYE (ESTIMATED FROM RABBIT DATA AND DATA FOR ANALOGOUS
POLYMER).
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE):
SEVERELY IRRITATING TO EYE WITH POTENTIAL DAMAGE (RABBIT).
(SURFACTANT): SLIGHTLY IRRITATING TO EYE (RABBIT).
(DIETHANOLAMINE):
DAMAGING TO EYES, PARTICULARLY AT CONCENTRATION GREATER THAN 15%.
RESPIRATORY OR SKIN SENSITIZATION:
THE PRODUCT IS NOT EXPECTED TO BE DERMALLY SENSITIZING; HOWEVER, CERTAIN
INDIVIDUALS MAY EXPERIENCE ALLERGIC REACTIONS TO RESIDUAL MONOMER CONTENT.
(FUNCTIONAL POLYMERS):
NOT DERMALLY SENSITIZING (GUINEA PIG) (ANALOGOUS POLYMER AND DATA).
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE): NOT DERMALLY SENSITIZING (GUINEA PIG).
(SURFACTANT): NO DATA.
(DIETHANOLAMINE): NOT DERMALLY SENSITIZING (GUINEA PIG AND HUMAN).
MUTAGENICITY: THIS PRODUCT IS NOT EXPECTED TO BE MUTAGENIC.
(FUNCTIONAL POLYMERS):
NOT MUTAGENIC (AMES TEST SYSTEM) (ANALOGOUS POLYMER AND DATA).
(ORGANIC PHOSPHONATE):
NOT MUTAGENIC IN A STANDARD BATTERY OF GENETIC TOXICOLOGICAL TESTS.
(COCAMIDE DIETHANOLAMINE):
NOT MUTAGENIC (AMES TEST SYSTEMS WITH AND WITHOUT ACTIVATION). DID NOT
INDUCE CHROMOSOMAL ABERRATIONS OR SISTER CHROMATID EXCHANGES WITH OR
WITHOUT METABOLIC ACTIVATION IN CHINESE HAMSTER OVARY CELLS. INCONCLUSIVE
RESULTS WERE OBSERVED IN MOUSE LYMPHOMA FORWARD MUTATION ASSAYS.
(SURFACTANT): NOT MUTAGENIC (AMES TEST SYSTEM).
(DIETHANOLAMINE):
NOT MUTAGENIC (AMES, RAT LIVER CELL, CHINESE HAMSTER OVARY E. COLI AND
MAMMALIAN CELL GENE MUTATION, MOUSE LYMPHOMA TEST SYSTEMS...WITH OR WITHOUT
ACTIVATION).
CARCINOGENICITY: THIS PRODUCT MAY BE CARCINOGENIC.
(FUNCTIONAL POLYMERS): NO DATA.
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE):
LIVER AND KIDNEY TUMORS DEVELOPED IN MICE, BUT THIS INCREASE WAS ATTRIBUTED
TO FREE DIETHANOLAMINE PRESENT. EQUIVOCAL EVIDENCE IN RATS. DETERMINED TO
BE POSSIBLY CARCINOGENIC TO HUMANS (EPA AND IARC).
(SURFACTANT): NO DATA.
(DIETHANOLAMINE): INCREASED LIVER AND KIDNEY TUMORS DEVELOPED IN RATS.
DETERMINED TO BE POSSIBLY CARCINOGENIC TO HUMANS (IARC AND NTP).
REPRODUCTIVE / DEVELOPMENTAL TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO BE DEVELOPMENTALLY HARMFUL.
(FUNCTIONAL POLYMERS): NO DATA.
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE):
SKELETAL RETARDATION IN RAT FETUSES WERE CONSIDERED TO BE INCIDENTAL
BECAUSE THE VALUES WERE WITHIN THE NORMAL RANGE OF VARIATION FOR THIS
STRAIN (ORAL ADMINISTRATION).
NOAEL: 1000 MG/KG/DAY.
(SURFACTANT): NO DATA.
(DIETHANOLAMINE):
NO TREATMENT-RELATED MORPHOLOGICAL ABNORMALITIES IN PUPS WERE DETECTED IN
ORALLY ADMINISTERED RATS.
CHRONIC/SUBCHRONIC TOXICITY:
SPECIFIC TARGET ORGAN/SYSTEMIC TOXICITY - SINGLE EXPOSURE:
(FUNCTIONAL POLYMERS):
HIGH EXPOSURES MAY CAUSE KIDNEY EFFECTS (ANALOGOUS POLYMER AND DATA).
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE):
NO PATHOLOGICAL CHANGES WERE OBSERVED IN THE LIVER AND KIDNEYS OF MICE
(DERMAL APPLICATION). KIDNEY DAMAGE WAS NOTED IN RATS AT HIGHER DOSE RATES
(200 AND 400 MG/KG).
(SURFACTANT): NO ADVERSE EFFECTS ANTICIPATED BASED ON SIMILAR COMPOUNDS.
(DIETHANOLAMINE): NO DATA.
CHRONIC/SUBCHRONIC TOXICITY:
SPECIFIC TARGET ORGAN/SYSTEMIC TOXICITY - REPEATED EXPOSURE:
(FUNCTIONAL POLYMERS):
TWO-YEAR FEEDING STUDIES ON RATS AND DOGS YIELDED NO ADVERSE HEALTH AFFECTS
(ANALOGOUS POLYMER AND DATA).
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE): NO DATA.
(SURFACTANT): NO DATA.
(DIETHANOLAMINE):
LIVER AND KIDNEY DAMAGE AND ABNORMALITIES WERE OBSERVED IN RATS BY
INHALATION AND ORAL ADMINISTRATION. DECREASED SPERM MOTILITY AND SPERM
COUNT RESULTED IN MALE RATS.
ASPIRATION HAZARD: THIS PRODUCT IS NOT EXPECTED TO BE AN ASPIRATION HAZARD.
ADDITIONAL INFORMATION: NONE.
| SECTION 12 ECOLOGICAL INFORMATION | |
IF AVAILABLE, ECOLOGICAL DATA FOR THE PRODUCT IS GIVEN; OTHERWISE COMPONENT
DATA IS LISTED.
ACUTE ECOTOXICITY: THIS PRODUCT MAY BE HARMFUL TO AQUATIC SPECIES.
(FUNCTIONAL POLYMERS):
LC50 (FATHEAD MINNOW & RAINBOW TROUT): >550 MG/L/96H
EC50 (DAPHNIA MAGNA): >520 MG/L/48H
EC50 (ALGAE): >50 MG/L/96 HR (ANALOGOUS POLYMER AND DATA).
(ORGANIC PHOSPHONATE):
LC50 (LABEO BOGA): >250 MG/L/48 HR
EC50 (DAPHNIA MAGNA): 130 MG/L/24 HR.
(COCAMIDE DIETHANOLAMINE):
LC50 (ZEBRA FISH): 3.6 MG/L/96H
EC50 (DAPHNIA MAGNA): 3.3 MG/L/24 HR
EC50 (ALGAE): 2.2 MG/L/72 HR.
(SURFACTANT): NO DATA.
(DIETHANOLAMINE):
LC50 (GOLDFISH): 800 MG/L/24 HR
EC50 (DAPHNIA MAGNA): 77.5 MG/L/48H
EC50 (ALGAE): 7.8-75 MG/L/72H.
MOBILITY:
(FUNCTIONAL POLYMERS): NO DATA.
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE): NO DATA.
(SURFACTANT): NO DATA.
(DIETHANOLAMINE):
SHOULD LEACH IN SOIL. EXTREMELY MOBILE IN SOIL (KOC ESTIMATED TO BE 4).
PERSISTENCE/DEGRADABILITY:
(FUNCTIONAL POLYMERS):
NOT READILY BIODEGRADABLE. DEGRADATION MAY BE SLOW OR NEGLIGIBLE.
(ORGANIC PHOSPHONATE): NOT READILY BIODEGRADABLE (17% IN 28 DAYS).
(COCAMIDE DIETHANOLAMINE): NO DATA.
(SURFACTANT): NO DATA.
(DIETHANOLAMINE):
EXPECTED TO BIODEGRADE FAIRLY RAPIDLY FOLLOWING ACCLIMATION (97% IN 10
DAYS).
BIOACCUMULATION:
(FUNCTIONAL POLYMERS): NO DATA.
(ORGANIC PHOSPHONATE): NO DATA.
(COCAMIDE DIETHANOLAMINE): NO DATA.
(SURFACTANT): NO DATA.
(DIETHANOLAMINE):
A BIOCONCENTRATION FACTOR (BCF) OF <1 WAS ESTIMATED,
WHICH SUGGESTS INSIGNIFICANT TO LOW POTENTIAL.
OTHER ADVERSE EFFECTS: NONE.
| SECTION 13 DISPOSAL CONSIDERATION | |
ENVIRONMENTAL PRECAUTIONS:
PREVENT THE MATERIAL FROM ENTERING DRAINS OR WATER COURSES. DO NOT
DISCHARGE DIRECTLY TO A WATER SOURCE. ADVISE AUTHORITIES IF SPILLAGE HAS
ENTERED WATERCOURSE OR SEWER OR HAS CONTAMINATED SOIL OR VEGETATION.
PRODUCT DISPOSAL:
DISPOSE IN ACCORDANCE WITH ALL LOCAL, STATE (PROVINCIAL), AND FEDERAL
REGULATIONS. UNDER RCRA, IT IS THE RESPONSIBILITY OF THE PRODUCT'S USER TO
DETERMINE AT THE TIME OF DISPOSAL, WHETHER THE PRODUCT MEETS RCRA CRITERIA
FOR HAZARDOUS WASTE. THIS IS BECAUSE THE PRODUCT USES, TRANSFORMATIONS,
MIXTURES, PROCESSES, ETC. MAY RENDER THE RESULTING MATERIALS HAZARDOUS.
CONTAINER DISPOSAL:
DO NOT REMOVE LABEL UNTIL CONTAINER IS THOROUGHLY CLEANED. EMPTY CONTAINERS
MAY CONTAIN HAZARDOUS RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE WAY.
| SECTION 14 TRANSPORT INFORMATION | |
DOT PROPER SHIPPING NAME: NOT REGULATED
UN NUMBER: NOT APPLICABLE.
UN CLASS: NOT APPLICABLE.
UN PACKAGING GROUP: NOT APPLICABLE.
REPORTABLE QUANTITY: 100 POUNDS (DIETHANOLAMINE)
MARINE POLLUTANT: NONE.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND MAY BE
INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS. CONSULT
CURRENT IATA REGULATIONS PRIOR TO SHIPPING BY AIR.
| SECTION 15 REGULATORY INFORMATION | |
US TOXIC SUBSTANCE CONTROL ACT:
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY LISTING
REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL
SUBSTANCE INVENTORY.
CANADIAN DOMESTIC SUBSTANCE LIST:
ONE OR MORE COMPONENT(S) OF THIS PRODUCT ARE NOT LISTED ON THE CANADIAN
DOMESTIC LIST. LIMITED QUANTITIES MAY BE PERMITTED.
EU EXISTING INVENTORY OF CHEMICAL SUBSTANCES:
ONE OR MORE COMPONENT(S) OF THIS PRODUCT ARE NOT IN COMPLIANCE WITH THE
INVENTORY LISTING REQUIREMENTS OF THE E.U. EXISTING INVENTORY OF CHEMICAL
SUBSTANCES (EINECS). ONE OR MORE COMPONENT(S) OF THIS PRODUCT HAVE NOT BEEN
PRE-LISTED UNDER REACH. LIMITED QUANTITIES MAY BE PERMITTED.
TSCA SEC.12(B) EXPORT NOTIFICATION:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL AT OR ABOVE DE MINIMIS
CONCENTRATIONS WHICH REQUIRES REPORTING.
CANADIAN WHMIS CLASSIFICATION: D.2.A, D.2.B
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CPR AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
MASSACHUSETTS RIGHT-TO-KNOW:
THIS PRODUCT CONTAINS MATERIALS SUBJECT TO DISCLOSURE UNDER THE
MASSACHUSETTS' RIGHT-TO-KNOW LAW:
DIETHANOLAMINE
NEW JERSEY RIGHT-TO-KNOW:
THIS PRODUCT CONTAINS MATERIALS SUBJECT TO DISCLOSURE UNDER THE NEW
JERSEY'S RIGHT-TO-KNOW LAW:
DIETHANOLAMINE (0686)
PENNSYLVANIA RIGHT-TO-KNOW:
THIS PRODUCT CONTAINS MATERIALS SUBJECT TO DISCLOSURE UNDER THE
PENNSYLVANIA'S RIGHT-TO-KNOW LAW:
DIETHANOLAMINE
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS MATERIALS WHICH THE STATE OF CALIFORNIA HAS FOUND
TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM:
COCAMIDE DIETHANOLAMINE
DIETHANOLAMINE
SARA TITLE III-SECTION 311/312 CATEGORIZATION (40 CFR 370):
IMMEDIATE, DELAYED HAZARD
SARA TITLE III-SECTION 313 (40 CFR 372):
THIS PRODUCT CONTAINS MATERIALS WHICH ARE LISTED IN SECTION 313 AT OR ABOVE
DE MINIMIS CONCENTRATIONS:
DIETHANOLAMINE
CERCLA HAZARDOUS SUBSTANCE (40 CFR 302):
THIS PRODUCT CONTAINS MATERIALS SUBJECT TO REPORTING UNDER CERCLA AND
SECTION 304 OF EPCRA: DIETHANOLAMINE (100 POUNDS)
WATER HAZARD CLASS (WGK):
THIS PRODUCT IS WATER-ENDANGERING (WGK=2).
OTHER CHEMICAL INVENTORIES:
AUSTRALIA (AICS): ONE OR MORE COMPONENT(S) NOT LISTED.
CHINA (IECSC): ONE OR MORE COMPONENT(S) NOT LISTED.
JAPAN (ENCS): ONE OR MORE COMPONENT(S) NOT LISTED.
KOREA (KCI): ONE OR MORE COMPONENT(S) NOT LISTED.
PHILIPPINES (PICCS): ONE OR MORE COMPONENT(S) NOT LISTED.
| SECTION 16 OTHER INFORMATION | |
NFPA RATING - HEALTH 3
NFPA RATING - FIRE 1
NFPA RATING - REACTIVITY 0
NFPA RATING - SPECIAL NONE
MSDS DATE ISSUED: SEPTEMBER 19, 2013
MSDS CURRENT VERSION: 1.0
VERSION DATE: SEPTEMBER 19, 2013
MSDS REVISION HISTORY: V1.0 INITIAL VERSION.
ABBREVIATIONS:
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
CAS#: CHEMICAL ABSTRACT SERVICES NUMBER
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
DOT: US DEPARTMENT OF TRANSPORTATION
RCRA: US RESOURCE CONSERVATION AND RECOVERY ACT
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
PEL: PERMISSIBLE EXPOSURE LIMIT
STEL: SHORT TERM EXPOSURE LIMIT
WEEL: WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
NTP: NATIONAL TOXICOLOGY PROGRAM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
R: RISK
S: SAFETY
LD50: LETHAL DOSE 50%
LC50: LETHAL CONCENTRATION 50%
EC50: EFFECTIVE CONCENTRATION 50% BCF BIOCONCENTRATION FACTOR
BOD: BIOLOGICAL OXYGEN DEMAND
KOC: SOIL ORGANIC CARBON PARTITION COEFFICIENT.
TLM: MEDIAN TOLERANCE LIMIT
KEY REFERENCES:
UNITED STATES NATIONAL LIBRARY OF MEDICINE'S TOXNET PATTY'S TOXICOLOGY, 5TH
EDITION
EUROPEAN COMMISSION'S INSTITUTE FOR HEALTH AND CONSUMER PROTECTION
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
UNITED STATES NATIONAL TOXICOLOGY PROGRAM
UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
UNITED STATES DEPARTMENT OF TRANSPORTATION
SUPPLIER MATERIAL SAFETY DATA SHEETS
DISCLAIMER:
THE DATA CONTAINED HEREIN IS BASED ON INFORMATION THAT THE COMPANY BELIEVES
TO BE RELIABLE, BUT NO EXPRESSED OR IMPLIED WARRANTY IS MADE WITH REGARD TO
THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR A GIVEN SITUATION. SUCH
DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESCRIBED AND NOT TO SUCH
PRODUCTS IN COMBINATION WITH ANY OTHER PRODUCT AND NO AGENT OF THE COMPANY
IS AUTHORIZED TO VARY ANY OF SUCH DATA. THE COMPANY AND ITS AGENTS DISCLAIM
ALL LIABILITY FOR ANY ACTION TAKEN OR FOREGONE ON RELIANCE UPON SUCH DATA.
PREPARED BY: CHEMONE COMPLIANCE, LLC
REVISION DATE: SEPTEMBER 19, 2013