| Common Name: | ZEREX RADIATOR SUPER PROTECTOR & WATER PUMP LUBRICANT |
| Manufacturer: | ASHLAND CHEMICAL |
| SDS Revision Date: | 5/22/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4NPP6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ASHLAND(R*)
SAFETY DATA SHEET
ZEREX(TM) RADIATOR SUPER PROTECTOR & WATER PUMP LUBRICANT
ZXC04
REVISION DATE: 05/22/2015
PRINT DATE: 1/8/2016
SDS NUMBER: R0296913
VERSION: 1.0
29 CFR 1910.1200 (OSHA HAZCOM 2012)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: ZEREX(TM) RADIATOR SUPER PROTECTOR & WATER PUMP LUBRICANT
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
ASHLAND
P.O. BOX 2219
COLUMBUS, OH 43216
UNITED STATES OF AMERICA
EHS CUSTOMER: REQUESTS@ASHLAND.COM
EMERGENCY TELEPHONE NUMBER: 1-800-ASHLAND (1-800-274-5263)
REGULATORY INFORMATION NUMBER: 1-800-325-3751
PRODUCT INFORMATION: 614-790-3333
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
GHS LABEL ELEMENT:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR EYE PROTECTION/FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%)
SODIUM NITRATE 7631-99-4 OX. SOL. 1; H271 2.04
EYE IRRIT. 2A; H319
SODIUM 2492-26-4 MET. CORR. 1; H290 1.05
MERCAPTOBENZOTHIAZOLE SKIN CORR. 1C; H314
EYE DAM. 1; H318
SKIN SENS. 1; H317
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR.
IF UNCONSCIOUS PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL
ATTENTION.
IF ON SKIN, RINSE WELL WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
IN CASE OF EYE CONTACT:
IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
IF SWALLOWED:
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVEREXPOSURE TO THIS PRODUCT (OR A COMPONENT) MAY CAUSE METHEMOGLOBINEMIA,
WHICH IN SUFFICIENT CONCENTRATION CAUSES CYANOSIS. SEVERE CYANOSIS MAY
REQUIRE INTRAVENOUS INJECTION OF METHYLENE BLUE. METHYLENE BLUE IS
CONTRAINDICATED IF THE PATIENT HAS CONFIRMED OR SUSPECTED
GLUCOSE-6-PHOSPHATE DEHYDROGENASE DEFICIENCY.
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA)
COUGH
CYANOSIS (CAUSES BLUE COLORING OF THE SKIN AND NAILS FROM LACK OF OXYGEN)
METHEMOGLOBINEMIA (BLOOD ABNORMALITY WHICH CAUSES A BLUE COLORING TO THE
SKIN)
CONVULSIONS
DIFFICULTY IN BREATHING
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
NOTES TO PHYSICIAN: NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
WATER SPRAY
FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
NITROGEN OXIDES (NOX)
CARBON DIOXIDE AND CARBON MONOXIDE
OXIDES OF PHOSPHORUS
POTASSIUM OXIDE
SULFUR OXIDES
NITROGEN OXIDES (NOX)
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION:
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF
IN ACCORDANCE WITH LOCAL REGULATIONS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
OTHER INFORMATION:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
PERSONS SUSCEPTIBLE TO SKIN SENSITISATION PROBLEMS OR ASTHMA, ALLERGIES,
CHRONIC OR RECURRENT RESPIRATORY DISEASE SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS MIXTURE IS BEING USED.
CONTAINER HAZARDOUS WHEN EMPTY.
AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
AVOID CONTACT WITH SKIN AND EYES.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
ELECTRICAL INSTALLATIONS / WORKING MATERIALS MUST COMPLY WITH THE
TECHNOLOGICAL SAFETY STANDARDS.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS
THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
HAND PROTECTION:
MATERIAL: NEOPRENE
REMARKS:
THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE
PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF
THE EYES TO LIQUID, VAPOR OR MIST.
SKIN AND BODY PROTECTION:
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
SAFETY SHOES
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
DISCARD GLOVES THAT SHOW TEARS, PINHOLES, OR SIGNS OF WEAR.
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER).
HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
WHEN USING DO NOT EAT OR DRINK.
WHEN USING DO NOT SMOKE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
ODOUR: NO DATA AVAILABLE
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE:
212 DEG. F / 100 DEG. C (1,013.333333 HPA)
CALCULATED PHASE TRANSITION LIQUID/GAS
FLASH POINT: NOT APPLICABLE
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: 32 HPA (25 DEG. C) CALCULATED VAPOR PRESSURE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 1.036 (60.00 DEG. F)
DENSITY: 1.036 G/CM3 (60.00 DEG. F)
SOLUBILITY(IES):
WATER SOLUBILITY: COMPLETELY SOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
CONDITIONS TO AVOID:
EXCESSIVE HEAT
EXPOSURE TO MOISTURE
INCOMPATIBLE MATERIALS:
COMBUSTIBLE MATERIAL
HEAVY METALS
ORGANIC MATERIALS
POWDERED METALS
REDUCING AGENTS
STRONG ACIDS
STRONG OXIDIZING AGENTS
WATER
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY FORM:
CARBON DIOXIDE AND CARBON MONOXIDE
NITROGEN OXIDES (NOX)
SULPHUR OXIDES
NITROGEN OXIDES
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
EYE CONTACT
INGESTION
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
SODIUM NITRATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): CA. 3,430 MG/KG
METHOD: OECD TEST GUIDELINE 401
SODIUM MERCAPTOBENZOTHIAZOLE:
ACUTE ORAL TOXICITY:
LD50 (RAT): 2,100 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >6.5 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >7,940 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PRODUCT:
REMARKS: MAY CAUSE SKIN IRRITATION AND/OR DERMATITIS.
COMPONENTS:
SODIUM NITRATE:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 404
RESULT: NOT IRRITATING TO SKIN
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
SODIUM MERCAPTOBENZOTHIAZOLE:
SPECIES: RABBIT
RESULT: CORROSIVE AFTER 1 TO 4 HOURS OF EXPOSURE
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
REMARKS:
VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN.,
CAUSES SERIOUS EYE IRRITATION.
COMPONENTS:
SODIUM NITRATE:
SPECIES: RABBIT
RESULT: IRRITATING TO EYES
METHOD: OECD TEST GUIDELINE 405
SODIUM MERCAPTOBENZOTHIAZOLE:
SPECIES: RABBIT
RESULT: CORROSIVE TO EYES
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
SODIUM MERCAPTOBENZOTHIAZOLE:
TEST TYPE: MAXIMISATION TEST (GPMT)
SPECIES: GUINEA PIG
ASSESSMENT: MAY CAUSE SENSITISATION BY SKIN CONTACT.
METHOD: OECD TEST GUIDELINE 406
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
SODIUM MERCAPTOBENZOTHIAZOLE:
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
RESULT: NEGATIVE
GENOTOXICITY IN VIVO:
TEST TYPE: IN VIVO MICRONUCLEUS TEST
TEST SPECIES: MOUSE
RESULT: NEGATIVE
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
COMPONENTS:
SODIUM NITRATE:
TOXICITY TO FISH:
LC50 (RAINBOW TROUT, DONALDSON TROUT (ONCORHYNCHUS MYKISS)):
1,355 - 2,063 MG/L
EXPOSURE TIME: 96 H
METHOD: STATIC
REMARKS: MORTALITY
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
LC50 (WATER FLEA (DAPHNIA MAGNA)): 3,581 MG/L
EXPOSURE TIME: 48 H
METHOD: STATIC
REMARKS: MORTALITY
SODIUM MERCAPTOBENZOTHIAZOLE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): 0.73 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: FLOW-THROUGH TEST
METHOD: OECD TEST GUIDELINE 203
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
LC50 (BLUEGILL (LEPOMIS MACROCHIRUS)): 3.8 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: STATIC TEST
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (WATER FLEA (DAPHNIA MAGNA)): 19 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 202
TOXICITY TO ALGAE:
IC50 (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 0.3 MG/L
EXPOSURE TIME: 96 H
METHOD: OECD TEST GUIDELINE 201
ERC50 (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 0.5 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
NOEC (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 0.066 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
TOXICITY TO FISH (CHRONIC TOXICITY):
NOEC (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): 0.041 MG/L
EXPOSURE TIME: 89 D
END POINT: GROWTH RATE
TEST TYPE: FLOW-THROUGH TEST
METHOD: OECD TEST GUIDELINE 210
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 0.08 MG/L
EXPOSURE TIME: 21 D
END POINT: REPRODUCTION TEST
METHOD: OECD TEST GUIDELINE 211
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
SODIUM MERCAPTOBENZOTHIAZOLE:
BIODEGRADABILITY:
RESULT: NOT READILY BIODEGRADABLE.
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
BIOACCUMULATIVE POTENTIAL:
COMPONENTS:
SODIUM MERCAPTOBENZOTHIAZOLE:
BIOACCUMULATION:
SPECIES: CYPRINUS CARPIO (CARP)
BIOCONCENTRATION FACTOR (BCF): <8
EXPOSURE TIME: 6 WEEKS
CONCENTRATION: 0.01 MG/L
REMARKS:
INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR SUBSTANCES.
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 2.42
PH: 7
MOBILITY IN SOIL:
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
ADDITIONAL ECOLOGICAL INFORMATION:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL., HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
GENERAL ADVICE:
THE PRODUCT SHOULD NOT BE ALLOWED TO ENTER DRAINS, WATER COURSES OR THE
SOIL.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
SEND TO A LICENSED WASTE MANAGEMENT COMPANY.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATION:
ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
CLASS HAZARDS GROUP POLLUTANT /
LTD. QTY.
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: NOT DANGEROUS GOODS
INTERNATIONAL MARITIME DANGEROUS GOODS: NOT DANGEROUS GOODS
TRANSPORT CANADA - INLAND WATERWAYS: NOT DANGEROUS GOODS
TRANSPORT CANADA - RAIL: NOT DANGEROUS GOODS
TRANSPORT CANADA - ROAD: NOT DANGEROUS GOODS
U.S. DOT - INLAND WATERWAYS: NOT DANGEROUS GOODS
U.S. DOT - RAIL: NOT DANGEROUS GOODS
U.S. DOT - ROAD: NOT DANGEROUS GOODS
*ORM = ORM-D
CBL = COMBUSTIBLE LIQUID
MARINE POLLUTANT: NO
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY,
END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING
DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
| SECTION 15. REGULATORY INFORMATION | |
SARA 311/312 HAZARDS: ACUTE HEALTH HAZARD
SARA 313 COMPONENT(S):
SODIUM NITRATE 7631-99-4 2.04%
CALIFORNIA PROP 65:
PROPOSITION 65 WARNINGS ARE NOT REQUIRED FOR THIS PRODUCT BASED ON THE
RESULTS OF A RISK ASSESSMENT.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA: ON TSCA INVENTORY
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL.
AUSTR: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
ENCS: NOT IN COMPLIANCE WITH THE INVENTORY
KECL: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
REVISION DATE: 05/22/2015
NFPA:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 3
FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION: NOT APPLICABLE
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.:
H271: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER.
H290: MAY BE CORROSIVE TO METALS.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET:
ASHLAND INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS
THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED
CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN PREPARED
BY ASHLAND'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT (1-800-325-3751).
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE,
USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT ASSOCIATION"
(IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM