| Common Name: | ROHPER 1-GL 2PK V7400HD RUST INH GR PRIM, 245507 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 8/27/2013 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 2ZLW4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
DATE PRINTED: 8/27/2013
MATERIAL SAFETY DATA SHEET
RUST-OLEUM CORPORATION
24 HOUR ASSISTANCE: 1-847-367-7700
RUST-OLEUM CORP.
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: ROHPER 1-GL 2PK V7400HD RUST INH GR PRIM
PRODUCT NUMBER: 245507
PRODUCT USE/CLASS: PRIMER/ALKYD
REVISION DATE: 8/27/2013
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARED BY: REGULATORY DEPARTMENT
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. FLAMMABLE LIQUID AND VAPOR.
CAUSES NOSE AND THROAT IRRITATION. HARMFUL IF INHALED. MAY AFFECT THE
BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. VAPOR
HARMFUL. CAUSES EYE, SKIN, NOSE, AND THROAT IRRITATION. MAY CAUSE EYE,
SKIN, OR RESPIRATORY TRACT IRRITATION. KEEP OUT OF REACH OF CHILDREN.
HARMFUL IF INHALED USE VENTILATION NECESSARY TO KEEP EXPOSURES BELOW
RECOMMENDED EXPOSURE LIMITS, IF ANY.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION. CAUSES SKIN
IRRITATION. ALLERGIC REACTIONS ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. MAY
CAUSE HEADACHES AND DIZZINESS. HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO
THE EYES, NOSE, THROAT AND LUNGS. HIGH GAS, VAPOR, MIST OR DUST
CONCENTRATIONS MAY BE HARMFUL IF INHALED. PROLONGED OR EXCESSIVE INHALATION
MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND
CAUSE DAMAGE.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. IARC LISTS
ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B). CONTAINS TITANIUM
DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC
TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO TITANIUM DIOXIDE IS THOUGHT
TO OCCUR DURING THE USE OF PRODUCTS IN WHICH TITANIUM DIOXIDE IS BOUND TO
OTHER MATERIALS, SUCH AS IN PAINTS DURING BRUSH APPLICATION OR DRYING.
RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL OF EXPOSURE TO DUST FROM
REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE ACTUAL CONCENTRATION
OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC MONOGRAPH, VOL. 93, 2010)
HIGH CONCENTRATIONS MAY LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS,
DIZZINESS, NAUSEA, HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
TALC 14807-96-6 25.0
LIMESTONE 1317-65-3 20.0
MINERAL SPIRITS 64742-88-7 15.0
STODDARD SOLVENTS 8052-41-3 10.0
TITANIUM DIOXIDE 13463-67-7 10.0
STRONTIUM ZINC PHOSPHOSILICATE MIXTURE 10.0
ZINC OXIDE 1314-13-2 5.0
ETHYLBENZENE 100-41-4 1.0
CRYSTALLINE SILICA 14808-60-7 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
TALC 2 MG/M3 N.E. 0.1 MG/M3 N.E.
[RESPIRABLE]
LIMESTONE N.E. N.E. 15 MG/M3 N.E.
[TOTAL DUST]
MINERAL SPIRITS 100 PPM N.E. 100 PPM N.E.
STODDARD SOLVENTS 100 PPM N.E. 500 PPM N.E.
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
[TOTAL DUST]
STRONTIUM ZINC N.E. N.E. N.E. N.E.
PHOSPHOSILICATE
ZINC OXIDE 2 MG/M3 10 MG/M3 5 MG/M3 N.E.
[RESPIRABLE]
ETHYLBENZENE 20 PPM 125 PPM 100 PPM N.E.
CRYSTALLINE SILICA 0.025 MG/M3 N.E. 0.1 MG/M3 N.E.
[RESPIRABLE] [RESPIRABLE]
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES
OR KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL
CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT, DEG. F: 88 (SETAFLASH)
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN TRAVEL TO A SOURCE
OF IGNITION AND FLASH BACK. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS
AND OPEN FLAME. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP OF
STEAM. KEEP CONTAINERS TIGHTLY CLOSED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP
AND POSSIBLE AUTOIGNITION OR EXPLOSION. EVACUATE AREA AND FIGHT FIRE FROM
A SAFE DISTANCE. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. ELIMINATE ALL IGNITION SOURCES; USE EXPLOSION-PROOF
EQUIPMENT. PLACE MATERIAL IN A CONTAINER AND DISPOSE OF ACCORDING TO LOCAL,
PROVINCIAL, STATE AND FEDERAL REGULATIONS. REMOVE ALL SOURCES OF IGNITION,
VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS.
DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS.
DO NOT INCINERATE CLOSED CONTAINERS. VENTILATE AREA, ISOLATE SPILLED
MATERIAL, AND REMOVE WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED
ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE,
AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY WITH
ADEQUATE VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. KEEP CONTAINER CLOSED WHEN NOT IN USE. PRODUCT SHOULD BE STORED
IN TIGHTLY SEALED CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN
MATERIALS. STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE
120 DEG. F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR
STORAGE OF NFPA CLASS I FLAMMABLE LIQUIDS. AVOID EXCESS HEAT.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION. USE GLOVES TO PREVENT PROLONGED SKIN CONTACT.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: SOLVENT LIKE
APPEARANCE: LIQUID
EVAPORATION RATE: SLOWER THAN ETHER
SOLUBILITY IN WATER: SLIGHT
FREEZE POINT: N.D.
SPECIFIC GRAVITY: 1.408
PH: N.D.
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION. AVOID TEMPERATURES ABOVE
120 DEG. F. AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS
SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
CHEMICAL NAME LD50 LC50
TALC N.E. TCLO:
11 MG/M3 (INHALATION)
LIMESTONE >5000 MG/KG N.E.
(RAT, ORAL)
MINERAL SPIRITS >5000 MG/KG >1400 PPM
(RAT, ORAL) (RAT, INHALATION, 4HR)
STODDARD SOLVENTS >5000 MG/KG N.E.
(RAT, ORAL)
TITANIUM DIOXIDE >7500 MG/KG N.E.
(RAT, ORAL)
STRONTIUM ZINC PHOSPHOSILICATE N.E. N.E.
ZINC OXIDE >5000 MG/KG >5700 MG/M3
(RAT, ORAL) (RAT, INHALATION)
ETHYLBENZENE 3500 MG/KG N.E.
(RAT, ORAL)
CRYSTALLINE SILICA N.E. N.E.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. PRODUCT IS A MIXTURE OF LISTED
COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER. SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1263 1263 N.A.
PROPER SHIPPING PAINT PRODUCTS PAINT PAINT PAINT PRODUCTS
NAME IN LIMITED IN LIMITED
QUANTITIES QUANTITIES
HAZARD CLASS N.A. 3 3 N.A.
PACKING GROUP N.A. III III N.A.
LIMITED QUANTITY YES YES YES YES
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
STRONTIUM ZINC PHOSPHOSILICATE MIXTURE
ZINC OXIDE 1314-13-2
XYLENE 1330-20-7
ALUMINUM OXIDE 1344-28-1
ETHYLBENZENE 100-41-4
COBALT 2-ETHYLHEXANOATE 136-52-7
NEODECANOIC ACID, COBALT SALT 27253-31-2
DIETHYLENE GLYCOL METHYL ETHER 111-77-3
1,2,4-TRIMETHYLBENZENE 95-63-6
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA COMPONENTS EXIST IN THIS PRODUCT.
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
B2
D2A
D2B
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 336
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE
AS OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS
OF HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL,
WE ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY
OF THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.