| Common Name: | CLR PRO HEAVY DUTY CLEANER |
| Manufacturer: | JELMAR |
| SDS Revision Date: | 3/1/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 423N36 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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JELMAR(R*)
MAKERS OF CLR(R*) TARN-X(R*)
SAFETY DATA SHEET
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: CLR(R*) PRO HEAVY DUTY CLEANER
RESTRICTIONS ON USE:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, ACIDS AND BLEACH.
PRODUCT USE:
AQUEOUS INDUSTRIAL STRENGTH DEGREASER CLEANER FOR REMOVAL OF OIL, GREASE
AND TAR ON CEMENT, TERRAZZO, STONE FLOORS, BLACKTOP, SIDEWALKS, MOTORS,
GARAGE FLOORS, BARBEQUE GRILLS, POOL DECKS, AND MOTORS RETAIL PACKAGE:
(26 FL. OZ., 42 FL. OZ.)
MANUFACTURER: JELMAR, LLC
ADDRESS:
5550 W. T OUHY AVE.
SKOKIE, IL 60077
USA
1(847) 675-8400
EMERGENCY PHONE NUMBER:
1(800) 323-5497 (USA) 8:30 A.M. - 4:30 P.M. CST MONDAY - FRIDAY
EMERGENCY 24 HOUR CONTACT:
CHEMTREC: 1(800) 424-9300
| SECTION 2 - HAZARDS IDENTIFICATION | |
COMPLIES WITH 29CFR 1900.1200 DATED MAY 2012
EXCLAMATION MARK
WARNING:
ACUTE EYE IRRITATION (CATEGORY 2B)
ACUTE DERMAL IRRITATION (CATEGORY 3)
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: NO INFORMATION AVAILABLE.
DO NOT GET IN EYES, ON SKIN OR CLOTHING.
DO NOT MIX WITH BLEACH OR OTHER HOUSEHOLD CHEMICALS HARMFUL; FUMES MAY
RESULT.
DO NOT INGEST.
DO NOT BREATHE VAPOR OR MIST. USE IN WELL VENTILATED AREAS. KEEP CONTAINER
CLOSED WHEN NOT IN USE.
KEEP OUT OF REACH OF CHILDREN
HAZARD STATEMENT(S):
CAUSES EYE IRRITATION.
MAY CAUSE SKIN IRRITATION.
PRECAUTIONARY STATEMENT(S):
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER.
WASH SKIN THOROUGH AFTER HANDLING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
DO NOT EAT, DRINK OR SMOKE WHEN HANDLING THIS PRODUCT.
WEAR PROTECTIVE GLOVES.
IF SWALLOWED:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. AVOID
BREATHING FUMES.
| SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS | |
COMPONENT CAS# OSHA HAZARD % BY WEIGHT
1. ALCOHOLS, C9-11, ETHOXYLATED 68439-46-3 YES 2.00-9.00
2. SODIUM METASILICATE ANHYDROUS 6834-92-0 YES 1.00-4.75
3. SODIUM XYLENESULPHONATE 1300-72-7 YES 1.00-3.00
THE EXACT PERCENTAGES (CONCENTRATION) OF MIXTURE HAS BEEN WITHHELD AS A
TRADE SECRET IN ACCORDANCE TO PARAGRAPH (I) OF SUBSECTION 1910.1200.
| SECTION 4 - FIRST AID MEASURES | |
EYE CONTACT:
IN CASE OF EYE CONTACT, IMMEDIATELY RINSE EYE THOROUGHLY WITH PLENTY OF
WATER. REMOVE CONTACT LENSES, AND CONTINUE RINSING FOR AT LEAST 15 MINUTES.
IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
SKIN CONTACT:
CAN BE IRRITATING TO SKIN, PROLONGED CONTACT CAN BE MORE SEVERE, NO ADVERSE
EFFECTS DURING NORMAL USAGE. IN CASE OF SKIN CONTACT, RINSE AREA FOR AT
LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES, WASH THOROUGHLY
BEFORE REUSE. IF IRRITATION PERSISTS GET MEDICAL ATTENTION.
INHALATION:
NOT A SIGNIFICANT ROUTE OF EXPOSURE. REMOVE TO FRESH AIR. IF BREATHING IS
DIFFICULT, GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING. IF FULLY CONSCIOUS, DRINK 16 OUNCES OF WATER. CALL
A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE AN UNCONSCIOUS
PERSON ANYTHING TO INGEST.
| SECTION 5 - FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
NOT FLAMMABLE. USE APPROPRIATE MEDIA FOR AREA. USE WATER SPRAY, DRY
CHEMICAL, ALCOHOL-RESISTANT FOAM OR CARBON DIOXIDE.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON MONOXIDE. THERMAL DECOMPOSITION CAN LEAD TO IRRITATING GASES AND
VAPORS.
FIRE FIGHTING METHODS:
EVACUATE AREA OF PERSONNEL. WEAR PROTECTIVE NIOSH-APPROVED SELF-CONTAINED
BREATHING APPARATUS. REMAIN UPWIND OF FIRE TO AVOID HAZARDOUS VAPORS AND
DECOMPOSITION PRODUCTS. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
RUN-OFF OF LARGE QUANTITIES OF PRODUCT FROM FIRE CONTROL MAY CAUSE
POLLUTION. CONTACT APPROPRIATE AGENCIES.
FIRE AND EXPLOSION HAZARDS: NONE KNOWN.
| SECTION 6 - ACCIDENTAL RELEASES MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
AVOID CONTACT WITH SKIN AND EYES
SMALL SPILL:
NO SPECIAL CLEAN-UP PROCEDURE IS NECESSARY FOR SMALL (LESS THAN 1 GALLON)
SPILLS. FLUSH SPILL AREA WITH WATER. WEAR RUBBER GLOVES.
LARGE SPILL:
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8. ISOLATE AREA, AND DENY
ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL. DAM SPILL, AND ABSORB WITH
EARTH, SAND OR SIMILAR MATERIAL. PLACE IN NON-LEAKING CONTAINERS. DISPOSE
OF COLLECTED MATERIAL ACCORDING TO LOCAL, STATE, AND FEDERAL REGULATIONS.
FLUSH RESIDUE WITH LARGE AMOUNT OF WATER. AREA MAY BE SLIPPERY. AVOID
DIRECT DISCHARGE TO SEWERS AND SURFACE WATERS. DO NOT TRANSFER TO METAL
CONTAINERS.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING AND STORAGE:
AVOID CONTACT WITH EYES, SKIN OR CLOTHING. MAY BE HARMFUL IF SWALLOWED. USE
WITH ADEQUATE VENTILATION. AVOID BREATHING VAPORS OR MIST. DO NOT EAT,
DRINK, OR SMOKE IN WORK AREA. WASH HANDS THOROUGHLY AFTER USE. CONSUMER
SIZE CONTAINER (26 AND 42 FLUID OUNCES), SHOULD BE RINSED AND RECYCLED.
STORE IN COOL, WELL-VENTILATED AREA AWAY FROM HEAT. KEEP CONTAINERS TIGHTLY
CLOSED. AVOID CONTACT WITH STRONG OXIDIZING AGENTS, ACIDS, BASES, AND
BLEACH. STORE PRODUCT IN ORIGINAL CONTAINER. DO NOT STORE IN METAL VESSELS.
DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT.
KEEP OUT OF REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENT OSHA ACGIH
PEL STEL/C TWA STEL/C
1. ALCOHOLS, C9-11, N.E N.E. N.E. N.E.
ETHOXYLATED
2. SODIUM METASILICATE N.E. N.E. N.E. N.E.
ANHYDROUS
3. SODIUM XYLENESULPHONATE N.E. N.E. N.E. N.E.
VENTILATION REQUIREMENT:
AVOID PROLONGED BREATHING MISTS OR DUSTS OF THIS PRODUCT. USE WITH ADEQUATE
VENTILATION. DO NOT USE IN CLOSED OR CONFINED SPACES.
RESPIRATORY PROTECTION:
NONE REQUIRED DURING NORMAL HOUSEHOLD USE.
EMERGENCY RESPONDERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA)
TO AVOID INHALATION OF PRODUCT.
EYE PROTECTION:
DO NOT WEAR CONTACT LENSES. GOGGLES SUGGESTED DURING NORMAL HOUSEHOLD
USAGE. EMERGENCY RESPONDERS SHOULD WEAR FULL EYE AND FACE PROTECTION.
SKIN PROTECTION:
RUBBER GLOVES WITH PROTECTIVE CUFF. EMERGENCY RESPONDERS SHOULD WEAR
IMPERMEABLE GLOVES.
OTHER PROTECTION:
EMERGENCY RESPONDERS SHOULD WEAR CHEMICAL TYPE (IMPERMEABLE) PROTECTIVE
CLOTHING AND FOOTWEAR WHERE DIRECT CONTACT WITH CHEMICALS IN THIS PRODUCT
IS POSSIBLE.
WORK/HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER AFTER USE OR HANDLING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR LIQUID
ODOR: SURFACTANT
ODOR THRESHOLD: N.D.
PH @ 20 DEG. C: 12.40-13.00
MELTING POINT: N.D.
FREEZING POINT: N.D
BOILING POINT: 93.3 DEG. C / 200 DEG. F
BOILING POINT RANGE: N.A.
FLASH POINT: NONE
EVAPORATION RATE: N.D
FLAMMABILITY: NOT FLAMMABLE
UPPER/LOWER FLAMMABILITY: N.A.
VAPOR PRESSURE: N.D
VAPOR DENSITY (MMHg): N.D.
RELATIVE DENSITY @ 20 DEG. C: 1.030 - 1.040
SOLUBILITY IN WATER: 100%
PARTITION COEFFICIENT; N-OCTANOL/WATER: N.D.
AUTO IGNITION TEMPERATURE: N.A.
DECOMPOSITION TEMPERATURE: N.A.
VISCOSITY: N.D.
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVITY: N.A.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: N.D.
CONDITIONS TO AVOID: AVOID ELEVATED TEMPERATURES.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS, ACIDS, AND BLEACH.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES, VAPORS AND
CARBON OXIDES.
IN THE EVENT OF FIRE: SEE SECTION 5.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYES, SKIN, INHALATION, INGESTION.
EYES:
IRRITANT:
AVOID EYE CONTACT. EFFECTS MAY VARY DEPENDING ON LENGTH OF EXPOSURE,
SOLUTION CONCENTRATION
SKIN: MILD IRRITANT. PROLONGED CONTACT MAY CAUSE DERMATITIS, AND ITCHING.
INHALATION: NO ADVERSE EFFECTS EXPECTED UNDER TYPICAL USE CONDITIONS.
INGESTION: VOMITING AND GASTROINTESTINAL DISTURBANCE.
LD50 ACUTE EYE IRRITATION: GHS TOXICITY CATEGORY 2B
LD50 ACUTE DERMAL IRRATION - RABBITS: GHS CATEGORY 3.
LD50 ACUTE ORAL TOXICITY - RATS: >5,000 MG/KG
LD50 ACUTE DERMAL TOXICITY - RABBITTS: >5,000 MG/KG
LD50 ACUTE INHALATION TOXICITY - RATS: NOT TOXIC BY INHALATION.
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES THAT ARE CONSIDERED
CARCINOGENIC BY THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS
AND HAVE NOT BEEN FOUND TO BE POTENTIAL CARCINOGENS IN THE INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER (IARC) MONOGRAPHS OR FOUND TO BE POTENTIAL
CARCINOGENS BY OSHA.
REPRODUCTIVE TOXICITY: N.A.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: N.A.
SPECIFIC ORGAN TOXICITY - REPEATED DOSE: N.A.
| SECTION 12 - ECOLOGICAL INFORMATION | |
ALCOHOLS, C9-11, ETHOXYLATED:
ECOTOXICITY: NO DATA ON PRODUCT ITSELF
TOXICITY TO FISH - COMPONENTS:
ALCOHOL, C9-11, ETHOXYLATED:
LC50 (96 HR.): 8.5 MG/L
SPECIES: FATHEAD MINNOW (PIMEPHALES PROMELAS).
TOXICITY TO DAPHNIA - COMPONENTS:
ALCOHOL, C9-11, ETHOXYLATED:
EC50 (48 HR.): 5.3 MG/L
SPECIES: DAPHNIA
TOXICITY TO OTHER ORGANISMS: NO DATA AVAILABLE.
PERSISTENCE / DEGRADABILITY:
BIODEGRADABILITY:
READILY BIODEGRADABLE, AS DEFINED BY OECD, SUBSTANCE THAT DEGRADES >60-70%
WITHIN A 10 DAY WINDOW OVER 28 DAYS.
MOBILITY: NO DATA AVAILABLE
BIOACCUMULATION: NO DATA ON THE PRODUCT ITSELF.
SODIUM XYLENESULPHONATE (SXS):
ECOTOXICITY:
ALGAE EC50 ALGAE: >=230 MG/KG, 72 HOURS
CRUSTACEA EC50 DAPHNIA: >=1000 MG/L, 48 HOURS
FISH LC50 FISH: >=1000 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
SODIUM METASILICATE ANHYDROUS:
ECOTOXICITY:
AQUATIC TOXICITY:
THIS MATERIAL HAS EXHIBITED MODERATE TOXICITY TO AQUATIC ORGANISMS.
FATE AND TRANSPORT:
BIODEGRADATION:
THIS MATERIAL IS INORGANIC AND NOT SUBJECT TO BIODEGRADATION.
PERSISTENCE: THIS MATERIAL IS BELIEVED TO PERSIST IN THE ENVIRONMENT.
BIOCONCENTRATION:
THIS MATERIAL IS NOT EXPECTED TO BIOCONCENTRATE IN ORGANISMS.
ADDITIONAL ECOLOGICAL INFORMATION:
THIS MATERIAL HAS EXHIBITED SLIGHT TOXICITY TO TERRESTRIAL ORGANISMS.
POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL) ARE EXPECTED
FROM THIS COMPONENT.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
RINSE EMPTY BOTTLES AND RECYCLE. DISPOSE OF UNUSED PRODUCT IN A PERMITTED
HAZARDOUS WASTE MANAGEMENT FACILITY FOLLOWING ALL LOCAL, STATE, AND FEDERAL
REGULATIONS.
FOLLOW LABEL WARNINGS, SINCE CONTAINERS MAY RETAIN SOME RESIDE OF THE
PRODUCT. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT MAY CHANGE THE
WASTE MANAGEMENT OPTIONS. IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR
TO DETERMINE THE TOXICITY AND PHYSICAL PROPERTIES OF THE MATERIAL GENERATED
TO DETERMINE THE PROPER WASTE IDENTIFICATION AND DISPOSAL METHODS IN
COMPLIANCE WITH APPLICABLE REGULATIONS. STATE AND LOCAL DISPOSAL
REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
UN NUMBER: N.A.
UN PROPER SHIPPING NAME: N.A.
DOT (DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME):
NOT REGULATED BY DOT.
PACKAGING GROUP: N.A.
ENVIRONMENTAL HAZARD:
MARINE: NO
TDG CLASSIFICATION: NOT REGULATED
IMDG CLASSIFICATION: NOT REGULATED
IATA CLASSIFICATION:
PASSENGER: NOT REGULATED
WHIMS (CANADA):
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE SDS CONTAINS ALL
THE INFORMATION REQUIRED BY CPR.
| SECTION 15 - REGULATORY INFORMATION | |
FEDERAL REGULATIONS:
TSCA INVENTORY STATUS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY OR ARE
EXEMPT FROM TSCA INVENTORY REQUIREMENTS.
SARA TITLE III SECTION 311/312 CATEGORY:
IMMEDIATE (ACUTE) HEALTH HAZARD: YES
DELAYED (CHRONIC) HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE HAZARD: NO
SARA SECTIONS 302/304/313/HAP: NO
INTERNATIONAL CHEMICAL INVENTORY STATUS:
EUROPEAN UNION (EINECS): YES
JAPAN (METI): YES
AUSTRALIA (ACIS): YES
KOREA (KECL): YES
CANADA (DSL): YES
CANADA (NDSL): NO
PHILIPPINES: YES
STATES RIGHT TO KNOW:
CALIFORNIA, NEW JERSEY, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS, AND
WISCONSIN. COMPLIES WITH LISTED STATES RIGHT TO KNOW ACTS.
THE FOLLOWING STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA
STATE DRINKING WATER ACT. CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND/OR TO CAUSE BIRTH DEFECTS AND OTHER
REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
HAZARDOUS WASTE NUMBER: D002
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
AVOID EXPOSURE TO EXCESS HEAT, AND PREVENT FROM FREEZING.
NFPA: 1, 0, 1.0
TOTAL VOC (WT. %):
0.128% - DOES NOT INCLUDE ANY CARB APPLICABLE EXEMPTIONS (VOLATILE ORGANIC
COMPOUNDS)/CALIFORNIA AIR RESOURCES BOARD
CLR(R*) GREASE MAGNET CHEMICAL FATE INFORMATION:
28-DAY BIODEGRADATION. THE MATTER IS READILY BIODEGRADABLE.
FOOD FACILITY CATEGORIES:
PER FEDERAL GUIDELINES AS DETAILED IN FDA 21 CFR:
(A1) GENERAL PURPOSE CLEANERS
(A4) FLOOR & WALL DEGREASERS
(A8) DEGREASERS/CARBON REMOVERS
OTHER PRECAUTIONS: NONE REQUIRED.
SDS ABBREVIATIONS:
N.A.: NOT APPLICABLE
N.D.: NOT DETERMINED
N.E.: NOT ESTABLISHED
C: CEILING LIMIT
HAP: HAZARDOUS AIR POLLUTANT
VOC: VOLATILE ORGANIC COMPOUND
REVISION: SECTION 3 - ADDITIONAL INFORMATION; SECTION 12
R. A. GAUDREAULT
ALTHOUGH THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE PRESENTED
IN GOOD FAITH AND BELIEVED TO BE CORRECT AS OF THE DATE HEREOF, JELMAR
OFFERS NO REPRESENTATIONS AS TO THE COMPLETENESS OR ACCURACY THEREOF.
INFORMATION IS PROVIDED UPON THE CONDITION THAT THE PERSONS RECEIVING SAME
WILL MAKE THEIR OWN DETERMINATION AS TO ITS SUITABILITY FOR THEIR PURPOSES
PRIOR TO USE. IN NO EVENT WILL JELMAR BE RESPONSIBLE FOR DAMAGES OF ANY
NATURE WHATSOEVER RESULTING FROM USE OF OR RELIANCE UPON SAID INFORMATION.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE
ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH
INFORMATION HEREIN REFERS.
020216
DATE ISSUED: 1-MARCH-2017