| Common Name: | OFF! DEEP WOODS SPORTSMEN INSECT REPELLENT I |
| Manufacturer: | S.C. JOHNSON |
| SDS Revision Date: | 2/23/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4HK66 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SC JOHNSON
A FAMILY COMPANY
SAFETY DATA SHEET
ACCORDING TO HAZARD COMMUNICATION STANDARD; 29 CFR 1910.1200
OFF!(R*) DEEP WOODS(R*) SPORTSMEN INSECT REPELLENT I
VERSION: 1.1
REVISION DATE: 02/23/2015
PRINT DATE: 03/04/2015
SDS NUMBER: 350000003959
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT INFORMATION:
PRODUCT NAME: OFF!(R*) DEEP WOODS(R*) SPORTSMEN INSECT REPELLENT I
RECOMMENDED USE: INSECT REPELLENT
MANUFACTURER, IMPORTER, SUPPLIER:
S.C. JOHNSON & SON, INC.
1525 HOWE STREET
RACINE, WI 53403-2236
TELEPHONE: +18005585252
EMERGENCY TELEPHONE NUMBER:
24 HOUR MEDICAL EMERGENCY PHONE: (866)231-5406
24 HOUR INTERNATIONAL EMERGENCY PHONE: (703)527-3887
24 HOUR TRANSPORT EMERGENCY PHONE: (800)424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GLOBALLY HARMONIZED SYSTEM (GHS) CLASSIFICATION:
HAZARD CLASSIFICATION: EYE IRRITATION
HAZARD CATEGORY: CATEGORY 2B
HAZARDS IDENTIFICATION: CAUSES EYE IRRITATION.
LABELLING:
HAZARD STATEMENTS: CAUSES EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
KEEP OUT OF REACH OF CHILDREN. READ LABEL BEFORE USE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ ATTENTION.
WASH HANDS THOROUGHLY AFTER HANDLING.
OTHER HAZARDS: NONE IDENTIFIED
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WEIGHT PERCENT
N,N-DIETHYL-M-TOLUAMIDE 134-62-3 60.00 - 100.00
THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
FOR ADDITIONAL INFORMATION ON PRODUCT INGREDIENTS, SEE
WWW.WHATSINSIDESCJOHNSON.COM.
| 4. FIRST AID MEASURES | |
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IF EYE IRRITATION
PERSISTS: GET MEDICAL ADVICE/ ATTENTION.
SKIN CONTACT:
IF YOU SUSPECT A REACTION TO THIS PRODUCT, DISCONTINUE USE AND REMOVE
CONTAMINATED CLOTHING.
INHALATION: NO SPECIAL REQUIREMENTS.
INGESTION: NO SPECIAL REQUIREMENTS
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIFIC HAZARDS DURING FIREFIGHTING:
CONTAINER MAY MELT AND LEAK IN HEAT OF FIRE. DO NOT ALLOW RUN-OFF FROM
FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
FURTHER INFORMATION:
FIGHT FIRE FROM MAXIMUM DISTANCE OR PROTECTED AREA. WEAR FULL PROTECTIVE
CLOTHING AND POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CASE
OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
WEAR PERSONAL PROTECTIVE EQUIPMENT.
WASH THOROUGHLY AFTER HANDLING.
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
OUTSIDE OF NORMAL USE, AVOID RELEASE TO THE ENVIRONMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
DIKE LARGE SPILLS.
CLEAN RESIDUE FROM SPILL SITE.
| 7. HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES AND LIPS.
FOR PERSONAL PROTECTION SEE SECTION 8.
USE ONLY AS DIRECTED.
KEEP OUT OF REACH OF CHILDREN AND PETS.
WASH THOROUGHLY AFTER HANDLING.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
NORMAL MEASURES FOR PREVENTIVE FIRE PROTECTION.
STORAGE:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
KEEP CONTAINER CLOSED WHEN NOT IN USE.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
KEEP IN A DRY, COOL AND WELL-VENTILATED PLACE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
ACGIH OR OSHA EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED FOR THIS PRODUCT
OR REPORTABLE INGREDIENTS UNLESS NOTED IN THE TABLE ABOVE.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION: DO NOT SPRAY IN ENCLOSED AREAS.
HAND PROTECTION: NO SPECIAL REQUIREMENTS.
EYE PROTECTION: NO SPECIAL REQUIREMENTS.
SKIN AND BODY PROTECTION: NO SPECIAL REQUIREMENTS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WASH THOROUGHLY AFTER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM: LIQUID
COLOR: YELLOW
ODOR: MILD
ODOUR THRESHOLD:
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT INITIAL BOILING POINT AND BOILING RANGE:
545 DEG. F
FLASH POINT:
> 148.8 DEG. C
> 299.84 DEG. F
METHOD: TAG CLOSED CUP (TCC)
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS):
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 1 G/CM3
SOLUBILITY(IES): NEGLIGIBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS TOTAL VOC (WT. %)*:
0 % - ADDITIONAL EXEMPTIONS MAY APPLY *AS DEFINED BY US FEDERAL AND STATE
CONSUMER PRODUCT REGULATIONS
OTHER INFORMATION: NONE IDENTIFIED
| 10. STABILITY AND REACTIVITY | |
POSSIBILITY OF HAZARDOUS REACTIONS:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: DIRECT SOURCES OF HEAT.
INCOMPATIBLE MATERIALS: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPOURS.
| 11. TOXICOLOGICAL INFORMATION | |
EMERGENCY OVERVIEW: WARNING
ACUTE ORAL TOXICITY:
LD50: 2,420 MG/KG
ACUTE INHALATION TOXICITY:
GHS LC50 (DUST AND MIST): 5.95 MG/L
ACUTE DERMAL TOXICITY:
LD50: 4,223 MG/KG
GHS PROPERTIES CLASSIFICATION ROUTES OF ENTRY
ACUTE TOXICITY NO CLASSIFICATION PROPOSED
SKIN CORROSION/IRRITATION NO CLASSIFICATION PROPOSED
EYE IRRITATION CATEGORY 2B
SKIN SENSITISATION NO CLASSIFICATION PROPOSED
RESPIRATORY SENSITISATION NO CLASSIFICATION PROPOSED
GERM CELL MUTAGENICITY NO CLASSIFICATION PROPOSED
CARCINOGENICITY NO CLASSIFICATION PROPOSED
REPRODUCTIVE TOXICITY NO CLASSIFICATION PROPOSED
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - SINGLE
EXPOSURE
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - REPEATED
EXPOSURE
ASPIRATION HAZARD NO CLASSIFICATION PROPOSED
AGGRAVATED MEDICAL CONDITION: DO NOT APPLY TO CUTS OR IRRITATED SKIN.
| 12. ECOLOGICAL INFORMATION | |
PRODUCT: THE PRODUCT ITSELF HAS NOT BEEN TESTED.
TOXICITY:
THE INGREDIENTS IN THIS FORMULA HAVE BEEN REVIEWED AND NO ADVERSE IMPACT
TO THE ENVIRONMENT IS EXPECTED WHEN USED ACCORDING TO LABEL DIRECTIONS.
TOXICITY TO FISH:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
N,N-DIETHYL-M- STATIC TEST ONCORHYNCHUS MYKISS 71.25 96 H
TOLUAMIDE LC50 (RAINBOW TROUT) MG/L
TOXICITY TO AQUATIC INVERTEBRATES:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
N,N-DIETHYL-M- NO DATA AVAILABLE
TOLUAMIDE
TOXICITY TO AQUATIC PLANTS:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
N,N-DIETHYL-M- NO DATA AVAILABLE
TOLUAMIDE
PERSISTENCE AND DEGRADABILITY:
COMPONENT BIODEGRADATION EXPOSURE TIME SUMMARY
N,N-DIETHYL-M-TOLUAMIDE NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL:
COMPONENT BIOCONCENTRATION PARTITION COEFFICIENT N-
FACTOR (BCF) OCTANOL/WATER (LOG)
N,N-DIETHYL-M-TOLUAMIDE NO DATA AVAILABLE NO DATA AVAILABLE
MOBILITY:
COMPONENT END POINT VALUE
N,N-DIETHYL-M-TOLUAMIDE NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT:
COMPONENT RESULTS
N,N-DIETHYL-M-TOLUAMIDE NOT FULFILLING PBT AND VPVB CRITERIA
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
PESTICIDAL WASTE:
FOR DISPOSAL INFORMATION, PLEASE READ AND FOLLOW DISPOSAL INSTRUCTIONS ON
THE PESTICIDE LABEL.
CONSUMER MAY DISCARD EMPTY CONTAINER IN TRASH, OR RECYCLE WHERE FACILITIES
EXIST.
| 14. TRANSPORT INFORMATION | |
PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP-TO-DATE
SHIPPING INFORMATION.
LAND TRANSPORT:
NOT CLASSIFIED AS DANGEROUS IN THE MEANING OF TRANSPORT REGULATIONS.
SEA TRANSPORT:
NOT CLASSIFIED AS DANGEROUS IN THE MEANING OF TRANSPORT REGULATIONS.
AIR TRANSPORT:
NOT CLASSIFIED AS DANGEROUS IN THE MEANING OF TRANSPORT REGULATIONS.
| 15. REGULATORY INFORMATION | |
FIFRA LABELING:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS, AND FOR
WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS.
FOLLOWING IS THE HAZARD INFORMATION AS REQUIRED ON THE PESTICIDE LABEL:
WARNING:
CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY.
HARMFUL IF SWALLOWED.
USE OF THIS PRODUCT MAY CAUSE SKIN REACTIONS IN RARE CASES.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT COMPLY WITH THE NEW SUBSTANCES NOTIFICATION
REQUIREMENTS UNDER THE CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA).
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE HARM.
REGISTRATION # / AGENCY: 4822-276/EPA
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 1
REACTIVITY 0
NFPA RATINGS:
HEALTH 2
FIRE 1
REACTIVITY 0
SPECIAL
THIS INFORMATION IS BEING PROVIDED IN ACCORDANCE WITH THE OCCUPATIONAL
SAFETY AND HEALTH ADMINISTRATION (OSHA) REGULATION (29 CFR 1910.1200). THE
INFORMATION SUPPLIED IS DESIGNED FOR WORKPLACES WHERE PRODUCT USE AND
FREQUENCY OF EXPOSURE EXCEEDS THAT ESTABLISHED FOR THE LABELED CONSUMER
USE.
FURTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TO BE
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESSED OR
IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED HEREIN. ACTUAL
CONDITIONS OF USE ARE BEYOND THE SELLER'S CONTROL. USER IS RESPONSIBLE TO
EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR
USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND
REGULATIONS.
PREPARED BY:
SC JOHNSON GLOBAL SAFETY ASSESSMENT & REGULATORY AFFAIRS (GSARA)