| Common Name: | PROPYLENE |
| Manufacturer: | WORTHINGTON CYLINDER |
| SDS Revision Date: | 2/26/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 33V969 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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W
WORTHINGTON INDUSTRIES
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: PROPYLENE
OTHER MEANS OF IDENTIFICATION:
SDS NUMBER: WC001
PRODUCT CODE: MAP-PRO(TM), PRO-MAX(TM)
CAS NUMBER: 115-07-1
RECOMMENDED USE: HAND TORCH FUEL
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER/SUPPLIER: WORTHINGTON CYLINDER CORPORATION
ADDRESS:
300 E. BREED ST.
CHILTON, WI 53014
UNITED STATES
CONTACT PERSON: ANN STIEFVATER
E-MAIL ADDRESS: ANN.STIEFVATER@WORTHINGTONINDUSTRIES.COM
TELEPHONE NUMBER: 1-920-849-1740
EMERGENCY TELEPHONE NUMBER:
1-703-527-3887 INTERNATIONAL / CHEMTREC 1-800-424-9300 DOMESTIC
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE GASES: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: SIMPLE ASPHYXIANT
LABEL ELEMENTS:
FLAME
GAS CYLINDER
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE GAS. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR RESPIRATORY PROTECTION.
RESPONSE:
LEAKING GAS FIRE:
DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY. ELIMINATE ALL
IGNITION SOURCES IF SAFE TO DO SO.
STORAGE: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF WASTE AND RESIDUES IN ACCORDANCE WITH LOCAL AUTHORITY
REQUIREMENTS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
PROPYLENE 115-07-1 99.5 - 100
IMPURITIES:
CHEMICAL NAME CAS NUMBER %
PROPANE 74-98-6 0 - 0.5
COMPOSITION COMMENTS: GAS CONCENTRATIONS ARE IN PERCENT BY VOLUME.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE FROM FURTHER EXPOSURE. FOR THOSE PROVIDING ASSISTANCE, AVOID
EXPOSURE TO YOURSELF OR OTHERS. USE ADEQUATE RESPIRATORY PROTECTION. IF
RESPIRATORY TRACT IRRITATION, DIZZINESS, NAUSEA, OR UNCONSCIOUSNESS OCCURS,
SEEK IMMEDIATE MEDICAL ASSISTANCE. IF BREATHING HAS STOPPED, ASSIST
VENTILATION WITH A MECHANICAL DEVICE OR USE MOUTH-TO-MOUTH RESUSCITATION.
SKIN CONTACT:
NOT LIKELY, DUE TO THE FORM OF THE PRODUCT. IF FROSTBITE OCCURS, IMMERSE
AFFECTED AREA IN WARM WATER (NOT EXCEEDING 105 DEG. F/41 DEG. C). KEEP
IMMERSED FOR 20 TO 40 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY.
EYE CONTACT:
NOT LIKELY, DUE TO THE FORM OF THE PRODUCT. IF FROSTBITE OCCURS,
IMMEDIATELY FLUSH EYES WITH PLENTY OF WARM WATER (NOT EXCEEDING 105 DEG.
F/41 DEG. C) FOR AT LEAST 15 MINUTES. IF EASY TO DO, REMOVE CONTACT LENSES.
GET MEDICAL ATTENTION PROMPTLY IF SYMPTOMS PERSIST OR OCCUR AFTER WASHING.
INGESTION:
THIS MATERIAL IS A GAS UNDER NORMAL ATMOSPHERIC CONDITIONS AND INGESTION
IS UNLIKELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
EXPOSURE TO RAPIDLY EXPANDING GAS OR VAPORIZING LIQUID MAY CAUSE FROSTBITE
("COLD BURN"). VERY HIGH EXPOSURE CAN CAUSE SUFFOCATION FROM LACK OF
OXYGEN. SYMPTOMS MAY INCLUDE LOSS OF MOBILITY/CONSCIOUSNESS. VICTIM MAY
NOT BE AWARE OF ASPHYXIATION. ASPHYXIATION MAY BRING ABOUT UNCONSCIOUSNESS
WITHOUT WARNING AND SO RAPIDLY THAT VICTIM MAY BE UNABLE TO PROTECT
THEMSELF.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
EXPOSURE MAY AGGRAVATE PRE-EXISTING RESPIRATORY DISORDERS. PROVIDE GENERAL
SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
GENERAL INFORMATION:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2). WATER FOG. FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE GAS. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE
FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
DO NOT EXTINGUISH FIRES UNLESS GAS FLOW CAN BE STOPPED SAFELY; EXPLOSIVE
RE-IGNITION MAY OCCUR. PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS
FROM THE VICINITY OF THE INCIDENT. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. FOR FIRES INVOLVING THIS
MATERIAL, DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER
PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING APPARATUS. STOP
FLOW OF MATERIAL. USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL AND TO
PROTECT PERSONNEL EFFECTING SHUTOFF. IF A LEAK OR SPILL HAS NOT IGNITED,
USE WATER SPRAY TO DISPERSE THE VAPORS AND TO PROTECT PERSONNEL ATTEMPTING
TO STOP LEAK. PREVENT RUNOFF FROM FIRE CONTROL OR DILUTION FROM ENTERING
STREAMS, SEWERS OR DRINKING WATER SUPPLY.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER
UNTIL WELL AFTER FIRE IS OUT.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE GAS. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY
EXPLODE WHEN EXPOSED TO HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE THE AREA PROMPTLY. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. IN THE EVENT OF A LEAK
EVACUATE ALL PERSONNEL UNTIL VENTILATION CAN RESTORE OXYGEN CONCENTRATIONS
TO SAFE LEVELS. KEEP UNNECESSARY PERSONNEL AWAY. ELIMINATE ALL IGNITION
SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). DO NOT
TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM.
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. IF POSSIBLE,
TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN LIQUID. ISOLATE
AREA UNTIL GAS HAS DISPERSED. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE
SDS.
ENVIRONMENTAL PRECAUTIONS:
SHOULD NOT BE RELEASED INTO THE ENVIRONMENT. PREVENT FURTHER LEAKAGE OR
SPILLAGE IF SAFE TO DO SO.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
HANDLE, STORE OR OPEN NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES OF
IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT. ALL EQUIPMENT USED WHEN
HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT BREATHE GAS. AVOID PROLONGED
EXPOSURE. DO NOT ENTER STORAGE AREAS OR CONFINED SPACES UNLESS ADEQUATELY
VENTILATED. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. OXYGEN
CONCENTRATION SHOULD NOT FALL BELOW 19.5% AT SEA LEVEL (PO2 = 135 MMHg).
MECHANICAL VENTILATION OR LOCAL EXHAUST VENTILATION MAY BE REQUIRED. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE AT TEMPERATURES NOT EXCEEDING 49 DEG. C/120 DEG. F. KEEP AWAY FROM
HEAT, SPARKS AND OPEN FLAME. PREVENT ELECTROSTATIC CHARGE BUILD-UP BY USING
COMMON BONDING AND GROUNDING TECHNIQUES. STORE IN A COOL, DRY PLACE OUT OF
DIRECT SUNLIGHT. CYLINDERS SHOULD BE STORED UPRIGHT, WITH VALVE PROTECTION
CAP IN PLACE, AND FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED OVER.
PROTECT CYLINDERS FROM DAMAGE. STORED CONTAINERS SHOULD BE PERIODICALLY
CHECKED FOR GENERAL CONDITION AND LEAKAGE. STORE IN ORIGINAL TIGHTLY CLOSED
CONTAINER. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A WELL-VENTILATED PLACE.
USE CARE IN HANDLING/STORAGE. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE
SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
IMPURITIES TYPE VALUE
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
PROPYLENE (CAS 115-07-1) TWA 500 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
IMPURITIES TYPE VALUE
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION AND MINIMIZE THE RISK OF INHALATION OF GAS.
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR APPROVED SAFETY GLASSES OR GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES. NITRILE, BUTYL RUBBER OR
NEOPRENE GLOVES ARE RECOMMENDED.
SKIN PROTECTION:
OTHER: WEAR PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW
RECOMMENDED EXPOSURE LIMITS (WHERE APPLICABLE) OR TO AN ACCEPTABLE LEVEL
(IN COUNTRIES WHERE EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED), AN APPROVED
RESPIRATOR MUST BE WORN. WEAR AIR SUPPLIED RESPIRATORY PROTECTION.
THERMAL HAZARDS:
CONTACT WITH LIQUEFIED GAS MIGHT CAUSE FROSTBITES, IN SOME CASES WITH
TISSUE DAMAGE. WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN
NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
DO NOT EAT, DRINK OR SMOKE WHEN USING THE PRODUCT. WASH THOROUGHLY AFTER
HANDLING. PROVIDE EYEWASH STATION AND SAFETY SHOWER. HANDLE IN ACCORDANCE
WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: GAS.
FORM: COMPRESSED LIQUEFIED GAS.
COLOR: COLORLESS.
ODOR: HYDROCARBON OR MERCAPTAN IF ODORIZED.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE.
MELTING POINT/FREEZING POINT: -301 DEG. F (-185 DEG. C)
INITIAL BOILING POINT AND BOILING RANGE: -54.4 DEG. F (-48 DEG. C)
BOILING POINT PRESSURE: 101.33 KPA
FLASH POINT: -162.0 DEG. F (-107.8 DEG. C)
EVAPORATION RATE: NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): EXTREMELY FLAMMABLE GAS.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 2% V/V
FLAMMABILITY LIMIT - UPPER (%): 11% V/V
VAPOR PRESSURE: 109.73 PSIG
VAPOR PRESSURE TEMP.: 69.8 DEG. F (21 DEG. C)
VAPOR DENSITY: 1.5 (AIR=1)
VAPOR DENSITY TEMP.: 32 DEG. F (0 DEG. C) (GAS)
RELATIVE DENSITY: 0.52 (LIQUID) (H2O=1)
SOLUBILITY(IES):
SOLUBILITY (WATER): 384 MG/L - SLIGHTLY SOLUBLE IN WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): 1.77
AUTO-IGNITION TEMPERATURE: 927 DEG. F (497.22 DEG. C)
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
MOLECULAR WEIGHT: 42 G/MOL
OXIDIZING PROPERTIES: NOT OXIDIZING.
PERCENT VOLATILE: 100%
SURFACE TENSION: 16.7 MN/M (194 DEG. F (90 DEG. C))
VOC: 100% EPA ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY:
STABLE UNDER NORMAL TEMPERATURE CONDITIONS AND RECOMMENDED USE.
POSSIBILITY OF HAZARDOUS REACTIONS:
POLYMERIZATION WILL NOT OCCUR. MAY FORM EXPLOSIVE MIXTURE WITH AIR. THIS
PRODUCT MAY REACT WITH OXIDIZING AGENTS.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. AVOID
TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. STRONG ACIDS. HALOGENS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION OF THIS PRODUCT CAN GENERATE CARBON MONOXIDE AND
CARBON DIOXIDE. HYDROCARBONS.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
HIGH CONCENTRATIONS: SUFFOCATION (ASPHYXIANT) HAZARD - IF ALLOWED TO
ACCUMULATE TO CONCENTRATIONS THAT REDUCE OXYGEN BELOW SAFE BREATHING
LEVELS. BREATHING OF HIGH CONCENTRATIONS MAY CAUSE DIZZINESS,
LIGHT-HEADEDNESS, HEADACHE, NAUSEA AND LOSS OF COORDINATION. CONTINUED
INHALATION MAY RESULT IN UNCONSCIOUSNESS.
SKIN CONTACT: CONTACT WITH LIQUEFIED GAS MAY CAUSE FROSTBITE.
EYE CONTACT: CONTACT WITH LIQUEFIED GAS MAY CAUSE FROSTBITE.
INGESTION:
THIS MATERIAL IS A GAS UNDER NORMAL ATMOSPHERIC CONDITIONS AND INGESTION
IS UNLIKELY.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EXPOSURE TO RAPIDLY EXPANDING GAS OR VAPORIZING LIQUID MAY CAUSE FROSTBITE
("COLD BURN"). VERY HIGH EXPOSURE CAN CAUSE SUFFOCATION FROM LACK OF
OXYGEN. VICTIM MAY NOT BE AWARE OF ASPHYXIATION. ASPHYXIATION MAY BRING
ABOUT UNCONSCIOUSNESS WITHOUT WARNING AND SO RAPIDLY THAT VICTIM MAY BE
UNABLE TO PROTECT THEMSELF.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT EXPECTED TO BE ACUTELY TOXIC.
COMPONENTS SPECIES TEST RESULTS
PROPYLENE (CAS 115-07-1)
ACUTE:
INHALATION:
GAS
LC50 RAT >65000 PPM, 4 HOURS
SKIN CORROSION/IRRITATION: NOT CLASSIFIED.
SERIOUS EYE DAMAGE/EYE IRRITATION: NOT CLASSIFIED.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
PROPYLENE (CAS 115-07-1) 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO
HUMANS.
NTP REPORT ON CARCINOGENS: NOT LISTED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT LIKELY, DUE TO THE FORM OF THE PRODUCT.
CHRONIC EFFECTS:
EXPOSURE OVER A LONG PERIOD OF TIME MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: THE PRODUCT IS READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL: THE PRODUCT IS NOT EXPECTED TO BIOACCUMULATE.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
PROPYLENE (CAS 115-07-1) 1.77
PROPANE (CAS 74-98-6) 2.36
MOBILITY IN SOIL: NOT RELEVANT, DUE TO THE FORM OF THE PRODUCT.
OTHER ADVERSE EFFECTS:
THE PRODUCT CONTAINS VOLATILE ORGANIC COMPOUNDS WHICH HAVE A PHOTOCHEMICAL
OZONE CREATION POTENTIAL.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
USE THE CONTAINER UNTIL EMPTY. DO NOT DISPOSE OF ANY NON-EMPTY CONTAINER.
EMPTY CONTAINERS HAVE RESIDUAL VAPOR THAT IS FLAMMABLE AND EXPLOSIVE.
CYLINDERS SHOULD BE EMPTIED AND RETURNED TO A HAZARDOUS WASTE COLLECTION
POINT. DO NOT PUNCTURE OR INCINERATE EVEN WHEN EMPTY. DISPOSE IN ACCORDANCE
WITH ALL APPLICABLE REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 DEG. F
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1077
UN PROPER SHIPPING NAME: PROPYLENE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP:
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: 19, T50
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: 304
PACKAGING BULK: 314, 315
IATA:
UN NUMBER: UN1077
UN PROPER SHIPPING NAME: PROPYLENE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP:
ENVIRONMENTAL HAZARDS: NO
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
IMDG:
UN NUMBER: UN1077
UN PROPER SHIPPING NAME: PROPYLENE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP:
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT ESTABLISHED.
GENERAL INFORMATION:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY. BEFORE TRANSPORTING PRODUCT CONTAINERS: ENSURE THAT CONTAINERS
ARE FIRMLY SECURED. ENSURE CYLINDER VALVE IS CLOSED AND NOT LEAKING. ENSURE
VALVE OUTLET CAP NUT OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED. ENSURE
VALVE PROTECTION DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED. ENSURE
ADEQUATE VENTILATION. ENSURE COMPLIANCE WITH APPLICABLE REGULATIONS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
PROPANE (CAS 74-98-6) LISTED
PROPYLENE (CAS 115-07-1) LISTED
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: YES
REACTIVITY HAZARD: NO
PRESSURE HAZARD: YES
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
PROPYLENE 115-07-1 99.5 - 100
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130):
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
US STATE REGULATIONS:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65): THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS
CURRENTLY LISTED AS CARCINOGENS OR REPRODUCTIVE TOXINS.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
US. RHODE ISLAND RTK:
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES YES
(AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES YES
IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL YES
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL YES
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
*A "YES" INDICATES THIS PRODUCT COMPLIES WITH THE INVENTORY REQUIREMENTS
ADMINISTERED BY THE GOVERNING COUNTRY(S).
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 26-FEBRUARY-2017
REVISION DATE:
VERSION #: 01
FURTHER INFORMATION:
THE CLASSIFICATION FOR HEALTH AND ENVIRONMENTAL HAZARDS IS DERIVED
BY A COMBINATION OF CALCULATION METHODS AND TEST DATA, IF AVAILABLE.
HMIS(R*) RATINGS:
HEALTH 1
FLAMMABILITY 4
PHYSICAL HAZARD 1
NFPA RATINGS:
1
4
1
REFERENCES:
HSDB(R*) - HAZARDOUS SUBSTANCES DATA BANK
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY
NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS
ACGIH DOCUMENTATION OF THE THRESHOLD LIMIT VALUES AND BIOLOGICAL EXPOSURE
INDICES
EPA: AQUIRE DATABASE
NLM: HAZARDOUS SUBSTANCES DATA BASE
DISCLAIMER:
ALL INFORMATION IN THIS SAFETY DATA SHEET IS BELIEVED TO BE ACCURATE AND
RELIABLE. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND IS MADE WITH REGARD
TO THE ACCURACY OF INFORMATION OR THE SUITABILITY OF THE RECOMMENDATIONS
CONTAINED HEREIN. IT IS THE USER'S RESPONSIBILITY TO ASSESS THE SAFETY AND
TOXICITY OF THIS PRODUCT UNDER THEIR OWN CONDITIONS OF USE AND TO COMPLY
WITH ALL APPLICABLE LAWS AND REGULATIONS.
909050
SDS US