| Common Name: | HANDI-FOAM HIGH DENSITY, HANDI-FOAM HIGH DENSITY |
| Manufacturer: | ICP ADHESIVES & SEALANTS |
| SDS Revision Date: | 9/12/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 458J57, 603H56, 603H57 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ICP ADHESIVES & SEALANTS
SAFETY DATA SHEET
LOW PRESSURE POLYURETHANE FOAM
A-SIDE COMPONENT HD (HFO)
| SECTION 1 - IDENTIFICATION |  |
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME: HANDI-FOAM HIGH DENSITY
ID SDS: A16179A
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
GENERAL USE:
LOW PRESSURE POLYURETHANE FOAM, SIDE-A COMPONENT, FOR PROFESSIONAL USE ONLY
USES ADVISED AGAINST: NO FURTHER INFORMATION AVAILABLE
1.3 DETAILS OF THE SUPPLIER AND OF THE SAFETY DATA SHEET:
MANUFACTURER:
ICP ADHESIVES & SEALANTS
2775 BARBER ROAD
NORTON, OHIO 44203
IN OHIO:
330-753-4585; 1-800-321-5585 (MONDAY-FRIDAY, 8:00 AM - 5:00 PM EST)
1.4 EMERGENCY TELEPHONE NUMBERS:
IN THE U.S.A:
CHEMTEL (24 HOURS): 1-800-255-3924
INTERNATIONAL:
CHEMTEL (24 HOURS): 1-813-248-0585
| SECTION 2 - HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF SUBSTANCE OR MIXTURE:
PRODUCT DEFINITION: MIXTURE
CLASSIFICATION:
SKIN IRRITATION: CATEGORY 2
SKIN SENSITIZATION: CATEGORY 1
EYE IRRITATION: CATEGORY 2A
ACUTE TOXICITY INHALATION: CATEGORY 4
RESPIRATORY SENSITIZING: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 3 (STOT SE 3)
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2 (STOT RE 2)
2.2 LABEL ELEMENTS:
HAZARD SYMBOLS:
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H319: CAUSES SERIOUS EYE IRRITATION
H332: HARMFUL IF INHALED
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
PREVENTION:
P102: KEEP OUT OF REACH OF CHILDREN
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOR/SPRAY
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING
P264:
WASH HANDS AND OTHER SKIN AREAS EXPOSED TO MATERIAL THOROUGHLY AFTER
HANDLING
P271: USE OUTDOORS OR IN A WELL-VENTILATED AREA
P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING AND EYE PROTECTION
P284: WEAR RESPIRATORY PROTECTION
RESPONSE:
P302+P352+P333+P313:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE.
P314: GET MEDICAL ATTENTION IF YOU FEEL UNWELL
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER OR DOCTOR.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE:
P405: STORE LOCKED UP
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
P501
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS OTHERWISE CLASSIFIED THAT HAVE BEEN IDENTIFIED.
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES: NOT APPLICABLE
3.2 MIXTURES:
CHEMICAL CHARACTERIZATION (PREPARATION):
% BY WEIGHT INGREDIENT CAS NO.
30-60 4,4' DIPHENYLMETHANE DIISOCYANATE 101-68-8
30-60 POLYMETHYLENE POLYPHENYL ISOCYANATE 9016-87-9
<10 NITROGEN 7727-37-9
5-10 TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE 29118-24-9
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO THE HEALTH OR THE ENVIRONMENT AND HENCE
REQUIRE REPORTING IN THIS SECTION.
| SECTION 4 - FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF PRODUCT VAPORS CAUSES RESPIRATORY IRRITATION OR DISTRESS, MOVE THE
EXPOSED PERSON TO FRESH AIR IMMEDIATELY. IF BREATHING IS DIFFICULT OR
IRREGULAR, ADMINISTER OXYGEN. IF RESPIRATORY ARREST OCCURS, START
ARTIFICIAL RESPIRATION BY A TRAINED INDIVIDUAL. LOOSEN TIGHT FITTING
CLOTHING SUCH AS A JACKET OR TIE. SEEK MEDICAL ATTENTION IMMEDIATELY.
ASTHMATIC SYMPTOMS MAY DEVELOP AND MAY BE IMMEDIATE OR DELAYED UP TO
SEVERAL HOURS. EXTREME ASTHMATIC REACTIONS CAN BE LIFE THREATENING.
PERSONS RECEIVING SIGNIFICANT EXPOSURE SHOULD BE OBSERVED FOR 24-48
HOURS FOR SIGNS OF RESPIRATORY DISTRESS.
EYE:
IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES,
HOLDING THE EYES OPEN WITH FINGERS AND OCCASIONALLY LIFTING THE UPPER AND
LOWER LIDS. USE LUKEWARM WATER IF POSSIBLE. IF PRESENT AND EASY TO DO,
REMOVE CONTACT LENSES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
SKIN:
FLUSH SKIN WITH LARGE AMOUNTS OF WATER WHILE REMOVING CONTAMINATED
CLOTHING. GENTLY WIPE PRODUCT FROM SKIN WITH A DAMP CLOTH AND CONTINUE
RINSING FOR 15 MINUTES. WASH CLOTHING BEFORE REUSE. CALL A PHYSICIAN IF
IRRITATION PERSISTS.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET
MEDICAL ADVICE/ATTENTION.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3 NOTES TO THE PHYSICIAN:
IF CASE OF AN ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW LABEL OR SDS IF POSSIBLE). EPINEPHRINE AND OTHER
SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN PERSONS EXPOSED
TO HIGH PROPELLANT CONCENTRATIONS (ENCLOSED SPACES OR WITH DELIBERATE
ABUSE). THE USE OF OTHER DRUGS WITH LESS ARRHYTHMOGENIC POTENTIAL SHOULD BE
CONSIDERED. IF SYMPATHOMIMETIC DRUGS ARE ADMINISTERED, OBSERVE VICTIM FOR
THE DEVELOPMENT OF CARDIAC ARRHYTHMIAS.
| SECTION 5 - FIRE FIGHTING MEASURES | |
5.1 EXTINGUISHABLE MEDIA:
SUITABLE METHODS OF EXTINCTION:
USE DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL RESISTANT FOAMS AND WATER SPRAY
UNSUITABLE METHODS OF EXTINCTION: NONE
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CANS, CYLINDERS, OR REFILLABLE CYLINDERS MAY EXPLODE DUE TO THE BUILDUP OF
PRESSURE WHEN EXPOSED TO EXTREME HEAT. DURING A FIRE, ISOCYANATE VAPORS OR
OTHER IRRITATING, HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL
DECOMPOSITION OR COMBUSTION. OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT OR MAY BE
DELAYED. HAZARDOUS DECOMPOSITION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED
TO: NITROGEN OXIDES, HYDROGEN CYANIDE, CARBON MONOXIDE, AND CARBON DIOXIDE.
5.3 ADVICE FOR FIREFIGHTERS:
KEEP UPWIND OF FIRE. WEAR FULL FIRE-FIGHTING TURN-OUT GEAR (FULL BUNKER
GEAR) AND RESPIRATORY PROTECTION (SCBA). USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PERSONAL PROTECTIVE EQUIPMENT RECOMMENDED IN SECTION 8. ISOLATE THE
HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ELIMINATE SOURCES OF IGNITION. VENTILATE THE AREA.
6.2 ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL OR RUN-OFF AND PREVENT CONTACT WITH
SOIL AND ENTRY INTO DRAINS, SEWERS OR WATERWAYS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
COVER DRAINS AND CONTAIN SPILL. COVER SPILLED MATERIAL WITH A LARGE
QUANTITY OF INERT ABSORBENT. COLLECT MATERIAL AND PLACE INTO AN APPROVED,
OPEN-HEAD METAL CONTAINER. DECONTAMINATE THE SPILL AND WASTE AREA WITH A
NEUTRALIZATION SOLUTION. WAIT 15 MINUTES. REPEAT APPLICATIONS OF
DECONTAMINATION SOLUTION, WITH SCRUBBING, FOLLOWED BY ABSORBENT UNTIL THE
SURFACE IS DECONTAMINATED. ALLOW CONTAINER TO VENT FOR 72 HOURS TO LET
CARBON DIOXIDE ESCAPE. DISPOSE OF WASTE VIA A LICENSED WASTE DISPOSAL
CONTRACTOR IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, PROVINCIAL
AND LOCAL REGULATIONS. ENSURE ADEQUATE VENTILATION.
ADDITIONAL SPILL PROCEDURES-NEUTRALIZATION SOLUTIONS (DECONTAMINATION):
USE TEN PARTS OF SOLUTION FOR EACH PART OF THE SPILL.
(1) AN AQUEOUS SOLUTION CONTAINING 3-8% AMMONIUM HYDROXIDE OR CONCENTRATED
AMMONIA AND 0.2-0.5% LIQUID DETERGENT
(2) AN AQUEOUS SOLUTION CONTAINING 5-10% SODIUM BICARBONATE AND 0.2-0.5%
LIQUID DETERGENT
6.4 REFERENCE TO OTHER SECTIONS:
FOR INDICATIONS ABOUT WASTE TREATMENT AND DISPOSAL, SEE SECTION 13
SEE SECTION 7 FOR INFORMATION ABOUT SAFE HANDLING
| SECTION 7 - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. OBSERVE LABEL PRECAUTIONS, DO
NOT USE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY DURING APPLICATION. USE
ADEQUATE VENTILATION TO KEEP AIRBORNE ISOCYANATE LEVELS BELOW EXPOSURE
LIMITS. RECOMMEND WEARING RESPIRATORY PROTECTION WHEN SPRAYING THIS
MATERIAL. WARNING SYMPTOMS (IRRITATION OF THE EYES, NOSE, OR THROAT, OR
ODOR) ARE NOT ADEQUATE TO PREVENT OVEREXPOSURE FROM INHALATION. INDIVIDUALS
WITH LUNG OR BREATHING PROBLEMS OR PRIOR ALLERGIC REACTIONS TO ISOCYANATES
MUST NOT BE EXPOSED. AVOID CONTACT WITH SKIN OR EYES. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT DURING USE (SEE SECTION 8). WASH THOROUGHLY
AFTER HANDING PRODUCT. DO NOT PUNCTURE OR INCINERATE CYLINDERS. CONTAINERS
ARE UNDER PRESSURE. KEEP CONTAINERS CLOSED WHEN NOT IN USE.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
CONTENTS UNDER PRESSURE. EXPOSURE TO HIGH TEMPERATURES CAN CAUSE CONTAINERS
TO RUPTURE OR EXPLODE.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A DRY, WELL-VENTILATED AREA AND AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10.5). STORAGE TEMPERATURE IS 60-90 DEG. F (16-32 DEG. C).
PRODUCTS STORED BELOW 60 DEG. F (16 DEG. C) OR ABOVE 90 DEG. F (32 DEG. C)
MUST BE GIVEN ADEQUATE TIME TO WARM UP/COOL DOWN. DO NOT EXPOSE THE
CYLINDERS TO OPEN FLAME OR TEMPERATURES ABOVE 122 DEG. F (50 DEG. C);
STORAGE AT ELEVATED TEMPERATURES CAN CAUSE THE CONTAINER TO RUPTURE.
EXCESSIVE HEAT CAN CAUSE PREMATURE AGING OF COMPONENTS RESULTING IN A
SHORTER SHELF LIFE. PROTECT UNUSED PRODUCT FROM FREEZING. STORAGE BELOW 60
DEG. F (16 DEG. C) MAY AFFECT FOAM QUALITY IF CHEMICALS ARE NOT WARMED TO
ROOM TEMPERATURE BEFORE USING. PROTECT CONTAINERS FROM PHYSICAL ABUSE.
ALWAYS STORE THE CYLINDERS IN THE UPRIGHT POSITION. KEEP OUT OF REACH OF
CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
INGREDIENT CAS NUMBER OSHA-PEL ACGIH-TLV OTHER
4,4' DIPHENYLMETHANE 101-68-8 0.2 MG/M3; 0.051 MG/M3; NIOSH-0.2
DIISOCYANATE 0.02 PPM 0.005 PPM MG/M3;
CEIL (8 HOURS TWA) 0.02 PPM CEIL
0.051 MG/M3;
0.005 PPM TWA
TRANS-1,3,3,3- 471-480-0 WEEL 800 PPM
TETRAFLUOROPROP-
1-ENE
8.2 EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE LOCAL AND GENERAL EXHAUST VENTILATION TO CONTROL LEVELS OF EXPOSURE.
EYE/FACE PROTECTION:
WEAR PROTECTIVE GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
HAND PROTECTION:
USE CHEMICALLY RESISTANT GLOVES (I.E. NITRILE GLOVES). NITRILE/BUTADIENE
RUBBER, BUTYL RUBBER, POLYETHYLENE, PVC (VINYL), OR NEOPRENE GLOVES ARE
ALSO EFFECTIVE. GLOVE SELECTION SHOULD TAKE INTO ACCOUNT POTENTIAL BODY
REACTIONS TO CERTAIN MATERIALS AND MANUFACTURER'S INSTRUCTIONS FOR USE.
BREAK THROUGH TIME OF SELECTED GLOVES MUST BE GREATER THAN THE INTENDED
USE PERIOD.
OTHER PROTECTIVE EQUIPMENT:
USE CLOTHING THAT PROTECTS AGAINST DERMAL EXPOSURE. APPROPRIATE PROTECTIVE
CLOTHING VARIES DEPENDING ON THE POTENTIAL FOR EXPOSURE. TO ENSURE PROPER
SKIN PROTECTION, WEAR PPE IN SUCH A MANNER THAT NO SKIN IS EXPOSED.
RESPIRATORY PROTECTION:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINES. USE
PRODUCTS ONLY IN A WELL-VENTILATED AREA. ENGINEERING AND ADMINISTRATIVE
(WORK PRACTICES) CONTROLS SHOULD BE IMPLEMENTED TO PROTECT THE WORKERS. IF
ATMOSPHERIC LEVELS ARE EXPECTED TO EXCEED THE EXPOSURE LEVELS, USE A NIOSH
APPROVED AIR PURIFYING RESPIRATOR EQUIPPED WITH AN ORGANIC VAPOR CARTRIDGE
AND A PARTICULATE FILTER. IF ATMOSPHERIC LEVELS EXCEED 10 TIMES THE TLV OR
PEL LEVEL FOR WHICH AN AIR-PURIFYING RESPIRATOR IS EFFECTIVE, USE A POWERED
AIR PURIFYING RESPIRATOR (PAPR). THE TYPE OF RESPIRATORY PROTECTION
SELECTED MUST COMPLY WITH THE REQUIREMENTS SET FORTH IN OSHA'S RESPIRATORY
PROTECTION STANDARD (29 CFR 1910.134). THE ODOR AND IRRITANCY OF THIS
MATERIAL IS INADEQUATE TO WARN OF EXCESSIVE EXPOSURE.
HYGIENE MEASURES:
AN EYE WASH STATION OR PORTABLE EYE WASH STATION SHOULD BE IN THE AREA.
WASH HANDS THOROUGHLY AFTER USE, BEFORE EATING, DRINKING OR USING THE
LAVATORY. EMPLOYEES/USERS SHOULD BE EDUCATED AND TRAINED IN THE SAFE USE
AND HANDLING OF THIS PRODUCT.
MEDICAL SURVEILLANCE:
ALL EMPLOYEES/END-USERS WHO WORK WITH ISOCYANATES SHOULD UNDERGO A MEDICAL
EVALUATION. A HISTORY OF ECZEMA OR RESPIRATORY ALLERGIES ARE POSSIBLE
REASONS FOR MEDICAL EXCLUSION FROM WORKING WITH ISOCYANATES. USERS WITH A
PRIOR HISTORY OF ISOCYANATE SENSITIZATION SHOULD BE EXCLUDED FROM FURTHER
WORK WITH ISOCYANATES. ONCE A USER IS DIAGNOSED WITH BEING SENSITIZED TO
ISOCYANATES, NO FURTHER EXPOSURE SHOULD BE PERMITTED.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM:
AMBER TO DARK BROWN LIQUID. FORMS AN OFF-WHITE TO YELLOWISH FROTH WHEN
RELEASED FROM THE CONTAINER
ODOR: SLIGHTLY MUSTY
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE:
MDI BOILS AT 406 DEG. F (208 DEG. C), HFO-1234ZE BOILS AT -19 DEG. C
(-2.2 DEG. F)
FLASH POINT:
MDI 399 DEG. F (>204 DEG. C) CLOSED CUP, HFO-1234ZE DOES NOT FLASH
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY: NO APPLICABLE
LOWER FLAMMABILITY/EXPLOSIVE LIMIT: NOT AVAILABLE
UPPER FLAMMABILITY/EXPLOSIVE LIMIT: NOT AVAILABLE
VAPOR PRESSURE IN CONTAINER:
CONTENTS UNDER PRESSURE HAVE A VAPOR PRESSURE >50 PSI (>345KPA)
VAPOR PRESSURE OF LIQUID:
LIQUID PHASE VAPOR PRESSURE: <1 MMHg @ 40 DEG. C
VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY/SPECIFIC GRAVITY: APPROX. 1.2 @ 25 DEG. C (WATER = 1)
SOLUBILITY:
INSOLUBLE; REACTS SLOWLY WITH WATER DURING CURE, LIBERATING TRACES OF CO2
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NOT AVAILABLE
VOC CONTENT (CALCULATED MINUS EXEMPT COMPOUNDS): 0 G/L
| SECTION 10 - STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF USE AND RECOMMENDED STORAGE CONDITIONS.
SEE SECTION 7 FOR STORAGE RECOMMENDATIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
EXPOSURE TO ELEVATED TEMPERATURES CAN CAUSE CONTAINERS TO RUPTURE OR
EXPLODE. AVOID MOISTURE, MATERIAL REACTS SLOWLY WITH WATER RELEASING CARBON
DIOXIDE. CONTENTS ARE UNDER PRESSURE.
10.4 CONDITIONS TO AVOID:
TEMPERATURES BELOW 60 DEG. F (16 DEG. C) OR TEMPERATURES ABOVE 90 DEG. F
(32 DEG. C). AVOID HEAT AND FLAMES.
10.5 INCOMPATIBLE MATERIALS:
ALCOHOLS, STRONG BASES, AMINES, METAL COMPOUNDS, AMMONIA, AND STRONG
OXIDIZERS. AVOID CONTAMINATION WITH WATER.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
SEE SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS RELATED TO COMBUSTION.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE BASED ON TEST DATA AND/OR INFORMATION ON
THE COMPONENTS, THIS MATERIAL MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
ISOCYANATES VAPORS AT CONCENTRATIONS ABOVE THE CONCENTRATION LIMITS OR
GUIDELINES CAN IRRITATE THE MUCOUS MEMBRANES IN THE RESPIRATORY TRACT WITH
SYMPTOMS OF BURNING SENSATION, RUNNY NOSE, SORE THROAT, COUGHING, CHEST
DISCOMFORT, SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION (DIFFICULTY
BREATHING). PERSONS WITH A PRE-EXISTING, NONSPECIFIC BRONCHIAL
HYPERACTIVITY CAN RESPOND TO CONCENTRATIONS BELOW THE EXPOSURE LIMITS OR
GUIDELINES WITH SIMILAR SYMPTOMS AS WELL AS ASTHMA ATTACK OR ASTHMA-LIKE
SYMPTOMS. EXPOSURE WELL ABOVE THE EXPOSURE LIMITS OR GUIDELINES MAY LEAD
TO BRONCHITIS, BRONCHIAL SPASM AND PULMONARY EDEMA (FLUID IN THE LUNGS).
CHEMICAL OR HYPERSENSITIVITY PNEUMONITIS, WITH FLU-LIKE SYMPTOMS HAS ALSO
BEEN REPORTED. THESE SYMPTOMS CAN BE DELAYED UP TO SEVERAL HOURS AFTER
EXPOSURE. THESE EFFECTS ARE USUALLY REVERSIBLE; HOWEVER, INCREASED LUNG
SENSITIVITY MAY PERSIST FOR A LONGER PERIOD OF TIME. MAY BE HARMFUL IF
INHALED. INHALATION OF THE PROPELLANT MAY CAUSE LIGHTHEADEDNESS, HEADACHE
AND LETHARGY.
EYE CONTACT:
MAY CAUSE EYE IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, SWELLING, STINGING,
AND TEARING. MAY CAUSE TEMPORARY CORNEAL INJURY. PRODUCT VAPOR MAY CAUSE
EYE IRRITATION WITH SYMPTOMS OF BURNING AND TEARING.
SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, EDEMA, DRYING,
DEFATTING AND CRACKING OF THE SKIN. MAY CAUSE AN ALLERGIC REACTION. CAN
CAUSE SENSITIZATION. PERSONS PREVIOUSLY SENSITIZED CAN EXPERIENCE ALLERGIC
SKIN REACTIONS. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE GASTROINTESTINAL IRRITATION: STOMACH
DISTRESS, NAUSEA, OR VOMITING.
ACUTE ORAL TOXICITY:
EXPECTED TO HAVE LOW ACUTE ORAL TOXICITY. 4,4'- DIPHENYLMETHANE
DIISOCYANATE: LD50, RAT >5000 MG/KG
ACUTE INHALATION TOXICITY:
AT ROOM TEMPERATURE, VAPORS ARE MINIMAL. SEE ABOVE FOR POSSIBLE EXPOSURES.
4,4'- DIPHENYLMETHANE DIISOCYANATE: LC50, RAT 490 MG/M3, 4H
ACUTE DERMAL TOXICITY:
EXPECTED TO HAVE A LOW ACUTE DERMAL TOXICITY. 4,4'- DIPHENYLMETHANE
DIISOCYANATE: LD50, RABBIT >5000 MG/KG
SKIN IRRITATION: CAUSES SKIN IRRITATION
EYE IRRITATION: CAUSES MODERATE TO SERIOUS EYE IRRITATION
SENSITIZATION: MAY CAUSE SKIN AND RESPIRATORY SENSITIZATION
GENOTOXICITY:
GENETIC TOXICITY DATA FOR MDI IS INCONCLUSIVE. SOME IN-VITRO STUDIES YIELD
POSITIVE RESULTS, WHILE OTHER TEST DATA WERE NEGATIVE
MUTAGENICITY: TEST DATA USING LABORATORY ANIMALS WAS PREDOMINATELY NEGATIVE
SPECIFIC ORGAN TOXICITY - SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION
SPECIFIC ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO THE LUNGS, CENTRAL NERVOUS SYSTEM AND SKIN
ASPIRATION HAZARD: NO DATA AVAILABLE
11.2 FURTHER INFORMATION:
MDI AND PMDI:
IARC GROUP 3 CARCINOGEN - NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO
HUMANS. NOT LISTED AS A CARCINOGEN BY ACGIH, OSHA OR NTP. MDI/PMDI DID NOT
CAUSE BIRTH DEFECTS IN LABORATORY ANIMALS; FETAL EFFECTS OCCURRED ONLY AT
HIGH DOSES WHICH WERE TOXIC TO THE MOTHER. LUNG TUMORS HAVE BEEN OBSERVED
IN LABORATORY ANIMALS EXPOSED TO RESPIRABLE AEROSOL DROPLETS OF MDI/PMDI
(6 MG/M3) FOR THEIR LIFETIME. TUMORS OCCURRED CONCURRENTLY WITH RESPIRATORY
IRRITATION AND LUNG INJURY. CURRENT EXPOSURE GUIDELINES ARE EXPECTED TO
PROTECT AGAINST THESE EFFECTS.
| SECTION 12 - ECOLOGICAL INFORMATION | |
12.1 ECOTOXICITY:
ECOTOXICOLOGICAL DATA REPORTED ARE FOR A COMPARABLE PRODUCT. THE
ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT GENERALLY UNDER CONDITIONS OF
MAXIMIZING PRODUCTION OF SOLUBLE SPECIES. THIS MATERIAL IS NOT CLASSIFIED
AS DANGEROUS TO AQUATIC ORGANISMS (LD50/EC50 GREATER THAN 100 MG/L IN THE
MOST SENSITIVE SPECIES).
ACUTE AND PROLONGED TOXICITY TO FISH:
LC50 - BRACHYDANIO RERIO (ZEBRA FISH), 96H: >1000 MG/L
TOXICITY TO AQUATIC INVERTEBRATES:
EC50 - DAPHNIA MAGNA (WATER FLEA) 48H: >1000 MG/L
TOXICITY TO AQUATIC PLANTS:
NOEC - DESMODESMUS SUBSPICATUS (GREEN ALGAE) STATIC, 72 H:
>1640 MG/L, GROWTH RATE INHIBITION
TOXICITY TO AQUATIC MICROBES:
OECD 209 TEST - ACTIVATED SLUDGE 3 H: >100 MG/L, RESPIRATION INHIBITION
TOXICITY TO SOIL DWELLING ORGANISMS:
EC50- EISENIA FETIDA (EARTHWORMS) 14 D: >1000 MG/KG
12.2 PERSISTENCE AND DEGRADABILITY:
PRODUCT IS NOT READILY BIODEGRADABLE. IN AQUATIC AND TERRESTRIAL
ENVIRONMENTS, THIS MATERIAL REACTS WITH WATER, FORMING PREDOMINANTLY
INSOLUBLE AND STABLE POLYUREAS. IN THE ATMOSPHERIC ENVIRONMENT, THIS
MATERIAL IS EXPECTED TO HAVE A SHORT TROPOSPHERIC HALF- LIFE, BASED
ON DATA FROM SIMILAR DIISOCYANATES.
12.3 BIOACCUMULATION POTENTIAL: BIOACCUMULATION POTENTIAL IS LOW.
12.4 MOBILITY:
EXPECTED TO HAVE LOW MOBILITY BASED ON PRODUCT'S REACTIVITY WITH WATER,
WHICH FORMS PREDOMINATELY INSOLUBLE POLYUREAS.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
12.6 OTHER ADVERSE EFFECTS:
ADDITIONAL ECOLOGICAL INFORMATION:
DO NOT ALLOW MATERIAL TO RUN INTO SURFACE WATERS, WASTEWATER, OR SOIL.
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
ALWAYS WEAR PROPER PROTECTIVE EQUIPMENT AS YOU WOULD WHILE SPRAYING THE
TWO-COMPONENT FOAM IN A WELL-VENTILATED AREA.
PROCEDURE FOR HANDLING EMPTY OR PARTIALLY USED DISPOSABLE CYLINDERS
(NOT RETURNABLE):
1. DO NOT INCINERATE CYLINDERS.
2. EMPTY CYLINDERS BY DISPENSING THE FOAM INTO A WASTE CONTAINER LIKE A
CARDBOARD BOX OR PLASTIC BAG. DEPRESSURIZE THE USED CYLINDERS USING THE
DISPENSING UNIT WITH A NEW NOZZLE ATTACHED. SPRAY THE FOAM UNTIL ONE OF
THE COMPONENTS/CYLINDERS NO LONGER SPRAYS CHEMICAL.
3. REMOVE THE NOZZLE AND THEN CONTINUE TO DEPRESSURIZE BY DISPENSING THE
REMAINING CHEMICAL(S) INTO A WASTE CONTAINER (A BOX LINED WITH A PLASTIC
BAG) THAT HAS ADEQUATE INDUSTRIAL LIQUID ABSORBING MEDIUM IN THE BOTTOM.
DISPENSE THE RESIDUAL CHEMICALS UNTIL THE PRESSURE IS DOWN TO A MINIMUM
OR THERE ARE JUST LARGE BUBBLES IN THE HOSE.
4. CLOSE THE CYLINDER VALVES COMPLETELY, AND THEN OPERATE THE DISPENSING
UNIT AGAIN TO EMPTY AND DEPRESSURIZE THE HOSES. USE A 9/16" WRENCH AND
REMOVE THE HOSES FROM THE CYLINDERS. USE CAUTION IN CASE THERE IS SOME
RESIDUAL CHEMICAL AND/OR PRESSURE IN THE HOSES.
5. INVERT THE CYLINDER AND POINT AWAY FROM FACE. SLOWLY OPEN THE CYLINDER
OVER THE WASTE CONTAINER TO CATCH ANY RESIDUAL SPRAY.
6. RETURN THE CYLINDER TO AN UPRIGHT POSITION. SHAKE THE CONTAINER; THERE
SHOULD NOT BE ANY SLOSHING OF LIQUID. MAKE SURE TO LEAVE VALVES OPEN-DO NOT
CLOSE.
7. THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF EMPTY
CYLINDERS, UNUSED MATERIAL AND RESIDUES IN COMPLIANCE TO ALL APPLICABLE
FEDERAL, STATE, INTERNATIONAL AND LOCAL REGULATIONS REGARDING THE
TREATMENT, STORAGE, AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.
CHECK WITH YOUR LOCAL WASTE DISPOSAL SERVICE FOR GUIDANCE.
NOTE:
AFTER DISPENSING IF ONE CYLINDER HAS CHEMICAL LEFT IN IT; TREAT AS
HAZARDOUS MATERIAL.
| SECTION 14 - TRANSPORTATION | |
NOTE:
TRANSPORTATION INFORMATION IS FOR REFERENCE ONLY. CUSTOMER IS URGED TO
CONSULT 49 CFR 100-177, IMDG, IATA, EC, UNITED NATIONS TDG AND WHMIS
(CANADA) TDG INFORMATION MANUALS FOR DETAILED REGULATIONS AND EXCEPTIONS
COVERING SPECIFIC CONTAINER SIZES, PACKAGING MATERIALS AND METHODS OF
SHIPPING.
CONTAINERS GREATER THAN 1000 CU. CM. (1 LITER)
GROUND UN3500 CHEMICAL UNDER PRESSURE N.O.S. (HYDROFLUOROOLEFIN, NITROGEN)
2.2 (NON-FLAMMABLE GAS LABEL)
AIR UN3500 CHEMICAL UNDER PRESSURE N.O.S. (HYDROFLUOROOLEFIN, NITROGEN)
2.2 (NON-FLAMMABLE GAS LABEL)
PACKING INSTRUCTION (CARGO & PASSENGER) 218
WATER UN3500 CHEMICAL UNDER PRESSURE N.O.S. (HYDROFLUOROOLEFIN, NITROGEN)
2.2 (NON-FLAMMABLE GAS LABEL)
| SECTION 15 - REGULATORY | |
15.1 SAFETY, HEALTH, AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC
FOR THE SUBSTANCE OR MIXTURE:
U.S. FEDERAL REGULATIONS:
OSHA HAZARD COMMUNICATION STANDARD:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS IN ACCORDANCE WITH OSHA 29 CFR
1910-1200
TSCA STATUS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TOXIC SUBSTANCE CONTROL
ACT (TSCA) INVENTORY. THIS PRODUCT IS NOT SUBJECT TO TSCA 12(B) EXPORT
NOTIFICATION.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA):
SARA SECTION 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD, SUDDEN RELEASE OF PRESSURE
HAZARD
SARA 313 INFORMATION:
MDI AND PMDI ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY SECTION 313 OF
THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986.
SARA 302/304 EXTREMELY HAZARDOUS SUBSTANCE:
NO COMPONENTS OF THE PRODUCT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING
LEVELS ESTABLISHED BY THESE SECTIONS OF THE TITLE III OF SARA.
SARA 302/304 EMERGENCY PLANNING & NOTIFICATION:
NO COMPONENTS OF THE PRODUCT EXCEED THE THRESHOLD (DE MINIMIS) REPORT
LEVELS ESTABLISHED BY THESE SECTIONS OF THE TITLE III OF SARA.
COMPREHENSIVE RESPONSE COMPENSATION AND LIABILITY ACT (CERCLA):
THIS PRODUCT CONTAINS THE FOLLOWING CERCLA REPORTABLE SUBSTANCES:
4,4'- DIPHENYLMETHANE DIISOCYANATE (CAS #101-68-8), RQ- 2,268 KG (5,000
LBS).
CLEAN AIR ACT (CAA):
4,4'- DIPHENYLMETHANE DIISOCYANATE (CAS #101-68-8) IS LISTED AS A HAZARDOUS
AIR POLLUTANT (HAP) DESIGNATED IN CAA SECTION 112 (B). THIS PRODUCT DOES
NOT CONTAIN ANY CLASS 1 OR CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT (CWA):
4,4'- DIPHENYLMETHANE DIISOCYANATE (CAS #101-68-8) IS LISTED AS A HAZARDOUS
SUBSTANCE UNDER THE CWA. NONE OF THE CHEMICALS IN THESE PRODUCTS ARE
LISTED AS PRIORITY POLLUTANTS UNDER THE CWA. NONE OF THE CHEMICALS LISTED
IN THESE PRODUCTS ARE LISTED AS TOXIC POLLUTANTS UNDER THE CWA.
U.S. STATE REGULATIONS:
CALIFORNIA PROP 65, SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986:
NONE OF THE CHEMICALS ARE LISTED.
OTHER U.S. STATE INVENTORIES:
4, 4'- DIPHENYLMETHANE DIISOCYANATE (CAS #101-68-8) IS LISTED ON THE
FOLLOWING STATE HAZARDOUS SUBSTANCE INVENTORIES, RIGHT- TO-KNOW LISTS
AND/OR AIR QUALITY/AIR POLLUTANTS LISTS:
CA, DE, ID, IL, ME, MA, MN, NJ, PA, WA, WI
POLYMERIC MDI (CAS #9016-87-9) IS LISTED ON THE FOLLOWING STATE HAZARDOUS
SUBSTANCE INVENTORIES, RIGHT-TO-KNOW LISTS AND/OR AIR QUALITY/AIR
POLLUTANTS LISTS: DE, NJ, MN
1,1,1,2- TETRAFLUOROETHANE (CAS #811-97-2) IS LISTED ON THE FOLLOWING STATE
HAZARDOUS SUBSTANCE INVENTORIES, RIGHT-TO-KNOW LISTS AND/OR AIR QUALITY/AIR
POLLUTANTS LISTS: ME, WI
CANADIAN INGREDIENT DISCLOSURE LIST (IDL):
4,4'- DIPHENYLMETHANE DIISOCYANATE (CAS #101-68-8) IS LISTED ON THE IDL.
CANADIAN NATIONAL POLLUTANT RELEASE INVENTORY (NPRI):
MDI AND PMDI ARE LISTED ON THE NPRI
WGK, GERMANY (WATER DANGER/PROTECTION): 1
GLOBAL CHEMICAL INVENTORY LISTS:
UNITED STATES:
TOXIC SUBSTANCE CONTROL ACT (TSCA): YES
CANADA:
DOMESTIC SUBSTANCES LIST (DSL): YES
CANADA:
NON-DOMESTIC SUBSTANCES LIST (NDSL): NO
15.2 CHEMICAL SAFETY ASSESSMENT:
FOR THIS PRODUCT A CHEMICAL SAFETY ASSESSMENT WAS NOT CARRIED OUT
| SECTION 16 - OTHER | |
SAFETY GLASSES
LAB COAT
GLOVES
VAPOR RESPIRATOR
FAN
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 1
REACTIVITY 1
HMIS:
HEALTH HAZARD 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
HAZARD RATING:
0=MINIMAL
1=SLIGHT
2=MODERATE
3=SEVERE
4=EXTREME
ABBREVIATIONS AND ACRONYMS:
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS
BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN IRRITATION: CATEGORY 2
SKIN SENSITIZATION: CATEGORY 1
EYE IRRITATION: CATEGORY 2B
ACUTE TOXICITY INHALATION: CATEGORY 4
RESPIRATORY SENSITIZING: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 3 (STOT SE 3)
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE:
CATEGORY 2 (STOT RE 2) - INHALATION
SPF - SPRAY POLYURETHANE FOAM
THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE PRESENTED IN GOOD
FAITH AND BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. THE MANUFACTURER
MAKES NO REPRESENTATIONS AS TO THE COMPLETENESS OR ACCURACY THEREOF.
INFORMATION IS SUPPLIED UPON THE CONDITION THAT THE PERSONS RECEIVING IT
WILL MAKE THEIR OWN DETERMINATION AS TO ITS SUITABILITY FOR THEIR PURPOSES
PRIOR TO USE. IN NO EVENT WILL THE MANUFACTURER BE RESPONSIBLE FOR DAMAGES
OF ANY NATURE WHATSOEVER RESULTING FROM THE USE OF OR RELIANCE UPON
INFORMATION. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED,
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE ARE MADE HEREUNDER WITH
RESPECT TO THIS INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.
INFORMATION CONTAINED HEREIN IS DEEMED TO BE RELIABLE, CONSERVATIVE AND
ACCURATE. ICP ADHESIVES & SEALANTS, INC. RESERVES THE RIGHT TO CHANGE THE
DESIGN, SPECIFICATIONS OR ANY OTHER FEATURES AT ANY TIME AND WITHOUT
NOTICE, WHILE OTHERWISE MAINTAINING REGULATORY COMPLIANCE.
REVISION: SEPTEMBER 12, 2018 (DATE OF PREPARATION)
VERSION: 3.2
REPLACES: FEBRUARY 15, 2018
VERSION: 3.1
LOW PRESSURE SPF SIDE A HD (HFO)
ISSUE DATE: DECEMBER 2015
LAST REV: SEPTEMBER 2018
ICP ADHESIVES & SEALANTS
SAFETY DATA SHEET
LOW PRESSURE POLYURETHANE FOAM
B-SIDE COMPONENT HD (HFO)
| SECTION 1 - IDENTIFICATION | |
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME: HANDI-FOAM HIGH DENSITY
ID SDS: A16179B
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
GENERAL USE:
LOW PRESSURE POLYURETHANE FOAM, SIDE-B COMPONENT, FOR PROFESSIONAL USE ONLY
USES ADVISED AGAINST: NO FURTHER INFORMATION AVAILABLE
1.3 DETAILS OF THE SUPPLIER AND OF THE SAFETY DATA SHEET:
MANUFACTURER:
ICP ADHESIVES & SEALANTS, INC.
2775 BARBER ROAD
NORTON, OHIO 44203
IN OHIO:
330-753-4585; 1-800-321-5585 (MONDAY-FRIDAY, 8:00 AM - 5:00 PM EST)
1.4 EMERGENCY TELEPHONE NUMBERS:
IN THE U.S.A:
CHEMTEL (24 HOURS): 1-800-255-3924
INTERNATIONAL:
CHEMTEL (24 HOURS): 1-813-248-0585
| SECTION 2 - HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF SUBSTANCE OR MIXTURE:
PRODUCT DEFINITION: MIXTURE
CLASSIFICATION:
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2 (STOT RE 2)
2.2 LABEL ELEMENTS:
HAZARD SYMBOLS:
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
PREVENTION:
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P260: DO NOT BREATHE MIST/VAPORS/SPRAY
P264:
WASH HANDS AND OTHER SKIN AREAS EXPOSED TO MATERIAL THOROUGHLY AFTER
HANDLING
P271: USE OUTDOORS OR IN A WELL-VENTILATED AREA
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING AND EYE PROTECTION
P285:
IN CASE OF INADEQUATE VENTILATION: WEAR RESPIRATORY PROTECTION
RESPONSE:
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P321:
SPECIFIC TREATMENT:
SEEK IMMEDIATE MEDICAL ADVICE. REFER TO PRODUCT LABEL AND SECTION 4 OF THIS
SDS
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE:
P405: STORE LOCKED UP
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
| SECTION 3 - COMPOSITION/ INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES: NOT APPLICABLE
3.2 MIXTURES:
CHEMICAL CHARACTERIZATION (PREPARATION):
% BY WEIGHT INGREDIENT CAS NO.
20-40 TRIS (1-CHLORO-2-PROPYL) PHOSPHATE 13674-84-5
10-20 (1E)- 1,3,3,3-TETRAFLUORO-1-PROPENE 29118-24-9
<10% 2,2'OXYBISETHANOL 111-46-6
<10% NITROGEN 7727-37-9
<3% N-CYCLOHEXYL-N-METHYLCYCLOHEXYLAMINE 7560-83-0
<1% ETHYLENE GLYCOL 107-21-1
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO THE HEALTH OR THE ENVIRONMENT AND HENCE
REQUIRE REPORTING IN THIS SECTION.
| SECTION 4 - FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF PRODUCT VAPORS CAUSES RESPIRATORY IRRITATION OR DISTRESS, MOVE THE
EXPOSED PERSON TO FRESH AIR IMMEDIATELY. IF BREATHING IS DIFFICULT OR
IRREGULAR, ADMINISTER OXYGEN. IF RESPIRATORY ARREST OCCURS, START
ARTIFICIAL RESPIRATION BY A TRAINED INDIVIDUAL. LOOSEN TIGHT FITTING
CLOTHING SUCH AS A JACKET OR TIE. SEEK MEDICAL ATTENTION IMMEDIATELY.
EYE:
IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES,
HOLDING THE EYES OPEN WITH FINGERS AND OCCASIONALLY LIFTING THE UPPER AND
LOWER LIDS. USE LUKEWARM WATER IF POSSIBLE. IF PRESENT AND EASY TO DO,
REMOVE CONTACT LENSES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
SKIN:
FLUSH SKIN WITH LARGE AMOUNTS OF WATER WHILE REMOVING CONTAMINATED
CLOTHING. GENTLY WIPE PRODUCT FROM SKIN WITH A DAMP CLOTH AND CONTINUE
RINSING FOR 15 MINUTES. WASH CLOTHING BEFORE REUSE. CALL A PHYSICIAN IF
IRRITATION PERSISTS.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET
MEDICAL ADVICE/ATTENTION.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS
4.3 NOTES TO THE PHYSICIAN:
IF CASE OF AN ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW LABEL OR SDS IF POSSIBLE). EPINEPHRINE AND OTHER
SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN PERSONS EXPOSED
TO HIGH PROPELLANT CONCENTRATIONS (ENCLOSED SPACES OR WITH DELIBERATE
ABUSE). THE USE OF OTHER DRUGS WITH LESS ARRHYTHMOGENIC POTENTIAL SHOULD BE
CONSIDERED. IF SYMPATHOMIMETIC DRUGS ARE ADMINISTERED, OBSERVE VICTIM FOR
THE DEVELOPMENT OF CARDIAC ARRHYTHMIAS.
| SECTION 5 - FIRE FIGHTING MEASURES | |
5.1 EXTINGUISHABLE MEDIA:
SUITABLE METHODS OF EXTINCTION:
USE DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL RESISTANT FOAMS AND WATER SPRAY
UNSUITABLE METHODS OF EXTINCTION: NONE
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CANS, CYLINDERS, OR REFILLABLE CYLINDERS MAY EXPLODE DUE TO THE BUILDUP OF
PRESSURE WHEN EXPOSED TO EXTREME HEAT. HIGHLY TOXIC GASES MAY BE GENERATED
BY THERMAL DECOMPOSITION OR COMBUSTION. OVEREXPOSURE TO DECOMPOSITION
PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY
APPARENT OR MAY BE DELAYED. HAZARDOUS DECOMPOSITION PRODUCTS MAY INCLUDE
AND ARE NOT LIMITED TO: CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES, OXIDES
OF NITROGEN.
5.3 ADVICE FOR FIREFIGHTERS:
KEEP UPWIND OF FIRE. WEAR FULL FIRE-FIGHTING TURN-OUT GEAR (FULL BUNKER
GEAR) AND RESPIRATORY PROTECTION (SCBA). USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PERSONAL PROTECTIVE EQUIPMENT RECOMMENDED IN SECTION 8. ISOLATE THE
HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ELIMINATE SOURCES OF IGNITION. VENTILATE THE AREA.
6.2 ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL OR RUN-OFF AND PREVENT CONTACT WITH
SOIL AND ENTRY INTO DRAINS, SEWERS OR WATERWAYS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
COVER DRAINS AND CONTAIN SPILL. COVER SPILLED MATERIAL WITH A LARGE
QUANTITY OF INERT ABSORBENT. COLLECT MATERIAL AND PLACE INTO AN APPROVED,
OPEN-HEAD METAL CONTAINER. CLEAN CONTAMINATED AREA WITH SOAP AND WATER.
6.4 REFERENCE TO OTHER SECTIONS:
FOR INDICATIONS ABOUT WASTE TREATMENT AND DISPOSAL, SEE SECTION 13
SEE SECTION 7 FOR INFORMATION ABOUT SAFE HANDLING
| SECTION 7 - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. OBSERVE LABEL PRECAUTIONS, DO NOT
USE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
WEAR ALL APPROPRIATE PROTECTIVE EQUIPMENT SPECIFIED IN SECTION 8. KEEP
CYLINDERS/VALVES CLOSED WHEN NOT IN USE. RECOMMEND USING IN A
WELL-VENTILATED AREA WITH RESPIRATORY PROTECTION. AVOID CONTACT WITH EYES
AND SKIN. KEEP OUT OF REACH OF CHILDREN.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
CHEMICALS UNDER PRESSURE. EXPOSURE TO HIGH TEMPERATURES CAN CAUSE
CONTAINERS TO RUPTURE OR EXPLODE.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A DRY, WELL-VENTILATED AREA AND AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10.5). STORAGE TEMPERATURE IS 60-90 DEG. F (16-32 DEG. C).
PRODUCTS STORED BELOW 60 DEG. F (16 DEG. C) OR ABOVE 90 DEG. F (32 DEG. C)
MUST BE GIVEN ADEQUATE TIME TO WARM UP/COOL DOWN. DO NOT EXPOSE THE
TANKS/KITS TO OPEN FLAME OR TEMPERATURES ABOVE 122 DEG. F (50 DEG. C);
STORAGE AT ELEVATED TEMPERATURES CAN CAUSE THE CONTAINER TO RUPTURE.
EXCESSIVE HEAT CAN CAUSE PREMATURE AGING OF COMPONENTS RESULTING IN A
SHORTER SHELF LIFE. PROTECT UNUSED PRODUCT FROM FREEZING. STORAGE BELOW 60
DEG. F (16 DEG. C) MAY AFFECT FOAM QUALITY IF CHEMICALS ARE NOT WARMED TO
ROOM TEMPERATURE BEFORE USING. PROTECT CONTAINERS FROM PHYSICAL ABUSE.
ALWAYS STORE THE CONTAINERS IN THE UPRIGHT POSITION. KEEP OUT OF REACH OF
CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
INGREDIENT CAS NUMBER OSHA-PEL ACGIH-CEILING OTHER
LIMIT VALUE
DIETHYLENE GLYCOL 111-46-6 WEEL 10 MG/KG
TRANS-1,3,3,3-
TETRAFLUOROPROP- 29118-24-9 WEEL 800 PPM
1-ENE
ETHYLENE GLYCOL 107-21-1 100 MG/M3
8.2 EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE LOCAL AND GENERAL EXHAUST VENTILATION TO CONTROL LEVELS OF EXPOSURE.
EYE/FACE PROTECTION:
WEAR PROTECTIVE GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
HAND PROTECTION:
USE CHEMICALLY RESISTANT GLOVES (I.E. NITRILE GLOVES). NITRILE/BUTADIENE
RUBBER, BUTYL RUBBER, POLYETHYLENE, PVC (VINYL), OR NEOPRENE GLOVES ARE
ALSO EFFECTIVE. GLOVE SELECTION SHOULD TAKE INTO ACCOUNT POTENTIAL BODY
REACTIONS TO CERTAIN MATERIALS AND MANUFACTURER'S INSTRUCTIONS FOR USE.
BREAK THROUGH TIME OF SELECTED GLOVES MUST BE GREATER THAN THE INTENDED
USE PERIOD.
OTHER PROTECTIVE EQUIPMENT:
USE CLOTHING THAT PROTECTS AGAINST DERMAL EXPOSURE. APPROPRIATE PROTECTIVE
CLOTHING VARIES DEPENDING ON THE POTENTIAL FOR EXPOSURE. TO ENSURE PROPER
SKIN PROTECTION, WEAR PPE IN SUCH A MANNER THAT NO SKIN IS EXPOSED.
RESPIRATORY PROTECTION:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINES. USE
PRODUCTS ONLY IN A WELL-VENTILATED AREA. ENGINEERING AND ADMINISTRATIVE
(WORK PRACTICES) CONTROLS SHOULD BE IMPLEMENTED TO PROTECT THE WORKERS. IF
ATMOSPHERIC LEVELS ARE EXPECTED TO EXCEED THE EXPOSURE LEVELS, USE A NIOSH
APPROVED AIR PURIFYING RESPIRATOR EQUIPPED WITH AN ORGANIC VAPOR CARTRIDGE
AND A PARTICULATE FILTER. IF ATMOSPHERIC LEVELS EXCEED 10 TIMES THE TLV OR
PEL LEVEL FOR WHICH AN AIR-PURIFYING RESPIRATOR IS EFFECTIVE, USE A POWERED
AIR PURIFYING RESPIRATOR (PAPR). THE TYPE OF RESPIRATORY PROTECTION
SELECTED MUST COMPLY WITH THE REQUIREMENTS SET FORTH IN OSHA'S RESPIRATORY
PROTECTION STANDARD (29 CFR 1910.134). THE ODOR AND IRRITANCY OF THIS
MATERIAL IS INADEQUATE TO WARN OF EXCESSIVE EXPOSURE.
HYGIENE MEASURES:
AN EYE WASH STATION OR PORTABLE EYE WASH STATION SHOULD BE IN THE AREA.
WASH HANDS THOROUGHLY AFTER USE, BEFORE EATING, DRINKING OR USING THE
LAVATORY. EMPLOYEES/USERS SHOULD BE EDUCATED AND TRAINED IN THE SAFE USE
AND HANDLING OF THIS PRODUCT.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM:
AMBER TO DARK BROWN LIQUID. FORMS AN OFF-WHITE TO YELLOWISH FROTH WHEN
RELEASED FROM THE CONTAINER
ODOR: SLIGHT ETHER AND AMINE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE:
PROPELLANT -19 DEG. C (-2.2 DEG. F)
FLASH POINT: PROPELLANT DOES NOT FLASH
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY: NO APPLICABLE
LOWER FLAMMABILITY/EXPLOSIVE LIMIT: NOT AVAILABLE
UPPER FLAMMABILITY/EXPLOSIVE LIMIT: NOT AVAILABLE
VAPOR PRESSURE IN CONTAINER: NOT AVAILABLE
VAPOR PRESSURE OF LIQUID: NOT AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY/SPECIFIC GRAVITY: APPROX. 1.2 @ 25 DEG. C (WATER = 1)
SOLUBILITY:
WATER: PARTLY SOLUBLE, DOES NOT REACT
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NOT AVAILABLE
| SECTION 10 - STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF USE AND RECOMMENDED STORAGE CONDITIONS.
SEE SECTION 7 FOR STORAGE RECOMMENDATIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
EXPOSURE TO ELEVATED TEMPERATURES CAN CAUSE CONTAINERS TO RUPTURE OR
EXPLODE. CONTENTS ARE UNDER PRESSURE.
10.4 CONDITIONS TO AVOID:
TEMPERATURES BELOW 60 DEG. F (16 DEG. C) OR TEMPERATURES ABOVE 90 DEG. F
(32 DEG. C). AVOID HEAT AND FLAMES.
10.5 INCOMPATIBLE MATERIALS:
ALCOHOLS, STRONG BASES, AMINES, METAL COMPOUNDS, AMMONIA, AND STRONG
OXIDIZERS.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
SEE SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DUE TO COMBUSTION.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE BASED ON TEST DATA AND/OR INFORMATION ON
THE COMPONENTS, THIS MATERIAL MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
MIST OR VAPOR MAY CAUSE IRRITATION OF THE NOSE, THROAT AND RESPIRATORY
TRACT. SYMPTOMS MAY INCLUDE SORE THROAT, COUGHING, HEADACHE, NAUSEA AND
SHORTNESS OF BREATH. INHALATION OF PROPELLANT MAY CAUSE LIGHTHEADEDNESS,
HEADACHE AND LETHARGY.
SKIN CONTACT:
MAY CAUSE MILD SKIN IRRITATION. SYMPTOMS MAY INCLUDE LOCALIZED REDNESS AND
DISCOMFORT.
EYE CONTACT:
MAY CAUSE SERIOUS EYE IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, SWELLING,
STINGING, AND TEARING. MAY CAUSE TEMPORARY CORNEAL INJURY. PRODUCT VAPOR
MAY CAUSE EYE IRRITATION WITH SYMPTOMS OF BURNING AND TEARING.
INGESTION:
MAY CAUSE GASTROINTESTINAL IRRITATION: STOMACH DISTRESS, NAUSEA, OR
VOMITING. REPEATED INGESTION MAY BE HARMFUL.
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION: NONE
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT
SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS ARE LISTED.
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS ARE LISTED
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED
PROBABLE ROUTES OF EXPOSURE: INHALATION, EYE CONTACT AND SKIN CONTACT.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
IRRITATING TO EYES AND SKIN.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION)
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
SPECIFIC ORGAN TOXICITY-SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC ORGAN TOXICITY-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: NO DATA AVAILABLE
11.2 FURTHER INFORMATION:
NONE OF THE COMPONENTS OF THIS PRODUCT ARE LISTED AS CARCINOGENS BY IARC,
ACGIH, NTP OR OSHA. NO DATA IS AVAILABLE REGARDING THE MUTAGENICITY OR
TERATOGENICITY OF THIS PRODUCT, NOR IS THERE ANY AVAILABLE DATA THAT
INDICATES THAT IT CAUSES ADVERSE OR FERTILITY EFFECTS. CHRONIC TOXICITY
FROM PROLONGED AND REPEATED EXPOSURE TO DIETHYLENE GLYCOL (DEG) IS
ASSOCIATED WITH KIDNEY, AND TO A LESSER DEGREE LIVER EFFECTS. AVAILABLE
DATA INDICATES THAT DEG IS NEGATIVE IN IN-VITRO GENOTOXICITY TESTS. SOME
POSITIVE RESULTS WERE OBTAINED IN IN-VIVO GENOTOXICITY STUDIES, HOWEVER,
ONLY AT HIGH TOXIC DOSES OF DEG. OVERALL, DEG IS CONSIDERED NON-GENOTOXIC.
SEVERAL ANIMAL REPRODUCTIVE TOXICITY STUDIES INDICATE THAT HUMAN DATA OR
CASE REPORTS ON REPRODUCTIVE AND DEVELOPMENTAL EFFECTS OF DEG ARE
AVAILABLE. ETHYLENE GLYCOL: EXPOSURE TO VAPORS OF ETHYLENE GLYCOL AT ROOM
TEMPERATURE IS EXPECTED TO BE MINIMAL. ETHYLENE GLYCOL MAY CAUSE BIRTH
DEFECTS. IF A LARGE AMOUNT OF VAPORS ARE ALLOWED TO ACCUMULATE, THE
MATERIAL MAY CAUSE RESPIRATORY IRRITATION AND SYMPTOMS SUCH AS HEADACHE
AND NAUSEA. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFE
PRACTICES.
| SECTION 12 - ECOLOGICAL INFORMATION | |
12.1 ECOTOXICITY:
THE ECOTOXICITY OF THIS PRODUCT HAS NOT BEEN EXPERIMENTALLY DETERMINED.
HOWEVER, IT IS EXPECTED TO HAVE LOW ACUTE AQUATIC TOXICITY BASED ON THE
ACUTE AQUATIC TOXICITY OF THE INDIVIDUAL COMPONENTS AND THEIR
CONCENTRATIONS IN THIS COMPOSITION.
12.2 PERSISTENCE AND DEGRADABILITY: PRODUCT IS READILY BIODEGRADABLE.
12.3 BIOACCUMULATION POTENTIAL: PRODUCT IS NOT EXPECTED TO BIOACCUMULATE
12.4 MOBILITY: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
12.6 OTHER ADVERSE EFFECTS:
ADDITIONAL ECOLOGICAL INFORMATION:
DO NOT ALLOW MATERIAL TO RUN INTO SURFACE WATERS, WASTEWATER, OR SOIL.
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
ALWAYS WEAR PROPER PROTECTIVE EQUIPMENT AS YOU WOULD WHILE SPRAYING THE
TWO-COMPONENT FOAM IN A WELL-VENTILATED AREA.
PROCEDURE FOR HANDLING EMPTY OR PARTIALLY USED DISPOSABLE CYLINDERS (NOT
RETURNABLE):
1. DO NOT INCINERATE CYLINDERS.
2. EMPTY CYLINDERS BY DISPENSING THE FOAM INTO A WASTE CONTAINER LIKE A
CARDBOARD BOX OR PLASTIC BAG. DEPRESSURIZE THE USED CYLINDERS USING THE
DISPENSING UNIT WITH A NEW NOZZLE ATTACHED. SPRAY THE FOAM UNTIL ONE OF
THE COMPONENTS/CYLINDERS NO LONGER SPRAYS CHEMICAL.
3. REMOVE THE NOZZLE AND THEN CONTINUE TO DEPRESSURIZE BY DISPENSING THE
REMAINING CHEMICAL(S) INTO A WASTE CONTAINER (A BOX LINED WITH A PLASTIC
BAG) THAT HAS ADEQUATE INDUSTRIAL LIQUID ABSORBING MEDIUM IN THE BOTTOM.
DISPENSE THE RESIDUAL CHEMICALS UNTIL THE PRESSURE IS DOWN TO A MINIMUM
OR THERE ARE JUST LARGE BUBBLES IN THE HOSE.
4. CLOSE THE CYLINDER VALVES COMPLETELY, AND THEN OPERATE THE DISPENSING
UNIT AGAIN TO EMPTY AND DEPRESSURIZE THE HOSES. USE A 9/16" WRENCH AND
REMOVE THE HOSES FROM THE CYLINDERS. USE CAUTION IN CASE THERE IS SOME
RESIDUAL CHEMICAL AND/OR PRESSURE IN THE HOSES.
5. INVERT THE CYLINDER AND POINT AWAY FROM FACE. SLOWLY OPEN THE CYLINDER
OVER THE WASTE CONTAINER TO CATCH ANY RESIDUAL SPRAY.
6. RETURN THE CYLINDER TO AN UPRIGHT POSITION. SHAKE THE CONTAINER; THERE
SHOULD NOT BE ANY SLOSHING OF LIQUID. MAKE SURE TO LEAVE VALVES OPEN-DO
NOT CLOSE.
7. THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF EMPTY
CYLINDERS, UNUSED MATERIAL AND RESIDUES IN COMPLIANCE TO ALL APPLICABLE
FEDERAL, STATE, INTERNATIONAL AND LOCAL REGULATIONS REGARDING THE
TREATMENT, STORAGE, AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.
CHECK WITH YOUR LOCAL WASTE DISPOSAL SERVICE FOR GUIDANCE.
NOTE:
AFTER DISPENSING IF ONE CYLINDER HAS CHEMICAL LEFT IN IT; TREAT AS
HAZARDOUS MATERIAL.
| SECTION 14 - TRANSPORTATION | |
NOTE:
TRANSPORTATION INFORMATION IS FOR REFERENCE ONLY. CUSTOMER IS URGED TO
CONSULT 49 CFR 100-177, IMDG, IATA, EC, UNITED NATIONS TDG AND WHMIS
(CANADA) TDG INFORMATION MANUALS FOR DETAILED REGULATIONS AND EXCEPTIONS
COVERING SPECIFIC CONTAINER SIZES, PACKAGING MATERIALS AND METHODS OF
SHIPPING.
CONTAINERS GREATER THAN 1000 CU. CM. (1 LITER)
GROUND UN3500 CHEMICAL UNDER PRESSURE N.O.S. (HYDROFLUOROOLEFIN, NITROGEN)
2.2 (NON-FLAMMABLE GAS LABEL)
AIR UN3500 CHEMICAL UNDER PRESSURE N.O.S. (HYDROFLUOROOLEFIN, NITROGEN)
2.2 (NON-FLAMMABLE GAS LABEL)
PACKING INSTRUCTION (CARGO & PASSENGER) 218
WATER UN3500 CHEMICAL UNDER PRESSURE N.O.S. (HYDROFLUOROOLEFIN, NITROGEN)
2.2 (NON-FLAMMABLE GAS LABEL)
| SECTION 15 - REGULATORY | |
15.1 SAFETY, HEALTH, AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC
FOR THE SUBSTANCE OR MIXTURE:
U.S. FEDERAL REGULATIONS:
OSHA HAZARD COMMUNICATION STANDARD:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS IN ACCORDANCE WITH OSHA 29 CFR
1910-1200
TSCA STATUS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TOXIC SUBSTANCE CONTROL
ACT (TSCA) INVENTORY. THIS PRODUCT IS NOT SUBJECT TO TSCA 12(B) EXPORT
NOTIFICATION.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA):
SARA SECTION 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD, SUDDEN RELEASE OF PRESSURE HAZARD
SARA 313 INFORMATION:
NO COMPONENTS OF THE PRODUCT ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF
1986.
SARA 302/304 EXTREMELY HAZARDOUS SUBSTANCE:
NO COMPONENTS OF THE PRODUCT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING
LEVELS ESTABLISHED BY THESE SECTIONS OF THE TITLE III OF SARA.
SARA 302/304 EMERGENCY PLANNING & NOTIFICATION:
NO COMPONENTS OF THE PRODUCT EXCEED THE THRESHOLD (DE MINIMIS) REPORT
LEVELS ESTABLISHED BY THESE SECTIONS OF THE TITLE III OF SARA.
COMPREHENSIVE RESPONSE COMPENSATION AND LIABILITY ACT (CERCLA):
NONE OF THE SUBSTANCES IN THIS PRODUCT ARE CONTAINED IN LEVELS THAT EXCEED
THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED BY CERCLA
CLEAN AIR ACT (CAA):
THIS PRODUCT DOES NOT HAVE ANY COMPONENTS LISTED AS A HAZARDOUS AIR
POLLUTANT (HAP) DESIGNATED IN CAA SECTION 112 (B). THIS PRODUCT DOES NOT
CONTAIN ANY CLASS 1 OR CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT (CWA):
THIS PRODUCTS DOES NOT HAVE ANY COMPONENTS LISTED AS A HAZARDOUS SUBSTANCE
UNDER THE CWA. NONE OF THE CHEMICALS IN THESE PRODUCTS ARE LISTED AS
PRIORITY POLLUTANTS UNDER THE CWA. NONE OF THE CHEMICALS LISTED IN THESE
PRODUCTS ARE LISTED AS TOXIC POLLUTANTS UNDER THE CWA.
U.S. STATE REGULATIONS:
CALIFORNIA PROP 65, SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986:
WARNING! CANCER & REPRODUCTIVE HARMWWW. P65WARNINGS.CA.GOV
OTHER U.S. STATE INVENTORIES:
DIETHYLENE GLYCOL (CAS #111-46-6) IS LISTED ON THE FOLLOWING STATE
HAZARDOUS SUBSTANCE INVENTORIES, RIGHT-TO-KNOW LISTS AND/OR AIR QUALITY/AIR
POLLUTANTS LISTS: MN, PA
GLOBAL CHEMICAL INVENTORY LISTS:
UNITED STATES:
TOXIC SUBSTANCE CONTROL ACT (TSCA):
YES, ALL OF THE COMPONENTS ARE LISTED ON TSCA
CANADA:
DOMESTIC SUBSTANCES LIST (DSL):
YES, ALL OF THE COMPONENTS ARE LISTED ON THE DSL
CANADA:
NON-DOMESTIC SUBSTANCES LIST (NDSL): NO
15.2 CHEMICAL SAFETY ASSESSMENT:
FOR THIS PRODUCT A CHEMICAL SAFETY ASSESSMENT WAS NOT CARRIED OUT
| SECTION 16 - OTHER | |
SAFETY GLASSES
LAB COAT
GLOVES
VAPOR RESPIRATOR
FAN
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 1
REACTIVITY 1
HMIS:
HEALTH HAZARD 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
HAZARD RATING:
0=MINIMAL
1=SLIGHT
2=MODERATE
3=SEVERE
4=EXTREME
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS
BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
PRESS. GAS: GASES UNDER PRESSURE - COMPRESSED GAS
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2 (STOT RE 2)
THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE PRESENTED IN GOOD
FAITH AND BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. THE MANUFACTURER
MAKES NO REPRESENTATIONS AS TO THE COMPLETENESS OR ACCURACY THEREOF.
INFORMATION IS SUPPLIED UPON THE CONDITION THAT THE PERSONS RECEIVING IT
WILL MAKE THEIR OWN DETERMINATION AS TO ITS SUITABILITY FOR THEIR PURPOSES
PRIOR TO USE. IN NO EVENT WILL THE MANUFACTURER BE RESPONSIBLE FOR DAMAGES
OF ANY NATURE WHATSOEVER RESULTING FROM THE USE OF OR RELIANCE UPON
INFORMATION. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED,
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE ARE MADE HEREUNDER WITH
RESPECT TO THIS INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.
INFORMATION CONTAINED HEREIN IS DEEMED TO BE RELIABLE, CONSERVATIVE AND
ACCURATE. ICP ADHESIVES & SEALANTS, INC. RESERVES THE RIGHT TO CHANGE THE
DESIGN, SPECIFICATIONS OR ANY OTHER FEATURES AT ANY TIME AND WITHOUT
NOTICE, WHILE OTHERWISE MAINTAINING REGULATORY COMPLIANCE.
REVISION: SEPTEMBER 12, 2018 (DATE OF PREPARATION)
VERSION: 3.2
REPLACES: FEBRUARY 15, 2018
VERSION: 3.1
LOW PRESSURE SPF HD SIDE B (HFO)
ISSUE DATE: MARCH 2016
LAST REV: SEPTEMBER 2018