| Common Name: | 24049 SUPERCOOL R-134A REFRIGERANT PLUS LEAK STOP |
| Manufacturer: | TIRE SEAL |
| SDS Revision Date: | 11/12/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 5DPW5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SUPERCOOL(R*)
"QUALITY PRODUCTS... GREAT SERVICE"
24049 SUPERCOOL R-134A REFRIGERANT PLUS LEAK STOP
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
REVISION DATE: 11/12/2014
SUPERSEDES: 08/25/2014
VERSION: 4.1
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
TRADE NAME: 24049 SUPERCOOL R-134A REFRIGERANT PLUS LEAK STOP
CAS NO: 811-97-2
PRODUCT CODE: 24049
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE:
R-134A WITH LEAK STOP IS USED AS AN R-134A REFRIGERANT CHARGE AND LEAK STOP
IN R-134A REFRIGERATION SYSTEMS.
USE OF THE SUBSTANCE/MIXTURE: REFRIGERANT GAS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
TIRE SEAL, INC.
3574 CORONA STREET
33461 LAKE WORTH, FLORIDA
USA
T: 561-582-2245
F: 561-582-1499
WWW.SUPERCOOL.AC
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
USA PHONE: 1-800-373-7542
INT'L: 1-484-951-2432
DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US): NOT CLASSIFIED
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
SIGNAL WORD (GHS-US): WARNING
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
CONTAINS GAS UNDER PRESSURE; MAY BURST IF HEATED.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION
(GHS-US)
1,2-BENZENEDICARBOXYLIC (CAS NO) 68515-49-1 5 - 13 ACUTE TOX. 4 (ORAL),
ACID DIC9-11 BRANCHED H302
ALKYLESTERS, C10 RICH ACUTE TOX. 4
(DERMAL), H312
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
CONTENT UNDER PRESSURE. "FROSTBITE-LIKE" EFFECTS MAY OCCUR IF THE LIQUID OR
ESCAPING VAPORS CONTACT THE EYES OR SKIN. GROSS INHALATION OVER EXPOSURE
MAY CAUSE: CENTRAL NERVOUS SYSTEM DEPRESSION WITH DIZZINESS, CONFUSION,
INCOORDINATION, DROWSINESS OR UNCONSCIOUSNESS OR DEATH. VOMITING: PREVENT
ASPHYXIA/ASPIRATION PNEUMONIA.
FIRST-AID MEASURES AFTER INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT GIVE
OXYGEN. GET MEDICAL ATTENTION.
FIRST-AID MEASURES AFTER SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF SOAP AND WATER
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. REMOVE CONTAMINATED
CLOTHING AND SHOES, AND LAUNDER BEFORE REUSE. USE APPROVED SKIN LOTIONS OR
CREAMS TO REPLACE LOST SKIN OILS. TREAT FOR FROSTBITE IF NECESSARY BY
GENTLY WARMING AFFECTED AREA.
FIRST-AID MEASURES AFTER EYE CONTACT:
IN CASE OF CONTACT, OR SUSPECTED CONTACT, IMMEDIATELY FLUSH EYES WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION
IMMEDIATELY AFTER FLUSHING.
FIRST-AID MEASURES AFTER INGESTION:
DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH. GET MEDICAL ATTENTION!
IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION:
CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS. MENTAL CONFUSION.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE. BC POWDER. WATER FOG, CARBON DIOXIDE, FOAM, DRY CHEMICAL.
USE WATER SPRAY TO KEEP CONTAINERS COOL THAT ARE EXPOSED TO HEAT OR FLAMES.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. ADVICE FOR FIREFIGHTERS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
WARNING!
CONTENTS UNDER PRESSURE. CONTAINER MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR. WEAR APPROVED POSITIVE-PRESSURE SELF-CONTAINED
BREATHING APPARATUS AND PROTECTIVE CLOTHING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
WEAR APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT TO PREVENT SKIN AND EYE
CONTACT.
6.1.2. FOR EMERGENCY RESPONDERS: NO ADDITIONAL INFORMATION AVAILABLE
6.2. ENVIRONMENTAL PRECAUTIONS: NO ADDITIONAL INFORMATION AVAILABLE
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
INCREASE AREA VENTILATION. DO NOT PUNCTURE OR INCINERATE CONTAINER.
CONTENTS UNDER PRESSURE.
6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
CAUTION:
COMPRESSED GAS. DO NOT PUNCTURE, INCINERATE OR STORE ABOVE 120 DEG. F. DO
NOT STORE IN PASSENGER COMPARTMENT OF AUTOMOBILE. AVOID BREATHING VAPORS,
IF EXPOSED TO HIGH VAPOR CONCENTRATION, LEAVE AREA AT ONCE. AVOID CONTACT
WITH SKIN AND EYES. SHOULD NOT BE MIXED WITH AIR FOR LEAK TESTING OR USED
FOR ANY OTHER PURPOSE ABOVE ATMOSPHERIC PRESSURE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS: DO NOT STORE ABOVE 120 DEG. F.
STORAGE TEMPERATURE:
<49 DEG. C DO NOT STORE IN PASSENGER COMPARTMENT OF AUTOMOBILES.
STORAGE AREA: STORE IN A DRY AREA. STORE IN A COOL AREA.
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION AS NECESSARY TO MAINTAIN EXPOSURES TO WITHIN
APPLICABLE LIMITS. SHOWERS. EYEWASH STATIONS.
HAND PROTECTION: INSULATED GLOVES.
EYE PROTECTION:
SAFETY GLASSES. SAFETY GLASSES. WEAR SAFETY GLASSES OR GOGGLES TO PROTECT
AGAINST EXPOSURE.
SKIN AND BODY PROTECTION:
AVOID SKIN CONTACT. WEAR PROTECTIVE CLOTHING AND GLOVES.
RESPIRATORY PROTECTION: USE IN A WELL VENTILATED AREA.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR, COLORLESS LIQUID OR GAS AT AMBIENT TEMPERATURES.
COLOR: COLORLESS TO YELLOWISH.
ODOR: ETHER-LIKE ODOUR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: -26.5 DEG. C
FLASH POINT: NO DATA AVAILABLE
SELF IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
GAS GROUP: LIQUEFIED GAS
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS. STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
DO NOT EXPOSE TO HEAT OR STORE AT TEMPERATURES ABOVE 120 DEG. F.
10.5. INCOMPATIBLE MATERIALS: NO ADDITIONAL INFORMATION AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. THIS MATERIAL CAN BE DECOMPOSED BY HIGH
TEMPERATURES FORMING HYDROFLUORIC ACID AND POSSIBLY CARBONYL FLUORIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
LD50 ORAL RAT: 2000 MG/KG (RAT)
LD50 DERMAL RABBIT: 2000 MG/KG (RABBIT)
ATE (ORAL): 2000.000 MG/KG BODY WEIGHT
ATE (DERMAL): 2000.000 MG/KG BODY WEIGHT
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
ADDITIONAL INFORMATION:
DI-ISODECYL PHTHALATE (DIDP) HAS BEEN TESTED IN REPRODUCTIVE TOXICOLOGY
STUDIES IN LABORATORY RATS (TWO-GENERATION STUDIES). THERE WERE NO EFFECTS
ON FERTILITY, REPRODUCTIVE PERFORMANCE, OR EVIDENCE OF ALTERATION OF
ENDOCRINE PROCESSES. A SMALL, STATISTICALLY SIGNIFICANT DECREASE IN
OFFSPRING SURVIVAL WAS OBSERVED. IN EVALUATING THESE AND RELATED STUDIES,
THE EU RISK ASSESSMENT FOR DIDP HAS CONCLUDED THAT CLASSIFICATION AND
LABELING IS NOT REQUIRED FOR ANY EFFECT INCLUDING REPRODUCTIVE AND
DEVELOPMENTAL EFFECTS. IN ADDITION THE NTP CENTER FOR EVALUATION OF RISKS
TO HUMAN REPRODUCTION HAS CONCLUDED THAT THERE IS NEGLIGIBLE CONCERN FOR
REPRODUCTIVE EFFECTS IN ADULTS AND MINIMAL CONCERN FOR DEVELOPMENTAL
EFFECTS IN FETUSES AND CHILDREN DUE TO DIDP EXPOSURE.
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY:
(NOT EXPECTED TO CAUSE CANCER. THIS OIL MEETS THE IP-346 CRITERIA OF LESS
THAN 3 PERCENT PAH'S AND IS NOT CONSIDERED A CARCINOGEN BY THE
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER.)
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION:
CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS. MENTAL CONFUSION.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY: NO ADDITIONAL INFORMATION AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
PERSISTENCE AND DEGRADABILITY: EXPECTED TO BE READILY BIODEGRADABLE.
12.3. BIOACCUMULATIVE POTENTIAL:
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
BIOACCUMULATIVE POTENTIAL: NO BIOACCUMULATION DATA AVAILABLE.
12.4. MOBILITY IN SOIL:
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
SURFACE TENSION: 0.033 N/M
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH ADR / RID / IMDG / IATA / ADN
14.1. UN NUMBER:
UN-NO.(DOT): 3159
14.2. UN PROPER SHIPPING NAME:
DOT PROPER SHIPPING NAME: 1,1,1,2-TETRAFLUORETHANE
DEPARTMENT OF TRANSPORTATION (DOT) HAZARD CLASSES:
2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
14.3. ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
OVERLAND TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
24049 SUPERCOOL R-134A REFRIGERANT PLUS LEAK STOP (811-97-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
24049 SUPERCOOL R-134A REFRIGERANT PLUS LEAK STOP (811-97-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
NOT CLASSIFIED
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR 1999/45/EC:
15.2.2. NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
24049 SUPERCOOL R-134A REFRIGERANT PLUS LEAK STOP(811-97-2):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
STATE OR LOCAL REGULATIONS:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16: OTHER INFORMATION | |
FULL TEXT OF H-PHRASES: SEE SECTION 16
ACUTE TOX. 4 (DERMAL): ACUTE TOXICITY (DERMAL) CATEGORY 4
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL) CATEGORY 4
H302: HARMFUL IF SWALLOWED
H312: HARMFUL IN CONTACT WITH SKIN
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN.
NFPA REACTIVITY 1 - NORMALLY STABLE, BUT CAN BECOME UNSTABLE AT
ELEVATED TEMPERATURES AND PRESSURES OR MAY REACT
WITH WATER WITH SOME RELEASE OF ENERGY, BUT NOT
VIOLENTLY.
SDS US (GHS HAZCOM 2012) - TSI
THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED,
EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF TIRE SEAL, INC. THE DATA
ON THIS SHEET RELATED ONLY TO THE SPECIFIC MATERIAL DESIGNED HEREIN. TIRE
SEAL, INC. ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OR RELIANCE UPON
THESE DATA.
12/11/2014
EN (ENGLISH US)