| Common Name: | TOUGH GUY SOY BASED HD PAINT REMOVER - LIQUID, SKU: 3HFE4 |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 6/1/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3HFE4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
PREPARED ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH
26, 2012 / RULES AND REGULATIONS
W.W. GRAINGER, INC.
100 GRAINGER PARKWAY
LAKE FOREST, ILLINOIS 60045
| 1. IDENTIFICATION |  |
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME: TOUGH GUY(R*) SOY BASED HD PAINT REMOVER - LIQUID
SKU: 3HFE4
REVISION DATE: 06.01.15
SUPERSEDES DATE: 01.04.13
1.2 RELEVANT USES:
SOY-BASED MIXTURE; PRIMARY USE - PAINT STRIPPING AND GRAFFITI REMOVAL FOR
HORIZONTAL SURFACES; TERRAZZO FLOOR STRIPPING.
1.3 DETAILS OF MANUFACTURER:
W.W. GRAINGER, INC.
100 GRAINGER PARKWAY
LAKE FOREST, ILLINOIS 60045
USA
WWW.GRAINGER.COM
| 2. HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
SKIN IRRITANT: H315
EYE IRRITANT 2A: H319
REPRODUCTIVE 1B: H360
STOT SE 3: H335
2.2 LABEL ELEMENTS:
GHS - US LABELLING:
HAZARD PICTOGRAMS (GHS-US):
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
PRECAUTIONARY STATEMENTS (GHS-US) (PREVENTION):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P261: AVOID BREATHING FUME, MIST, OR VAPORS
P264: WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION
PRECAUTIONARY STATEMENTS (GHS-US) (RESPONSE):
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION
P312: CALL A DOCTOR, A POISON CENTER IF YOU FEEL UNWELL
P321: SPECIFIC TREATMENT (SEE FIRST AID INSTRUCTIONS ON LABEL)
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE
2.3 OTHER HAZARDS: NONE UNDER NORMAL CONDITIONS.
2.4 UNKNOWN ACUTE TOXICITY (GHS-US): NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCE: NOT APPLICABLE.
3.2 MIXTURE:
COMPOSITION: N-METHYL-2-PYRROLIDONE
CAS NO: 872-50-4
WEIGHT: <40%
ALL OTHER INGREDIENTS ARE TRADE SECRET AS AUTHORIZED BY 29 CFR 1910.1200(I)
(1). SPECIFIC INFORMATION WILL BE MADE AVAILABLE TO HEALTH-CARE
PROFESSIONALS, EMPLOYEES OR REPRESENTATIVES AS REQUIRED BY 29 CFR
1910.1200(I) (1) (IV) FOR MEDICAL EVALUATION OF TREATMENT.
| 4. FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
IF EXPOSED OR CONCERNED, GET MEDICAL ATTENTION. SHOW THIS SAFETY DATA SHEET
TO THE DOCTOR IN ATTENDANCE. WASH CONTAMINATED CLOTHING BEFORE RE-USE.
NEVER GIVE ANYTHING TO AN UNCONSCIOUS PERSON.
FIRST-AID MEASURES AFTER INHALATION:
IF INHALED:
REMOVE TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. GET MEDICAL ATTENTION. IF BREATHING IS DIFFICULT, SUPPLY OXYGEN.
IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION.
FIRST-AID MEASURES AFTER SKIN CONTACT:
IF ON SKIN (OR CLOTHING):
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN WITH WATER FOR AT LEAST
15 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY.
FIRST-AID MEASURES AFTER EYE CONTACT:
IF IN EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES IF PRESENT AND EASY TO DO SO. GET MEDICAL ATTENTION
IMMEDIATELY. CONTINUE RINSING.
FIRST-AID MEASURES AFTER INGESTION:
IF SWALLOWED:
RINSE MOUTH THOROUGHLY. DO NOT INDUCE VOMITING WITHOUT ADVICE FROM POISON
CONTROL CENTER OR MEDICAL PROFESSIONAL. GET MEDICAL ATTENTION IMMEDIATELY.
4.2 MORE IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: MAY CAUSE SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION.
CHRONIC SYMPTOMS: MAY DAMAGE FERTILITY. MAY DAMAGE THE UNBORN CHILD.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE.
| 5. FIRE-FIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM; DRY POWDER; CARBON DIOXIDE; WATER SPRAY; SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD:
RAGS SOAKED WITH PRODUCT MAY PRESENT A FIRE OR SPONTANEOUS COMBUSTION
HAZARD.
EXPLOSION HAZARD: PRODUCT IS NOT EXPLOSIVE.
REACTIVITY: NO DANGEROUS REACTIONS KNOWN UNDER NORMAL USE.
5.3 ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. DO NOT DISPOSE OF FIRE-FIGHTING WATER IN
THE ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
SPECIFIC EMERGENCY MEASURES ARE REQUIRED OTHER THAN GOOD LABORATORY HYGIENE
AND SAFETY PRACTICES.
6.1.1 FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: WEAR PROTECTIVE EQUIPMENT AS DESCRIBED IN SECTION 8.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2 FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE OR FACE PROTECTION;
APPROVED SUPPLIED-AIR RESPIRATOR, IN CASE OF EMERGENCY.
6.2 ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN ANY SPILLS WITH DIKES OR ABSORBENTS TO PREVENT MIGRATION AND ENTRY
INTO SEWERS OR STREAMS.
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. PLACE IN A SUITABLE CONTAINER FOR DISPOSAL IN ACCORDANCE
WITH THE WASTE REGULATIONS.
6.4 REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE.
| 7. HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: STABLE (SHELF LIFE >2 YEARS).
STORAGE CONDITIONS:
STORE IN DRY, WELL-VENTILATED AREA. KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE MATERIALS: COMBUSTIBLE MATERIALS.
7.3 SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| 8. EXPOSURE CONTROL/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
1-METHYL-2-PYRROLIDONE (872-50-4):
REMARK (ACGIH): OELS NOT ESTABLISHED
REMARK (OSHA): OELS NOT ESTABLISHED
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS
TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. USE
EXPLOSION-PROOF EQUIPMENT WITH FLAMMABLE MATERIALS. ENSURE ADEQUATE
VENTILATION, ESPECIALLY IN CONFINED AREAS.
PERSONAL PROTECTIVE EQUIPMENT: GLOVES; PROTECTIVE GOGGLES.
HAND PROTECTION:
USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL WHEN PROLONGED OR REPEATED
CONTACT COULD OCCUR. GLOVES SHOULD BE CLASSIFIED UNDER STANDARD EN 374 OR
ASTM F1296.
SUGGESTED GLOVE MATERIALS ARE:
NEOPRENE, NITRILE/BUTADIENE RUBBER, POLYETHYLENE, ETHYL VINYL ALCOHOL
LAMINATE, PVC OR VINYL. SUITABLE GLOVES FOR THIS SPECIFIC APPLICATION
CAN BE RECOMMENDED BY THE GLOVE SUPPLIER. CHANGE CONTAMINATED GLOVES
IMMEDIATELY.
EYE PROTECTION:
WEAR EYE PROTECTION, INCLUDING CHEMICAL SPLASH GOGGLES AND A FACE SHIELD
WHEN POSSIBILITY EXISTS FOR EYE CONTACT DUE TO SPRAYING LIQUID.
SKIN AND BODY PROTECTION:
WEAR LONG SLEEVES, AND CHEMICALLY IMPERVIOUS PPE/COVERALLS TO MINIMIZE
BODILY EXPOSURE.
RESPIRATORY PROTECTION:
USE NIOSH-APPROVED DUST/PARTICULATE RESPIRATOR. WHERE VAPOR OR MIST EXCEED
PELS OR OTHER APPLICABLE OELS, USE NIOSH-APPROVED RESPIRATORY PROTECTIVE
EQUIPMENT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: YELLOW LIQUID
ODOR: MILD
PH @ 1% SOLUTION: 8.0 - 9.0
FREEZING POINT: NO DATA AVAILABLE.
BOILING POINT: 251 DEG. C (>483 DEG. F)
FLASH POINT: >116 DEG. C (>240 DEG. F)
RELATIVE DENSITY: 0.994
SOLUBILITY: NOT SOLUABLE
9.2. OTHER INFORMATION:
VOC CONTENT (METHOD 310): 4.98%
| 10. STABILITY & REACTIVITY | |
10.1. REACTIVITY:
NO DANGEROUS REACTIONS KNOWN UNDER NORMAL CONDITIONS OF USE.
10.2. CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED HANDLING AND STORAGE CONDITIONS (SEE SECTION 7).
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
10.4. CONDITIONS TO AVOID: IGNITION SOURCES.
10.5. INCOMPATIBLE MATERIALS: ACIDS. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES (CO, CO2).
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY: NOT CLASSIFIED
W.W. GRAINGER DOES NOT TEST ON ANIMALS. THE FOLLOWING INFORMATION IS FROM
RAW MATERIALS ONLY:
1-METHYL-2-PYRROLIDONE (872-50-4):
LD50 ORAL RAT: 3598 MG/KG
LD50 DERMAL RAT: 2500 MG/KG
LD50 DERMAL RABBIT: >5000 MG/KG
LC50 INHALATION RAT (MG/L): 3.1 MG/L/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH:
HUMAN - A 24 HOUR HUMAN SKIN PATCH TEST INDICATED THAT UNDILUTED MATERIAL
PRODUCED VERY MILD IRRITATION. IRRITANCY WAS LESS THAN THAT PRODUCED BY A
4% AQUEOUS SOAP SOLUTION.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH:
HUMAN - A 24 HOUR HUMAN SKIN PATCH TEST INDICATED THAT UNDILUTED MATERIAL
PRODUCED VERY MILD IRRITATION. IRRITANCY WAS LESS THAN THAT PRODUCED BY A
4% AQUEOUS SOAP SOLUTION.
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER SKIN CONTACT: MAY CAUSE SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION.
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
AQUATIC TOXICITY RATING NOT DETERMINED. ALL POSSIBLE MEASURES SHOULD BE
TAKEN TO PREVENT RELEASE INTO THE ENVIRONMENT.
12.2. PERSISTENCE/DEGRADABILITY: READILY BIODEGRADIBLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DO NOT DISCHARGE TO PUBLIC WASTEWATER SYSTEMS WITHOUT PERMIT OF POLLUTION
CONTROL AUTHORITIES. NO DISCHARGE TO SURFACE WATERS IS ALLOWED WITHOUT AN
NPDES PERMIT.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
| 14. TRANSPORTATION INFORMATION | |
IN ACCORDANCE WITH DOT: NOT HAZARDOUS FOR TRANSPORT.
DOT PROPER SHIPPING NAME: NOT LISTED
TRANSPORT BY SEA: NON-HAZARDOUS
TRANSPORT BY AIR: NON-HAZARDOUS
IMDG CLASSIFICATION: NONE
DANGEROUS GOODS (CANADA): NOT LISTED
| 15. REGULATORY INFORMATION | |
15.1 US FEDERAL REGULATIONS:
TOUGH GUY(R*) SOY BASED HD PAINT REMOVER - LIQUID:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT ARE LISTED IN THE EPA (ENVIRONMENT
PROTECTION AGENCY) TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
1-METHYL-2-PYRROLIDONE (872-50-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON UNITED STATES SARA SECTION 313
SARA SECTION 313 - EMISSION REPORTING: 1% DE MINIMIS CONCENTRATION
15.2 INTERNATIONAL REGULATIONS:
CHEMICAL INVENTORIES:
IN COMPLIANCE DENOTES ALL COMPONENTS ARE ON INVENTORY OR EXEMPT.
U. S. (TSCA): IN COMPLIANCE
EUROPE (EINECS): LISTED ON EINECS
AUSTRALIA (NOHSC): IN COMPLIANCE
CHINA: IN COMPLIANCE
CANADA (CEPA): LISTED ON DSL.
JAPAN (ENCS): LISTED ON MITI
KOREA: IN COMPLIANCE
PHILIPPINES: IN COMPLIANCE
15.3 OTHER REGULATORY INFORMATION:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS, OR MAY CONTAIN, TRACE QUANTITIES OF A SUBSTANCE
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE
TOXICITY:
1-METHYL-2-PYRROLIDONE (872-50-4):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
1-METHYL-2-PYRROLIDONE (872-50-4):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST:
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST:
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST:
| 16. OTHER INFORMATION | |
INDICATION OF CHANGES: SDS CONVERSION FROM MSDS
REVISION DATE: 6.1.15
OTHER INFORMATION:
AUTHOR: RMF
NFPA RATING:
2
1
0
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE
TEMPORARY INCAPACITATION OR POSSIBLE RESIDUAL
INJURY UNLESS PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 1 - MUST BE PREHEATED BEFORE IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 2
FLAMMABILITY 1
PHYSICAL 0
PERSONAL PROTECTION
MANUFACTURER DISCLAIMER:
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT