| Common Name: | ZEREX 0 SUPER CLEANER |
| Manufacturer: | ASHLAND CHEMICAL |
| SDS Revision Date: | 5/23/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4NPP4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
ASHLAND(R*)
SAFETY DATA SHEET
ZEREX(TM) 0 SUPER CLEANER
ZXC02
REVISION DATE: 05/23/2015
PRINT DATE: 1/20/2016
SDS NUMBER: R0296910
VERSION: 1.0
29 CFR 1910.1200 (OSHA HAZCOM 2012)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: ZEREX(TM) 0 SUPER CLEANER
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
ASHLAND
P.O. BOX 2219
COLUMBUS, OH 43216
UNITED STATES OF AMERICA
EHS CUSTOMER REQUESTS@ASHLAND.COM
EMERGENCY TELEPHONE NUMBER: 1-800-ASHLAND (1-800-274-5263)
REGULATORY INFORMATION NUMBER: 1-800-325-3751
PRODUCT INFORMATION: 614-790-3333
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
OXIDIZING LIQUIDS: CATEGORY 1
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - REPEATED EXPOSURE (INHALATION):
CATEGORY 2 (RESPIRATORY TRACT)
GHS LABEL ELEMENT:
HAZARD PICTOGRAMS:
FLAME OVER CIRCLE
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DAMAGE TO ORGANS (RESPIRATORY TRACT) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT.
KEEP/STORE AWAY FROM CLOTHING/COMBUSTIBLE MATERIALS.
TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION.
WEAR FIRE/FLAME RESISTANT/RETARDANT CLOTHING.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF ON CLOTHING: RINSE IMMEDIATELY CONTAMINATED CLOTHING AND
SKIN WITH PLENTY OF WATER BEFORE REMOVING CLOTHES.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH.
IN CASE OF MAJOR FIRE AND LARGE QUANTITIES:
EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%)
SODIUM NITRATE 7631-99-4 OX. SOL. 1; H271 2.73
EYE IRRIT. 2A; H319
ETHYLENEDI- 64-02-8 ACUTE TOX. 4; H302 2.72
AMINETETRAACETIC ACUTE TOX. 4; H332
ACID, TETRASODIUM EYE IRRIT. 2A; H319
SALT STOT RE 2; H373
SODIUM HYDROXIDE 1310-73-2 MET. CORR. 1; H290 1.72
SKIN CORR. 1A; H314
AQUATIC ACUTE 3; H402
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
CALL A POISON CENTRE OR DOCTOR/PHYSICIAN IF EXPOSED OR YOU FEEL UNWELL.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR.
IF UNCONSCIOUS PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL
ATTENTION.
IF ON SKIN, RINSE WELL WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
IN CASE OF EYE CONTACT:
IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
IF SWALLOWED:
OBTAIN MEDICAL ATTENTION.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVEREXPOSURE TO THIS PRODUCT (OR A COMPONENT) MAY CAUSE METHEMOGLOBINEMIA,
WHICH IN SUFFICIENT CONCENTRATION CAUSES CYANOSIS. SEVERE CYANOSIS MAY
REQUIRE INTRAVENOUS INJECTION OF METHYLENE BLUE. METHYLENE BLUE IS
CONTRAINDICATED IF THE PATIENT HAS CONFIRMED OR SUSPECTED
GLUCOSE-6-PHOSPHATE DEHYDROGENASE DEFICIENCY.
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA)
IRRITATION (NOSE, THROAT, AIRWAYS)
COUGH
CYANOSIS (CAUSES BLUE COLORING OF THE SKIN AND NAILS FROM LACK OF OXYGEN)
METHEMOGLOBINEMIA (BLOOD ABNORMALITY WHICH CAUSES A BLUE COLORING TO THE
SKIN)
LUNG EDEMA (FLUID BUILDUP IN THE LUNG TISSUE)
CONVULSIONS
DIFFICULTY IN BREATHING
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
INHALED.
NOTES TO PHYSICIAN: NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
WATER SPRAY
FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
HYDROCARBONS
NITROGEN OXIDES (NOX)
AMMONIA
TOXIC FUMES
CORROSIVE VAPORS
SODIUM OXIDES
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION: STANDARD PROCEDURE FOR CHEMICAL FIRES.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
OTHER INFORMATION:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
CONTAINER HAZARDOUS WHEN EMPTY.
AVOID CONTACT WITH SKIN AND EYES.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
ELECTRICAL INSTALLATIONS/WORKING MATERIALS MUST COMPLY WITH THE
TECHNOLOGICAL SAFETY STANDARDS.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
SODIUM HYDROXIDE 1310-73-2 CEILING 2 MG/M3 ACGIH
CEIL_TIME 2 MG/M3 NIOSH/GUIDE
PEL 2 MG/M3 OSHA_TRANS
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION
TO MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW
LEVELS THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
HAND PROTECTION:
MATERIAL: NEOPRENE
REMARKS:
THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE
PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF
THE EYES TO LIQUID, VAPOR OR MIST.
SKIN AND BODY PROTECTION:
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
SAFETY SHOES
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
DISCARD GLOVES THAT SHOW TEARS, PINHOLES, OR SIGNS OF WEAR.
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER).
HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
WHEN USING DO NOT EAT OR DRINK.
WHEN USING DO NOT SMOKE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
ODOUR: NO DATA AVAILABLE
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 11.2
GLP: SEE USER DEFINED FREE TEXT
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE:
212 DEG. F / 100 DEG. C (1,013.333333 HPA)
CALCULATED PHASE TRANSITION LIQUID/GAS
FLASH POINT: NOT APPLICABLE
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE:
23.3333333 HPA (20 DEG. C)
CALCULATED VAPOR PRESSURE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: NO DATA AVAILABLE
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
CONDITIONS TO AVOID:
EXCESSIVE HEAT
EXPOSURE TO SUNLIGHT.
EXPOSURE TO MOISTURE
INCOMPATIBLE MATERIALS:
ACIDS
ALUMINUM
COMBUSTIBLE MATERIAL
COPPER
COPPER ALLOYS
HALOGENATED HYDROCARBONS
METALS
NICKEL
ORGANIC MATERIALS
ORGANIC NITRO COMPOUNDS
OXIDIZING AGENTS
POWDERED METALS
REDUCING AGENTS
REACTIVE METALS SUCH AS ALUMINUM AND MAGNESIUM
STEEL
STRONG BASES
WATER
ZINC
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
CORROSIVE VAPORS
NITROGEN OXIDES (NOX)
SODIUM OXIDES
TOXIC FUMES
AMMONIA
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
EYE CONTACT
INGESTION
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
SODIUM NITRATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): CA. 3,430 MG/KG
METHOD: OECD TEST GUIDELINE 401
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
ACUTE ORAL TOXICITY:
LD50 (RAT, FEMALE): 1,780 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >1 - 5 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >5,000 MG/KG
SODIUM HYDROXIDE:
ACUTE ORAL TOXICITY:
LDLO (RABBIT): 500 MG/KG
ACUTE INHALATION TOXICITY:
ASSESSMENT: NOT CLASSIFIED AS ACUTELY TOXIC BY INHALATION UNDER GHS.
REMARKS: MODERATE RESPIRATORY IRRITANT
ACUTE DERMAL TOXICITY:
SYMPTOMS: CORROSION
ASSESSMENT: NOT CLASSIFIED AS ACUTELY TOXIC BY DERMAL ABSORPTION UNDER GHS.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PRODUCT:
REMARKS: MAY CAUSE SKIN IRRITATION AND/OR DERMATITIS.
COMPONENTS:
SODIUM NITRATE:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 404
RESULT: NOT IRRITATING TO SKIN
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
SPECIES: RABBIT
RESULT: NOT IRRITATING TO SKIN
SODIUM HYDROXIDE:
RESULT: CORROSIVE TO SKIN
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
REMARKS:
VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN.,
CAUSES SERIOUS EYE IRRITATION.
COMPONENTS:
SODIUM NITRATE:
SPECIES: RABBIT
RESULT: IRRITATING TO EYES
METHOD: OECD TEST GUIDELINE 405
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
RESULT: SEVERELY IRRITATING TO EYES
SODIUM HYDROXIDE:
RESULT: CORROSIVE TO EYES
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
TEST TYPE: MAXIMISATION TEST (GPMT)
SPECIES: GUINEA PIG
ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION.
METHOD: OECD TEST GUIDELINE 406
SODIUM HYDROXIDE:
EXPOSURE ROUTES: SKIN CONTACT
SPECIES: HUMANS
RESULT: NEGATIVE
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
TEST SPECIES: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (RESPIRATORY TRACT) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
COMPONENTS:
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
EXPOSURE ROUTES: INHALATION
TARGET ORGANS: RESPIRATORY TRACT
ASSESSMENT:
THE SUBSTANCE OR MIXTURE IS CLASSIFIED AS SPECIFIC TARGET ORGAN TOXICANT,
REPEATED EXPOSURE, CATEGORY 2.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
COMPONENTS:
SODIUM NITRATE:
TOXICITY TO FISH:
LC50 (RAINBOW TROUT, DONALDSON TROUT (ONCORHYNCHUS MYKISS)):
1,355 - 2,063 MG/L
EXPOSURE TIME: 96 H
METHOD: STATIC
REMARKS: MORTALITY
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
LC50 (WATER FLEA (DAPHNIA MAGNA)): 3,581 MG/L
EXPOSURE TIME: 48 H
METHOD: STATIC
REMARKS: MORTALITY
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
TOXICITY TO FISH:
LC50 (BLUEGILL (LEPOMIS MACROCHIRUS)): 792 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (WATER FLEA (DAPHNIA MAGNA)): 140 MG/L
EXPOSURE TIME: 48 H
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
TOXICITY TO ALGAE:
NOEC (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): >100 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
METHOD: DIRECTIVE 67/548/EEC, ANNEX V, C.3.
TOXICITY TO FISH (CHRONIC TOXICITY):
NOEC (DANIO RERIO (ZEBRA FISH)): >=25.7 MG/L
EXPOSURE TIME: 35 D
TEST TYPE: FLOW-THROUGH TEST
METHOD: OECD TEST GUIDELINE 210
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 25 MG/L
EXPOSURE TIME: 21 D
TEST TYPE: SEMI-STATIC TEST
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
SODIUM HYDROXIDE:
TOXICITY TO FISH:
LC50 (WESTERN MOSQUITOFISH (GAMBUSIA AFFINIS)): 125 MG/L
EXPOSURE TIME: 96 H
METHOD: STATIC
REMARKS: MORTALITY
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (WATER FLEA (DAPHNIA MAGNA)): 34.59 - 47.13 MG/L
EXPOSURE TIME: 48 H
REMARKS: INTOXICATION
TOXICITY TO BACTERIA:
REMARKS: NOT APPLICABLE
ECOTOXICOLOGY ASSESSMENT:
ACUTE AQUATIC TOXICITY: NEUTRALISATION WILL REDUCE ECOTOXIC EFFECTS.
CHRONIC AQUATIC TOXICITY:
THIS PRODUCT HAS NO KNOWN ECOTOXICOLOGICAL EFFECTS.
PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
BIODEGRADABILITY:
RESULT: NOT READILY BIODEGRADABLE.
BIODEGRADATION: <10%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301E
BIODEGRADATION: 90 - 100%
EXPOSURE TIME: 72 D
METHOD: OECD TEST GUIDELINE 301E
BIOACCUMULATIVE POTENTIAL:
COMPONENTS:
ETHYLENEDIAMINETETRAACETIC ACID, TETRASODIUM SALT:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: <3
MOBILITY IN SOIL:
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE
COMPONENTS:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
GENERAL ADVICE:
DO NOT DISPOSE OF WASTE INTO SEWER.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
SEND TO A LICENSED WASTE MANAGEMENT COMPANY.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATION:
ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
CLASS HAZARDS GROUP POLLUTANT /
LTD. QTY.
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: NOT DANGEROUS GOODS
INTERNATIONAL MARITIME DANGEROUS GOODS: NOT DANGEROUS GOODS
TRANSPORT CANADA - INLAND WATERWAYS: NOT DANGEROUS GOODS
TRANSPORT CANADA - RAIL: NOT DANGEROUS GOODS
TRANSPORT CANADA - ROAD: NOT DANGEROUS GOODS
U.S. DOT - INLAND WATERWAYS: NOT DANGEROUS GOODS
U.S. DOT - RAIL: NOT DANGEROUS GOODS
U.S. DOT - ROAD: NOT DANGEROUS GOODS
*ORM = ORM-D
CBL = COMBUSTIBLE LIQUID
MARINE POLLUTANT: NO
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY,
END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING
DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ CALCULATED PRODUCT RQ
(LBS) (LBS)
SODIUM HYDROXIDE 1310-73-2 1000 57947.499565
SARA 311/312 HAZARDS:
FIRE HAZARD
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SARA 313 COMPONENT(S):
SODIUM NITRATE 7631-99-4 2.73%
PENNSYLVANIA RIGHT TO KNOW:
WATER 7732-18-5 70.00 - 90.00%
SODIUM GLUCONATE 527-07-1 10.00 - 20.00%
SODIUM NITRATE 7631-99-4 1.00 - 5.00%
SODIUM HYDROXIDE 1310-73-2 1.00 - 5.00%
NEW JERSEY RIGHT TO KNOW:
WATER 7732-18-5 70.00 - 90.00%
SODIUM GLUCONATE 527-07-1 10.00 - 20.00%
SODIUM NITRATE 7631-99-4 1.00 - 5.00%
ETHYLENEDIAMINETETRAACETIC ACID, 64-02-8 1.00 - 5.00%
TETRASODIUM SALT
SODIUM HYDROXIDE 1310-73-2 1.00 - 5.00%
CALIFORNIA PROP 65:
PROPOSITION 65 WARNINGS ARE NOT REQUIRED FOR THIS PRODUCT BASED ON THE
RESULTS OF A RISK ASSESSMENT.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA: ON TSCA INVENTORY
AUSTR: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL.
ENCS: NOT IN COMPLIANCE WITH THE INVENTORY
KECL: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
REVISION DATE: 05/23/2015
NFPA:
HEALTH 2
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION: NOT APPLICABLE
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.
H271: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER.
H290: MAY BE CORROSIVE TO METALS.
H302: HARMFUL IF SWALLOWED.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H373:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
INHALED.
H402: HARMFUL TO AQUATIC LIFE.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET
ASHLAND INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS
THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED
CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN PREPARED
BY ASHLAND'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT (1-800-325-3751).
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE,
USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT
ASSOCIATION" (IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM