| Common Name: | HI-TACK SPRAY ADHESIVE 76 |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/30/2016 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3MA22 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) HI-TACK SPRAY ADHESIVE 76
03/30/16
3M
SAFETY DATA SHEET
COPYRIGHT, 2016, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 16-5855-8
VERSION NUMBER: 8.00
ISSUE DATE: 03/30/16
SUPERCEDES DATE: 01/16/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) HI-TACK SPRAY ADHESIVE 76
PRODUCT IDENTIFICATION NUMBERS:
62-4943-4920-2, 62-4943-4921-0, 62-4943-4950-9, 62-4943-4955-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AEROSOL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE AEROSOL: CATEGORY 1.
GAS UNDER PRESSURE: LIQUEFIED GAS.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SIMPLE ASPHYXIANT.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (RESPIRATORY IRRITATION): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING CONTENTS CAN
BE HARMFUL OR FATAL.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
DIMETHYL ETHER 115-10-6 35 - 45 TRADE SECRET *
METHYL ACETATE 79-20-9 20 - 30 TRADE SECRET *
NON-HAZARDOUS COMPONENTS TRADE SECRET* 10 - 20 TRADE SECRET *
(N.J.T.S REG NO. 04499600-6481P)
CYCLOHEXANE 110-82-7 7 - 13 TRADE SECRET *
1,1-DIFLUOROETHANE 75-37-6 1 - 5 TRADE SECRET *
LIGHT PETROLEUM DISTILLATES 64742-47-8 0.5 - 1.5 TRADE SECRET *
PETROLEUM NAPTHA 64742-48-9 0.5 - 1.5 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED
TO KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
IF POSSIBLE, SEAL LEAKING CONTAINER. PLACE LEAKING CONTAINERS IN A
WELL-VENTILATED AREA, PREFERABLY AN OPERATING EXHAUST HOOD, OR IF
NECESSARY OUTDOORS ON AN IMPERMEABLE SURFACE UNTIL APPROPRIATE PACKAGING
FOR THE LEAKING CONTAINER OR ITS CONTENTS IS AVAILABLE. COLLECT AS MUCH
OF THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A
METAL CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES.
SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER
IGNITION SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. STORE
AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
CYCLOHEXANE 110-82-7 ACGIH TWA: 100 PPM
CYCLOHEXANE 110-82-7 OSHA TWA:
1050 MG/M3
(300 PPM)
DIMETHYL ETHER 115-10-6 AIHA TWA:
1880 MG/M3
(1000 PPM)
DIMETHYL ETHER 115-10-6 CMRG TWA: 1000 PPM
JET FUELS 64742-47-8 ACGIH TWA (AS TOTAL A3:
(NON-AEROSOL), HYDROCARBON CONFIRMED
AS TOTAL VAPOR, ANIMAL
HYDROCARBON NON-AEROSOL): CARCIN.,
VAPOR 200 MG/M3 SKIN
NOTATION
KEROSINE 64742-47-8 ACGIH TWA (AS TOTAL A3:
(PETROLEUM) HYDROCARBON CONFIRMED
VAPOR, ANIMAL
NON-AEROSOL): CARCIN.,
200 MG/M3 SKIN
NOTATION
LIGHT PETROLEUM 64742-47-8 CMRG TWA: 165 PPM
DISTILLATES
PETROLEUM NAPTHA 64742-48-9 MANUFACTURER TWA: 100 PPM
DETERMINED
1,1-DIFLUOROETHANE 75-37-6 AIHA TWA:
2700 MG/M3
(1000 PPM)
1,1-DIFLUOROETHANE 75-37-6 CMRG TWA: 1000 PPM
METHYL ACETATE 79-20-9 ACGIH TWA: 200 PPM
STEL: 250 PPM
METHYL ACETATE 79-20-9 OSHA TWA:
610 MG/M3
(200 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
DO NOT REMAIN IN AREA WHERE AVAILABLE OXYGEN MAY BE REDUCED. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IF VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND
DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE
CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER
FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: BUTYL RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
ORGANIC VAPOR RESPIRATORS MAY HAVE SHORT SERVICE LIFE.
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: GAS
SPECIFIC PHYSICAL FORM: AEROSOL
ODOR, COLOR, GRADE: CLEAR-AMBER, MILD SOLVENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FLASH POINT: -40 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP]
EVAPORATION RATE: 1.9 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS):
FLAMMABLE AEROSOL: CATEGORY 1.
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR DENSITY: 2.97 [REF STD: AIR=1]
DENSITY: 0.782 G/ML
SPECIFIC GRAVITY: 0.782 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
<=428 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: LOW SOLIDS LESS EXEMPTS]
VOLATILE ORGANIC COMPOUNDS:
<=3.57 LB/GAL [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
[DETAILS: LOW SOLIDS LESS EXEMPTS]
PERCENT VOLATILE: APPROXIMATELY 85% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
<=54.7% [TEST METHOD: CALCULATED PER CARB TITLE 2]
SOLIDS CONTENT: 7.1%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
SIMPLE ASPHYXIATION:
SIGNS/SYMPTOMS MAY INCLUDE INCREASED HEART RATE, RAPID RESPIRATIONS,
DROWSINESS, HEADACHE, INCOORDINATION, ALTERED JUDGEMENT, NAUSEA, VOMITING,
LETHARGY, SEIZURES, COMA, AND MAY BE FATAL.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED
OR HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
SINGLE EXPOSURE, ABOVE RECOMMENDED GUIDELINES, MAY CAUSE:
CARDIAC SENSITIZATION:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS,
CHEST PAIN, AND MAY BE FATAL.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR (4 HR) CALCULATED ATE:
>50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
DIMETHYL ETHER INHALATION- RAT LC50: 164,000 PPM
GAS
(4 HOURS)
METHYL ACETATE DERMAL RAT LD50: >2,000 MG/KG
METHYL ACETATE INHALATION- RAT LC50: >49 MG/L
VAPOR
(4 HOURS)
METHYL ACETATE INGESTION RAT LD50: >5,000 MG/KG
CYCLOHEXANE DERMAL RAT LD50: >2,000 MG/KG
CYCLOHEXANE INHALATION- RAT LC50: >32.9 MG/L
VAPOR
(4 HOURS)
CYCLOHEXANE INGESTION RAT LD50: 6,200 MG/KG
1,1-DIFLUOROETHANE INHALATION- RAT LC50: >437,000 PPM
GAS
(4 HOURS)
1,1-DIFLUOROETHANE INGESTION RAT LD50: >1,500 MG/KG
NON-HAZARDOUS COMPONENTS DERMAL RABBIT LD50: >2,000 MG/KG
(N.J.T.S REG NO.
04499600-6481P)
NON-HAZARDOUS COMPONENTS INGESTION RAT LD50: >5,000 MG/KG
(N.J.T.S REG NO.
04499600-6481P)
PETROLEUM NAPTHA INHALATION- LC50 ESTIMATED
VAPOR TO BE: 20 - 50 MG/L
LIGHT PETROLEUM DISTILLATES DERMAL RABBIT LD50: >3,160 MG/KG
PETROLEUM NAPTHA DERMAL RABBIT LD50: >3,000 MG/KG
LIGHT PETROLEUM DISTILLATES INHALATION- RAT LC50: >3 MG/L
DUST/MIST
(4 HOURS)
LIGHT PETROLEUM DISTILLATES INGESTION RAT LD50: >5,000 MG/KG
PETROLEUM NAPTHA INGESTION RAT LD50: >5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT NO SIGNIFICANT IRRITATION
CYCLOHEXANE RABBIT MILD IRRITANT
NON-HAZARDOUS COMPONENTS PROFESSIONAL NO SIGNIFICANT IRRITATION
(N.J.T.S REG NO. 04499600-6481P) JUDGEMENT
LIGHT PETROLEUM DISTILLATES RABBIT MILD IRRITANT
PETROLEUM NAPTHA RABBIT IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT MODERATE IRRITANT
CYCLOHEXANE RABBIT MILD IRRITANT
LIGHT PETROLEUM DISTILLATES RABBIT MILD IRRITANT
PETROLEUM NAPTHA RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
METHYL ACETATE HUMAN NOT SENSITIZING
LIGHT PETROLEUM DISTILLATES GUINEA PIG NOT SENSITIZING
PETROLEUM NAPTHA GUINEA PIG NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
DIMETHYL ETHER IN VITRO NOT MUTAGENIC
DIMETHYL ETHER IN VIVO NOT MUTAGENIC
METHYL ACETATE IN VITRO NOT MUTAGENIC
METHYL ACETATE IN VIVO NOT MUTAGENIC
CYCLOHEXANE IN VITRO NOT MUTAGENIC
CYCLOHEXANE IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
1,1-DIFLUOROETHANE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
1,1-DIFLUOROETHANE IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
LIGHT PETROLEUM DISTILLATES IN VITRO NOT MUTAGENIC
PETROLEUM NAPTHA IN VIVO NOT MUTAGENIC
PETROLEUM NAPTHA IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIMETHYL ETHER INHALATION RAT NOT CARCINOGENIC
1,1-DIFLUOROETHANE INHALATION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
LIGHT PETROLEUM DISTILLATES DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PETROLEUM NAPTHA DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PETROLEUM NAPTHA INHALATION HUMAN SOME POSITIVE DATA
AND EXIST, BUT THE DATA
ANIMAL ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
DIMETHYL ETHER INHALATION NOT TOXIC TO DEVELOPMENT
CYCLOHEXANE INHALATION NOT TOXIC TO FEMALE REPRODUCTION
CYCLOHEXANE INHALATION NOT TOXIC TO MALE REPRODUCTION
CYCLOHEXANE INHALATION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
1,1-DIFLUOROETHANE INHALATION NOT TOXIC TO DEVELOPMENT
PETROLEUM NAPTHA INHALATION NOT TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL ETHER RAT NOAEL: 40.000 PPM DURING ORGANOGENESIS
CYCLOHEXANE RAT NOAEL: 24 MG/L 2 GENERATION
CYCLOHEXANE RAT NOAEL: 24 MG/L 2 GENERATION
CYCLOHEXANE RAT NOAEL: 6.9 MG/L 2 GENERATION
1,1-DIFLUOROETHANE RAT NOAEL: 50.000 PPM DURING ORGANOGENESIS
PETROLEUM NAPTHA RAT NOAEL: 2.4 MG/L DURING ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIMETHYL ETHER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
DIMETHYL ETHER INHALATION CARDIAC SOME POSITIVE DATA
SENSITIZATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ACETATE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
METHYL ACETATE INHALATION BLINDNESS SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
CYCLOHEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
CYCLOHEXANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CYCLOHEXANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
1,1-DIFLUOROETHANE INHALATION CARDIAC CAUSES DAMAGE TO
SENSITIZATION ORGANS
1,1-DIFLUOROETHANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
1,1-DIFLUOROETHANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
LIGHT PETROLEUM INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
DISTILLATES SYSTEM DEPRESSION OR DIZZINESS
LIGHT PETROLEUM INHALATION RESPIRATORY SOME POSITIVE DATA
DISTILLATES IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
LIGHT PETROLEUM INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
DISTILLATES SYSTEM DEPRESSION OR DIZZINESS
PETROLEUM NAPTHA INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
PETROLEUM NAPTHA INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PETROLEUM NAPTHA INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PETROLEUM NAPTHA INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL ETHER RAT LOAEL: 30 MINUTES
10,000 PPM
DIMETHYL ETHER DOG NOAEL: 5 MINUTES
100,000 PPM
METHYL ACETATE HUMAN NOAEL:
AND NOT AVAILABLE
ANIMAL
METHYL ACETATE HUMAN NOAEL:
AND NOT AVAILABLE
ANIMAL
METHYL ACETATE NOAEL:
NOT AVAILABLE
METHYL ACETATE NOAEL:
NOT AVAILABLE
CYCLOHEXANE HUMAN NOAEL:
AND NOT AVAILABLE
ANIMAL
CYCLOHEXANE HUMAN NOAEL:
AND NOT AVAILABLE
ANIMAL
CYCLOHEXANE PROFESSIONAL NOAEL:
JUDGEMENT NOT AVAILABLE
1,1-DIFLUOROETHANE HUMAN NOAEL: POISONING AND/OR
AND NOT AVAILABLE ABUSE
ANIMAL
1,1-DIFLUOROETHANE HUMAN NOAEL:
AND 100,000 PPM
ANIMAL
1,1-DIFLUOROETHANE NOT NOAEL: NOT AVAILABLE
AVAILABLE NOT AVAILABLE
LIGHT PETROLEUM HUMAN NOAEL:
DISTILLATES AND NOT AVAILABLE
ANIMAL
LIGHT PETROLEUM NOAEL:
DISTILLATES NOT AVAILABLE
LIGHT PETROLEUM PROFESSIONAL NOAEL:
DISTILLATES JUDGEMENT NOT AVAILABLE
PETROLEUM NAPTHA HUMAN NOAEL:
AND NOT AVAILABLE
ANIMAL
PETROLEUM NAPTHA NOAEL:
NOT AVAILABLE
PETROLEUM NAPTHA DOG NOAEL: 4 HOURS
6.5 MG/L
PETROLEUM NAPTHA PROFESSIONAL NOAEL:
JUDGEMENT NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIMETHYL ETHER INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL ETHER INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
HEMATOPOIETIC EXIST, BUT THE DATA
SYSTEM ARE NOT SUFFICIENT
LIVER FOR CLASSIFICATION
IMMUNE SYSTEM
KIDNEY AND/OR
BLADDER
CYCLOHEXANE INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CYCLOHEXANE INHALATION AUDITORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CYCLOHEXANE INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CYCLOHEXANE INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CYCLOHEXANE INHALATION PERIPHERAL NERVOUS ALL DATA ARE
SYSTEM NEGATIVE
1,1-DIFLUOROETHANE INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
KIDNEY AND/OR ARE NOT SUFFICIENT
BLADDER FOR CLASSIFICATION
RESPIRATORY SYSTEM
PETROLEUM NAPTHA INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PETROLEUM NAPTHA INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PETROLEUM NAPTHA INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PETROLEUM NAPTHA INHALATION BONE, TEETH, NAILS, ALL DATA ARE
AND/OR HAIR NEGATIVE
BLOOD
LIVER
MUSCLES
PETROLEUM NAPTHA INHALATION HEART ALL DATA ARE
NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 20,000 PPM 30 WEEKS
METHYL ACETATE RAT NOAEL: 1.1 MG/L 28 DAYS
METHYL ACETATE RAT NOAEL: 6.1 MG/L 28 DAYS
CYCLOHEXANE RAT NOAEL: 24 MG/L 90 DAYS
CYCLOHEXANE RAT NOAEL: 1.7 MG/L 90 DAYS
CYCLOHEXANE RABBIT NOAEL: 2.7 MG/L 10 WEEKS
CYCLOHEXANE MOUSE NOAEL: 24 MG/L 14 WEEKS
CYCLOHEXANE RAT NOAEL: 8.6 MG/L 30 WEEKS
1,1-DIFLUOROETHANE RAT NOAEL: 25,000 PPM 2 YEARS
PETROLEUM NAPTHA RAT LOAEL: 4.6 MG/L 6 MONTHS
PETROLEUM NAPTHA RAT LOAEL: 1.9 MG/L 13 WEEKS
PETROLEUM NAPTHA MULTIPLE NOAEL: 0.6 MG/L 90 DAYS
ANIMAL
SPECIES
PETROLEUM NAPTHA RAT NOAEL: 5.6 MG/L 12 WEEKS
PETROLEUM NAPTHA MULTIPLE NOAEL: 1.3 MG/L 90 DAYS
ANIMAL
SPECIES
ASPIRATION HAZARD:
NAME VALUE
CYCLOHEXANE ASPIRATION HAZARD
LIGHT PETROLEUM DISTILLATES ASPIRATION HAZARD
PETROLEUM NAPTHA ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. FACILITY MUST BE
CAPABLE OF HANDLING AEROSOL CANS. AS A DISPOSAL ALTERNATIVE, UTILIZE AN
ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D001 (IGNITABLE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
CYCLOHEXANE 110-82-7 TRADE SECRET 7 - 13
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 1
SPECIAL HAZARDS NONE
AEROSOL STORAGE CODE: 3
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 16-5855-8
VERSION NUMBER: 8.00
ISSUE DATE: 03/30/16
SUPERCEDES DATE: 01/16/15
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