| Common Name: | TEST DOCUMENT, TEST COLOR, Z35R00000-EXP |
| Manufacturer: | SHERWIN-WILLIAMS |
| SDS Revision Date: | 9/16/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 54TJ89 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
Z35R00000-EXP
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME:
TEST DOCUMENT
TEST COLOR
PRODUCT CODE: Z35R00000-EXP
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS #: NOT APPLICABLE.
PRODUCT TYPE: SPRAY
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
THE SHERWIN-WILLIAMS COMPANY
101 PROSPECT AVENUE N.W.
CLEVELAND, OHIO 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: NOT AVAILABLE.
REGULATORY INFORMATION TELEPHONE NUMBER: (216) 566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY: CATEGORY 2
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
17%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
SUSPECTED OF DAMAGING THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR
EYE OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. DO
NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. USE ONLY OUTDOORS OR
IN A WELL-VENTILATED AREA. DO NOT BREATHE VAPOR. WASH HANDS THOROUGHLY
AFTER HANDLING.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. DO NOT INDUCE VOMITING.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING AND
WASH IT BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DANGER:
RAGS, STEEL WOOL, OTHER WASTE SOAKED WITH THIS PRODUCT, AND SANDING
RESIDUE MAY SPONTANEOUSLY CATCH FIRE IF IMPROPERLY DISCARDED. IMMEDIATELY
PLACE RAGS, STEEL WOOL, OTHER WASTE SOAKED WITH THIS PRODUCT, AND SANDING
RESIDUE IN A SEALED, WATER-FILLED, METAL CONTAINER. DISPOSE OF IN
ACCORDANCE WITH LOCAL FIRE REGULATIONS. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN CAUSE PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING
AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. KEEP UPRIGHT IN A COOL, DRY PLACE. DO NOT DISCARD EMPTY CAN IN
TRASH COMPACTOR.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
METHYL ACETATE 32.5 79-20-9
PROPANE 17 74-98-6
METHYL ETHYL KETONE 15.42 78-93-3
BUTANE 8 106-97-8
1-METHOXY-2-PROPANOL ACETATE 6.21 108-65-6
METHYL ISOBUTYL KETONE 3.28 108-10-1
XYLENE 3.11 1330-20-7
ACETONE 2.3 67-64-1
ETHYLBENZENE 0.55 100-41-4
TOLUENE 0.12 108-88-3
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS
DUE TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT: GET MEDICAL ATTENTION.
INHALATION:
IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER SHOULD WEAR
AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN.
SKIN CONTACT:
CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. DO NOT
INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS. ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. IN A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT
EXPLOSION. GAS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE
OR EXPLOSION. BURSTING AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT
HIGH SPEED. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
IN THE CASE OF AEROSOLS BEING RUPTURED, CARE SHOULD BE TAKEN DUE TO THE
RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND PROPELLANT. IF A LARGE NUMBER
OF CONTAINERS ARE RUPTURED, TREAT AS A BULK MATERIAL SPILLAGE ACCORDING TO
THE INSTRUCTIONS IN THE CLEAN-UP SECTION. SHUT OFF ALL IGNITION SOURCES.
NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS: NO SPECIFIC HAZARD.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL: USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT.
LARGE SPILL: USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. AVOID EXPOSURE - OBTAIN
SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING PREGNANCY. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT
GET IN EYES OR ON SKIN OR CLOTHING. DO NOT SWALLOW. USE ONLY WITH ADEQUATE
VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE.
STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION
SOURCE. USE EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL
HANDLING) EQUIPMENT. USE ONLY NON-SPARKING TOOLS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
WORKERS SHOULD WASH HANDS AND FACE BEFORE EATING, DRINKING AND SMOKING.
REMOVE CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING
EATING AREAS. SEE ALSO SECTION 8 FOR ADDITIONAL INFORMATION ON HYGIENE
MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. PROTECT FROM SUNLIGHT. STORE
LOCKED UP. ELIMINATE ALL IGNITION SOURCES.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME EXPOSURE LIMITS
METHYL ACETATE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 200 PPM 8 HOURS.
TWA: 606 MG/M3 8 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 757 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 200 PPM 10 HOURS.
TWA: 610 MG/M3 10 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 760 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
TWA: 610 MG/M3 8 HOURS.
PROPANE NIOSH REL (UNITED STATES, 10/2013).
TWA: 1000 PPM 10 HOURS.
TWA: 1800 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 1000 PPM 8 HOURS.
TWA: 1800 MG/M3 8 HOURS.
METHYL ETHYL KETONE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 200 PPM 8 HOURS.
TWA: 590 MG/M3 8 HOURS.
STEL: 300 PPM 15 MINUTES.
STEL: 885 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 200 PPM 10 HOURS.
TWA: 590 MG/M3 10 HOURS.
STEL: 300 PPM 15 MINUTES.
STEL: 885 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
TWA: 590 MG/M3 8 HOURS.
BUTANE NIOSH REL (UNITED STATES, 10/2013).
TWA: 800 PPM 10 HOURS.
TWA: 1900 MG/M3 10 HOURS.
ACGIH TLV (UNITED STATES, 3/2015).
STEL: 1000 PPM 15 MINUTES.
1-METHOXY-2-PROPANOL ACETATE AIHA WEEL (UNITED STATES, 10/2011).
TWA: 50 PPM 8 HOURS.
METHYL ISOBUTYL KETONE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 20 PPM 8 HOURS.
STEL: 75 PPM 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 50 PPM 10 HOURS.
TWA: 205 MG/M3 10 HOURS.
STEL: 75 PPM 15 MINUTES.
STEL: 300 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 410 MG/M3 8 HOURS.
XYLENE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 100 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
ACETONE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 250 PPM 8 HOURS.
STEL: 500 PPM 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 250 PPM 10 HOURS.
TWA: 590 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 1000 PPM 8 HOURS.
TWA: 2400 MG/M3 8 HOURS.
ETHYLBENZENE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
TOLUENE OSHA PEL Z2 (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
CEIL: 300 PPM
AMP: 500 PPM 10 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 375 MG/M3 10 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 560 MG/M3 15 MINUTES.
ACGIH TLV (UNITED STATES, 3/2015).
TWA: 20 PPM 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME EXPOSURE LIMITS
METHYL ACETATE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 606 MG/M3 8 HOURS.
15 MIN OEL: 757 MG/M3 15 MINUTES.
15 MIN OEL: 250 PPM 15 MINUTES.
8 HRS OEL: 200 PPM 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 200 PPM 8 HOURS.
STEL: 250 PPM 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 200 PPM 8 HOURS.
STEL: 250 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 200 PPM 8 HOURS.
TWAEV: 606 MG/M3 8 HOURS.
STEV: 250 PPM 15 MINUTES.
STEV: 757 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 250 PPM 15 MINUTES.
TWA: 200 PPM 8 HOURS.
PROPANE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 1000 PPM 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 1000 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 1000 PPM 8 HOURS.
TWAEV: 1800 MG/M3 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 1000 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 1250 PPM 15 MINUTES.
TWA: 1000 PPM 8 HOURS.
METHYL ETHYL KETONE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
15 MIN OEL: 300 PPM 15 MINUTES.
8 HRS OEL: 200 PPM 8 HOURS.
8 HRS OEL: 590 MG/M3 8 HOURS.
15 MIN OEL: 885 MG/M3 15 MINUTES.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 50 PPM 8 HOURS.
STEL: 100 PPM 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 200 PPM 8 HOURS.
STEL: 300 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 50 PPM 8 HOURS.
TWAEV: 150 MG/M3 8 HOURS.
STEV: 100 PPM 15 MINUTES.
STEV: 300 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 300 PPM 15 MINUTES.
TWA: 200 PPM 8 HOURS.
TOLUENE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
ABSORBED THROUGH SKIN.
8 HRS OEL: 50 PPM 8 HOURS.
8 HRS OEL: 188 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 20 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
ABSORBED THROUGH SKIN.
TWAEV: 50 PPM 8 HOURS.
TWAEV: 188 MG/M3 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
ABSORBED THROUGH SKIN.
STEL: 60 PPM 15 MINUTES.
TWA: 50 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: VARIOUS
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: -29 DEG. C (-20.2 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 5.6 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 16%
VAPOR PRESSURE: 13.5 KPA (101 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 1.55 [AIR = 1]
RELATIVE DENSITY: 0.77
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): -0.01 CM2/S (-1 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 34.96 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME).
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
METHYL ACETATE LD50 DERMAL RABBIT >5 G/KG
LD50 ORAL RAT >5 G/KG
METHYL ETHYL KETONE LD50 DERMAL RABBIT 6480 MG/KG
LD50 ORAL RAT 2737 MG/KG
BUTANE LC50 INHALATION VAPOR RAT 658000 MG/M3 4 HOURS
1-METHOXY- LD50 DERMAL RABBIT >5 G/KG
2-PROPANOL ACETATE LD50 ORAL RAT 8532 MG/KG
METHYL ISOBUTYL LD50 ORAL RAT 2080 MG/KG
KETONE
XYLENE LC50 INHALATION GAS. RAT 5000 PPM 4 HOURS
LD50 ORAL RAT 4300 MG/KG
ACETONE LD50 ORAL RAT 5800 MG/KG
ETHYLBENZENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
TOLUENE LC50 INHALATION VAPOR RAT 49 G/M3 4 HOURS
LD50 ORAL RAT 636 MG/KG
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
METHYL EYES: RABBIT 24 HOURS
ACETATE MODERATE 100 MILLIGRAMS
IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 500 MILLIGRAMS
SKIN: RABBIT 24 HOURS
MODERATE 20 MILLIGRAMS
IRRITANT
METHYL ETHYL SKIN: RABBIT 24 HOURS
KETONE MILD IRRITANT 14 MILLIGRAMS
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
METHYL EYES: RABBIT 24 HOURS
ISOBUTYL MODERATE 100 MICROLITERS
KETONE IRRITANT
EYES: RABBIT 40 MILLIGRAMS
SEVERE IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 500 MILLIGRAMS
XYLENE EYES: RABBIT 87 MILLIGRAMS
MILD IRRITANT
EYES: RABBIT 24 HOURS
SEVERE IRRITANT 5 MILLIGRAMS
SKIN: RAT 8 HOURS
MILD IRRITANT 60 MICROLITERS
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 100 PERCENT
MODERATE
IRRITANT
ACETONE EYES: HUMAN 186300 PARTS
MILD IRRITANT PER MILLION
EYES: RABBIT 10 MICROLITERS
MILD IRRITANT
EYES: RABBIT 24 HOURS
MODERATE 20 MILLIGRAMS
IRRITANT
EYES: RABBIT 20 MILLIGRAMS
SEVERE IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 500 MILLIGRAMS
SKIN: RABBIT 395 MILLIGRAMS
MILD IRRITANT
ETHYLBENZENE EYES: RABBIT 500 MILLIGRAMS
SEVERE IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 15 MILLIGRAMS
TOLUENE EYES: RABBIT 0.5 MINUTES
MILD IRRITANT 100 MILLIGRAMS
EYES: RABBIT 870 MICROGRAMS
MILD IRRITANT
EYES: RABBIT 24 HOURS
SEVERE IRRITANT 2 MILLIGRAMS
SKIN: PIG 24 HOURS
MILD IRRITANT 250 MICROLITERS
SKIN: RABBIT 435 MILLIGRAMS
MILD IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 20 MILLIGRAMS
IRRITANT
SKIN: RABBIT 500 MILLIGRAMS
MODERATE
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
METHYL ISOBUTYL KETONE 2B
XYLENE 3
ETHYLBENZENE 2B
TOLUENE 3
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
PROPANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
METHYL ETHYL KETONE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
BUTANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
METHYL ISOBUTYL KETONE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
XYLENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
ACETONE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
ETHYLBENZENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
TOLUENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
PROPANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
METHYL ETHYL KETONE CATEGORY 2 NOT DETERMINED NOT DETERMINED
BUTANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
METHYL ISOBUTYL KETONE CATEGORY 2 NOT DETERMINED NOT DETERMINED
XYLENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ACETONE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ETHYLBENZENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
TOLUENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
PROPANE ASPIRATION HAZARD - CATEGORY 1
BUTANE ASPIRATION HAZARD - CATEGORY 1
XYLENE ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
TOLUENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 10470.3 MG/KG
INHALATION (GASES) 133705.2 PPM
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
METHYL ACETATE ACUTE LC50: FISH - PIMEPHALES 96 HOURS
320000 (MICRO)G/L PROMELAS
FRESH WATER
METHYL ETHYL KETONE ACUTE EC50: ALGAE - SKELETONEMA 96 HOURS
>500000 (MICRO)G/L COSTATUM
MARINE WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
5091000 (MICRO)G/L MAGNA - LARVAE
FRESH WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
3220000 (MICRO)G/L PROMELAS
FRESH WATER
METHYL ISOBUTYL ACUTE LC50: FISH - PIMEPHALES 96 HOURS
KETONE 505000 (MICRO)G/L PROMELAS
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
78 MG/L MAGNA
FRESH WATER
CHRONIC NOEC: FISH - PIMEPHALES 33 DAYS
168 MG/L PROMELAS - EMBRYO
FRESH WATER
XYLENE ACUTE LC50: CRUSTACEANS - 48 HOURS
8500 (MICRO)G/L PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO)G/L PROMELAS
FRESH WATER
ACETONE ACUTE EC50: ALGAE - SELENASTRUM 96 HOURS
7200000 (MICRO)G/L SP.
FRESH WATER
ACUTE LC50: CRUSTACEANS - 48 HOURS
6000000 (MICRO)G/L GAMMARUS PULEX
FRESH WATER
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
6900 MG/L MAGNA
FRESH WATER
ACUTE LC50: FISH - POECILIA 96 HOURS
5600 PPM RETICULATA
FRESH WATER
CHRONIC NOEC: ALGAE - ULVA PERTUSA 96 HOURS
4.95 MG/L
MARINE WATER
CHRONIC NOEC: CRUSTACEANS - 21 DAYS
0.016 ML/L DAPHNIIDAE
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
0.1 ML/L MAGNA - NEONATE
FRESH WATER
ETHYLBENZENE ACUTE EC50: ALGAE - 72 HOURS
4600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: ALGAE - 96 HOURS
3600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - ARTEMIA 48 HOURS
6530 (MICRO)G/L SP. - NAUPLII
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2930 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO)G/L MYKISS
FRESH WATER
TOLUENE ACUTE EC50: ALGAE - 72 HOURS
12500 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - 48 HOURS
11600 (MICRO)G/L GAMMARUS
FRESH WATER PSEUDOLIMNAEUS -
ADULT
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
6000 (MICRO)G/L MAGNA - JUVENILE
FRESH WATER (FLEDGLING,
HATCHLING, WEANLING)
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
5500 (MICRO)G/L KISUTCH - FRY
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
1000 (MICRO)G/L MAGNA
FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
METHYL ETHYL KETONE READILY
1-METHOXY-2-PROPANOL READILY
ACETATE
METHYL ISOBUTYL KETONE READILY
XYLENE READILY
ACETONE READILY
ETHYLBENZENE READILY
TOLUENE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
XYLENE 8.1 TO 25.9 LOW
TOLUENE 90 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE
OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY
BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS
CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1950 UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS AEROSOLS AEROSOLS
TRANSPORT HAZARD 2.1 2.1 2.1
CLASS(ES)
FLAMMABLE GAS, CLASS 2.1, CLASS 2.1,
CLASS/DIVISION FLAMMABLE FLAMMABLE
2.1 GASES GASES
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION PRODUCT
CLASSIFIED
AS PER THE
FOLLOWING
SECTIONS
OF THE
TRANSPORTATION
OF DANGEROUS
GOODS
REGULATIONS:
2.13-2.17
(CLASS 2).
ERG NO.: 126 ERG NO.: 126 ERG NO.: 126
IATA IMDG
UN NUMBER UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS, FLAMMABLE AEROSOLS
TRANSPORT HAZARD CLASS(ES) 2.1 2.1
CLASS 2.1, CLASS 2.1 - FLAMMABLE
FLAMMABLE GASES
GASES
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION EMERGENCY SCHEDULES
(EMS): F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE
THAT THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL
PACKAGING MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND
COMPLIANCE WITH THE APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF
THE PERSON OFFERING THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND
UNLOADING DANGEROUS GOODS MUST BE TRAINED ON ALL OF THE RISKS DERIVING
FROM THE SUBSTANCES AND ON ALL ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK
OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS
MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE AEROSOLS - CATEGORY 1 ON BASIS OF TEST DATA
GASES UNDER PRESSURE - COMPRESSED GAS CALCULATION METHOD
SKIN CORROSION/IRRITATION - CATEGORY 2 CALCULATION METHOD
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
CARCINOGENICITY - CATEGORY 2 CALCULATION METHOD
TOXIC TO REPRODUCTION (UNBORN CHILD) - CATEGORY 2 CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(RESPIRATORY TRACT IRRITATION) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(NARCOTIC EFFECTS) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY CALCULATION METHOD
(REPEATED EXPOSURE) - CATEGORY 2
ASPIRATION HAZARD - CATEGORY 1 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 9/16/2016
DATE OF ISSUE/DATE OF REVISION: 9/16/2016
DATE OF PREVIOUS ISSUE: 9/16/2016
VERSION: 1.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA
SHEET (SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE
INFORMATION PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE
ADDITION OF ANY MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF
THE PRODUCT. PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT
AS SPECIFICALLY INSTRUCTED BY SHERWIN-WILLIAMS, INCLUDING BUT NOT LIMITED
TO THE INCORPORATION OF NON SHERWIN-WILLIAMS PRODUCTS OR THE USE OR
ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY SHERWIN-WILLIAMS.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF
THIS PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY
PURPOSE OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS
WITHOUT FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.