| Common Name: | FROTH-PAK ISO INT AF HFC, FROTH-PAK POLYOL INT 1.75 HFC BLEND |
| Manufacturer: | DOW CHEMICAL |
| SDS Revision Date: | 4/26/2016 |
| SDS Format: | No Format Specified |
| Item Number(s): | 48WK26 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DOW(R*)
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
PRODUCT NAME: FROTH-PAK(TM) ISO INT AF HFC
ISSUE DATE: 04/26/2016
PRINT DATE: 11/02/2017
THE DOW CHEMICAL COMPANY ENCOURAGES AND EXPECTS YOU TO READ AND UNDERSTAND
THE ENTIRE (M)SDS, AS THERE IS IMPORTANT INFORMATION THROUGHOUT THE
DOCUMENT. WE EXPECT YOU TO FOLLOW THE PRECAUTIONS IDENTIFIED IN THIS
DOCUMENT UNLESS YOUR USE CONDITIONS WOULD NECESSITATE OTHER APPROPRIATE
METHODS OR ACTIONS.
| 1. IDENTIFICATION |  |
PRODUCT NAME: FROTH-PAK(TM) ISO INT AF HFC
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
IDENTIFIED USES:
FOR INDUSTRIAL USE. COMPONENT(S) FOR THE MANUFACTURE OF URETHANE POLYMERS.
WE RECOMMEND THAT YOU USE THIS PRODUCT IN A MANNER CONSISTENT WITH THE
LISTED USE. IF YOUR INTENDED USE IS NOT CONSISTENT WITH THE STATED USE,
PLEASE CONTACT YOUR SALES OR TECHNICAL SERVICE REPRESENTATIVE.
COMPANY IDENTIFICATION:
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
CUSTOMER INFORMATION NUMBER:
800-258-2436
SDSQUESTION@DOW.COM
EMERGENCY TELEPHONE NUMBER:
24-HOUR EMERGENCY CONTACT:
CHEMTREC: +1 800-424-9300
LOCAL EMERGENCY CONTACT: 800-424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
THIS MATERIAL IS HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD 29CFR 1910.1200.
GASES UNDER PRESSURE: LIQUEFIED GAS
ACUTE TOXICITY: CATEGORY 4 - INHALATION
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2B
RESPIRATORY SENSITISATION: CATEGORY 1
SKIN SENSITISATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: CATEGORY 2 - INHALATION
LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER!
HAZARDS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN AND EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HARMFUL IF INHALED.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DAMAGE TO ORGANS (RESPIRATORY TRACT) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/ FUME/ GAS/ MIST/ VAPOURS/ SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NO DATA AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT IS A MIXTURE.
COMPONENT CASRN CONCENTRATION
DIPHENYLMETHANE DIISOCYANATE, ISOMERS 9016-87-9 >=60.0 - <=100.0 %
AND HOMOLOGUES
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8 30.0 - 60.0 %
1,1,1,2-TETRAFLUOROETHANE 811-97-2 >=5.0 - <=10.0 %
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION AND USE
THE RECOMMENDED PROTECTIVE CLOTHING (CHEMICAL RESISTANT GLOVES, SPLASH
PROTECTION). IF POTENTIAL FOR EXPOSURE EXISTS REFER TO SECTION 8 FOR
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT.
INHALATION:
MOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION;
IF BY MOUTH TO MOUTH USE RESCUER PROTECTION (POCKET MASK, ETC). IF
BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. CALL A PHYSICIAN OR TRANSPORT TO A MEDICAL FACILITY.
SKIN CONTACT:
REMOVE MATERIAL FROM SKIN IMMEDIATELY BY WASHING WITH SOAP AND PLENTY OF
WATER. REMOVE CONTAMINATED CLOTHING AND SHOES WHILE WASHING. SEEK MEDICAL
ATTENTION IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. AN MDI SKIN
DECONTAMINATION STUDY DEMONSTRATED THAT CLEANING VERY SOON AFTER EXPOSURE
IS IMPORTANT, AND THAT A POLYGLYCOL-BASED SKIN CLEANSER OR CORN OIL MAY BE
MORE EFFECTIVE THAN SOAP AND WATER. DISCARD ITEMS WHICH CANNOT BE
DECONTAMINATED, INCLUDING LEATHER ARTICLES SUCH AS SHOES, BELTS AND
WATCHBANDS. SUITABLE EMERGENCY SAFETY SHOWER FACILITY SHOULD BE AVAILABLE
IN WORK AREA.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH WATER; REMOVE CONTACT LENSES, IF PRESENT, AFTER
THE FIRST 5 MINUTES, THEN CONTINUE FLUSHING EYES FOR AT LEAST 15 MINUTES.
OBTAIN MEDICAL ATTENTION WITHOUT DELAY, PREFERABLY FROM AN OPHTHALMOLOGIST.
SUITABLE EMERGENCY EYE WASH FACILITY SHOULD BE IMMEDIATELY AVAILABLE.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY MEDICAL PERSONNEL.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASIDE FROM THE INFORMATION FOUND UNDER DESCRIPTION OF FIRST AID MEASURES
(ABOVE) AND INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED (BELOW), ANY ADDITIONAL IMPORTANT SYMPTOMS AND EFFECTS ARE DESCRIBED
IN SECTION 11: TOXICOLOGY INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
EXCESSIVE EXPOSURE MAY AGGRAVATE PREEXISTING ASTHMA AND OTHER RESPIRATORY
DISORDERS (E.G. EMPHYSEMA, BRONCHITIS, REACTIVE AIRWAYS DYSFUNCTION
SYNDROME). MAINTAIN ADEQUATE VENTILATION AND OXYGENATION OF THE PATIENT.
MAY CAUSE RESPIRATORY SENSITIZATION OR ASTHMA-LIKE SYMPTOMS.
BRONCHODILATORS, EXPECTORANTS AND ANTITUSSIVES MAY BE OF HELP. TREAT
BRONCHOSPASM WITH INHALED BETA2 AGONIST AND ORAL OR PARENTERAL
CORTICOSTEROIDS. RESPIRATORY SYMPTOMS, INCLUDING PULMONARY EDEMA, MAY BE
DELAYED. PERSONS RECEIVING SIGNIFICANT EXPOSURE SHOULD BE OBSERVED 24-48
HOURS FOR SIGNS OF RESPIRATORY DISTRESS. IF YOU ARE SENSITIZED TO
DIISOCYANATES, CONSULT YOUR PHYSICIAN REGARDING WORKING WITH OTHER
RESPIRATORY IRRITANTS OR SENSITIZERS. EXPOSURE MAY INCREASE "MYOCARDIAL
IRRITABILITY". DO NOT ADMINISTER SYMPATHOMIMETIC DRUGS SUCH AS EPINEPHRINE
UNLESS ABSOLUTELY NECESSARY. TREATMENT OF EXPOSURE SHOULD BE DIRECTED AT
THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION OF THE PATIENT.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG OR FINE SPRAY. DRY CHEMICAL FIRE EXTINGUISHERS. CARBON DIOXIDE
FIRE EXTINGUISHERS. FOAM. ALCOHOL RESISTANT FOAMS (ATC TYPE) ARE PREFERRED.
GENERAL PURPOSE SYNTHETIC FOAMS (INCLUDING AFFF) OR PROTEIN FOAMS MAY
FUNCTION, BUT WILL BE LESS EFFECTIVE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE DIRECT WATER STREAM. MAY SPREAD FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS COMBUSTION PRODUCTS:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR
IRRITATING. COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
NITROGEN OXIDES. ISOCYANATES. HYDROGEN CYANIDE. CARBON MONOXIDE. CARBON
DIOXIDE. HYDROGEN HALIDES. HALOGENATED HYDROCARBONS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
SOME COMPONENTS OF THIS PRODUCT WILL BURN IN A FIRE SITUATION. PRODUCT
REACTS WITH WATER. REACTION MAY PRODUCE HEAT AND/OR GASES. THIS REACTION
MAY BE VIOLENT. CONTAINER MAY RUPTURE FROM GAS GENERATION IN A FIRE
SITUATION. BLOWING AGENT VAPORIZES QUICKLY AT ROOM TEMPERATURE. VIOLENT
STEAM GENERATION OR ERUPTION MAY OCCUR UPON APPLICATION OF DIRECT WATER
STREAM TO HOT LIQUIDS. DENSE SMOKE IS PRODUCED WHEN PRODUCT BURNS.
ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
KEEP PEOPLE AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY. STAY UPWIND.
KEEP OUT OF LOW AREAS WHERE GASES (FUMES) CAN ACCUMULATE. WATER IS NOT
RECOMMENDED, BUT MAY BE APPLIED IN LARGE QUANTITIES AS A FINE SPRAY WHEN
OTHER EXTINGUISHING AGENTS ARE NOT AVAILABLE. DO NOT USE DIRECT WATER
STREAM. MAY SPREAD FIRE. FIGHT FIRE FROM PROTECTED LOCATION OR SAFE
DISTANCE. CONSIDER THE USE OF UNMANNED HOSE HOLDERS OR MONITOR NOZZLES.
IMMEDIATELY WITHDRAW ALL PERSONNEL FROM THE AREA IN CASE OF RISING SOUND
FROM VENTING SAFETY DEVICE OR DISCOLORATION OF THE CONTAINER. MOVE
CONTAINER FROM FIRE AREA IF THIS IS POSSIBLE WITHOUT HAZARD. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND FIRE-AFFECTED ZONE UNTIL FIRE
IS OUT. CONTAIN FIRE WATER RUN-OFF IF POSSIBLE. FIRE WATER RUNOFF, IF NOT
CONTAINED, MAY CAUSE ENVIRONMENTAL DAMAGE. REVIEW THE "ACCIDENTAL RELEASE
MEASURES" AND THE "ECOLOGICAL INFORMATION" SECTIONS OF THIS (M)SDS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT,
TROUSERS, BOOTS, AND GLOVES). AVOID CONTACT WITH THIS MATERIAL DURING FIRE
FIGHTING OPERATIONS. IF CONTACT IS LIKELY, CHANGE TO FULL CHEMICAL
RESISTANT FIRE FIGHTING CLOTHING WITH SELF-CONTAINED BREATHING APPARATUS.
IF THIS IS NOT AVAILABLE, WEAR FULL CHEMICAL RESISTANT CLOTHING WITH SELF-
CONTAINED BREATHING APPARATUS AND FIGHT FIRE FROM A REMOTE LOCATION. FOR
PROTECTIVE EQUIPMENT IN POST-FIRE OR NON-FIRE CLEAN-UP SITUATIONS, REFER
TO THE RELEVANT SECTIONS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ISOLATE AREA. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING THE
AREA. REFER TO SECTION 7, HANDLING, FOR ADDITIONAL PRECAUTIONARY MEASURES.
KEEP PERSONNEL OUT OF LOW AREAS. KEEP PERSONNEL OUT OF CONFINED OR POORLY
VENTILATED AREAS. KEEP UPWIND OF SPILL. VENTILATE AREA OF LEAK OR SPILL.
CONFINED SPACE ENTRY PROCEDURES MUST BE FOLLOWED BEFORE ENTERING THE AREA.
SEE SECTION 10 FOR MORE SPECIFIC INFORMATION.
USE APPROPRIATE SAFETY EQUIPMENT. FOR ADDITIONAL INFORMATION, REFER TO
SECTION 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FROM ENTERING INTO SOIL, DITCHES, SEWERS, WATERWAYS AND/OR
GROUNDWATER. SEE SECTION 12, ECOLOGICAL INFORMATION.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLED MATERIAL IF POSSIBLE. ABSORB WITH MATERIALS SUCH AS:
DIRT. VERMICULITE. SAND. CLAY. DO NOT USE ABSORBENT MATERIALS SUCH AS:
CEMENT POWDER (NOTE: MAY GENERATE HEAT). COLLECT IN SUITABLE AND PROPERLY
LABELED OPEN CONTAINERS. SEE SECTION 13, DISPOSAL CONSIDERATIONS, FOR
ADDITIONAL INFORMATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED OR REPEATED
CONTACT WITH SKIN. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING VAPOR.
USE WITH ADEQUATE VENTILATION. THIS MATERIAL IS HYGROSCOPIC IN NATURE.
KEEP CONTAINER CLOSED. DO NOT ENTER CONFINED SPACES UNLESS ADEQUATELY
VENTILATED. SEE SECTION 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
SPILLS OF THESE ORGANIC MATERIALS ON HOT FIBROUS INSULATIONS MAY LEAD TO
LOWERING OF THE AUTOIGNITION TEMPERATURES POSSIBLY RESULTING IN SPONTANEOUS
COMBUSTION.
CONDITIONS FOR SAFE STORAGE:
STORE IN A DRY PLACE. AVOID PROLONGED EXPOSURE TO HEAT AND AIR. PROTECT
FROM ATMOSPHERIC MOISTURE. BLOWING AGENT MAY MIGRATE FROM PRODUCT AND
ACCUMULATE IN SOME STORAGE SITUATIONS. ELEVATED TEMPERATURES CAN CAUSE
PRESSURE BUILDUP IN CLOSED CONTAINERS DUE TO THE RELEASE OF BLOWING AGENTS.
STORE IN THE FOLLOWING MATERIAL(S): CARBON STEEL. STAINLESS STEEL.
POLYPROPYLENE. POLYETHYLENE-LINED CONTAINER. TEFLON. GLASS-LINED CONTAINER.
ALUMINUM. PLASITE 3066 LINED CONTAINER. PLASITE 3070 LINED CONTAINER. 316
STAINLESS STEEL. SEE SECTION 10 FOR MORE SPECIFIC INFORMATION.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS ARE LISTED BELOW, IF THEY EXIST.
COMPONENT REGULATION TYPE OF LISTING VALUE/NOTATION
4,4' -METHYLENEDIPHENYL DOW IHG TWA 0.005 PPM
DIISOCYANATE
DOW IHG STEL 0.02 PPM
ACGIH TWA 0.005 PPM
OSHA Z-1 C 0.2 MG/M3
0.02 PPM
CAL PEL PEL 0.051 MG/M3
0.005 PPM
1,1,1,2-TETRAFLUOROETHANE US WEEL TWA 1,000 PPM
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION MAY BE
NECESSARY FOR SOME OPERATIONS. PROVIDE GENERAL AND/OR LOCAL EXHAUST
VENTILATION TO CONTROL AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
EXHAUST SYSTEMS SHOULD BE DESIGNED TO MOVE THE AIR AWAY FROM THE SOURCE
OF VAPOR/AEROSOL GENERATION AND PEOPLE WORKING AT THIS POINT. THE ODOR AND
IRRITANCY OF THIS MATERIAL ARE INADEQUATE TO WARN OF EXCESSIVE EXPOSURE.
LETHAL CONCENTRATIONS MAY EXIST IN AREAS WITH POOR VENTILATION.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION: USE CHEMICAL GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL. EXAMPLES OF PREFERRED
GLOVE BARRIER MATERIALS INCLUDE: BUTYL RUBBER. POLYETHYLENE. CHLORINATED
POLYETHYLENE. ETHYL VINYL ALCOHOL LAMINATE ("EVAL"). EXAMPLES OF ACCEPTABLE
GLOVE BARRIER MATERIALS INCLUDE: VITON. NEOPRENE. POLYVINYL CHLORIDE ("PVC"
OR "VINYL"). NITRILE/BUTADIENE RUBBER ("NITRILE" OR "NBR"). NOTICE: THE
SELECTION OF A SPECIFIC GLOVE FOR A PARTICULAR APPLICATION AND DURATION OF
USE IN A WORKPLACE SHOULD ALSO TAKE INTO ACCOUNT ALL RELEVANT WORKPLACE
FACTORS SUCH AS, BUT NOT LIMITED TO: OTHER CHEMICALS WHICH MAY BE HANDLED,
PHYSICAL REQUIREMENTS (CUT/PUNCTURE PROTECTION, DEXTERITY, THERMAL
PROTECTION), POTENTIAL BODY REACTIONS TO GLOVE MATERIALS, AS WELL AS THE
INSTRUCTIONS/SPECIFICATIONS PROVIDED BY THE GLOVE SUPPLIER.
OTHER PROTECTION:
USE PROTECTIVE CLOTHING CHEMICALLY RESISTANT TO THIS MATERIAL. SELECTION
OF SPECIFIC ITEMS SUCH AS FACE SHIELD, BOOTS, APRON, OR FULL BODY SUIT
WILL DEPEND ON THE TASK.
RESPIRATORY PROTECTION:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE.
WHEN ATMOSPHERIC LEVELS MAY EXCEED THE EXPOSURE GUIDELINE, USE AN
APPROVED AIRPURIFYING RESPIRATOR EQUIPPED WITH AN ORGANIC VAPOR
SORBENT AND A PARTICLE FILTER. FOR SITUATIONS WHERE THE ATMOSPHERIC
LEVELS MAY EXCEED THE LEVEL FOR WHICH AN AIR-PURIFYING RESPIRATOR IS
EFFECTIVE, USE A POSITIVE-PRESSURE AIR-SUPPLYING RESPIRATOR (AIR LINE
OR SELF-CONTAINED BREATHING APPARATUS). FOR EMERGENCY RESPONSE OR FOR
SITUATIONS WHERE THE ATMOSPHERIC LEVEL IS UNKNOWN, USE AN APPROVED
POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS OR POSITIVEPRESSURE
AIR LINE WITH AUXILIARY SELF-CONTAINED AIR SUPPLY. IN CONFINED OR POORLY
VENTILATED AREAS, USE AN APPROVED SELF-CONTAINED BREATHING APPARATUS OR
POSITIVE PRESSURE AIR LINE WITH AUXILIARY SELF-CONTAINED AIR SUPPLY.
THE FOLLOWING SHOULD BE EFFECTIVE TYPES OF AIR-PURIFYING RESPIRATORS:
ORGANIC VAPOR CARTRIDGE WITH A PARTICULATE PRE-FILTER.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUEFIED GAS
COLOR: BROWN
ODOR: MUSTY
ODOR THRESHOLD: NO TEST DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/RANGE: NO TEST DATA AVAILABLE
FREEZING POINT: NO TEST DATA AVAILABLE
BOILING POINT (760 MMHg): NO TEST DATA AVAILABLE
FLASH POINT:
CLOSED CUP: GAS
EVAPORATION RATE (BUTYL ACETATE = 1): NO TEST DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
LOWER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
VAPOR PRESSURE:
1,551.3 KPA AT 54 DEG. C (129 DEG. F) CONTAINER IS UNDER PRESSURE.
RELATIVE VAPOR DENSITY (AIR = 1): NO TEST DATA AVAILABLE
RELATIVE DENSITY (WATER = 1):
1.24 AT 25 DEG. C (77 DEG. F) / 25 DEG. C ESTIMATED.
WATER SOLUBILITY: INSOLUBLE, REACTS, EVOLUTION OF CO2
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO TEST DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO TEST DATA AVAILABLE
KINEMATIC VISCOSITY: NO TEST DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES: NO
MOLECULAR WEIGHT: NO TEST DATA AVAILABLE
NOTE:
THE PHYSICAL DATA PRESENTED ABOVE ARE TYPICAL VALUES AND SHOULD NOT BE
CONSTRUED AS A SPECIFICATION.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS. SEE STORAGE, SECTION 7.
POSSIBILITY OF HAZARDOUS REACTIONS:
CAN OCCUR. ELEVATED TEMPERATURES CAN CAUSE HAZARDOUS POLYMERIZATION.
POLYMERIZATION CAN BE CATALYZED BY: STRONG BASES. WATER.
CONDITIONS TO AVOID:
EXPOSURE TO ELEVATED TEMPERATURES CAN CAUSE PRODUCT TO DECOMPOSE. ELEVATED
TEMPERATURES CAN CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS DUE TO THE
RELEASE OF BLOWING AGENTS. GENERATION OF GAS DURING DECOMPOSITION CAN CAUSE
PRESSURE IN CLOSED SYSTEMS. PRESSURE BUILD-UP CAN BE RAPID. AVOID MOISTURE.
MATERIAL REACTS SLOWLY WITH WATER, RELEASING CARBON DIOXIDE WHICH CAN CAUSE
PRESSURE BUILDUP AND RUPTURE OF CLOSED CONTAINERS. ELEVATED TEMPERATURES
ACCELERATE THIS REACTION.
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH:
ACIDS. ALCOHOLS. AMINES. WATER. AMMONIA. BASES. METAL COMPOUNDS. MOIST AIR.
STRONG OXIDIZERS. DIISOCYANATES REACT WITH MANY MATERIALS AND THE RATE OF
REACTION INCREASES WITH TEMPERATURE AS WELL AS INCREASED CONTACT; THESE
REACTIONS CAN BECOME VIOLENT. CONTACT IS INCREASED BY STIRRING OR IF THE
OTHER MATERIAL MIXES WITH THE DIISOCYANATE. DIISOCYANATES ARE NOT SOLUBLE
IN WATER AND SINK TO THE BOTTOM, BUT REACT SLOWLY AT THE INTERFACE. THE
REACTION FORMS CARBON DIOXIDE GAS AND A LAYER OF SOLID POLYUREA. REACTION
WITH WATER WILL GENERATE CARBON DIOXIDE AND HEAT. AVOID CONTACT WITH METALS
SUCH AS: ALUMINUM. ZINC. BRASS. TIN. COPPER. GALVANIZED METALS. AVOID
CONTACT WITH ABSORBENT MATERIALS SUCH AS: MOIST ORGANIC ABSORBENTS. AVOID
UNINTENDED CONTACT WITH POLYOLS. THE REACTION OF POLYOLS AND ISOCYANATES
GENERATE HEAT.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS DEPEND UPON TEMPERATURE, AIR SUPPLY AND THE PRESENCE
OF OTHER MATERIALS. GASES ARE RELEASED DURING DECOMPOSITION.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
ACUTE TOXICITY:
ACUTE ORAL TOXICITY:
LOW TOXICITY IF SWALLOWED. SMALL AMOUNTS SWALLOWED INCIDENTALLY AS A
RESULT OF NORMAL HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY;
HOWEVER, SWALLOWING LARGER AMOUNTS MAY CAUSE INJURY. OBSERVATIONS IN
ANIMALS INCLUDE: GASTROINTESTINAL IRRITATION.
AS PRODUCT:
SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
LD50, RAT, >2,000 MG/KG ESTIMATED.
ACUTE DERMAL TOXICITY:
PROLONGED SKIN CONTACT IS UNLIKELY TO RESULT IN ABSORPTION OF HARMFUL
AMOUNTS.
AS PRODUCT:
THE DERMAL LD50 HAS NOT BEEN DETERMINED.
LD50, RABBIT, >2,000 MG/KG ESTIMATED.
ACUTE INHALATION TOXICITY:
IN CONFINED OR POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE AND CAN
CAUSE UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN. EXCESSIVE
EXPOSURE MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT (NOSE AND THROAT)
AND LUNGS. MAY CAUSE PULMONARY EDEMA (FLUID IN THE LUNGS.) EFFECTS MAY BE
DELAYED. DECREASED LUNG FUNCTION HAS BEEN ASSOCIATED WITH OVEREXPOSURE TO
ISOCYANATES. EXCESSIVE EXPOSURE MAY INCREASE SENSITIVITY TO EPINEPHRINE
AND INCREASE MYOCARDIAL IRRITABILITY (IRREGULAR HEARTBEATS). MAY CAUSE
CENTRAL NERVOUS SYSTEM EFFECTS. SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE
ANESTHETIC OR NARCOTIC EFFECTS; DIZZINESS AND DROWSINESS MAY BE OBSERVED.
AS PRODUCT: THE LC50 HAS NOT BEEN DETERMINED.
SKIN CORROSION/IRRITATION:
PROLONGED CONTACT MAY CAUSE SKIN IRRITATION WITH LOCAL REDNESS.
MAY STAIN SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE MODERATE EYE IRRITATION.
MAY CAUSE SLIGHT TEMPORARY CORNEAL INJURY.
SENSITIZATION:
SKIN CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION.
ANIMAL STUDIES HAVE SHOWN THAT SKIN CONTACT WITH ISOCYANATES MAY PLAY A
ROLE IN RESPIRATORY SENSITIZATION.
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
MDI CONCENTRATIONS BELOW THE EXPOSURE GUIDELINES MAY CAUSE ALLERGIC
RESPIRATORY REACTIONS IN INDIVIDUALS ALREADY SENSITIZED.
ASTHMA-LIKE SYMPTOMS MAY INCLUDE COUGHING, DIFFICULT BREATHING AND A
FEELING OF TIGHTNESS IN THE CHEST. OCCASIONALLY, BREATHING DIFFICULTIES
MAY BE LIFE THREATENING.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ROUTE OF EXPOSURE: INHALATION
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
TISSUE INJURY IN THE UPPER RESPIRATORY TRACT AND LUNGS HAS BEEN OBSERVED
IN LABORATORY ANIMALS AFTER REPEATED EXCESSIVE EXPOSURES TO MDI/POLYMERIC
MDI AEROSOLS.
CARCINOGENICITY:
LUNG TUMORS HAVE BEEN OBSERVED IN LABORATORY ANIMALS EXPOSED TO RESPIRABLE
AEROSOL DROPLETS OF MDI/POLYMERIC MDI (6 MG/M3) FOR THEIR LIFETIME. TUMORS
OCCURRED CONCURRENTLY WITH RESPIRATORY IRRITATION AND LUNG INJURY. CURRENT
EXPOSURE GUIDELINES ARE EXPECTED TO PROTECT AGAINST THESE EFFECTS REPORTED
FOR MDI.
TERATOGENICITY:
IN LABORATORY ANIMALS, MDI/POLYMERIC MDI DID NOT CAUSE BIRTH DEFECTS; OTHER
FETAL EFFECTS OCCURRED ONLY AT HIGH DOSES WHICH WERE TOXIC TO THE MOTHER.
CONTAINS COMPONENT(S) WHICH DID NOT CAUSE BIRTH DEFECTS IN ANIMALS; OTHER
FETAL EFFECTS OCCURRED ONLY AT DOSES TOXIC TO THE MOTHER.
REPRODUCTIVE TOXICITY: NO RELEVANT DATA FOUND.
MUTAGENICITY:
GENETIC TOXICITY DATA ON MDI ARE INCONCLUSIVE. MDI WAS WEAKLY POSITIVE IN
SOME IN VITRO STUDIES; OTHER IN VITRO STUDIES WERE NEGATIVE. ANIMAL
MUTAGENICITY STUDIES WERE PREDOMINANTLY NEGATIVE.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
COMPONENTS INFLUENCING TOXICOLOGY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
ACUTE INHALATION TOXICITY: LC50, RAT, 4 HOUR, DUST/MIST, 0.49 MG/L
FOR SIMILAR MATERIAL(S):
2,4'-DIPHENYLMETHANE DIISOCYANATE (CAS 5873-54-1). LC50, RAT, 4 HOUR,
AEROSOL, 0.31 MG/L
FOR SIMILAR MATERIAL(S):
4,4'-METHYLENEDIPHENYL DIISOCYANATE (CAS 101-68-8). LC50, RAT, 1 HOUR,
AEROSOL, 2.24 MG/L
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
ACUTE INHALATION TOXICITY: LC50, RAT, 1 HOUR, DUST/MIST, 2.24 MG/L
1,1,1,2-TETRAFLUOROETHANE:
ACUTE INHALATION TOXICITY: LC50, RAT, 4 HOUR, VAPOUR, >1,500 MG/L
MDI BASED URETHANE POLYMER P83-1015:
ACUTE INHALATION TOXICITY: THE LC50 HAS NOT BEEN DETERMINED.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
TOXICITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY UNDER
CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR, GROWTH
RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES., >100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL: 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY UNDER
CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR, GROWTH
RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES., >100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL: 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
1,1,1,2-TETRAFLUOROETHANE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), SEMI-STATIC TEST, 96 HOUR,
450 MG/L
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, 980 MG/L
TOXICITY TO BACTERIA:
EC50, PSEUDOMONAS PUTIDA, STATIC TEST, 6 HOUR, GROWTH INHIBITION, >730 MG/L
MDI BASED URETHANE POLYMER P83-1015:
ACUTE TOXICITY TO FISH:
NOT EXPECTED TO BE ACUTELY TOXIC TO AQUATIC ORGANISMS.
PERSISTENCE AND DEGRADABILITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH WATER
FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE STABLE. IN THE
ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE A SHORT TROPOSPHERIC
HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY WITH RELATED DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH WATER
FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE STABLE. IN
THE ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE A SHORT
TROPOSPHERIC HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY WITH RELATED
DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
1,1,1,2-TETRAFLUOROETHANE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT). FAILS
TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 4 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301D OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 0.47 MG/MG
PHOTODEGRADATION
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 1,700 D
METHOD: ESTIMATED.
MDI BASED URETHANE POLYMER P83-1015:
BIODEGRADABILITY:
SURFACE PHOTODEGRADATION IS EXPECTED WITH EXPOSURE TO SUNLIGHT.
NO APPRECIABLE BIODEGRADATION IS EXPECTED.
BIOACCUMULATIVE POTENTIAL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS WITH
WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED
TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS WITH
WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED
TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
1,1,1,2-TETRAFLUOROETHANE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 1.68 ESTIMATED.
MDI BASED URETHANE POLYMER P83-1015:
BIOACCUMULATION:
NO BIOCONCENTRATION IS EXPECTED BECAUSE OF THE RELATIVELY HIGH MOLECULAR
WEIGHT (MW GREATER THAN 1000).
MOBILITY IN SOIL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
1,1,1,2-TETRAFLUOROETHANE:
POTENTIAL FOR MOBILITY IN SOIL IS HIGH (KOC BETWEEN 50 AND 150).
PARTITION COEFFICIENT (KOC): 97 ESTIMATED.
MDI BASED URETHANE POLYMER P83-1015: NO RELEVANT DATA FOUND.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
ALL DISPOSAL PRACTICES MUST BE IN COMPLIANCE WITH ALL FEDERAL, STATE/
PROVINCIAL AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY IN
DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH
APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR.
AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED
IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: COMPOSITION
INFORMATION. FOR UNUSED & UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS
INCLUDE SENDING TO A LICENSED, PERMITTED: RECYCLER. RECLAIMER. INCINERATOR
OR OTHER THERMAL DESTRUCTION DEVICE. FOR ADDITIONAL INFORMATION, REFER TO:
HANDLING & STORAGE INFORMATION, MSDS SECTION 7 STABILITY & REACTIVITY
INFORMATION, MSDS SECTION10 REGULATORY INFORMATION, MSDS SECTION 15
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP
REPORTABLE QUANTITY: MDI
CLASSIFICATION FOR SEA TRANSPORT (IMO-IMDG):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX I OR II OF MARPOL 73/78 AND THE IBC
OR IGC CODE: CONSULT IMO REGULATIONS BEFORE TRANSPORTING OCEAN BULK
CLASSIFICATION FOR AIR TRANSPORT (IATA/ICAO):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
THIS INFORMATION IS NOT INTENDED TO CONVEY ALL SPECIFIC REGULATORY
OR OPERATIONAL REQUIREMENTS/INFORMATION RELATING TO THIS PRODUCT.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND MAY BE
INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS. ADDITIONAL
TRANSPORTATION SYSTEM INFORMATION CAN BE OBTAINED THROUGH AN AUTHORIZED
SALES OR CUSTOMER SERVICE REPRESENTATIVE. IT IS THE RESPONSIBILITY OF THE
TRANSPORTING ORGANIZATION TO FOLLOW ALL APPLICABLE LAWS, REGULATIONS AND
RULES RELATING TO THE TRANSPORTATION OF THE MATERIAL.
| 15. REGULATORY INFORMATION | |
OSHA HAZARD COMMUNICATION STANDARD:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTIONS 311 AND 312:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SUDDEN RELEASE OF PRESSURE HAZARD
REACTIVITY HAZARD
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND WHICH ARE LISTED IN 40 CFR
372.
COMPONENTS CASRN
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES 9016-87-9
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8
PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
TO THE BEST OF OUR KNOWLEDGE, THIS PRODUCT DOES NOT CONTAIN CHEMICALS AT
LEVELS WHICH REQUIRE REPORTING UNDER THIS STATUTE.
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT
OF 1986):
THIS PRODUCT CONTAINS NO LISTED SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM, AT LEVELS WHICH
WOULD REQUIRE A WARNING UNDER THE STATUTE.
UNITED STATES TSCA INVENTORY (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY LISTING
REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL
SUBSTANCE INVENTORY.
| 16. OTHER INFORMATION | |
REVISION:
IDENTIFICATION NUMBER: 102984406 / A001
ISSUE DATE: 04/26/2016
VERSION: 1.0
MOST RECENT REVISION(S) ARE NOTED BY THE BOLD, DOUBLE BARS IN LEFT-HAND
MARGIN THROUGHOUT THIS DOCUMENT.
LEGEND:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
C: CEILING
CAL PEL:
CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
DOW IHG: DOW INDUSTRIAL HYGIENE GUIDELINE
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
PEL: PERMISSIBLE EXPOSURE LIMIT
STEL: SHORT TERM EXPOSURE LIMIT
TWA: TIME WEIGHTED AVERAGE
US WEEL: USA. WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS (WEEL)
INFORMATION SOURCE AND REFERENCES:
THIS SDS IS PREPARED BY PRODUCT REGULATORY SERVICES AND HAZARD
COMMUNICATIONS GROUPS FROM INFORMATION SUPPLIED BY INTERNAL REFERENCES
WITHIN OUR COMPANY.
THE DOW CHEMICAL COMPANY URGES EACH CUSTOMER OR RECIPIENT OF THIS (M)SDS
TO STUDY IT CAREFULLY AND CONSULT APPROPRIATE EXPERTISE, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
(M)SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THE INFORMATION HEREIN
IS PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS. IT IS THE BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED.
SINCE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF THE
MANUFACTURER, IT IS THE BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS
NECESSARY FOR THE SAFE USE OF THIS PRODUCT. DUE TO THE PROLIFERATION OF
SOURCES FOR INFORMATION SUCH AS MANUFACTURERSPECIFIC (M)SDSS, WE ARE NOT
AND CANNOT BE RESPONSIBLE FOR (M)SDSS OBTAINED FROM ANY SOURCE OTHER THAN
OURSELVES. IF YOU HAVE OBTAINED AN (M)SDS FROM ANOTHER SOURCE OR IF YOU
ARE NOT SURE THAT THE (M)SDS YOU HAVE IS CURRENT, PLEASE CONTACT US FOR
THE MOST CURRENT VERSION.
(R*) (TM) TRADEMARK OF THE DOW CHEMICAL COMPANY ("DOW") OR AN AFFILIATED
COMPANY OF DOW
DOW(R*)
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
PRODUCT NAME: FROTH-PAK(TM) POLYOL INT 1.75 HFC BLEND
ISSUE DATE: 05/24/2016
PRINT DATE: 11/02/2017
THE DOW CHEMICAL COMPANY ENCOURAGES AND EXPECTS YOU TO READ AND UNDERSTAND
THE ENTIRE (M)SDS, AS THERE IS IMPORTANT INFORMATION THROUGHOUT THE
DOCUMENT. WE EXPECT YOU TO FOLLOW THE PRECAUTIONS IDENTIFIED IN THIS
DOCUMENT UNLESS YOUR USE CONDITIONS WOULD NECESSITATE OTHER APPROPRIATE
METHODS OR ACTIONS.
| 1. IDENTIFICATION | |
PRODUCT NAME: FROTH-PAK(TM) POLYOL INT 1.75 HFC BLEND
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
IDENTIFIED USES:
FOR INDUSTRIAL USE. COMPONENT(S) FOR THE MANUFACTURE OF URETHANE POLYMERS.
WE RECOMMEND THAT YOU USE THIS PRODUCT IN A MANNER CONSISTENT WITH THE
LISTED USE. IF YOUR INTENDED USE IS NOT CONSISTENT WITH THE STATED USE,
PLEASE CONTACT YOUR SALES OR TECHNICAL SERVICE REPRESENTATIVE.
COMPANY IDENTIFICATION:
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
CUSTOMER INFORMATION NUMBER:
800-258-2436
SDSQUESTION@DOW.COM
EMERGENCY TELEPHONE NUMBER:
24-HOUR EMERGENCY CONTACT:
CHEMTREC: +1 800-424-9300
LOCAL EMERGENCY CONTACT: 800-424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
THIS MATERIAL IS HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD 29CFR 1910.1200.
GASES UNDER PRESSURE: LIQUEFIED GAS
REPRODUCTIVE TOXICITY: CATEGORY 2
LABEL ELEMENTS:
HAZARD PICTOGRAMS:
GAS CYLINDER
HEALTH HAZARD
SIGNAL WORD: WARNING!
HAZARDS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
WEAR PROTECTIVE GLOVES/ PROTECTIVE CLOTHING/ EYE PROTECTION/ FACE
PROTECTION.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ ATTENTION.
STORAGE:
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NO DATA AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT IS A MIXTURE.
COMPONENT CASRN CONCENTRATION
1,1,1,2-TETRAFLUOROETHANE 811-97-2 >=10.0 - <=30.0 %
GLYCEROL PROPYLENE OXIDE POLYMER 25791-96-2 >=10.0 - <=30.0 %
POLYESTER POLYOL, AROMATIC NOT AVAILABLE >=10.0 - <=30.0 %
SUCROSE , PROPYLENE OXIDE 9049-71-2 >=10.0 - <=30.0 %
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE 13674-84-5 >=10.0 - <=30.0 %
1,1,1,3,3-PENTAFLUOROPROPANE 460-73-1 >=1.0 - <=10.0 %
TRIETHYL PHOSPHATE 78-40-0 >=1.0 - <=5.0 %
ETHYLENE GLYCOL 107-21-1 >0.1 - <1.0 %
N,N,N',N',N''''-PENTAMETHYLENE 3855-32-1 >=0.1 - <1.0 %
TRIAMINE
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION AND USE THE
RECOMMENDED PROTECTIVE CLOTHING (CHEMICAL RESISTANT GLOVES, SPLASH
PROTECTION). IF POTENTIAL FOR EXPOSURE EXISTS REFER TO SECTION 8 FOR
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT.
INHALATION:
MOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION;
IF BY MOUTH TO MOUTH USE RESCUER PROTECTION (POCKET MASK, ETC). IF
BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. CALL A PHYSICIAN OR TRANSPORT TO A MEDICAL FACILITY.
SKIN CONTACT: WASH OFF WITH PLENTY OF WATER.
EYE CONTACT:
FLUSH EYES THOROUGHLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT
LENSES AFTER THE INITIAL 1-2 MINUTES AND CONTINUE FLUSHING FOR SEVERAL
ADDITIONAL MINUTES. IF EFFECTS OCCUR, CONSULT A PHYSICIAN, PREFERABLY
AN OPHTHALMOLOGIST.
INGESTION:
DO NOT INDUCE VOMITING. CALL A PHYSICIAN AND/OR TRANSPORT TO EMERGENCY
FACILITY IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASIDE FROM THE INFORMATION FOUND UNDER DESCRIPTION OF FIRST AID MEASURES
(ABOVE) AND INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL
TREATMENT NEEDED (BELOW), ANY ADDITIONAL IMPORTANT SYMPTOMS AND EFFECTS
ARE DESCRIBED IN SECTION 11: TOXICOLOGY INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
MAINTAIN ADEQUATE VENTILATION AND OXYGENATION OF THE PATIENT. THIS
MATERIAL IS A CHOLINESTERASE INHIBITOR. TREAT SYMPTOMATICALLY. IN CASE OF
SEVERE ACUTE POISONING, USE ANTIDOTE IMMEDIATELY AFTER ESTABLISHING AN
OPEN AIRWAY AND RESPIRATION. ATROPINE, ONLY BY INJECTION, IS THE
PREFERABLE ANTIDOTE. OXIMES, SUCH AS 2-PAM/PROTOPAM, MAY BE THERAPEUTIC
IF USED EARLY; HOWEVER, USE ONLY IN CONJUNCTION WITH ATROPINE. ATTEMPT
SEIZURE CONTROL WITH DIAZEPAM 5-10 MG (ADULTS) INTRAVENOUS OVER 2-3
MINUTES. REPEAT EVERY 5-10 MINUTES AS NEEDED. MONITOR FOR HYPOTENSION,
RESPIRATORY DEPRESSION, AND NEED FOR INTUBATION. CONSIDER SECOND AGENT
IF SEIZURES PERSIST AFTER 30 MG. IF SEIZURES PERSIST OR RECUR ADMINISTER
PHENOBARBITAL 600-1200 MG (ADULTS) INTRAVENOUS DILUTED IN 60 ML 0.9%
SALINE GIVEN AT 25-50 MG/MINUTE. EVALUATE FOR HYPOXIA, DYSRHYTHMIA,
ELECTROLYTE DISTURBANCE, HYPOGLYCEMIA (TREAT ADULTS WITH DEXTROSE 100 MG
INTRAVENOUS). IF EXPOSED, PLASMA AND RED BLOOD CELL CHOLINESTERASE TESTS
MAY INDICATE SIGNIFICANCE OF EXPOSURE (BASELINE DATA ARE USEFUL).
EXPOSURE MAY INCREASE "MYOCARDIAL IRRITABILITY". DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS SUCH AS EPINEPHRINE UNLESS ABSOLUTELY NECESSARY.
TREATMENT OF EXPOSURE SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND
THE CLINICAL CONDITION OF THE PATIENT.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG OR FINE SPRAY. DRY CHEMICAL FIRE EXTINGUISHERS. CARBON DIOXIDE
FIRE EXTINGUISHERS. FOAM. ALCOHOL RESISTANT FOAMS (ATC TYPE) ARE
PREFERRED. GENERAL PURPOSE SYNTHETIC FOAMS (INCLUDING AFFF) OR PROTEIN
FOAMS MAY FUNCTION, BUT WILL BE LESS EFFECTIVE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE DIRECT WATER STREAM. MAY SPREAD FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS COMBUSTION PRODUCTS:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR
IRRITATING.
COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
CARBON MONOXIDE. CARBON DIOXIDE. HYDROGEN HALIDES.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINER MAY RUPTURE FROM GAS GENERATION IN A FIRE SITUATION. BLOWING
AGENT VAPORIZES QUICKLY AT ROOM TEMPERATURE. VIOLENT STEAM GENERATION
OR ERUPTION MAY OCCUR UPON APPLICATION OF DIRECT WATER STREAM TO HOT
LIQUIDS.
ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
KEEP PEOPLE AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY. USE WATER SPRAY
TO COOL FIRE EXPOSED CONTAINERS AND FIRE AFFECTED ZONE UNTIL FIRE IS OUT
AND DANGER OF REIGNITION HAS PASSED. FIGHT FIRE FROM PROTECTED LOCATION OR
SAFE DISTANCE. CONSIDER THE USE OF UNMANNED HOSE HOLDERS OR MONITOR
NOZZLES. IMMEDIATELY WITHDRAW ALL PERSONNEL FROM THE AREA IN CASE OF
RISING SOUND FROM VENTING SAFETY DEVICE OR DISCOLORATION OF THE CONTAINER.
DO NOT USE DIRECT WATER STREAM. MAY SPREAD FIRE. MOVE CONTAINER FROM FIRE
AREA IF THIS IS POSSIBLE WITHOUT HAZARD. BURNING LIQUIDS MAY BE MOVED BY
FLUSHING WITH WATER TO PROTECT PERSONNEL AND MINIMIZE PROPERTY DAMAGE.
CONTAIN FIRE WATER RUN-OFF IF POSSIBLE. FIRE WATER RUN-OFF, IF NOT
CONTAINED, MAY CAUSE ENVIRONMENTAL DAMAGE. REVIEW THE "ACCIDENTAL RELEASE
MEASURES" AND THE "ECOLOGICAL INFORMATION" SECTIONS OF THIS (M)SDS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT,
TROUSERS, BOOTS, AND GLOVES). AVOID CONTACT WITH THIS MATERIAL DURING FIRE
FIGHTING OPERATIONS. IF CONTACT IS LIKELY, CHANGE TO FULL CHEMICAL
RESISTANT FIRE FIGHTING CLOTHING WITH SELF-CONTAINED BREATHING APPARATUS.
IF THIS IS NOT AVAILABLE, WEAR FULL CHEMICAL RESISTANT CLOTHING WITH
SELF-CONTAINED BREATHING APPARATUS AND FIGHT FIRE FROM A REMOTE LOCATION.
FOR PROTECTIVE EQUIPMENT IN POST-FIRE OR NON-FIRE CLEAN-UP SITUATIONS,
REFER TO THE RELEVANT SECTIONS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ISOLATE AREA. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING THE
AREA. KEEP PERSONNEL OUT OF CONFINED OR POORLY VENTILATED AREAS. KEEP
UPWIND OF SPILL. SPILLED MATERIAL MAY CAUSE A SLIPPING HAZARD. VENTILATE
AREA OF LEAK OR SPILL. CONFINED SPACE ENTRY PROCEDURES MUST BE FOLLOWED
BEFORE ENTERING THE AREA. REFER TO SECTION 7, HANDLING, FOR ADDITIONAL
PRECAUTIONARY MEASURES. USE APPROPRIATE SAFETY EQUIPMENT. FOR ADDITIONAL
INFORMATION, REFER TO SECTION 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FROM ENTERING INTO SOIL, DITCHES, SEWERS, WATERWAYS AND/OR
GROUNDWATER. SEE SECTION 12, ECOLOGICAL INFORMATION.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLED MATERIAL IF POSSIBLE.
ABSORB WITH MATERIALS SUCH AS:
DIRT. SAND. SAWDUST. ISOLATE AREA UNTIL GAS HAS DISPERSED. APPLY VAPOR
SUPPRESSION FOAMS UNTIL SPILL CAN BE CLEANED UP. KNOCK DOWN AND DILUTE
VAPORS WITH WATER FOG OR SPRAY. COLLECT IN SUITABLE AND PROPERLY LABELED
CONTAINERS. WASH THE SPILL SITE WITH WATER. SEE SECTION 13, DISPOSAL
CONSIDERATIONS, FOR ADDITIONAL INFORMATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING
VAPOR. USE WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED. SPILLS OF
THESE ORGANIC MATERIALS ON HOT FIBROUS INSULATIONS MAY LEAD TO LOWERING
OF THE AUTOIGNITION TEMPERATURES POSSIBLY RESULTING IN SPONTANEOUS
COMBUSTION. DO NOT ENTER CONFINED SPACES UNLESS ADEQUATELY VENTILATED.
SEE SECTION 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
SPILLS OF THESE ORGANIC MATERIALS ON HOT FIBROUS INSULATIONS MAY LEAD
TO LOWERING OF THE AUTOIGNITION TEMPERATURES POSSIBLY RESULTING IN
SPONTANEOUS COMBUSTION.
CONDITIONS FOR SAFE STORAGE:
STORE IN A DRY PLACE. AVOID PROLONGED EXPOSURE TO HEAT AND AIR. PROTECT
FROM ATMOSPHERIC MOISTURE. BLOWING AGENT MAY MIGRATE FROM PRODUCT AND
ACCUMULATE IN SOME STORAGE SITUATIONS. ELEVATED TEMPERATURES CAN CAUSE
PRESSURE BUILDUP IN CLOSED CONTAINERS DUE TO THE RELEASE OF BLOWING
AGENTS.
STORE IN THE FOLLOWING MATERIAL(S):
CARBON STEEL. STAINLESS STEEL. POLYPROPYLENE. POLYETHYLENE-LINED
CONTAINER. TEFLON. GLASS-LINED CONTAINER. ALUMINUM. PLASITE 3066 LINED
CONTAINER. PLASITE 3070 LINED CONTAINER. 316 STAINLESS STEEL. SEE SECTION
10 FOR MORE SPECIFIC INFORMATION.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS ARE LISTED BELOW, IF THEY EXIST.
COMPONENT REGULATION TYPE OF LISTING VALUE/NOTATION
1,1,1,2-TETRAFLUOROETHANE US WEEL TWA 1,000 PPM
1,1,1,3,3- US WEEL TWA 300 PPM
PENTAFLUOROPROPANE
TRIETHYL PHOSPHATE US WEEL TWA 7.45 MG/M3
ETHYLENE GLYCOL DOW IHG TWA 50 MG/M3
DOW IHG STEL 100 MG/M3
ACGIH C AEROSOL ONLY 100 MG/M3
CAL PEL C VAPOUR 100 MG/M3 40 PPM
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVEL BELOW EXPOSURE LIMIT
REQUIREMENTS OR GUIDELINES. IF THERE ARE NO APPLICABLE EXPOSURE LIMIT
REQUIREMENTS OR GUIDELINES, USE ONLY IN ENCLOSED SYSTEMS OR WITH LOCAL
EXHAUST VENTILATION. EXHAUST SYSTEMS SHOULD BE DESIGNED TO MOVE THE AIR
AWAY FROM THE SOURCE OF VAPOR/AEROSOL GENERATION AND PEOPLE WORKING AT
THIS POINT. LETHAL CONCENTRATIONS MAY EXIST IN AREAS WITH POOR
VENTILATION.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION: USE SAFETY GLASSES (WITH SIDE SHIELDS).
SKIN PROTECTION:
HAND PROTECTION:
USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL WHEN PROLONGED OR
FREQUENTLY REPEATED CONTACT COULD OCCUR.
EXAMPLES OF PREFERRED GLOVE BARRIER MATERIALS INCLUDE:
CHLORINATED POLYETHYLENE. POLYETHYLENE. ETHYL VINYL ALCOHOL LAMINATE
("EVAL"). POLYVINYL ALCOHOL ("PVA"). STYRENE/BUTADIENE RUBBER. VITON.
EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE:
BUTYL RUBBER. NATURAL RUBBER ("LATEX"). POLYVINYL CHLORIDE ("PVC" OR
"VINYL").
NOTICE:
THE SELECTION OF A SPECIFIC GLOVE FOR A PARTICULAR APPLICATION AND
DURATION OF USE IN A WORKPLACE SHOULD ALSO TAKE INTO ACCOUNT ALL RELEVANT
WORKPLACE FACTORS SUCH AS, BUT NOT LIMITED TO: OTHER CHEMICALS WHICH MAY
BE HANDLED, PHYSICAL REQUIREMENTS (CUT/PUNCTURE PROTECTION, DEXTERITY,
THERMAL PROTECTION), POTENTIAL BODY REACTIONS TO GLOVE MATERIALS, AS WELL
AS THE INSTRUCTIONS/SPECIFICATIONS PROVIDED BY THE GLOVE SUPPLIER.
OTHER PROTECTION: WEAR CLEAN, BODY-COVERING CLOTHING.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION SHOULD BE WORN WHEN THERE IS A POTENTIAL TO EXCEED
THE EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES. IF THERE ARE NO APPLICABLE
EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES, USE AN APPROVED RESPIRATOR.
WHEN RESPIRATORY PROTECTION IS REQUIRED, USE AN APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS OR POSITIVE-PRESSURE AIRLINE WITH
AUXILIARY SELF-CONTAINED AIR SUPPLY. FOR EMERGENCY CONDITIONS, USE AN
APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CONFINED
OR POORLY VENTILATED AREAS, USE AN APPROVED SELF-CONTAINED BREATHING
APPARATUS OR POSITIVE PRESSURE AIR LINE WITH AUXILIARY SELF-CONTAINED AIR
SUPPLY.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUEFIED GAS
COLOR: YELLOW
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO TEST DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/RANGE: NO TEST DATA AVAILABLE
FREEZING POINT: NO TEST DATA AVAILABLE
BOILING POINT (760 MMHg): NO TEST DATA AVAILABLE
FLASH POINT: >100 DEG. C (>212 DEG. F) ESTIMATED.
EVAPORATION RATE (BUTYL ACETATE = 1): NO TEST DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
LOWER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
VAPOR PRESSURE: NOT APPLICABLE
RELATIVE VAPOR DENSITY (AIR = 1): NO TEST DATA AVAILABLE
RELATIVE DENSITY (WATER = 1): 1.18 CALCULATED.
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO TEST DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO TEST DATA AVAILABLE
KINEMATIC VISCOSITY: 2240 CST ASTM D4878
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES: NO
MOLECULAR WEIGHT: NO DATA AVAILABLE
NOTE:
THE PHYSICAL DATA PRESENTED ABOVE ARE TYPICAL VALUES AND SHOULD NOT BE
CONSTRUED AS A SPECIFICATION.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS. SEE STORAGE, SECTION 7.
POSSIBILITY OF HAZARDOUS REACTIONS: WILL NOT OCCUR BY ITSELF.
CONDITIONS TO AVOID:
PRODUCT CAN OXIDIZE AT ELEVATED TEMPERATURES. ELEVATED TEMPERATURES CAN
CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS DUE TO THE RELEASE OF BLOWING
AGENTS. GENERATION OF GAS DURING DECOMPOSITION CAN CAUSE PRESSURE IN
CLOSED SYSTEMS.
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH OXIDIZING MATERIALS. AVOID CONTACT WITH: STRONG ACIDS.
STRONG BASES. AVOID UNINTENDED CONTACT WITH ISOCYANATES. THE REACTION OF
POLYOLS AND ISOCYANATES GENERATES HEAT.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS DEPEND UPON TEMPERATURE, AIR SUPPLY AND THE
PRESENCE OF OTHER MATERIALS.
DECOMPOSITION PRODUCTS CAN INCLUDE AND ARE NOT LIMITED TO:
CARBON DIOXIDE. ALCOHOLS. ETHERS. HYDROCARBONS. HYDROGEN HALIDES. KETONES.
POLYMER FRAGMENTS.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
ACUTE TOXICITY:
ACUTE ORAL TOXICITY:
LOW TOXICITY IF SWALLOWED. SMALL AMOUNTS SWALLOWED INCIDENTALLY AS A
RESULT OF NORMAL HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY;
HOWEVER, SWALLOWING LARGER AMOUNTS MAY CAUSE INJURY.
SIGNS AND SYMPTOMS OF EXCESSIVE EXPOSURE MAY INCLUDE:
MAY CAUSE LACRIMATION (TEARS). SALIVATION. CONVULSIONS. TREMORS.
INCREASED ACTIVITY (HYPERACTIVITY).
AS PRODUCT: SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
LD50, RAT, >2,000 MG/KG ESTIMATED.
ACUTE DERMAL TOXICITY:
PROLONGED SKIN CONTACT IS UNLIKELY TO RESULT IN ABSORPTION OF HARMFUL
AMOUNTS.
AS PRODUCT: THE DERMAL LD50 HAS NOT BEEN DETERMINED.
LD50, RABBIT, >2,000 MG/KG ESTIMATED.
ACUTE INHALATION TOXICITY:
PROLONGED EXCESSIVE EXPOSURE MAY CAUSE ADVERSE EFFECTS. IN CONFINED OR
POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE AND CAN CAUSE
UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN. MAY CAUSE
RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM DEPRESSION. EXCESSIVE
EXPOSURE MAY INCREASE SENSITIVITY TO EPINEPHRINE AND INCREASE MYOCARDIAL
IRRITABILITY (IRREGULAR HEARTBEATS). SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE
ANESTHETIC OR NARCOTIC EFFECTS; DIZZINESS AND DROWSINESS MAY BE OBSERVED.
AS PRODUCT: THE LC50 HAS NOT BEEN DETERMINED.
SKIN CORROSION/IRRITATION:
PROLONGED CONTACT MAY CAUSE SLIGHT SKIN IRRITATION WITH LOCAL REDNESS.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE SLIGHT EYE IRRITATION.
MAY CAUSE SLIGHT TEMPORARY CORNEAL INJURY.
SENSITIZATION:
FOR SKIN SENSITIZATION: NO RELEVANT DATA FOUND.
FOR RESPIRATORY SENSITIZATION: NO RELEVANT DATA FOUND.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
EVALUATION OF AVAILABLE DATA SUGGESTS THAT THIS MATERIAL IS NOT AN STOT-SE
TOXICANT.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
CONTAINS A COMPONENT WHICH IS REPORTED TO BE A WEAK ORGANOPHOSPHATE-TYPE
CHOLINESTERASE INHIBITOR.
CONTAINS COMPONENT(S) WHICH HAVE BEEN REPORTED TO CAUSE EFFECTS ON THE
FOLLOWING ORGANS IN ANIMALS:
HEART.
LIVER.
CARCINOGENICITY: NO RELEVANT DATA FOUND.
TERATOGENICITY:
CONTAINS COMPONENT(S) WHICH, IN LABORATORY ANIMALS, HAVE BEEN TOXIC TO THE
FETUS AT DOSES NONTOXIC TO THE MOTHER. CONTAINS COMPONENT(S) WHICH, IN
LABORATORY ANIMALS, HAVE BEEN TOXIC TO THE FETUS ONLY AT DOSES TOXIC TO
THE MOTHER.
REPRODUCTIVE TOXICITY:
IN ANIMAL STUDIES ON COMPONENT(S), EFFECTS ON REPRODUCTION WERE SEEN ONLY
AT DOSES THAT PRODUCED SIGNIFICANT TOXICITY TO THE PARENT ANIMALS.
MUTAGENICITY:
GENETIC TOXICITY STUDIES ON TESTED COMPONENTS WERE PREDOMINANTLY NEGATIVE.
CONTAINS COMPONENT(S) WHICH WERE NEGATIVE IN SOME ANIMAL GENETIC TOXICITY
STUDIES AND POSITIVE IN OTHERS.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
COMPONENTS INFLUENCING TOXICOLOGY:
1,1,1,2-TETRAFLUOROETHANE:
ACUTE INHALATION TOXICITY:
LC50, RAT, 4 HOUR, VAPOUR, >1,500 MG/L
GLYCEROL PROPYLENE OXIDE POLYMER:
ACUTE INHALATION TOXICITY:
AT ROOM TEMPERATURE, EXPOSURE TO VAPOR IS MINIMAL DUE TO LOW VOLATILITY;
SINGLE EXPOSURE IS NOT LIKELY TO BE HAZARDOUS. VAPOR FROM HEATED MATERIAL
OR MIST MAY CAUSE RESPIRATORY IRRITATION.
THE LC50 HAS NOT BEEN DETERMINED.
POLYESTER POLYOL, AROMATIC:
ACUTE INHALATION TOXICITY: THE LC50 HAS NOT BEEN DETERMINED.
SUCROSE , PROPYLENE OXIDE:
ACUTE INHALATION TOXICITY:
AT ROOM TEMPERATURE, EXPOSURE TO VAPOR IS MINIMAL DUE TO LOW VOLATILITY;
SINGLE EXPOSURE IS NOT LIKELY TO BE HAZARDOUS. VAPOR FROM HEATED MATERIAL
OR MIST MAY CAUSE RESPIRATORY IRRITATION.
TYPICAL FOR THIS FAMILY OF MATERIALS. NO DEATHS OCCURRED FOLLOWING
EXPOSURE TO A SATURATED ATMOSPHERE.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
ACUTE INHALATION TOXICITY:
NO DEATHS OCCURRED AT THIS CONCENTRATION. LC50, RAT, 4 HOUR, DUST/MIST,
>7 MG/L
1,1,1,3,3-PENTAFLUOROPROPANE:
ACUTE INHALATION TOXICITY:
PROLONGED EXCESSIVE EXPOSURE MAY CAUSE ADVERSE EFFECTS. IN CONFINED OR
POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE AND CAN CAUSE
UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN. MAY CAUSE
RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM DEPRESSION. SYMPTOMS
MAY INCLUDE HEADACHE, DIZZINESS AND DROWSINESS, PROGRESSING TO
INCOORDINATION AND UNCONSCIOUSNESS. SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE
ANESTHETIC OR NARCOTIC EFFECTS; DIZZINESS AND DROWSINESS MAY BE OBSERVED.
EXCESSIVE EXPOSURE MAY INCREASE SENSITIVITY TO EPINEPHRINE AND INCREASE
MYOCARDIAL IRRITABILITY (IRREGULAR HEARTBEATS).
LC50, RAT, 4 HOUR, VAPOUR, 1,096 MG/L
TRIETHYL PHOSPHATE:
ACUTE INHALATION TOXICITY:
LC50, RAT, 4 HOUR, DUST/MIST, >2.35 MG/L NO DEATHS OCCURRED AT THIS
CONCENTRATION.
ETHYLENE GLYCOL:
ACUTE INHALATION TOXICITY:
LC50, RAT, MALE AND FEMALE, 6 HOUR, DUST/MIST, >2.5 MG/L
N,N,N',N',N''''-PENTAMETHYLENE TRIAMINE:
ACUTE INHALATION TOXICITY:
LC50, RAT, 1 HOUR, VAPOUR, >1.48 MG/L NO DEATHS OCCURRED AT THIS
CONCENTRATION.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
TOXICITY:
1,1,1,2-TETRAFLUOROETHANE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), SEMI-STATIC TEST, 96 HOUR,
450 MG/L
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, 980 MG/L
TOXICITY TO BACTERIA:
EC50, PSEUDOMONAS PUTIDA, STATIC TEST, 6 HOUR, GROWTH INHIBITION,
>730 MG/L
GLYCEROL PROPYLENE OXIDE POLYMER:
ACUTE TOXICITY TO FISH:
FOR THIS FAMILY OF MATERIALS:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, MORTALITY,
>=10 MG/L
LOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, MORTALITY,
>10 MG/L
POLYESTER POLYOL, AROMATIC:
ACUTE TOXICITY TO FISH: NO RELEVANT DATA FOUND.
SUCROSE , PROPYLENE OXIDE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, 6,310 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, 9,890 MG/L,
OECD TEST GUIDELINE 202 OR EQUIVALENT
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, MORTALITY,
>=10 MG/L
LOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, MORTALITY,
>10 MG/L
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
ACUTE TOXICITY TO FISH:
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH), STATIC TEST, 96 HOUR,
84 MG/L, OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, 131 MG/L
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
ERC50, PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE), STATIC TEST, 96
HOUR, GROWTH RATE INHIBITION, 82 MG/L, OECD TEST GUIDELINE 201 OR
EQUIVALENT
TOXICITY TO BACTERIA:
EC50, ACTIVATED SLUDGE, RESPIRATION INHIBITION, 3 HOUR, 784 MG/L, OECD
209 TEST
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, NUMBER OF
OFFSPRING, 32 MG/L
MATC (MAXIMUM ACCEPTABLE TOXICANT LEVEL), DAPHNIA MAGNA (WATER FLEA),
SEMI-STATIC TEST, 21 D, NUMBER OF OFFSPRING, >32 MG/L
1,1,1,3,3-PENTAFLUOROPROPANE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), SEMI-STATIC TEST, 96 HOUR,
>100 MG/L
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, >100 MG/L
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
ERC50, SELENASTRUM CAPRICORNUTUM (GREEN ALGAE), STATIC TEST, 72 HOUR,
GROWTH RATE, >118 MG/L
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 14 D, MORTALITY,
29 MG/L
TRIETHYL PHOSPHATE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, LEUCISCUS IDUS (GOLDEN ORFE), STATIC TEST, 48 HOUR, 2,140 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, 350 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
EC50, DESMODESMUS SUBSPICATUS (GREEN ALGAE), 72 HOUR, GROWTH RATE
INHIBITION, 900 MG/L, OECD TEST GUIDELINE 201
TOXICITY TO BACTERIA:
EC50, ACTIVATED SLUDGE, RESPIRATION INHIBITION, 30 MIN, >2,985 MG/L,
OECD 209 TEST
ETHYLENE GLYCOL:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, PIMEPHALES PROMELAS (FATHEAD MINNOW), STATIC TEST, 96 HOUR, 72,860
MG/L, OTHER GUIDELINES
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, >100 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
ERC50, PSEUDOKIRCHNERIELLA SUBCAPITA, 96 HOUR, GROWTH RATE INHIBITION,
6,500 - 13,000 MG/L, OTHER GUIDELINES
TOXICITY TO BACTERIA:
EC50, ACTIVATED SLUDGE, 30 MIN, 225 MG/L, OECD 209 TEST
N,N,N',N',N''''-PENTAMETHYLENE TRIAMINE:
ACUTE TOXICITY TO FISH:
MAY INCREASE PH OF AQUATIC SYSTEMS TO >PH 10 WHICH MAY BE TOXIC TO AQUATIC
ORGANISMS.
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
PERSISTENCE AND DEGRADABILITY:
1,1,1,2-TETRAFLUOROETHANE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT). FAILS
TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 4 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301D OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 0.47 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 1,700 D
METHOD: ESTIMATED.
GLYCEROL PROPYLENE OXIDE POLYMER:
BIODEGRADABILITY:
FOR THIS FAMILY OF MATERIALS: BASED ON STRINGENT OECD TEST GUIDELINES,
THIS MATERIAL CANNOT BE CONSIDERED AS READILY BIODEGRADABLE; HOWEVER,
THESE RESULTS DO NOT NECESSARILY MEAN THAT THE MATERIAL IS NOT
BIODEGRADABLE UNDER ENVIRONMENTAL CONDITIONS. MATERIAL IS ULTIMATELY
BIODEGRADABLE (REACHES >70% MINERALIZATION IN OECD TEST(S) FOR INHERENT
BIODEGRADABILITY).
POLYESTER POLYOL, AROMATIC:
BIODEGRADABILITY: NO RELEVANT DATA FOUND.
SUCROSE , PROPYLENE OXIDE:
BIODEGRADABILITY:
BASED ON INFORMATION FOR A SIMILAR MATERIAL: MATERIAL IS INHERENTLY
BIODEGRADABLE (REACHES >20% BIODEGRADATION IN OECD TEST(S) FOR INHERENT
BIODEGRADABILITY).
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT). FAILS
TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 14 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301E OR EQUIVALENT
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 95 %
EXPOSURE TIME: 64 D
METHOD: OECD TEST GUIDELINE 302A OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.17 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 0.24 D
METHOD: ESTIMATED.
1,1,1,3,3-PENTAFLUOROPROPANE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT). FAILS
TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 8 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301D OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 0.60 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 360 D
METHOD: ESTIMATED.
TRIETHYL PHOSPHATE:
BIODEGRADABILITY:
MATERIAL IS ULTIMATELY BIODEGRADABLE (REACHES >70% MINERALIZATION IN OECD
TEST(S) FOR INHERENT BIODEGRADABILITY).
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: >90 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302B OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.58 MG/MG
ETHYLENE GLYCOL:
BIODEGRADABILITY:
MATERIAL IS READILY BIODEGRADABLE. PASSES OECD TEST(S) FOR READY
BIODEGRADABILITY. MATERIAL IS ULTIMATELY BIODEGRADABLE (REACHES >70%
MINERALIZATION IN OECD TEST(S) FOR INHERENT BIODEGRADABILITY).
10-DAY WINDOW: PASS
BIODEGRADATION: 90 - 100 %
EXPOSURE TIME: 10 D
METHOD: OECD TEST GUIDELINE 301A OR EQUIVALENT
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 90 %
EXPOSURE TIME: 1 D
METHOD: OECD TEST GUIDELINE 302B OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.29 MG/MG
N,N,N',N',N''''-PENTAMETHYLENE TRIAMINE:
BIODEGRADABILITY:
BASED ON INFORMATION FOR A SIMILAR MATERIAL: MATERIAL IS EXPECTED TO BE
READILY BIODEGRADABLE.
BIODEGRADATION: >70 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301B OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 3.42 MG/MG
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NO DATA AVAILABLE.
MOBILITY IN SOIL:
1,1,1,2-TETRAFLUOROETHANE:
POTENTIAL FOR MOBILITY IN SOIL IS HIGH (KOC BETWEEN 50 AND 150).
PARTITION COEFFICIENT (KOC): 97 ESTIMATED.
GLYCEROL PROPYLENE OXIDE POLYMER: NO RELEVANT DATA FOUND.
POLYESTER POLYOL, AROMATIC: NO RELEVANT DATA FOUND.
SUCROSE , PROPYLENE OXIDE: NO RELEVANT DATA FOUND.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
POTENTIAL FOR MOBILITY IN SOIL IS SLIGHT (KOC BETWEEN 2000 AND 5000).
PARTITION COEFFICIENT (KOC): 1300 ESTIMATED.
1,1,1,3,3-PENTAFLUOROPROPANE:
POTENTIAL FOR MOBILITY IN SOIL IS MEDIUM (KOC BETWEEN 150 AND 500).
PARTITION COEFFICIENT (KOC): 280 ESTIMATED.
TRIETHYL PHOSPHATE:
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
GIVEN ITS VERY LOW HENRY'S CONSTANT, VOLATILIZATION FROM NATURAL BODIES
OF WATER OR MOIST SOIL IS NOT EXPECTED TO BE AN IMPORTANT FATE PROCESS.
PARTITION COEFFICIENT (KOC): 48 ESTIMATED.
ETHYLENE GLYCOL:
GIVEN ITS VERY LOW HENRY'S CONSTANT, VOLATILIZATION FROM NATURAL BODIES OF
WATER OR MOIST SOIL IS NOT EXPECTED TO BE AN IMPORTANT FATE PROCESS.
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
PARTITION COEFFICIENT (KOC): 1 ESTIMATED.
N,N,N',N',N''''-PENTAMETHYLENE TRIAMINE:
POTENTIAL FOR MOBILITY IN SOIL IS LOW (KOC BETWEEN 500 AND 2000).
PARTITION COEFFICIENT (KOC): 940 ESTIMATED.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. ALL
DISPOSAL PRACTICES MUST BE IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY IN
DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH
APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR. AS
YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: COMPOSITION INFORMATION.
FOR UNUSED & UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS INCLUDE SENDING
TO A LICENSED, PERMITTED:
RECYCLER. RECLAIMER. INCINERATOR OR OTHER THERMAL DESTRUCTION DEVICE.
FOR ADDITIONAL INFORMATION, REFER TO:
HANDLING & STORAGE INFORMATION, MSDS SECTION 7 STABILITY & REACTIVITY
INFORMATION, MSDS SECTION10 REGULATORY INFORMATION, MSDS SECTION 15
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
CLASSIFICATION FOR SEA TRANSPORT (IMO-IMDG):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX I OR II OF MARPOL 73/78 AND THE IBC
OR IGC CODE: CONSULT IMO REGULATIONS BEFORE TRANSPORTING OCEAN BULK
CLASSIFICATION FOR AIR TRANSPORT (IATA/ICAO):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
THIS INFORMATION IS NOT INTENDED TO CONVEY ALL SPECIFIC REGULATORY OR
OPERATIONAL REQUIREMENTS/INFORMATION RELATING TO THIS PRODUCT.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND MAY BE
INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS. ADDITIONAL
TRANSPORTATION SYSTEM INFORMATION CAN BE OBTAINED THROUGH AN AUTHORIZED
SALES OR CUSTOMER SERVICE REPRESENTATIVE. IT IS THE RESPONSIBILITY OF THE
TRANSPORTING ORGANIZATION TO FOLLOW ALL APPLICABLE LAWS, REGULATIONS AND
RULES RELATING TO THE TRANSPORTATION OF THE MATERIAL.
| 15. REGULATORY INFORMATION | |
OSHA HAZARD COMMUNICATION STANDARD:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTIONS 311 AND 312:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SUDDEN RELEASE OF PRESSURE HAZARD
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS
ESTABLISHED BY SARA TITLE III, SECTION 313.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF
1980 (CERCLA) SECTION 103:
CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
COMPONENTS CASRN RQ
ETHYLENE GLYCOL 107-21-1 5000 LBS RQ
PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
THE FOLLOWING CHEMICALS ARE LISTED BECAUSE OF THE ADDITIONAL REQUIREMENTS
OF PENNSYLVANIA LAW:
COMPONENTS CASRN
1,4-DIOXANE 123-91-1
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT
OF 1986):
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
COMPONENTS CASRN
1,4-DIOXANE 123-91-1
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT
OF 1986):
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
COMPONENTS CASRN
ETHYLENE GLYCOL 107-21-1
UNITED STATES TSCA INVENTORY (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY
LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA)
CHEMICAL SUBSTANCE INVENTORY.
| 16. OTHER INFORMATION | |
REVISION:
IDENTIFICATION NUMBER: 102984265 / A001
ISSUE DATE: 05/24/2016
VERSION: 2.0
MOST RECENT REVISION(S) ARE NOTED BY THE BOLD, DOUBLE BARS IN LEFT-HAND
MARGIN THROUGHOUT THIS DOCUMENT.
LEGEND:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
C: CEILING LIMIT
CAL PEL:
CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS (TITLE
8, ARTICLE 107)
DOW IHG: DOW INDUSTRIAL HYGIENE GUIDELINE
STEL: SHORT TERM EXPOSURE LIMIT
TWA: TIME WEIGHTED AVERAGE
US WEEL: USA. WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS (WEEL)
INFORMATION SOURCE AND REFERENCES:
THIS SDS IS PREPARED BY PRODUCT REGULATORY SERVICES AND HAZARD
COMMUNICATIONS GROUPS FROM INFORMATION SUPPLIED BY INTERNAL REFERENCES
WITHIN OUR COMPANY.
THE DOW CHEMICAL COMPANY URGES EACH CUSTOMER OR RECIPIENT OF THIS (M)SDS
TO STUDY IT CAREFULLY AND CONSULT APPROPRIATE EXPERTISE, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
(M)SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THE INFORMATION HEREIN
IS PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS. IT IS THE BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED.
SINCE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF THE
MANUFACTURER, IT IS THE BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS
NECESSARY FOR THE SAFE USE OF THIS PRODUCT. DUE TO THE PROLIFERATION OF
SOURCES FOR INFORMATION SUCH AS MANUFACTURERSPECIFIC (M)SDSS, WE ARE NOT
AND CANNOT BE RESPONSIBLE FOR (M)SDSS OBTAINED FROM ANY SOURCE OTHER
THAN OURSELVES. IF YOU HAVE OBTAINED AN (M)SDS FROM ANOTHER SOURCE OR IF
YOU ARE NOT SURE THAT THE (M)SDS YOU HAVE IS CURRENT, PLEASE CONTACT US
FOR THE MOST CURRENT VERSION.
(R*) (TM) TRADEMARK OF THE DOW CHEMICAL COMPANY ("DOW") OR AN AFFILIATED
COMPANY OF DOW