| Common Name: | TOUCH N SEAL FOAM KIT 600 CCMC PART A, TOUCH N SEAL FOAM KIT 600 CMCC PART B |
| Manufacturer: | CONVENIENCE PRODUCTS |
| SDS Revision Date: | 3/4/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 444A88 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CP
CONVENIENCE PRODUCTS
SAFETY DATA SHEET
ACCORDING TO 1907/2006/EC (REACH), 1272/2008/EC (CLP), AND GHS
PRINTING DATE: 03.04.2014
REVISION: 03.04.2014
| 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: TOUCH N SEAL FOAM KIT 600 CCMC PART A
ARTICLE NUMBER: EHS2921 - SDS / A REGULAR
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NO FURTHER RELEVANT INFORMATION AVAILABLE.
APPLICATION OF THE SUBSTANCE / THE MIXTURE: POLYURETHANE-SEALANT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS, DIVISION OF CLAYTON CORP.
866 HORAN DRIVE
FENTON, MO 63026-2416
PHONE: 636-349-5855
FURTHER INFORMATION OBTAINABLE FROM: PRODUCT SAFETY DEPARTMENT
1.4 EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924
+1 (813)248-0585
| 2 HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
HEALTH HAZARD
RESP. SENS. 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
EXCLAMATION MARK
ACUTE TOX. 4:
H332: HARMFUL IF INHALED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
XN; HARMFUL:
R20-40-48/20:
HARMFUL BY INHALATION. LIMITED EVIDENCE OF A CARCINOGENIC EFFECT.
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
XN; SENSITISING:
R42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
XI; IRRITANT:
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT HAS TO BE LABELLED DUE TO THE CALCULATION PROCEDURE OF THE
"GENERAL CLASSIFICATION GUIDELINE FOR PREPARATIONS OF THE EU" IN THE LATEST
VALID VERSION.
WARNING!
PRESSURIZED CONTAINER.
CLASSIFICATION SYSTEM:
THE CLASSIFICATION IS ACCORDING TO THE LATEST EDITIONS OF THE EU-LISTS, AND
EXTENDED BY COMPANY AND LITERATURE DATA.
THE CLASSIFICATION IS IN ACCORDANCE WITH THE LATEST EDITIONS OF
INTERNATIONAL SUBSTANCES LISTS, AND IS SUPPLEMENTED BY INFORMATION FROM
TECHNICAL LITERATURE AND BY INFORMATION PROVIDED BY THE COMPANY.
2.2 LABEL ELEMENTS:
LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008:
THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION.
HAZARD PICTOGRAMS:
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELLING:
DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
4,4'-METHYLENEDIPHENYL DIISOCYANATE
HAZARD STATEMENTS:
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
H332: HARMFUL IF INHALED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
P101: IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION.
P260: DO NOT BREATHE MIST/VAPOURS/SPRAY.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE.
1,8% BY MASS OF THE CONTENTS ARE FLAMMABLE
HAZARD DESCRIPTION:
WHMIS-SYMBOLS:
A - COMPRESSED GAS
D2A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 0
REACTIVITY 1
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 2*
FIRE 0
REACTIVITY 1
* INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED
EXPOSURES.
HMIS LONG TERM HEALTH HAZARD SUBSTANCES:
9016-87-9: DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8: 4,4'-METHYLENEDIPHENYL DIISOCYANATE
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
DANGEROUS COMPONENTS:
CAS: 9016-87-9 DIPHENYLMETHANEDIISOCYANATE, 25-50%
ISOMERES AND HOMOLOGUES
XN R20; XN R42/43; XI R36/37/38
CARC. CAT. 3
RESP. SENS. 1, H334; STOT RE
2, H373
ACUTE TOX. 4, H332; SKIN
IRRIT. 2, H315; EYE IRRIT. 2,
H319; SKIN SENS. 1, H317;
STOT SE 3, H335
CAS: 101-68-8 4,4'-METHYLENEDIPHENYL 25-50%
EINECS: 202-966-0 DIISOCYANATE
INDEX NUMBER: 615-005-00-9 XN R20; XN R42/43; XI R36/37/38
CARC. CAT. 3
RESP. SENS. 1, H334; STOT
RE 2, H373
ACUTE TOX. 4, H332; SKIN
IRRIT. 2, H315; EYE IRRIT. 2,
H319; SKIN SENS. 1, H317;
STOT SE 3, H335
CAS: 811-97-2 NORFLURANE 10-25%
EINECS: 212-377-0 PRESS. GAS, H280
HALOGENATED HYDROCARBON <10%
XN R22
ACUTE TOX. 4, H302
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED RISK PHRASES REFER TO SECTION 16.
| 4 FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
DO NOT LEAVE AFFECTED PERSONS UNATTENDED.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE MEDICAL
OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
AFTER INHALATION:
SUPPLY FRESH AIR AND TO BE SURE CALL FOR A DOCTOR.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
DO NOT PULL SOLIDIFIED PRODUCT OFF THE SKIN.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
PROTECT UNHARMED EYE.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER.
CALL A DOCTOR IMMEDIATELY.
DO NOT REMOVE CONTACT LENSES IF WORN.
AFTER SWALLOWING:
UNLIKELY ROUTE OF EXPOSURE.
DO NOT INDUCE VOMITING; CALL FOR MEDICAL HELP IMMEDIATELY.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASTHMA ATTACKS
HEADACHE
ALLERGIC REACTIONS
COUGHING
BREATHING DIFFICULTY
DIZZINESS
HAZARDS:
DANGER OF IMPAIRED BREATHING.
DANGER OF PULMONARY OEDEMA.
DANGER OF CONVULSION.
DANGER OF DISTURBED CARDIAC RHYTHM.
CONDITION MAY DETERIORATE WITH ALCOHOL CONSUMPTION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
SEVERE ALLERGIC SKIN REACTION, BRONCHIAL SPASMS AND ANAPHYLACTIC SHOCK ARE
POSSIBLE.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
LATER OBSERVATION FOR PNEUMONIA AND PULMONARY OEDEMA.
MONITOR CIRCULATION, POSSIBLE SHOCK TREATMENT.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
| 5 FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER SPRAY OR ALCOHOL
RESISTANT FOAM.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOUR PRESSURE WHEN HEATED.
IN CASE OF FIRE, THE FOLLOWING CAN BE RELEASED:
NITROGEN OXIDES (NOX)
HYDROGEN CYANIDE (HCN)
CARBON MONOXIDE (CO)
UNDER CERTAIN FIRE CONDITIONS, TRACES OF OTHER TOXIC GASES CANNOT BE
EXCLUDED.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION: COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
| 6 ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
REMOVE PERSONS FROM DANGER AREA.
ENSURE ADEQUATE VENTILATION
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
PROTECT FROM HEAT.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
CLEAN THE AFFECTED AREA CAREFULLY; SUITABLE CLEANERS ARE:
WARM WATER AND CLEANSING AGENT
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
USE ONLY IN WELL VENTILATED AREAS.
TAKE NOTE OF EMISSION THRESHOLD.
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C, I.E. ELECTRIC LIGHTS. DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT SPRAY ONTO A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
STORE IN A COOL LOCATION.
PROVIDE VENTILATION FOR RECEPTACLES.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
DO NOT STORE TOGETHER WITH ACIDS.
STORE AWAY FROM OXIDIZING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
STORE RECEPTACLE IN A WELL VENTILATED AREA.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES:
NO FURTHER DATA; SEE ITEM 7.
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
PEL (USA):
SHORT-TERM VALUE: C 0,2 MG/M3, C 0,02 PPM
REL (USA):
SHORT-TERM VALUE: C 0,2* MG/M3, C 0,02* PPM
LONG-TERM VALUE: 0,05 MG/M3, 0,005 PPM
*10-MIN
TLV (USA): 0,051 MG/M3, 0,005 PPM
EL (CANADA):
SHORT-TERM VALUE: C 0,01 PPM
LONG-TERM VALUE: 0,005 PPM
SKIN; S
EV (CANADA): 0,005 PPM
811-97-2 NORFLURANE:
WEEL (USA): 1000 PPM
HALOGENATED HYDROCARBON:
PEL (USA): 790 MG/M3, 200 PPM
REL (USA): 790 MG/M3, 200 PPM
TLV (USA): 793 MG/M3, 200 PPM
EL (CANADA): 200 PPM
EV (CANADA):
SHORT-TERM VALUE: 990 MG/M3, 250 PPM
LONG-TERM VALUE: 790 MG/M3, 200 PPM
DNELS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PNECS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL INFORMATION:
THE LISTS VALID DURING THE MAKING WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
AVOID CONTACT WITH THE EYES AND SKIN.
RESPIRATORY PROTECTION:
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE IN CASE OF INSUFFICIENT
VENTILATION.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN HIGH CONCENTRATIONS ARE
PRESENT.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
DUE TO MISSING TESTS NO RECOMMENDATION TO THE GLOVE MATERIAL CAN BE GIVEN
FOR THE PRODUCT/ THE PREPARATION/ THE CHEMICAL MIXTURE.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION.
MATERIAL OF GLOVES:
NITRILE RUBBER, NBR
PVC GLOVES
FLUOROCARBON RUBBER (VITON)
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE
PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
NOT SUITABLE ARE GLOVES MADE OF THE FOLLOWING MATERIALS: NATURAL RUBBER, NR
EYE PROTECTION: CONTACT LENSES SHOULD NOT BE WORN.
SAFETY GLASSES
GOGGLES RECOMMENDED DURING REFILLING
BODY PROTECTION: IMPERVIOUS PROTECTIVE CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES:
SEE SECTION 7 FOR ADDITIONAL INFORMATION.
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: AEROSOLIZED LIQUID WITH COMPRESSED GAS IN CYLINDERS
COLOUR: CREAM COLOURED
ODOUR: CHARACTERISTIC
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: NOT APPLICABLE, AS AEROSOL.
FLASH POINT: NOT APPLICABLE, AS AEROSOL.
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO/SELF-IGNITION TEMPERATURE: 400 DEG. C (752 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
SELF-IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
EXPLOSION LIMITS:
LOWER: 0,4 VOL %
UPPER: NOT DETERMINED.
VAPOUR PRESSURE AT 20 DEG. C: 5716 HPA
DENSITY AT 20 DEG. C: 1,03 G/CM3
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
VOC (US EPA METHOD 24): 32,8 G/L
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
10.2 CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS WITH ALCOHOLS, AMINES, AQUEOUS ACIDS AND ALKALIS.
CONTACT WITH ACIDS RELEASES TOXIC GASES.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOUR PRESSURE WHEN HEATED.
REACTS WITH OXIDIZING AGENTS.
EXOTHERMIC POLYMERIZATION.
10.4 CONDITIONS TO AVOID: STORE AWAY FROM OXIDIZING AGENTS.
10.5 INCOMPATIBLE MATERIALS: CONTACT WITH ACIDS LIBERATES TOXIC GAS.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
AMMONIA
ISOCYANATE
NITROGEN OXIDES
| 11 TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES RELEVANT FOR CLASSIFICATION:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
ORAL:
LD50: 2200 MG/KG (MOUSE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
SENSITIZATION POSSIBLE THROUGH INHALATION.
SENSITIZATION POSSIBLE THROUGH SKIN CONTACT.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO THE CALCULATION METHOD
OF THE GENERAL EU CLASSIFICATION GUIDELINES FOR PREPARATIONS AS ISSUED IN
THE LATEST VERSION:
HARMFUL
IRRITANT
SENSITISATION: SENSITIZATION POSSIBLE BY INHALATION AND/OR DERMAL CONTACT.
REPEATED DOSE TOXICITY:
REPEATED EXPOSURES MAY RESULT IN SKIN AND/OR RESPIRATORY SENSITIVITY.
| 12 ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY:
THE PRODUCT CONTAINS MATERIALS THAT ARE HARMFUL TO THE ENVIRONMENT.
12.2 PERSISTENCE AND DEGRADABILITY:
THE PRODUCT IS PARTIALLY BIODEGRADABLE. SIGNIFICANT RESIDUALS REMAIN.
12.3 BIOACCUMULATIVE POTENTIAL: DOES NOT ACCUMULATE IN ORGANISMS.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
THIS STATEMENT WAS DEDUCED FROM PRODUCTS WITH A SIMILAR STRUCTURE OR
COMPOSITION.
DUE TO AVAILABLE DATA ON ELIMINABILITY/DECOMPOSITION AND BIOACCUMULATION
POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT BE EXCLUDED.
WATER HAZARD CLASS 1 (GERMAN REGULATION) (SELF-ASSESSMENT):
SLIGHTLY HAZARDOUS FOR WATER
DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND
WATER, WATER COURSE OR SEWAGE SYSTEM.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION:
CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE AFTER SOLIDIFICATION FOLLOWING
CONSULTATION WITH THE WASTE DISPOSAL FACILITY OPERATOR AND THE PERTINENT
AUTHORITIES AND ADHERING TO THE NECESSARY TECHNICAL REGULATIONS. CAN BE
BURNED WITH HOUSEHOLD GARBAGE AFTER CONSULTING WITH THE WASTE DISPOSAL
FACILITY OPERATOR AND THE PERTINENT AUTHORITIES AND ADHERING TO THE
NECESSARY TECHNICAL REGULATIONS.
CONTACT WASTE PROCESSORS FOR RECYCLING INFORMATION.
UNCLEANED PACKAGING:
RECOMMENDATION:
PACKAGINGS THAT MAY NOT BE CLEANSED ARE TO BE DISPOSED OF IN THE SAME
MANNER AS THE PRODUCT.
DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
DOT, ADR, IMDG, IATA: UN3500
14.2 UN PROPER SHIPPING NAME:
DOT, IMDG, IATA:
CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
ADR:
3500 CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
14.3 TRANSPORT HAZARD CLASS(ES):
DOT: NON-FLAMMABLE GAS, CLASS/DIVISION 2.2
CLASS: 2.2
LABEL: 2.2
ADR: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2 8A GASES.
LABEL: 2.2
IMDG, IATA: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2.2
LABEL: 2.2
14.4 PACKING GROUP:
DOT, ADR, IMDG, IATA: NOT REGULATED
14.5 ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
14.6 SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES.
DANGER CODE (KEMLER): 20
EMS NUMBER: F-D, S-U
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
LIMITED QUANTITIES (LQ): 120 ML
TRANSPORT CATEGORY: 3
TUNNEL RESTRICTION CODE: C/E
UN "MODEL REGULATION":
UN3500, CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON,
NITROGEN), 2.2
| 15 REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES CBD
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE CBD
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES 3
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 3
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
CANADA:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
NONE OF THE INGREDIENTS IS LISTED.
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
SUBSTANCES OF VERY HIGH CONCERN (SVHC) ACCORDING TO REACH, ARTICLE 57:
NONE OF THE INGREDIENTS IS LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
R20: HARMFUL BY INHALATION.
R22: HARMFUL IF SWALLOWED.
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R42/43: MAY CAUSE SENSITISATION BY INHALATION AND SKIN CONTACT.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (CANADA)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
FLAMMABLE AEROSOLS, HAZARD CATEGORY 3
PRESS. GAS:
GASES UNDER PRESSURE: COMPRESSED GAS
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
RESP. SENS. 1: SENSITISATION - RESPIRAT., HAZARD CATEGORY 1
SKIN SENS. 1: SENSITISATION - SKIN, HAZARD CATEGORY 1
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
SOURCES:
SDS PREPARED BY:
CHEMTEL INC.
1305 NORTH FLORIDA AVENUE
TAMPA, FLORIDA 33602-2902
USA
TOLL FREE NORTH AMERICA: 1-888-255-3924
INTL.: +01 813-248-0573
WEBSITE: WWW.CHEMTELINC.COM
CP
CONVENIENCE PRODUCTS
SAFETY DATA SHEET
ACCORDING TO 1907/2006/EC (REACH), 1272/2008/EC (CLP), AND GHS
PRINTING DATE: 03.04.2014
REVISION: 03.04.2014
| 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: TOUCH N SEAL FOAM KIT 600 CMCC PART B
ARTICLE NUMBER: EHS2921 - SDS / B REGULAR
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NO FURTHER RELEVANT INFORMATION AVAILABLE.
APPLICATION OF THE SUBSTANCE / THE MIXTURE: POLYMERIZATION CATALYST
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS, DIVISION OF CLAYTON CORP.
866 HORAN DRIVE
FENTON, MO 63026-2416
PHONE: 636-349-5855
1.4 EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924
+1 (813)248-0585
| 2 HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
EXCLAMATION MARK
ACUTE TOX. 4:
H302: HARMFUL IF SWALLOWED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
XN; HARMFUL:
R22: HARMFUL IF SWALLOWED.
XI; IRRITANT:
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT HAS TO BE LABELLED DUE TO THE CALCULATION PROCEDURE OF THE
"GENERAL CLASSIFICATION GUIDELINE FOR PREPARATIONS OF THE EU" IN THE LATEST
VALID VERSION.
WARNING!
PRESSURIZED CONTAINER.
CLASSIFICATION SYSTEM:
THE CLASSIFICATION IS ACCORDING TO THE LATEST EDITIONS OF THE EU-LISTS, AND
EXTENDED BY COMPANY AND LITERATURE DATA.
THE CLASSIFICATION IS IN ACCORDANCE WITH THE LATEST EDITIONS OF
INTERNATIONAL SUBSTANCES LISTS, AND IS SUPPLEMENTED BY INFORMATION FROM
TECHNICAL LITERATURE AND BY INFORMATION PROVIDED BY THE COMPANY.
2.2 LABEL ELEMENTS:
LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008:
THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION.
HAZARD PICTOGRAMS:
GHS07: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELLING:
HALOGENATED ALIPHATIC POLYETHER POLYOL
POLYETHER POLYOL
HALOGENATED HYDROCARBON
HAZARD STATEMENTS:
H229:
PRESSURISED CONTAINER: MAY BURST IF HEATED.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
P101: IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION.
P261: AVOID BREATHING MIST/VAPOURS/SPRAY.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P304+P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P330: RINSE MOUTH.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
CONTAINS NEODECANOIC ACID. MAY PRODUCE AN ALLERGIC REACTION.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE.
3,5% BY MASS OF THE CONTENTS ARE FLAMMABLE
HAZARD DESCRIPTION:
WHMIS-SYMBOLS:
A - COMPRESSED GAS
D2B - TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 0
REACTIVITY 1
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 0
REACTIVITY 1
HMIS LONG TERM HEALTH HAZARD SUBSTANCES: NONE OF THE INGREDIENTS IS LISTED.
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
DANGEROUS COMPONENTS:
CAS: 68441-62-3 HALOGENATED ALIPHATIC POLYETHER POLYOL 25-50%
XN R22; XI R36
ACUTE TOX. 4, H302; EYE IRRIT. 2, H319
POLYETHER POLYOL 25-50%
XN R22; XI R36/37/38
ACUTE TOX. 4, H302; SKIN IRRIT. 2, H315;
EYE IRRIT. 2, H319; STOT SE 3, H335
CAS: 811-97-2 NORFLURANE 10-25%
EINECS: 212-377-0 PRESS. GAS, H280
HALOGENATED HYDROCARBON <10%
XN R22
ACUTE TOX. 4, H302
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED RISK PHRASES REFER TO SECTION 16.
| 4 FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE MEDICAL
OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; CALL FOR MEDICAL HELP IMMEDIATELY.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
DIZZINESS
GASTRIC OR INTESTINAL DISORDERS.
COUGHING
ALLERGIC REACTIONS
HAZARDS NO FURTHER RELEVANT INFORMATION AVAILABLE.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
IN CASES OF IRRITATION TO THE LUNGS, INITIAL TREATMENT WITH CORTICAL
STEROID INHALANTS.
| 5 FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER SPRAY OR ALCOHOL
RESISTANT FOAM.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IN CASE OF FIRE, THE FOLLOWING CAN BE RELEASED:
NITROGEN OXIDES (NOX)
CARBON MONOXIDE (CO)
UNDER CERTAIN FIRE CONDITIONS, TRACES OF OTHER TOXIC GASES CANNOT BE
EXCLUDED.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOUR PRESSURE WHEN HEATED.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION: COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
| 6 ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
ENSURE ADEQUATE VENTILATION
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
ENSURE ADEQUATE VENTILATION.
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
NO SPECIAL MEASURES REQUIRED.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
DO NOT STORE TOGETHER WITH OXIDIZING AND ACIDIC MATERIALS.
STORE AWAY FROM FOODSTUFFS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
STORE RECEPTACLE IN A WELL VENTILATED AREA.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES:
NO FURTHER DATA; SEE ITEM 7.
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
811-97-2 NORFLURANE:
WEEL (USA): 1000 PPM
HALOGENATED HYDROCARBON:
PEL (USA): 790 MG/M3, 200 PPM
REL (USA): 790 MG/M3, 200 PPM
TLV (USA): 793 MG/M3, 200 PPM
EL (CANADA): 200 PPM
EV (CANADA):
SHORT-TERM VALUE: 990 MG/M3, 250 PPM
LONG-TERM VALUE: 790 MG/M3, 200 PPM
DNELS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PNECS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL INFORMATION:
THE LISTS VALID DURING THE MAKING WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
AVOID CONTACT WITH THE EYES AND SKIN.
DO NOT INHALE GASES / FUMES / AEROSOLS.
RESPIRATORY PROTECTION:
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE IN CASE OF INSUFFICIENT
VENTILATION.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN HIGH CONCENTRATIONS ARE
PRESENT.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
DUE TO MISSING TESTS NO RECOMMENDATION TO THE GLOVE MATERIAL CAN BE GIVEN
FOR THE PRODUCT/ THE PREPARATION/ THE CHEMICAL MIXTURE.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION.
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE
PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: CONTACT LENSES SHOULD NOT BE WORN.
SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES:
SEE SECTION 7 FOR ADDITIONAL INFORMATION.
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: AEROSOL
COLOUR: NOT DETERMINED.
ODOUR: SWEETISH
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: -15 DEG. F / -26 DEG. C
FLASH POINT: NOT APPLICABLE, AS AEROSOL.
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO/SELF-IGNITION TEMPERATURE: >500 DEG. F / >260 DEG. C
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
SELF-IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
VAPOUR PRESSURE AT 20 DEG. C: 5716 HPA
DENSITY: NOT DETERMINED.
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: FULLY MISCIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
VOC (US EPA METHOD 24): 32,0 G/L
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
10.2 CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS WITH CATALYSTS.
REACTS WITH PEROXIDES.
REACTS WITH STRONG OXIDIZING AGENTS.
REACTS WITH STRONG ACIDS.
EXOTHERMIC POLYMERIZATION.
10.4 CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.5 INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
PHOSPHORUS COMPOUNDS
CHLORINE COMPOUNDS
NITROGEN OXIDES (NOX)
POISONOUS GASES/VAPOURS
PHOSGENE
HYDROGEN CHLORIDE (HCl)
| 11 TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
SENSITIZING EFFECT BY SKIN CONTACT IS POSSIBLE BY PROLONGED EXPOSURE.
SENSITIZING EFFECT THROUGH INHALATION IS POSSIBLE BY PROLONGED EXPOSURE.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO THE CALCULATION METHOD
OF THE GENERAL EU CLASSIFICATION GUIDELINES FOR PREPARATIONS AS ISSUED IN
THE LATEST VERSION:
HARMFUL
IRRITANT
ASPHYXIANT GAS.
REPEATED DOSE TOXICITY:
REPEATED EXPOSURES MAY RESULT IN SKIN AND/OR RESPIRATORY SENSITIVITY.
| 12 ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY:
THE PRODUCT CONTAINS MATERIALS THAT ARE HARMFUL TO THE ENVIRONMENT.
12.2 PERSISTENCE AND DEGRADABILITY:
THE PRODUCT IS PARTIALLY BIODEGRADABLE. SIGNIFICANT RESIDUALS REMAIN.
12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ECOTOXICAL EFFECTS:
REMARK:
DUE TO MECHANICAL ACTIONS OF THE PRODUCT (E.G. AGGLUTINATIONS) DAMAGES MAY
OCCUR.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
THIS STATEMENT WAS DEDUCED FROM THE PROPERTIES OF THE SINGLE COMPONENTS.
THE PRODUCT CONTAINS HEAVY METALS. AVOID TRANSFER INTO THE ENVIRONMENT.
SPECIFIC PRELIMINARY TREATMENTS ARE NECESSARY
WATER HAZARD CLASS 1 (GERMAN REGULATION) (SELF-ASSESSMENT):
SLIGHTLY HAZARDOUS FOR WATER
DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND
WATER, WATER COURSE OR SEWAGE SYSTEM.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT
TO REACH SEWAGE SYSTEM. CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE AFTER
SOLIDIFICATION FOLLOWING CONSULTATION WITH THE WASTE DISPOSAL FACILITY
OPERATOR AND THE PERTINENT AUTHORITIES AND ADHERING TO THE NECESSARY
TECHNICAL REGULATIONS.
UNCLEANED PACKAGING:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
RECOMMENDED CLEANSING AGENTS:
WATER, IF NECESSARY TOGETHER WITH CLEANSING AGENTS.
| 14 TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
DOT, ADR, IMDG, IATA: UN3500
14.2 UN PROPER SHIPPING NAME:
DOT, IMDG, IATA:
CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
ADR:
3500 CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
14.3 TRANSPORT HAZARD CLASS(ES):
DOT: NON-FLAMMABLE GAS, CLASS/DIVISION 2.2
CLASS: 2.2
LABEL: 2.2
ADR: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2 8A GASES.
LABEL: 2.2
IMDG, IATA: CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
CLASS: 2.2
LABEL: 2.2
14.4 PACKING GROUP:
DOT, ADR, IMDG, IATA: NOT REGULATED
14.5 ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
14.6 SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES.
DANGER CODE (KEMLER): 20
EMS NUMBER: F-D, S-U
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
LIMITED QUANTITIES (LQ): 120 ML
TRANSPORT CATEGORY: 3
TUNNEL RESTRICTION CODE: C/E
UN "MODEL REGULATION":
UN3500, CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED HYDROCARBON, NITROGEN)
| 15 REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS IS LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY): NONE OF THE INGREDIENTS IS LISTED.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS IS LISTED.
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
CANADA:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
NONE OF THE INGREDIENTS IS LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
NONE OF THE INGREDIENTS IS LISTED.
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
SUBSTANCES OF VERY HIGH CONCERN (SVHC) ACCORDING TO REACH, ARTICLE 57:
NONE OF THE INGREDIENTS IS LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
R22: HARMFUL IF SWALLOWED.
R36: IRRITATING TO EYES.
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
FLAMMABLE AEROSOLS, HAZARD CATEGORY 3
PRESS. GAS:
GASES UNDER PRESSURE: COMPRESSED GAS
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
SOURCES:
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