| Common Name: | TIDE HE ORIGINAL |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 4/17/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 46F045 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
SAFETY DATA SHEET
ISSUING DATE: 17-APR-2015
REVISION DATE: 17-APR-2015
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT NAME: TIDE HE ORIGINAL
PRODUCT ID: 96733938_RET_NG
PRODUCT TYPE: FINISHED PRODUCT - CONSUMER (RETAIL) USE ONLY
RECOMMENDED USE: LAUNDRY CARE
RESTRICTIONS ON USE: USE ONLY AS DIRECTED ON LABEL.
MANUFACTURER:
PROCTER & GAMBLE - FABRIC AND HOME CARE DIVISION
IVORYDALE TECHNICAL CENTRE
5289 SPRING GROVE AVENUE
CINCINNATI, OHIO 45217-1087
USA
PROCTER & GAMBLE INC.
P.O. BOX 355, STATION A
TORONTO, ON M5W 1C5
1-800-331-3774
E-MAIL ADDRESS: PGSDS.IM@PG.COM
EMERGENCY TELEPHONE:
TRANSPORTATION (24 HR):
CHEMTREC: 1-800-424-9300
(U.S./ CANADA) OR: 1-703-527-3887
MEXICO TOLL FREE IN COUNTRY: 800-681-9531
| 2. HAZARD IDENTIFICATION | |
"CONSUMER PRODUCTS", AS DEFINED BY THE US CONSUMER PRODUCT SAFETY ACT AND
WHICH ARE USED AS INTENDED (TYPICAL CONSUMER DURATION AND FREQUENCY), ARE
EXEMPT FROM THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). THIS
SDS IS BEING PROVIDED AS A COURTESY TO HELP ASSIST IN THE SAFE HANDLING AND
PROPER USE OF THE PRODUCT.
THIS PRODUCT IS CLASSIFIED UNDER 29CFR 1910.1200(D) AND THE CANADIAN
HAZARDOUS PRODUCTS REGULATION AS FOLLOWS:
HAZARD CATEGORY:
SKIN CORROSION/IRRITATION: CATEGORY 2
EYE DAMAGE / IRRITATION: CATEGORY 2A
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION
CAUSES SKIN IRRITATION
HAZARD PICTOGRAMS: EXCLAMATION MARK
PRECAUTIONARY STATEMENTS - PREVENTION: WASH HANDS THOROUGHLY AFTER HANDLING
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SWALLOWED: DRINK 1 OR 2 GLASSES OF WATER
IF ON SKIN:
RINSE WITH PLENTY OF WATER
IF SKIN IRRITATION OCCURS, GET MEDICAL ADVICE/ATTENTION
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS ARE LISTED ACCORDING TO 29CFR 1910.1200 APPENDIX D AND THE
CANADIAN HAZARDOUS PRODUCTS REGULATION:
CHEMICAL NAME SYNONYMS TRADE CAS-NO WEIGHT %
SECRET
SODIUM CARBONATE NO 497-19-8 25 - 30
SILICIC ACID, ALUMINUM NO 1344-00-9 15 - 20
SODIUM SALT
BENZENESULFONIC ACID, NO 68081-81-2 5 - 10
MONO-C10-16-ALKYL DERIVS.,
SODIUM SALTS
SILICIC ACID, SODIUM SALT NO 1344-09-8 1 - 5
CARBONIC ACID DISODIUM NO 15630-89-4 1 - 5
SALT, COMPD. WITH HYDROGEN
PEROXIDE
SODIUM 2-(NONANOYLOXY) NO 91125-43-8 1 - 5
BENZENESULFONATE
SULFURIC ACID, NO 68081-98-1 1 - 5
MONO-C14-18-ALKYL ESTERS,
SODIUM SALTS
HEPTADECANOL, HYDROGEN NO 343978-15-4 1 - 5
SULFATE, BRANCHED, SODIUM
SALT
POLY(OXY-1,2-ETHANEDIYL), NO 68585-34-2 1 - 5
ALPHA-SULFO-OMEGA-HYDROXY-,
C10-16-ALKYL ETHERS,
SODIUM SALTS
HEXADECANOL, HYDROGEN NO 343978-24-5 1 - 5
SULFATE, BRANCHED, SODIUM
SALT
GLYCINE, N,N-BIS[2-[BIS NO 140-01-2 0.5 - 1.5
(CARBOXYMETHYL)AMINO]
ETHYL]-, SODIUM SALT (1:5)
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION
PERSISTS.
SKIN CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INGESTION:
DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NONE UNDER NORMAL USE CONDITIONS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIAL HAZARD: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
ADVICE FOR EMERGENCY RESPONDERS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT DUST CLOUD. PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. DISPOSE OF IN
ACCORDANCE WITH LOCAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED WHEN
NOT IN USE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE. KEEP
OUT OF THE REACH OF CHILDREN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME CAS-NO ACGIH TLV OSHA PEL MEXICO PEL
SILICIC ACID, ALUMINUM 1344-00-9 TWA:
SODIUM SALT 1 MG/M3
RESPIRABLE
FRACTION
CHEMICAL NAME CAS-NO ALBERTA QUEBEC ONTARIO TWAEV BRITISH COLUMBIA
SILICIC ACID, 1344-00-9 TWA: 1 MG/M3 TWA: 1.0 MG/M3
ALUMINUM
SODIUM SALT
NO RELEVANT EXPOSURE GUIDELINES FOR OTHER INGREDIENTS
EXPOSURE CONTROLS:
ENGINEERING MEASURES:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS: ENSURE ADEQUATE VENTILATION
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
USE APPROPRIATE EYE PROTECTION
HAND PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
FOR SENSITIVE SKIN OR PROLONGED USE, WEAR GLOVES
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
PROTECTIVE GLOVES
SKIN AND BODY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE @ 20 DEG. C: SOLID
APPEARANCE: WHITE POWDER
ODOR: SCENTED
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES NOTE
PH VALUE 10 - 11.5
MELTING/FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT/BOILING RANGE NO INFORMATION AVAILABLE
FLASH POINT NO INFORMATION AVAILABLE
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
RELATIVE DENSITY 420 - 650 G/L
WATER SOLUBILITY MODERATELY SOLUBLE @ 20 DEG. C
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE.
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE.
VISCOSITY OF PRODUCT NO INFORMATION AVAILABLE
VOC CONTENT (%):
PRODUCTS COMPLY WITH US STATE AND FEDERAL REGULATIONS FOR VOC CONTENT
IN CONSUMER PRODUCTS.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
STABILITY: STABLE UNDER NORMAL CONDITIONS.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE UNDER NORMAL PROCESSING.
MATERIALS TO AVOID: NONE IN PARTICULAR.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL USE.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO KNOWN EFFECT.
SKIN CONTACT: IRRITATING TO SKIN.
INGESTION: NO KNOWN EFFECT.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
ACUTE TOXICITY: NO KNOWN EFFECT.
SKIN CORROSION/IRRITATION: IRRITATING TO SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZATION: NO KNOWN EFFECT.
RESPIRATORY SENSITIZATION: NO KNOWN EFFECT.
GERM CELL MUTAGENICITY: NO KNOWN EFFECT.
NEUROLOGICAL EFFECTS: NO KNOWN EFFECT.
REPRODUCTIVE TOXICITY: NO KNOWN EFFECT.
DEVELOPMENTAL TOXICITY: NO KNOWN EFFECT.
TERATOGENICITY: NO KNOWN EFFECT.
STOT - SINGLE EXPOSURE: NO KNOWN EFFECT.
STOT - REPEATED EXPOSURE: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: NO KNOWN EFFECT.
ASPIRATION HAZARD: NO KNOWN EFFECT.
CARCINOGENICITY: NO KNOWN EFFECT.
COMPONENT INFORMATION:
CHEMICAL NAME CAS-NO LD50 ORAL LD50 DERMAL LC50
INHALATION
SODIUM CARBONATE 497-19-8 2800 MG/KG >2000 MG/KG
BW BW (US EPA
16 CFR
1500.40)
SILICIC ACID, 1344-00-9 >10000 MG/KG >5000 MG/KG >2.08 MG/L
ALUMINUM SODIUM BW (//OECD BW (//OECD AIR (//OECD
SALT 401) 402) 403)
BENZENESULFONIC 68081-81-2 1090.00 MG/KG
ACID, MONO-C10- (RAT)
16-ALKYL DERIVS.,
SODIUM SALTS
SILICIC ACID, 1344-09-8 3400 MG/KG >5000 MG/KG >2.06 MG/L
SODIUM SALT BW (SIMILAR BW (READ AIR (READ
TO OECD 401; ACROSS DATA ACROSS DATA
STANDARD ON AGSIL TM AGSIL TM 25
ACUTE METHOD; 25 POTASSIUM POTASSIUM
RAT) SILICATE SILICATE
SOLUTION; SOLUTION;
RAT) EPA OPPTS
870.1300;
STANDARD ACUTE
METHOD; RAT)
CARBONIC ACID 15630-89-4 893 MG/KG >2000 MG/KG
DISODIUM SALT, BW (U.S. EPA BW (EPA
COMPD. WITH OFFICE OF GUIDELINE;
HYDROGEN PESTICIDES STANDARD
PEROXIDE AND TOXIC ACUTE
SUBSTANCES METHOD;
(1984) RABBIT)
"ACUTE
EXPOSURE ORAL
TOXICITY";
STANDARD
ACUTE
METHOD; RAT)
SODIUM 91125-43-8 6030.00 MG/KG
2-(NONANOYLOXY) (RAT)
BENZENESULFONATE
POLY(OXY-1,2- 68585-34-2 >2001 MG/KG
ETHANEDIYL),
ALPHA-SULFO-
OMEGA-HYDROXY-,
C10-16-ALKYL
ETHERS, SODIUM
SALTS
GLYCINE, N,N-BIS 140-01-2 >5000 MG/KG >2000 MG/KG
[2-[BIS BW (READ BW (OECD
(CARBOXYMETHYL) ACROSS DATA 402 AND EU
AMINO]ETHYL]-, (TEST METHOD B.3;
SODIUM SALT (1:5) SUBSTANCE STANDARD
NAME NOT ACUTE METHOD;
INDICATED); RAT)
OECD 401;
STANDARD
ACUTE
METHOD; RAT)
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES (NON-HOUSEHOLD SETTING): 331
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
IMDG: NOT REGULATED
IATA: NOT REGULATED
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED
AS A HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302):
CHEMICAL NAME CAS-NO HAZARDOUS EXTREMELY HAZARDOUS CERCLA/SARA
SUBSTANCES SUBSTANCES RQS 302 TPQ
RQS
SODIUM HYDROXIDE 1310-73-2 1000 LB
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS HAZARDOUS AIR
POLLUTANTS (HAPS) UNDER SECTION 112 OF THE CLEAN AIR ACT AMENDMENTS OF
1990.
CLEAN WATER ACT:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE REGULATED
POLLUTANTS PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND
40 CFR 122.42):
CHEMICAL NAME CAS-NO CWA - CWA - CWA - CWA -
REPORTABLE TOXIC PRIORITY HAZARDOUS
QUANTITIES POLLUTANTS POLLUTANTS SUBSTANCES
SODIUM 1310-73-2 1000 LB X
HYDROXIDE
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
U.S. STATE REGULATIONS (RTK):
CHEMICAL NAME CAS-NO MASSACHUSETTS
SULFURIC ACID SODIUM SALT (1:2) 7757-82-6 X
CHEMICAL NAME CAS-NO PENNSYLVANIA
SULFURIC ACID SODIUM SALT (1:2) 7757-82-6 X
SODIUM HYDROXIDE 1310-73-2 X
INTERNATIONAL INVENTORIES:
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT(S) ARE LISTED ON THE
US TSCA INVENTORY.
CANADA: THIS PRODUCT IS IN COMPLIANCE WITH CEPA FOR IMPORT BY P&G.
LEGEND:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
CEPA - CANADIAN ENVIRONMENTAL PROTECTION ACT
| 16. OTHER INFORMATION | |
ISSUING DATE: 17-APR-2015
REVISION DATE: 17-APR-2015
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT
96733938_RET_NG - TIDE HE ORIGINAL