SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. V(TM) VALVOLINE(TM) SAFETY DATA SHEET ZEREX(TM) ORIGINAL ANTIFREEZE COOLANT 734250 REVISION DATE: 01/15/2018 PRINT DATE: 1/15/2018 SDS NUMBER: 000000139197 VERSION: 1.4 29 CFR 1910.1200 (OSHA HAZCOM 2012)
PRODUCT IDENTIFIER: TRADE NAME: ZEREX(TM) ORIGINAL ANTIFREEZE COOLANT RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: RECOMMENDED USE: COOLANT AND ANTIFREEZE. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: VALVOLINE LLC 100 VALVOLINE WAY LEXINGTON, KY 40509 UNITED STATES OF AMERICA (USA) 1-800-TEAMVAL (1-800-832-6825) EMERGENCY TELEPHONE NUMBER: 1-800-VALVOLINE (1-800-825-8654) REGULATORY INFORMATION NUMBER: 1-800-TEAMVAL (1-800-832-6825) PRODUCT INFORMATION: 1-800-TEAMVAL (1-800-832-6825)
GHS CLASSIFICATION: ACUTE TOXICITY (ORAL): CATEGORY 4 REPRODUCTIVE TOXICITY: CATEGORY 1B SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - REPEATED EXPOSURE (ORAL): CATEGORY 2 (KIDNEY, LIVER) GHS LABEL ELEMENTS: HAZARD PICTOGRAMS: HEALTH HAZARD EXCLAMATION MARK SIGNAL WORD: DANGER HAZARD STATEMENTS: HARMFUL IF SWALLOWED. MAY DAMAGE FERTILITY OR THE UNBORN CHILD. MAY CAUSE DAMAGE TO ORGANS (KIDNEY, LIVER) THROUGH PROLONGED OR REPEATED EXPOSURE IF SWALLOWED. PRECAUTIONARY STATEMENTS: PREVENTION: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE DUST/ FUME/ GAS/ MIST/ VAPORS/ SPRAY. WASH SKIN THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WEAR PROTECTIVE GLOVES/ PROTECTIVE CLOTHING/ EYE PROTECTION/ FACE PROTECTION. RESPONSE: IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. RINSE MOUTH. IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ ATTENTION. STORAGE: STORE LOCKED UP. DISPOSAL: DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT. OTHER HAZARDS: NONE KNOWN.
SUBSTANCE / MIXTURE: MIXTURE HAZARDOUS COMPONENTS: CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%) ETHYLENE GLYCOL 107-21-1 ACUTE TOX. 4; H302 95.7212 STOT RE 2; H373 DIETHYLENE GLYCOL 111-46-6 ACUTE TOX. 4; H302 4.7852 STOT RE 2; H373 DISODIUM 1330-43-4 REPR. 1B; H360 0.5018 TETRABORATE ANHYDROUS
GENERAL ADVICE: MOVE OUT OF DANGEROUS AREA. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. DO NOT LEAVE THE VICTIM UNATTENDED. IF INHALED: IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE. IF SYMPTOMS PERSIST, CALL A PHYSICIAN. IN CASE OF SKIN CONTACT: FIRST AID IS NOT NORMALLY REQUIRED. HOWEVER, IT IS RECOMMENDED THAT EXPOSED AREAS BE CLEANED BY WASHING WITH SOAP AND WATER. IN CASE OF EYE CONTACT: FLUSH EYES WITH WATER AS A PRECAUTION. REMOVE CONTACT LENSES. PROTECT UNHARMED EYE. IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST. IF SWALLOWED: OBTAIN MEDICAL ATTENTION. RINSE MOUTH WITH WATER. DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF SYMPTOMS PERSIST, CALL A PHYSICIAN. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: EFFECTS OF ACUTE ETHYLENE GLYCOL POISONING APPEAR IN THREE FAIRLY DISTINCT STAGES. THE INITIAL STAGE OCCURS SHORTLY AFTER EXPOSURE, LASTS 6-12 HOURS, AND IS CHARACTERIZED BY CENTRAL NERVOUS SYSTEM EFFECTS (TRANSIENT EXHILARATION, NAUSEA, VOMITING, AND IN SEVERE CASES, COMA, CONVULSIONS, AND POSSIBLE DEATH). THE SECOND STAGE LASTS FROM 12-36 HOURS AFTER EXPOSURE AND IS INITIATED BY THE ONSET OF COMA. THIS PHASE IS CHARACTERIZED BY TACHYPNIA, TACHYCARDIA, MILD HYPOTENSION, CYANOSIS, AND IN SEVERE CASES, PULMONARY EDEMA, BRONCHOPNEUMONIA, CARDIAC ENLARGEMENT, AND CONGESTIVE FAILURE. THE FINAL STAGE OCCURS 24-72 POST-EXPOSURE AND IS CHARACTERIZED BY RENAL FAILURE, RANGING FROM A MILD INCREASE IN BLOOD UREA NITROGEN AND CREATININE FOLLOWED BY RECOVERY, TO COMPLETE ANURIA WITH ACUTE TUBULAR NECROSIS THAT CAN LEAD TO DEATH. OXALURIA IS FOUND IN MOST CASES. THE MOST SIGNIFICANT LABORATORY FINDING IN ETHYLENE GLYCOL INTOXICATION IS SEVERE METABOLIC ACIDOSIS. SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE: STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA) IRRITATION (NOSE, THROAT, AIRWAYS) COUGH PAIN IN THE ABDOMEN AND LOWER BACK CYANOSIS (CAUSES BLUE COLORING OF THE SKIN AND NAILS FROM LACK OF OXYGEN) LUNG EDEMA (FLUID BUILDUP IN THE LUNG TISSUE) ACUTE KIDNEY FAILURE (SUDDEN SLOWING OR STOPPING OF URINE PRODUCTION) CONVULSIONS HARMFUL IF SWALLOWED. MAY DAMAGE FERTILITY OR THE UNBORN CHILD. NOTES TO PHYSICIAN: THIS PRODUCT CONTAINS ETHYLENE GLYCOL. ETHANOL DECREASES THE METABOLISM OF ETHYLENE GLYCOL TO TOXIC METABOLITES. ETHANOL SHOULD BE ADMINISTERED AS SOON AS POSSIBLE IN CASES OF SEVERE POISONING SINCE THE ELIMINATION HALF-LIFE OF ETHYLENE GLYCOL IS 3 HOURS. IF MEDICAL CARE WILL BE DELAYED SEVERAL HOURS, GIVE THE PATIENT THREE TO FOUR 1-OUNCE ORAL "SHOTS" OF 86-PROOF OR HIGHER WHISKEY BEFORE OR DURING TRANSPORT TO THE HOSPITAL. FOMEPIZOLE (4-METHYLPYRAZOLE) IS AN EFFECTIVE ANTAGONIST OF ALCOHOL DEHYDROGENASE, AND AS SUCH, MAY BE USED AS AN ANTIDOTE IN THE TREATMENT OF ETHYLENE GLYCOL POISONING. HEMODIALYSIS EFFECTIVELY REMOVES ETHYLENE GLYCOL AND ITS METABOLITES FROM THE BODY.
SUITABLE EXTINGUISHING MEDIA: USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND THE SURROUNDING ENVIRONMENT. WATER SPRAY FOAM CARBON DIOXIDE (CO2) DRY CHEMICAL UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET SPECIFIC HAZARDS DURING FIREFIGHTING: DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES. HAZARDOUS COMBUSTION PRODUCTS: ALCOHOLS ALDEHYDES CARBON DIOXIDE AND CARBON MONOXIDE ETHERS TOXIC FUMES HYDROCARBONS SPECIFIC EXTINGUISHING METHODS: PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS. FURTHER INFORMATION: FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF IN ACCORDANCE WITH LOCAL REGULATIONS. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: USE PERSONAL PROTECTIVE EQUIPMENT. ENSURE ADEQUATE VENTILATION. PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. ENVIRONMENTAL PRECAUTIONS: PREVENT PRODUCT FROM ENTERING DRAINS. PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE AUTHORITIES. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL. OTHER INFORMATION: COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
ADVICE ON SAFE HANDLING: DO NOT BREATHE VAPOURS/DUST. DO NOT SMOKE. CONTAINER HAZARDOUS WHEN EMPTY. AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID CONTACT WITH SKIN AND EYES. SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA. FOR PERSONAL PROTECTION SEE SECTION 8. DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS. CONDITIONS FOR SAFE STORAGE: KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. OBSERVE LABEL PRECAUTIONS.
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS: COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS (FORM OF PARAMETERS / EXPOSURE) PERMISSIBLE CONCENTRATION ETHYLENE 107-21-1 C 100 MG/M3 ACGIH GLYCOL AEROSOL ONLY C 50 PPM OSHA P0 125 MG/M3 C 40 PPM CAL PEL 100 MG/M3 VAPOUR DIETHYLENE 111-46-6 TWA 10 MG/M3 US WEEL GLYCOL DISODIUM 1330-43-4 TWA 1 MG/M3 NIOSH REL TETRABORATE ANHYDROUS PEL 5 MG/M3 CAL PEL TWA 10 MG/M3 OSHA P0 TWA 2 MG/M3 ACGIH INHALABLE FRACTION (BORATE) STEL 6 MG/M3 ACGIH INHALABLE FRACTION (BORATE) HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS: COMPONENTS CAS-NO. DISODIUM TETRABORATE ANHYDROUS 1330-43-4 ENGINEERING MEASURES: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS. PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY PROTECTION: IN THE CASE OF VAPOUR FORMATION USE A RESPIRATOR WITH AN APPROVED FILTER. A NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH AN APPROPRIATE CARTRIDGE AND/OR FILTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS (IF APPLICABLE) OR IF OVEREXPOSURE HAS OTHERWISE BEEN DETERMINED. PROTECTION PROVIDED BY AIR-PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE, AIR-SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN OR ANY OTHER CIRCUMSTANCES WHERE AN AIR-PURIFYING RESPIRATOR MAY NOT PROVIDE ADEQUATE PROTECTION. HAND PROTECTION: REMARKS: THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE PRODUCERS OF THE PROTECTIVE GLOVES. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. WEAR SPLASH-PROOF SAFETY GOGGLES IF MATERIAL COULD BE MISTED OR SPLASHED INTO EYES. SKIN AND BODY PROTECTION: WEAR AS APPROPRIATE: IMPERVIOUS CLOTHING SAFETY SHOES CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE DANGEROUS SUBSTANCE AT THE WORK PLACE. WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER). HYGIENE MEASURES: WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. WHEN USING DO NOT EAT OR DRINK. WHEN USING DO NOT SMOKE.
PHYSICAL STATE: LIQUID COLOUR: GREEN ODOUR: NO DATA AVAILABLE ODOUR THRESHOLD: NO DATA AVAILABLE PH: 9 - <11 MELTING POINT/FREEZING POINT: NO DATA AVAILABLE BOILING POINT/BOILING RANGE: 387.7 DEG. F / 197.6 DEG. C (1,013.232 HPA) CALCULATED PHASE TRANSITION LIQUID/GAS FLASH POINT: >232 DEG. F / >111 DEG. C EVAPORATION RATE: NO DATA AVAILABLE FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE UPPER EXPLOSION LIMIT: 15.3% (V) GLP: CALCULATED EXPLOSIVE LIMIT LOWER EXPLOSION LIMIT: 3.2% (V) GLP: CALCULATED EXPLOSIVE LIMIT VAPOUR PRESSURE: 0.12265 HPA (25 DEG. C) CALCULATED VAPOR PRESSURE RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE RELATIVE DENSITY: NO DATA AVAILABLE DENSITY: 1.1205 G/CM3 (15.6 DEG. C) SOLUBILITY(IES): WATER SOLUBILITY: NO DATA AVAILABLE SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE THERMAL DECOMPOSITION: NO DATA AVAILABLE VISCOSITY: VISCOSITY, DYNAMIC: NO DATA AVAILABLE VISCOSITY, KINEMATIC: NO DATA AVAILABLE OXIDIZING PROPERTIES: NO DATA AVAILABLE
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED. CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS. POSSIBILITY OF HAZARDOUS REACTIONS: PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION. CONDITIONS TO AVOID: EXCESSIVE HEAT INCOMPATIBLE MATERIALS: ACIDS ALDEHYDES ALKALI METALS ALKALINE EARTH METALS BASES STRONG ALKALIS STRONG OXIDIZING AGENTS SULPHUR COMPOUNDS HAZARDOUS DECOMPOSITION PRODUCTS: ALCOHOLS ALDEHYDES CARBON DIOXIDE AND CARBON MONOXIDE ETHERS HYDROCARBONS ORGANIC ACIDS KETONES
INFORMATION ON LIKELY ROUTES OF EXPOSURE: INHALATION SKIN CONTACT EYE CONTACT INGESTION ACUTE TOXICITY: HARMFUL IF SWALLOWED. PRODUCT: ACUTE ORAL TOXICITY: REMARKS: INGESTION OF MEDICATIONS CONTAMINATED WITH DIETHYLENE GLYCOL HAS CAUSED KIDNEY FAILURE AND DEATH IN HUMANS. PRODUCTS CONTAINING DIETHYLENE GLYCOL SHOULD BE CONSIDERED TOXIC BY INGESTION. ACUTE DERMAL TOXICITY: REMARKS: SKIN ABSORPTION OF THIS MATERIAL (OR A COMPONENT) MAY BE INCREASED THROUGH INJURED SKIN. COMPONENTS: ETHYLENE GLYCOL: ACUTE ORAL TOXICITY: LD0 (HUMAN): ESTIMATED 1.56 G/KG ASSESSMENT: THE COMPONENT/MIXTURE IS CLASSIFIED AS ACUTE ORAL TOXICITY, CATEGORY 4. ACUTE INHALATION TOXICITY: LC50 (RAT): 10.9 MG/L EXPOSURE TIME: 1 H TEST ATMOSPHERE: DUST/MIST ASSESSMENT: NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE INHALATION TOXICITY TESTS. ACUTE DERMAL TOXICITY: LD50 (RABBIT): 9,530 MG/KG ACUTE TOXICITY (OTHER ROUTES OF ADMINISTRATION): LD50 (RAT): 5,010 MG/KG APPLICATION ROUTE: INTRAPERITONEAL DIETHYLENE GLYCOL: ACUTE ORAL TOXICITY: LD50 (HUMAN): EXPECTED 1,120 MG/KG TARGET ORGANS: KIDNEY ACUTE INHALATION TOXICITY: LC50 (RAT): >4.6 MG/L EXPOSURE TIME: 4 H TEST ATMOSPHERE: DUST/MIST ASSESSMENT: NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE INHALATION TOXICITY TESTS. ACUTE DERMAL TOXICITY: LD50 (RABBIT): 13,300 MG/KG DISODIUM TETRABORATE ANHYDROUS: ACUTE INHALATION TOXICITY: LC50 (RAT): >2.03 MG/L EXPOSURE TIME: 4 H TEST ATMOSPHERE: DUST/MIST METHOD: OECD TEST GUIDELINE 403 ASSESSMENT: NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE INHALATION TOXICITY TESTS. ACUTE DERMAL TOXICITY: LD50 (RABBIT): >2,000 MG/KG ASSESSMENT: NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE DERMAL TOXICITY TESTS. SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: ETHYLENE GLYCOL: SPECIES: RABBIT RESULT: NO SKIN IRRITATION DIETHYLENE GLYCOL: SPECIES: HUMAN RESULT: SLIGHT, TRANSIENT IRRITATION DISODIUM TETRABORATE ANHYDROUS: SPECIES: RABBIT RESULT: NO SKIN IRRITATION SERIOUS EYE DAMAGE/EYE IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. PRODUCT: REMARKS: UNLIKELY TO CAUSE EYE IRRITATION OR INJURY. COMPONENTS: ETHYLENE GLYCOL: RESULT: SLIGHT, TRANSIENT IRRITATION DIETHYLENE GLYCOL: SPECIES: RABBIT RESULT: SLIGHT, TRANSIENT IRRITATION DISODIUM TETRABORATE ANHYDROUS: RESULT: SLIGHT, TRANSIENT IRRITATION RESPIRATORY OR SKIN SENSITISATION: SKIN SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: ETHYLENE GLYCOL: TEST TYPE: MAXIMISATION TEST SPECIES: GUINEA PIG ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION. DIETHYLENE GLYCOL: TEST TYPE: MAXIMISATION TEST SPECIES: GUINEA PIG METHOD: DIRECTIVE 67/548/EEC, ANNEX V, B.6. RESULT: DID NOT CAUSE SENSITISATION ON LABORATORY ANIMALS. DISODIUM TETRABORATE ANHYDROUS: TEST TYPE: BUEHLER TEST SPECIES: GUINEA PIG ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION. METHOD: OECD TEST GUIDELINE 406 GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: ETHYLENE GLYCOL: GENOTOXICITY IN VITRO: TEST TYPE: AMES TEST TEST SPECIES: SALMONELLA TYPHIMURIUM METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION RESULT: NEGATIVE DIETHYLENE GLYCOL: GENOTOXICITY IN VITRO: TEST TYPE: AMES TEST METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION METHOD: OECD TEST GUIDELINE 471 RESULT: NEGATIVE GLP: YES TEST SPECIES: CHINESE HAMSTER OVARY CELLS METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION METHOD: OECD TEST GUIDELINE 479 RESULT: NEGATIVE GLP: YES GENOTOXICITY IN VIVO: TEST TYPE: IN VIVO MICRONUCLEUS TEST TEST SPECIES: MOUSE METHOD: OECD TEST GUIDELINE 474 RESULT: NEGATIVE GLP: YES CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD. COMPONENTS: DISODIUM TETRABORATE ANHYDROUS: REPRODUCTIVE TOXICITY - ASSESSMENT: CLEAR EVIDENCE OF ADVERSE EFFECTS ON SEXUAL FUNCTION AND FERTILITY, AND/OR ON DEVELOPMENT, BASED ON ANIMAL EXPERIMENTS STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. STOT - REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: ETHYLENE GLYCOL: EXPOSURE ROUTES: INGESTION TARGET ORGANS: KIDNEY, LIVER ASSESSMENT: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. DIETHYLENE GLYCOL: EXPOSURE ROUTES: INGESTION TARGET ORGANS: KIDNEY ASSESSMENT: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. EXPERIENCE WITH HUMAN EXPOSURE: COMPONENTS: DIETHYLENE GLYCOL: LIVER FURTHER INFORMATION: PRODUCT: REMARKS: NO DATA AVAILABLE CARCINOGENICITY: IARC: GROUP 2A: PROBABLY CARCINOGENIC TO HUMANS SODIUM NITRATE 7631-99-4 OSHA: NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO 0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA. NTP: NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO 0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
ECOTOXICITY: PRODUCT: ECOTOXICOLOGY ASSESSMENT: ACUTE AQUATIC TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. CHRONIC AQUATIC TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION. COMPONENTS: ETHYLENE GLYCOL: TOXICITY TO FISH: LC50 (LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH)): 27,540 MG/L EXPOSURE TIME: 96 H TEST TYPE: STATIC TEST LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 8,050 MG/L EXPOSURE TIME: 96 H TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES: LC50 (DAPHNIA MAGNA (WATER FLEA)): >10,000 MG/L EXPOSURE TIME: 48 H TEST TYPE: STATIC TEST TOXICITY TO ALGAE: EC50 (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 6,500 - 13,000 MG/L END POINT: GROWTH INHIBITION EXPOSURE TIME: 7 DAYS TOXICITY TO FISH (CHRONIC TOXICITY): NOEC (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 32,000 MG/L EXPOSURE TIME: 7 D TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY): NOEC (DAPHNIA MAGNA (WATER FLEA)): 24,000 MG/L EXPOSURE TIME: 7 D DIETHYLENE GLYCOL: TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES: LC50 (WATER FLEA (DAPHNIA MAGNA)): >10,000 MG/L EXPOSURE TIME: 24 H TEST TYPE: STATIC TEST METHOD: DIN 38412 DISODIUM TETRABORATE ANHYDROUS: TOXICITY TO FISH: LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 79.7 MG/L EXPOSURE TIME: 96 H REMARKS: INFORMATION REFERS TO THE MAIN COMPONENT. TOXICITY TO ALGAE: NOEC (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 17.5 MG/L END POINT: GROWTH INHIBITION EXPOSURE TIME: 72 H TEST TYPE: STATIC TEST METHOD: OECD TEST GUIDELINE 201 REMARKS: INFORMATION REFERS TO THE MAIN COMPONENT. TOXICITY TO FISH (CHRONIC TOXICITY): NOEC (DANIO RERIO (ZEBRA FISH)): 5.6 MG/L EXPOSURE TIME: 34 D TEST TYPE: SEMI-STATIC TEST METHOD: OECD TEST GUIDELINE 210 REMARKS: INFORMATION REFERS TO THE MAIN COMPONENT. PERSISTENCE AND DEGRADABILITY: COMPONENTS: ETHYLENE GLYCOL: BIODEGRADABILITY: RESULT: READILY BIODEGRADABLE. BIODEGRADATION: 90 - 100% EXPOSURE TIME: 10 D METHOD: OECD TEST GUIDELINE 301 DIETHYLENE GLYCOL: BIODEGRADABILITY: RESULT: READILY BIODEGRADABLE. BIODEGRADATION: 70 - 80% EXPOSURE TIME: 28 D METHOD: OECD TEST GUIDELINE 301B DISODIUM TETRABORATE ANHYDROUS: BIODEGRADABILITY: RESULT: THE METHODS FOR DETERMINING BIODEGRADABILITY ARE NOT APPLICABLE TO INORGANIC SUBSTANCES. NO DATA AVAILABLE BIOACCUMULATIVE POTENTIAL: COMPONENTS: ETHYLENE GLYCOL: BIOACCUMULATION: SPECIES: CRAYFISH (PROCAMBARUS) BIOCONCENTRATION FACTOR (BCF): 0.27 EXPOSURE TIME: 61 D CONCENTRATION: 1000 MG/L METHOD: FLOW THROUGH PARTITION COEFFICIENT N-OCTANOL/WATER: LOG POW: -1.36 DIETHYLENE GLYCOL: BIOACCUMULATION: SPECIES: LEUCISCUS IDUS (GOLDEN ORFE) BIOCONCENTRATION FACTOR (BCF): 100 PARTITION COEFFICIENT N-OCTANOL/WATER: LOG POW: -1.47 NO DATA AVAILABLE MOBILITY IN SOIL: COMPONENTS: NO DATA AVAILABLE OTHER ADVERSE EFFECTS: NO DATA AVAILABLE PRODUCT: ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE COMPONENTS:
DISPOSAL METHODS: GENERAL ADVICE: DO NOT DISPOSE OF WASTE INTO SEWER. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. SEND TO A LICENSED WASTE MANAGEMENT COMPANY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. CONTAMINATED PACKAGING: EMPTY REMAINING CONTENTS. DISPOSE OF AS UNUSED PRODUCT. EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY CONTAINERS.
INTERNATIONAL TRANSPORT REGULATIONS: REGULATION: ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE CLASS HAZARDS GROUP POLLUTANT / LTD. QTY. U.S. DOT - ROAD: NOT DANGEROUS GOODS CFR_RAIL_C: NOT DANGEROUS GOODS U.S. DOT - INLAND WATERWAYS: NOT DANGEROUS GOODS TDG_ROAD_C: NOT DANGEROUS GOODS TDG_RAIL_C: NOT DANGEROUS GOODS TDG_INWT_C: NOT DANGEROUS GOODS INTERNATIONAL MARITIME DANGEROUS GOODS: NOT DANGEROUS GOODS INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: NOT DANGEROUS GOODS INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: NOT DANGEROUS GOODS MX_DG: NOT DANGEROUS GOODS *ORM = ORM-D CBL = COMBUSTIBLE LIQUID MARINE POLLUTANT: NO DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY, END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT: CERCLA REPORTABLE QUANTITY: COMPONENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ (LBS) ETHYLENE 107-21-1 5000 5224 GLYCOL SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY: THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ. SARA 311/312 HAZARDS: ACUTE HEALTH HAZARD CHRONIC HEALTH HAZARD SARA 313: ETHYLENE GLYCOL 107-21-1 95.72% CALIFORNIA PROP 65: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ETHYLENE GLYCOL 107-21-1 THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES: DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL AICS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY ENCS: NOT IN COMPLIANCE WITH THE INVENTORY KECI: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY TSCA: ON TSCA INVENTORY INVENTORIES: AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION), ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS (PHILIPPINES), TCSI (TAIWAN), TSCA (USA)
FURTHER INFORMATION: REVISION DATE: 01/15/2018 NFPA: HEALTH 1 FLAMMABILITY 1 INSTABILITY 0 SPECIAL HAZARD. HMIS III: HEALTH 1* FLAMMABILITY 1 PHYSICAL HAZARD 0 0 = NOT SIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH 4 = EXTREME * = CHRONIC NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION: COMBUSTIBLE LIQUID CLASS IIIB FULL TEXT OF H-STATEMENTS: H302: HARMFUL IF SWALLOWED. H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD. H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF SWALLOWED. SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET VALVOLINE INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN PREPARED BY VALVOLINE'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT (1-800-VALVOLINE). LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE, USED IN THIS SAFETY DATA SHEET: ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS BEI: BIOLOGICAL EXPOSURE INDEX CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY). CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION FG: FOOD GRADE GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS. H-STATEMENT: HAZARD STATEMENT IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION. IATA-DGR: DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT ASSOCIATION" (IATA). ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION ICAO-TI (ICAO): TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION" IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION. ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE ECXX: EFFECTIVE CONCENTRATION OF XX N.O.S.: NOT OTHERWISE SPECIFIED OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT OEL: OCCUPATIONAL EXPOSURE LIMIT P-STATEMENT: PRECAUTIONARY STATEMENT PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC PPE: PERSONAL PROTECTIVE EQUIPMENT STEL: SHORT-TERM EXPOSURE LIMIT STOT: SPECIFIC TARGET ORGAN TOXICITY TLV: THRESHOLD LIMIT VALUE TWA: TIME-WEIGHTED AVERAGE VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE WEL: WORKPLACE EXPOSURE LEVEL CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT DOT: DEPARTMENT OF TRANSPORTATION FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM NFPA: NATIONAL FIRE PROTECTION ASSOCIATION NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY RTK: RIGHT TO KNOW WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM |