| Common Name: | RUSTAID / GOOF OFF BATHROOM RUST STAIN CLEANER SPRAY, QSX20001, PSX20004, ESX200 |
| Manufacturer: | W.M. BARR |
| SDS Revision Date: | 8/18/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 48RF68 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
RUSTAID / GOOF OFF BATHROOM RUST STAIN CLEANER SPRAY
PRINTED: 08/28/2015
REVISION: 08/18/2015
SUPERSEDES REVISION: 05/29/2015
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: RUSTAID / GOOF OFF BATHROOM RUST STAIN CLEANER SPRAY
COMPANY NAME:
W. M. BARR
2105 CHANNEL AVENUE
MEMPHIS, TN 38113
PHONE NUMBER: (901)775-0100
WEB SITE ADDRESS: WWW.WMBARR.COM
EMERGENCY CONTACT:
3E 24 HOUR EMERGENCY CONTACT: (800)451-8346
INFORMATION:
W.M. BARR CUSTOMER SERVICE: (800)398-3892
INTENDED USE: REMOVES RUST AND RUST STAINS
PRODUCT CODE: QSX20001, PSX20004, ESX20005
ADDITIONAL INFORMATION:
THIS PRODUCT IS REGULATED BY THE UNITED STATES CONSUMER PRODUCT SAFETY
COMMISSION AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER THE
FEDERAL HAZARDOUS SUBSTANCES ACT. THESE REQUIREMENTS DIFFER FROM THE
CLASSIFICATION CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA
SHEETS (SDS). THE PRODUCT LABEL ALSO INCLUDES OTHER IMPORTANT INFORMATION,
INCLUDING DIRECTIONS FOR USE, AND SHOULD ALWAYS BE READ IN ITS ENTIRETY
PRIOR TO USING THE PRODUCT.
| 2. HAZARDS IDENTIFICATION | |
SKIN CORROSION/IRRITATION, CATEGORY 3
SERIOUS EYE DAMAGE/EYE IRRITATION, CATEGORY 2B
GHS SIGNAL WORD: WARNING
GHS HAZARD PHRASES:
H316: CAUSES MILD SKIN IRRITATION.
H320: CAUSES EYE IRRITATION.
GHS PRECAUTION PHRASES:
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
GHS RESPONSE PHRASES:
P305+351+338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P332+313: IF SKIN IRRITATION OCCURS, GET MEDICAL ADVICE/ATTENTION.
P337+313: IF EYE IRRITATION PERSISTS, GET MEDICAL ADVICE/ATTENTION.
GHS STORAGE AND DISPOSAL PHRASES: NO PHRASES APPLY.
HAZARD RATING SYSTEM:
HMIS:
HEALTH 1
FLAMMABILITY 0
PHYSICAL 0
PPE X
NFPA:
HEALTH 1
FLAMMABILITY 0
| INSTABILITY 0
SPECIAL HAZARD
OSHA REGULATORY STATUS:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS.
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC):
ACUTE EYE CONTACT:
MAY CAUSE MILD EYE IRRITATION. SYMPTOMS INCLUDE PAIN, STINGING, TEARING,
EXCESSIVE BLINKING, SWELLING, AND REDNESS. MAY CAUSE CONJUNCTIVITIS AND
CORNEAL BURNS.
ACUTE SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. SYMPTOMS MAY INCLUDE REDNESS AND BURNING OF THE
SKIN. REPEATED OR PROLONGED CONTACT MAY CAUSE DERMATITIS.
CONCENTRATED SOLUTIONS OF HYDROFLOURIC ACID IS EXTREMELY CORROSIVE TO THE
SKIN, WHICH CAN CAUSE SEVERE SKIN BURNS WITH ULCERATION AND PAIN. EFFECTS
FROM HYDROFLOURIC ACID CONTACT MAY NOT BE READILY APPARENT (DELAYED).
HYDROFLOURIC ACID BURNS MAY BE SLOW IN HEALING.
ACUTE INGESTION:
INGESTION MAY CAUSE CORROSION AND BURNS OF THE MOUTH, THROAT, ESOPHAGUS,
STOMACH, SMALL BOWEL, AND DIGESTIVE TRACT WITH VOMITING, ABDOMINAL PAIN,
COLLAPSE, AND POSSIBLE CONVULSIONS. DEATH MAY RESULT.
ACUTE INHALATION:
MAY CAUSE IRRITATION OF THE NOSE, THROAT, AND AIRWAYS. MAY CAUSE CENTRAL
NERVOUS SYSTEM DEPRESSION, DIZZINESS, DROWSINESS, WEAKNESS, NAUSEA,
HEADACHE, AND UNCONSCIOUSNESS.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
PREEXISTING DISORDERS OF THE LUNG AND KIDNEY.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CAS # HAZARDOUS COMPONENTS (CHEMICAL NAME) CONCENTRATION
144-62-7 OXALIC ACID {ETHANEDIOIC ACID} <7.0 %
57-55-6 PROPYLENE GLYCOL {1,2-PROPANEDIOL (NOT 313)} <5.0 %
7664-39-3 HYDROGEN FLUORIDE {HYDROFLUORIC ACID; FLOURIC <0.5 %
ACID}
ADDITIONAL CHEMICAL INFORMATION:
SPECIFIC PERCENTAGE OF COMPOSITION IS BEING WITHHELD AS A TRADE SECRET.
| 4. FIRST AID MEASURES | |
EMERGENCY AND FIRST AID PROCEDURES:
EYE CONTACT:
IMMEDIATELY BEGIN FLUSHING THE EYES WITH WATER, REMOVE ANY CONTACT LENS,
AND CONTINUE FLUSHING FOR A MINIMUM OF 15 MINUTES. AFTER THIS, GET
IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING WHILE
WASHING. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INGESTION:
CALL YOUR POISON CONTROL CENTER, HOSPITAL EMERGENCY ROOM OR PHYSICIAN
IMMEDIATELY FOR INSTRUCTIONS. YOU CAN IMMEDIATELY DRINK LARGE AMOUNTS
OF WATER OR MILK WITH ADDED MILK OF MAGNESIA. DO NOT INDUCE VOMITING
UNLESS DIRECTED BY MEDICAL PERSONNEL.
INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SIGNS AND SYMPTOMS OF EXPOSURE: SEE POTENTIAL HEALTH EFFECTS.
| 5. FIRE FIGHTING MEASURES | |
FLASH PT: NO DATA.
EXPLOSIVE LIMITS:
LEL: NO DATA.
UEL: NO DATA.
AUTOIGNITION PT: NO DATA.
SUITABLE EXTINGUISHING MEDIA:
NON-COMBUSTIBLE LIQUID - USE EXTINGUISHING MEDIA FOR UNDERLYING CAUSE
OF FIRE.
DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
FIRE FIGHTING INSTRUCTIONS:
SELF-CONTAINED RESPIRATORY PROTECTION SHOULD BE PROVIDED FOR FIRE FIGHTERS
FIGHTING FIRES IN BUILDINGS OR CONFINED AREAS. STORAGE CONTAINERS EXPOSED
TO FIRE SHOULD BE KEPT COOL WITH WATER SPRAY TO PREVENT PRESSURE BUILD-UP.
STAY AWAY FROM HEADS OF CONTAINERS THAT HAVE BEEN EXPOSED TO INTENSE HEAT
OR FLAME.
FLAMMABLE PROPERTIES AND HAZARDS:
FLASHPOINT: NO FLASH TO BOILING
WILL NOT BURN.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
ISOLATE HAZARD AREA. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM
ENTERING. STAY UPWIND. WEAR PROTECTIVE EQUIPMENT AND CLOTHING TO PREVENT
SKIN AND EYE CONTACT AND INHALATION OF VAPORS.
YOU MAY DILUTE AND SUPPRESS VAPORS WITH A WATER FOG. NEUTRALIZE PRODUCT
WITH LIME. COLLECT MATERIAL FOR PROPER DISPOSAL. PREVENT RUNOFF TO SEWERS
AND BODIES OF WATER.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID BREATHING OF VAPORS OR MIST.
PREVENT SKIN AND EYE CONTACT.
PREVENT INGESTION OF MATERIAL.
USE WITH A SOURCE OF WATER IN THE IMMEDIATE AREA FOR FLUSHING OF THE SKIN
AND EYES.
READ CAREFULLY ALL CAUTIONS AND DIRECTIONS ON PRODUCT LABEL BEFORE USE.
SINCE EMPTY CONTAINER RETAINS RESIDUE, FOLLOW ALL LABEL WARNINGS EVEN
AFTER CONTAINER IS EMPTY. DISPOSE OF EMPTY CONTAINER ACCORDING TO ALL
APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT REUSE THIS
CONTAINER.
PRECAUTIONS TO BE TAKEN IN STORING:
KEEP FROM FREEZING.
STORE AWAY FROM INCOMPATIBLE SUBSTANCES.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CAS # PARTIAL CHEMICAL OSHA TWA ACGIH TWA OTHER LIMITS
NAME
144-62-7 OXALIC ACID PEL: TLV: NO DATA.
{ETHANEDIOIC ACID} 1 MG/M3 1 MG/M3
STEL:
2 MG/M3
57-55-6 PROPYLENE GLYCOL NO DATA. NO DATA. NO DATA.
{1,2-PROPANEDIOL
(NOT 313)}
7664-39-3 HYDROGEN FLUORIDE PEL: CEIL: NO DATA.
{HYDROFLUORIC ACID; 3 PPM 3 PPM
FLOURIC ACID}
RESPIRATORY EQUIPMENT (SPECIFY TYPE):
WHEN USED AS DIRECTED, RESPIRATORY EQUIPMENT SHOULD NOT BE NEEDED. USE
WITH ADEQUATE VENTILATION
WEAR NIOSH APPROVED RESPIRATORY PROTECTIVE EQUIPMENT WHEN VAPOR OR MISTS
MAY EXCEED APPLICABLE CONCENTRATION LIMITS.
EYE PROTECTION:
WHERE THERE IS POTENTIAL FOR EYE CONTACT, WEAR CHEMICAL GOGGLES, OR
GOGGLES WITH A FACESHIELD. HAVE A SOURCE OF CLEAN WATER AVAILABLE FOR
IMMEDIATE FLUSHING OF THE EYES.
PROTECTIVE GLOVES:
WEAR IMPERMEABLE GLOVES. GLOVES CONTAMINATED WITH PRODUCT SHOULD BE
DISCARDED.
OTHER PROTECTIVE CLOTHING:
VARIOUS APPLICATION METHODS CAN DICTATE USE OF ADDITIONAL PROTECTIVE
SAFETY EQUIPMENT, SUCH AS IMPERMEABLE APRONS, ETC., TO MINIMIZE
EXPOSURE.
ENGINEERING CONTROLS (VENTILATION ETC.):
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
USE ONLY WITH ADEQUATE VENTILATION TO PREVENT BUILDUP OF VAPORS.
OPEN WINDOWS AND DOORS AND MAINTAIN A CROSS VENTILATION OF MOVING FRESH
AIR ACROSS THE WORK AREA.
IF STRONG ODOR IS NOTICED OR YOU EXPERIENCE SLIGHT DIZZINESS, HEADACHE,
NAUSEA OR EYE-WATERING -- STOP -- VENTILATION IS INADEQUATE. LEAVE AREA
IMMEDIATELY AND MOVE TO FRESH AIR.
WORK/HYGIENIC/MAINTENANCE PRACTICES:
WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING.
DO NOT EAT, DRINK, OR SMOKE IN THE WORK AREA.
CLOTHING THAT BECOMES SOILED WITH PRODUCT SHOULD BE REMOVED AS SOON AS
POSSIBLE AND LAUNDERED SEPARATELY.
DISCARD ANY CLOTHING OR OTHER PROTECTIVE EQUIPMENT THAT CANNOT BE
DECONTAMINATED.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATES:
[ ] GAS
[X] LIQUID
[ ] SOLID
APPEARANCE AND ODOR: CLEAR, GREEN, THIN
MELTING POINT: APPROX. 32.00 F
BOILING POINT: >=212.00 F
AUTOIGNITION PT: NO DATA.
FLASH PT: NO DATA.
EXPLOSIVE LIMITS:
LEL: NO DATA.
UEL: NO DATA.
SPECIFIC GRAVITY (WATER = 1): 1.03
DENSITY: 8.58 LB/GL
VAPOR PRESSURE (VS. AIR OR MM Hg): <1 MM HG AT 68.0 F
VAPOR DENSITY (VS. AIR = 1): NO DATA.
EVAPORATION RATE: <1
SOLUBILITY IN WATER: SOLUBLE
PH: <1
PERCENT VOLATILE: 92.6 % BY WEIGHT.
| 10. STABILITY AND REACTIVITY | |
STABILITY:
UNSTABLE [ ]
STABLE [X]
CONDITIONS TO AVOID - INSTABILITY: NO DATA AVAILABLE.
INCOMPATIBILITY - MATERIALS TO AVOID:
ALKALIES, SILVER COMPOUNDS, STRONG OXIDIZERS, STRONG BASES, STRONG ACIDS,
OLEUM, CYANIDES, SULFIDES, CARBONATES, ACTIVE METALS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
FLOURIDES, CARBON MONOXIDE, CARBON DIOXIDE, TOXIC FORMIC ACID, ORGANIC
COMPOUNDS.
POSSIBILITY OF HAZARDOUS REACTIONS:
WILL OCCUR [ ]
WILL NOT OCCUR [X]
CONDITIONS TO AVOID - HAZARDOUS REACTIONS: NO DATA AVAILABLE.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION:
PRODUCT HAS NOT BEEN TESTED AS A WHOLE. REFER TO SECTION 2 FOR ACUTE
AND CHRONIC HEALTH EFFECTS.
CAS# 144-62-7:
EYES, SPECIES: RABBIT, 100.0 MG, 4 S, SEVERE.
RESULT:
BEHAVIORAL: EXCITEMENT.
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION.
SKIN AND APPENDAGES:
OTHER: HAIR.
FOOD AND CHEMICAL TOXICOLOGY., PERGAMON PRESS INC., MAXWELL HOUSE,
FAIRVIEW PARK, ELMSFORD, NY 10523, VOL/P/YR: 20,573, 1982
CAS# 57-55-6:
ACUTE TOXICITY, LD50, ORAL, RAT, 20.00 GM/KG.
RESULT:
SENSE ORGANS AND SPECIAL SENSES (NOSE, EYE, EAR, AND TASTE):
OLFACTION: OTHER CHANGES.
SENSE ORGANS AND SPECIAL SENSES (NOSE, EYE, EAR, AND TASTE):
EYE: CONJUNCTIVE IRRITATION.
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES.
TOXICOLOGY AND APPLIED PHARMACOLOGY, ACADEMIC PRESS, INC., 1 E. FIRST
ST., DULUTH, MN 55802, VOL/P/YR: 45,362, 1978
CAS# 7664-39-3:
STANDARD DRAIZE TEST, EYES, HUMAN, 50.00 MG, SEVERE.
RESULT:
RELATED TO CHRONIC DATA - DEATH.
ANNALES DE MEDECINE LEGALE ET DE CRIMINOLOGIE., FOR PUBLISHER INFORMATION,
SEE MLDCAS, PARIS FRANCE, VOL/P/YR: 37,110, 1957
CAS # HAZARDOUS COMPONENTS NTP IARC ACGIH OSHA
(CHEMICAL NAME)
144-62-7 OXALIC ACID N.A. N.A. N.A. N.A.
{ETHANEDIOIC ACID}
57-55-6 PROPYLENE GLYCOL N.A. N.A. N.A. N.A.
{1,2-PROPANEDIOL
(NOT 313)}
7664-39-3 HYDROGEN FLUORIDE N.A. N.A. N.A. N.A.
{HYDROFLUORIC ACID;
FLOURIC ACID}
| 12. ECOLOGICAL INFORMATION | |
GENERAL ECOLOGICAL INFORMATION:
PRODUCT HAS NOT BEEN TESTED AS A WHOLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
DISPOSE IN ACCORDANCE WITH APPLICABLE LOCAL, STATE, AND FEDERAL
REGULATIONS.
| 14. TRANSPORT INFORMATION | |
LAND TRANSPORT (US DOT):
DOT PROPER SHIPPING NAME: COMPOUND CLEANING LIQUID
DOT HAZARD CLASS:
UN/NA NUMBER:
| 15. REGULATORY INFORMATION | |
EPA SARA (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986) LISTS
CAS # HAZARDOUS COMPONENTS S. 302 (EHS) S. 304 RQ S. 313 (TRI)
(CHEMICAL NAME)
144-62-7 OXALIC ACID NO NO NO
{ETHANEDIOIC ACID}
57-55-6 PROPYLENE GLYCOL NO NO NO
{1,2-PROPANEDIOL
(NOT 313)}
7664-39-3 HYDROGEN FLUORIDE YES 100 LB YES 100 YES
{HYDROFLUORIC ACID; LB
FLOURIC ACID}
THIS MATERIAL MEETS THE EPA 'HAZARD CATEGORIES' DEFINED FOR SARA TITLE III
SECTIONS 311/312 AS INDICATED:
[X] YES
[ ] NO ACUTE (IMMEDIATE) HEALTH HAZARD
[ ] YES
[X] NO CHRONIC (DELAYED) HEALTH HAZARD
[ ] YES
[X] NO FIRE HAZARD
[ ] YES
[X] NO SUDDEN RELEASE OF PRESSURE HAZARD
[ ] YES
[X] NO REACTIVE HAZARD
CAS # HAZARDOUS COMPONENTS (CHEMICAL NAME) OTHER US EPA OR STATE
LISTS
144-62-7 OXALIC ACID {ETHANEDIOIC ACID} CAA HAP,ODC: NO;
CWA NPDES: NO;
TSCA: YES - INVENTORY,
4 TEST; CA PROP.65: NO
57-55-6 PROPYLENE GLYCOL {1,2-PROPANEDIOL CAA HAP,ODC: NO;
(NOT 313)} CWA NPDES: NO;
TSCA: YES - INVENTORY;
CA PROP.65: NO
7664-39-3 HYDROGEN FLUORIDE {HYDROFLUORIC CAA HAP,ODC: HAP;
ACID; FLOURIC ACID} CWA NPDES: NO;
TSCA: YES - INVENTORY,
4 TEST, 12(B);
CA PROP.65: NO
| 16. OTHER INFORMATION | |
REVISION DATE: 08/18/2015
PREPARER NAME:
W.M. BARR EHS DEPT
(901)775-0100
ADDITIONAL INFORMATION ABOUT THIS PRODUCT: NO DATA AVAILABLE.
COMPANY POLICY OR DISCLAIMER:
THE INFORMATION CONTAINED HEREIN IS PRESENTED IN GOOD FAITH AND BELIEVED
TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. THIS INFORMATION IS
FURNISHED WITHOUT WARRANTY OF ANY KIND. EMPLOYERS SHOULD USE THIS
INFORMATION ONLY AS A SUPPLEMENT TO OTHER INFORMATION GATHERED BY THEM AND
MUST MAKE INDEPENDENT DETERMINATION OF SUITABILITY AND COMPLETENESS OF
INFORMATION FROM ALL SOURCES TO ASSURE PROPER USE OF THESE MATERIALS AND
THE SAFETY AND HEALTH OF EMPLOYEES. ANY USE OF THIS DATA AND INFORMATION
MUST BE DETERMINED BY THE USER TO BE IN ACCORDANCE WITH APPLICABLE
FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
LICENSED TO W.M. BARR AND COMPANY
GHS FORMAT