| Common Name: | SPIC AND SPAN FLOOR AND MULTI-SURFACE CLEANER -CONCENTRATE |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 4/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2NDT2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
SAFETY DATA SHEET
ISSUING DATE: 15-JAN-2015
REVISION DATE: 07-APR-2015
VERSION: 2
| 1. IDENTIFICATION |  |
PRODUCT NAME:
SPIC AND SPAN(R*) FLOOR AND MULTI-SURFACE CLEANER -CONCENTRATE
PRODUCT CODE(S): 4-40
PRODUCT ID: 15154370_PROF_NG
PRODUCT TYPE: FINISHED PRODUCT - PROFESSIONAL USE ONLY
RECOMMENDED USE: FLOOR CARE
RESTRICTIONS ON USE: USE ONLY AS DIRECTED ON LABEL.
MANUFACTURER:
PROCTER & GAMBLE PROFESSIONAL
2 P&G PLAZA
CINCINNATI, OHIO 45202
PROCTER & GAMBLE INC.
P.O. BOX 355, STATION A
TORONTO, ON M5W 1C5
1-800-332-7787
E-MAIL ADDRESS PGSDS.IM@PG.COM
EMERGENCY TELEPHONE:
TRANSPORTATION (24 HR):
CHEMTREC: 1-800-424-9300 (U.S./ CANADA) OR 1-703-527-3887
MEXICO TOLL FREE IN COUNTRY: 800-681-9531
| 2. HAZARD IDENTIFICATION | |
THIS PRODUCT IS CLASSIFIED UNDER 29 CFR 1910.1200(D) AND THE CANADIAN
HAZARDOUS PRODUCTS REGULATION AS FOLLOWS:
HAZARD CATEGORY:
EYE DAMAGE / IRRITATION: CATEGORY 2A
SIGNAL WORD: WARNING
HAZARD STATEMENTS: CAUSES SERIOUS EYE IRRITATION
HAZARD PICTOGRAMS: EXCLAMATION MARK
PRECAUTIONARY STATEMENTS - PREVENTION: NONE
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SWALLOWED: DRINK 1 OR 2 GLASSES OF WATER
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS ARE LISTED ACCORDING TO 29 CFR 1910.1200 APPENDIX D AND THE
CANADIAN HAZARDOUS PRODUCTS REGULATION:
CHEMICAL NAME SYNONYMS TRADE SECRET CAS-NO WEIGHT %
BENZENESULFONIC ACID, NO 68081-81-2 5 - 10
MONO-C10-16-ALKYL
DERIVS., SODIUM SALTS
POLY(OXY-1,2-ETHANEDIYL), NO 68585-34-2 5 - 10
ALPHA-SULFO-OMEGA-HYDROXY-,
C10-16-ALKYL ETHERS,
SODIUM SALTS
BENZENESULFONIC ACID, NO 28348-53-0 5 - 10
(1-METHYLETHYL)-,
SODIUM SALT (1:1)
ETHANOL NO 64-17-5 1 - 5
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION
PERSISTS.
SKIN CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INGESTION:
DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NONE UNDER NORMAL USE CONDITIONS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIAL HAZARD: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
ADVICE FOR EMERGENCY RESPONDERS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED WHEN
NOT IN USE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE. KEEP OUT
OF THE REACH OF CHILDREN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME CAS-NO ACGIH TLV OSHA PEL MEXICO PEL
ETHANOL 64-17-5 STEL: 1000 PPM TWA: 1000 PPM MEXICO:
TWA: 1900 MG/M3 TWA: 1000 PPM
(VACATED) TWA: MEXICO:
1000 PPM TWA: 1900 MG/M3
(VACATED) TWA:
1900 MG/M3
CHEMICAL NAME CAS-NO ALBERTA QUEBEC ONTARIO BRITISH
TWAEV COLUMBIA
ETHANOL 64-17-5 TWA: 1000 PPM TWA: STEL: STEL:
TWA: 1880 MG/M3 1000 PPM 1000 PPM 1000 PPM
TWA:
1880 MG/M3
NO RELEVANT EXPOSURE GUIDELINES FOR OTHER INGREDIENTS
EXPOSURE CONTROLS:
ENGINEERING MEASURES:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS: ENSURE ADEQUATE VENTILATION
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
USE APPROPRIATE EYE PROTECTION
HAND PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
PROTECTIVE GLOVES
SKIN AND BODY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE @ 20 DEG. C: LIQUID
APPEARANCE: GREEN
ODOR: SCENTED
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES NOTE
PH VALUE 10.2 - 11.0
MELTING/FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT/BOILING RANGE NO INFORMATION AVAILABLE
FLASH POINT 57 DEG. C / 134.6 DEG. F PRODUCT IS AN
AQUEOUS SOLUTION
CONTAINING </=24%
ALCOHOL AND >50%
WATER
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
RELATIVE DENSITY 1.14-1.16
WATER SOLUBILITY 100%
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE.
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE.
VISCOSITY OF PRODUCT NO INFORMATION AVAILABLE
VOC CONTENT (%) PRODUCTS COMPLY WITH US
STATE AND FEDERAL
REGULATIONS FOR VOC
CONTENT IN CONSUMER
PRODUCTS.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
STABILITY: STABLE UNDER NORMAL CONDITIONS.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE UNDER NORMAL PROCESSING.
MATERIALS TO AVOID: NONE IN PARTICULAR.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL USE.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO KNOWN EFFECT.
SKIN CONTACT: NO KNOWN EFFECT.
INGESTION: NO KNOWN EFFECT.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
ACUTE TOXICITY: NO KNOWN EFFECT.
SKIN CORROSION/IRRITATION: NO KNOWN EFFECT.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZATION: NO KNOWN EFFECT.
RESPIRATORY SENSITIZATION: NO KNOWN EFFECT.
GERM CELL MUTAGENICITY: NO KNOWN EFFECT.
NEUROLOGICAL EFFECTS: NO KNOWN EFFECT.
REPRODUCTIVE TOXICITY: NO KNOWN EFFECT.
DEVELOPMENTAL TOXICITY: NO KNOWN EFFECT.
TERATOGENICITY: NO KNOWN EFFECT.
STOT - SINGLE EXPOSURE: NO KNOWN EFFECT.
STOT - REPEATED EXPOSURE: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: NO KNOWN EFFECT.
ASPIRATION HAZARD: NO KNOWN EFFECT.
CARCINOGENICITY: NO KNOWN EFFECT.
COMPONENT INFORMATION:
CHEMICAL NAME CAS-NO LD50 ORAL LD50 DERMAL LC50
INHALATION
BENZENESULFONIC 68081-81-2 1090.00 MG/KG
ACID, MONO- (RAT)
C10-16-ALKYL
DERIVS., SODIUM
SALTS
POLY (OXY- 68585-34-2 >2001 MG/KG
1,2-ETHANEDIYL),
ALPHA-SULFO-
OMEGA-HYDROXY-,
C10-16-ALKYL
ETHERS, SODIUM
SALTS
BENZENESULFONIC 28348-53-0 5160.00 MG/KG
ACID, (RAT)
(1-METHYLETHYL)-,
SODIUM SALT (1:1)
ETHANOL 64-17-5 10470 MG/KG >15800 MG/KG 116.9 MG/L
BW (OECD 401) BW (RABBIT) AIR (//OECD
403)
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES (NON-HOUSEHOLD SETTING): 331
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
IMDG: NOT REGULATED
IATA: NOT REGULATED
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS HAZARDOUS AIR
POLLUTANTS (HAPS) UNDER SECTION 112 OF THE CLEAN AIR ACT AMENDMENTS
OF 1990.
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
ETHANOL IS ONLY A CONSIDERED A PROPOSITION 65 DEVELOPMENTAL HAZARD WHEN IT
IS INGESTED AS AN ALCOHOLIC BEVERAGE.
U.S. STATE REGULATIONS (RTK):
CHEMICAL NAME CAS-NO NEW JERSEY
ETHANOL 64-17-5 X
CHEMICAL NAME CAS-NO MASSACHUSETTS
ETHANOL 64-17-5 X
CHEMICAL NAME CAS-NO PENNSYLVANIA
ETHANOL 64-17-5 X
SULFURIC ACID SODIUM SALT (1:2) 7757-82-6 X
INTERNATIONAL INVENTORIES:
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT(S) ARE LISTED ON THE US
TSCA INVENTORY.
CANADA: THIS PRODUCT IS IN COMPLIANCE WITH CEPA FOR IMPORT BY P&G.
LEGEND:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
CEPA - CANADIAN ENVIRONMENTAL PROTECTION ACT
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH HAZARD 2
FLAMMABILITY 2
PHYSICAL HAZARD 0
HEALTH HAZARD 2
FLAMMABILITY 2
INSTABILITY 0
ISSUING DATE: 15-JAN-2015
REVISION DATE: 07-APR-2015
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT