| Common Name: | FIRE BARRIER CP-25WB+ |
| Manufacturer: | 3M |
| SDS Revision Date: | 10/3/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 5Z337, 5Z381, 5ZW91, 5ZW92, 5ZX52 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M BRAND FIRE BARRIER CP-25WB+
10/03/19
3M
SAFETY DATA SHEET
COPYRIGHT, 2019, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 09-5451-1
VERSION NUMBER: 26.06
ISSUE DATE: 10/03/19
SUPERCEDES DATE: 02/22/19
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M BRAND FIRE BARRIER CP-25WB+
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
42-0016-4710-8
42-0016-4716-5
98-0400-5381-5 00-51115-11640-7
98-0400-5383-1 00-51115-11642-1
98-0400-5456-5
98-0400-5573-7 000-51115-16515-3
98-0400-5629-7
42-0016-4715-7
98-0400-5380-7 00-51115-11639-1
98-0400-5382-3 00-51115-11641-4
98-0400-5406-0 00-51115-16515-3
98-0400-5562-0 000-51115-11642-1
98-0400-5610-7
7100006311, 7000006379, 7000059394, 7000145569, 7100025518, 7000006383,
7010353050, 7100137423
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: FIRE PROTECTION, USED AS FIRESTOP IN BUILDINGS.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
REPRODUCTIVE TOXICITY: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
WATER 7732-18-5 10 - 30 TRADE SECRET *
ZINC BORATE 2335 138265-88-0 10 - 30 TRADE SECRET *
POLYMER (NJTS REG. TRADE SECRET* 10 - 30 TRADE SECRET *
NO. 04499600-7270)
SODIUM SILICATE 1344-09-8 10 - 19 TRADE SECRET *
ETHYLHEXYLDIPHENYL PHOSPHATE 1241-94-7 3 - 7 TRADE SECRET *
IRON OXIDE 1309-37-1 1 - 5 TRADE SECRET *
OXIDE GLASS CHEMICALS 65997-17-3 1 - 5 TRADE SECRET *
POLYETHYLENE GLYCOL 25322-68-3 1 - 5 TRADE SECRET *
QUARTZ SILICA 14808-60-7 <1 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
NON-COMBUSTIBLE. USE A FIRE FIGHTING AGENT SUITABLE FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF PHOSPHORUS DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED, POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND PANTS,
BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE COVERING FOR
EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN
UP RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. USE PERSONAL
PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP COOL. STORE AWAY FROM HEAT. STORE AWAY FROM AREAS WHERE PRODUCT MAY
COME INTO CONTACT WITH FOOD OR PHARMACEUTICALS. STORE IN A DRY PLACE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
DUST, INERT 1309-37-1 OSHA TWA (AS TOTAL DUST):
OR NUISANCE 15 MG/M3
TWA (AS TOTAL DUST):
50 MILLIONS OF
PARTICLES/CU. FT.
(15 MG/M3)
TWA (RESPIRABLE
FRACTION):
15 MILLIONS OF
PARTICLES/CU. FT.
(5 MG/M3)
TWA (RESPIRABLE
FRACTION): 5 MG/M3
IRON OXIDE 1309-37-1 ACGIH TWA (RESPIRABLE A4:
FRACTION): 5 MG/M3 NOT CLASS.
AS HUMAN
CARCIN
IRON OXIDE 1309-37-1 OSHA TWA (AS FUME):
10 MG/M3
ROUGE 1309-37-1 OSHA TWA (AS TOTAL DUST):
15 MG/M3
TWA (RESPIRABLE
FRACTION): 5 MG/M3
QUARTZ SILICA 14808-60-7 ACGIH TWA (RESPIRABLE A2:
FRACTION): SUSPECTED
0.025 MG/M3 HUMAN
CARCIN.
QUARTZ SILICA 14808-60-7 OSHA TWA TABLE Z-1
(RESPIRABLE):
0.05 MG/M3
TWA TABLE Z-3
(RESPIRABLE):
0.1 MG/M3
POLYETHYLENE 25322-68-3 AIHA TWA (AS AEROSOL):
GLYCOL 10 MG/M3
OXIDE GLASS 65997-17-3 MANUFACTURER TWA (AS NON-FIBROUS,
CHEMICALS DETERMINED INHALABLE FRACTION)
(8 HOURS): 10 MG/M3
TWA (AS NON-FIBROUS,
RESPIRABLE) (8 HOURS):
3 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
NEOPRENE
NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
PHYSICAL STATE: SOLID
COLOR: RED
SPECIFIC PHYSICAL FORM: PASTE
ODOR: ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7.5 - 8
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: 100 DEG. C
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: 0.33 [REF/STD:BUOAC=1]
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: 17.5 MMHg [@ 20 DEG. C]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 1.35 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
<=0.5% WEIGHT [TEST METHOD: TESTED PER EPA METHOD 24]
VOC LESS H2O & EXEMPT SOLVENTS:
<=6 G/L [TEST METHOD: TESTED PER EPA METHOD 24]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
SILICA, CRYS 14808-60-7 KNOWN HUMAN CARCINOGEN NATIONAL TOXICOLOGY
AIRRESP PROGRAM CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO HUMANS FOR RESEARCH ON
CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
ZINC BORATE 2335 DERMAL RABBIT LD50: >5,000 MG/KG
ZINC BORATE 2335 INHALATION- RAT LC50: >4.95 MG/L
DUST/MIST
ZINC BORATE 2335 INGESTION RAT LD50: >5,000 MG/KG
POLYMER (NJTS REG. NO. DERMAL LD50 ESTIMATED TO BE
04499600-7270) >5,000 MG/KG
POLYMER (NJTS REG. NO. INGESTION RAT LD50: >2,000 MG/KG
04499600-7270)
SODIUM SILICATE DERMAL RABBIT LD50: >4,640 MG/KG
SODIUM SILICATE INGESTION RAT LD50: 500 MG/KG
ETHYLHEXYLDIPHENYL DERMAL RABBIT LD50: >7,940 MG/KG
PHOSPHATE
ETHYLHEXYLDIPHENYL INGESTION RAT LD50: >24,000 MG/KG
PHOSPHATE
IRON OXIDE DERMAL NOT LD50: 3,100 MG/KG
AVAILABLE
IRON OXIDE INGESTION NOT LD50: 3,700 MG/KG
AVAILABLE
POLYETHYLENE GLYCOL DERMAL RABBIT LD50: >20,000 MG/KG
POLYETHYLENE GLYCOL INGESTION RAT LD50: 32,770 MG/KG
OXIDE GLASS CHEMICALS DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
OXIDE GLASS CHEMICALS INGESTION LD50 ESTIMATED TO BE
2,000 - 5,000 MG/KG
QUARTZ SILICA DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50 ESTIMATED TO BE
>5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ZINC BORATE 2335 RABBIT NO SIGNIFICANT IRRITATION
POLYMER RABBIT MINIMAL IRRITATION
(NJTS REG. NO. 04499600-7270)
SODIUM SILICATE RABBIT CORROSIVE
IRON OXIDE RABBIT NO SIGNIFICANT IRRITATION
POLYETHYLENE GLYCOL RABBIT MINIMAL IRRITATION
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGMENT
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ZINC BORATE 2335 RABBIT SEVERE IRRITANT
POLYMER PROFESSIONAL MILD IRRITANT
(NJTS REG. NO. 04499600-7270) JUDGMENT
SODIUM SILICATE RABBIT CORROSIVE
IRON OXIDE RABBIT NO SIGNIFICANT IRRITATION
POLYETHYLENE GLYCOL RABBIT MILD IRRITANT
OXIDE GLASS CHEMICALS PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
ZINC BORATE 2335 GUINEA PIG NOT CLASSIFIED
SODIUM SILICATE MOUSE NOT CLASSIFIED
IRON OXIDE HUMAN NOT CLASSIFIED
POLYETHYLENE GLYCOL GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ZINC BORATE 2335 IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
SODIUM SILICATE IN VITRO NOT MUTAGENIC
SODIUM SILICATE IN VIVO NOT MUTAGENIC
IRON OXIDE IN VITRO NOT MUTAGENIC
POLYETHYLENE GLYCOL IN VITRO NOT MUTAGENIC
POLYETHYLENE GLYCOL IN VIVO NOT MUTAGENIC
OXIDE GLASS CHEMICALS IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
IRON OXIDE INHALATION HUMAN SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
POLYETHYLENE GLYCOL INGESTION RAT NOT CARCINOGENIC
OXIDE GLASS CHEMICALS INHALATION MULTIPLE SOME POSITIVE DATA EXIST,
ANIMAL BUT THE DATA ARE NOT
SPECIES SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA INHALATION HUMAN AND CARCINOGENIC
ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
ZINC BORATE 2335 INGESTION TOXIC TO MALE REPRODUCTION
ZINC BORATE 2335 INGESTION TOXIC TO DEVELOPMENT
SODIUM SILICATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
POLYETHYLENE GLYCOL INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
POLYETHYLENE GLYCOL INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
POLYETHYLENE GLYCOL NOT NOT CLASSIFIED FOR REPRODUCTION AND/OR
SPECIFIED DEVELOPMENT
POLYETHYLENE GLYCOL INGESTION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
ZINC BORATE 2335 RAT NOAEL: 100 MG/KG/DAY 92 DAYS
ZINC BORATE 2335 RAT LOAEL: 100 MG/KG/DAY DURING GESTATION
SODIUM SILICATE MOUSE NOAEL: 200 MG/KG/DAY DURING GESTATION
POLYETHYLENE GLYCOL RAT NOAEL: 1,125 MG/KG/DAY DURING GESTATION
POLYETHYLENE GLYCOL RAT NOAEL: 5 DAYS
5699 +/- 1341 MG/KG/DAY
POLYETHYLENE GLYCOL NOEL: N/A
POLYETHYLENE GLYCOL MOUSE NOAEL: DURING GESTATION
562 MG/ANIMAL/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ZINC BORATE 2335 INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
SODIUM SILICATE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
POLYETHYLENE GLYCOL INHALATION RESPIRATORY NOT CLASSIFIED
IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
ZINC BORATE 2335 SIMILAR NOAEL:
HEALTH NOT AVAILABLE
HAZARDS
SODIUM SILICATE OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
POLYETHYLENE GLYCOL RAT NOAEL: 2 WEEKS
1.008 MG/L
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ZINC BORATE 2335 INHALATION IMMUNE SYSTEM NOT CLASSIFIED
RESPIRATORY SYSTEM
HEART
ENDOCRINE SYSTEM
HEMATOPOIETIC SYSTEM
LIVER
NERVOUS SYSTEM
KIDNEY AND/OR BLADDER
ZINC BORATE 2335 INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
LIVER
KIDNEY AND/OR BLADDER
HEART
SKIN
BONE, TEETH, NAILS,
AND/OR HAIR
HEMATOPOIETIC SYSTEM
IMMUNE SYSTEM
NERVOUS SYSTEM
EYES
RESPIRATORY SYSTEM
VASCULAR SYSTEM
SODIUM SILICATE INGESTION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
SODIUM SILICATE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
BLOOD
SODIUM SILICATE INGESTION HEART NOT CLASSIFIED
LIVER
IRON OXIDE INHALATION PULMONARY FIBROSIS NOT CLASSIFIED
PNEUMOCONIOSIS
POLYETHYLENE GLYCOL INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
POLYETHYLENE GLYCOL INGESTION KIDNEY AND/OR BLADDER NOT CLASSIFIED
HEART
ENDOCRINE SYSTEM
HEMATOPOIETIC SYSTEM
LIVER
NERVOUS SYSTEM
OXIDE GLASS INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
CHEMICALS
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
ZINC BORATE 2335 RAT NOAEL: 0.15 MG/L 2 WEEKS
ZINC BORATE 2335 RAT NOAEL: 92 DAYS
375 MG/KG/DAY
SODIUM SILICATE DOG LOAEL: 4 WEEKS
2,400 MG/KG/DAY
SODIUM SILICATE RAT NOAEL: 3 MONTHS
804 MG/KG/DAY
SODIUM SILICATE RAT NOAEL: 8 WEEKS
1,259 MG/KG/DAY
IRON OXIDE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
POLYETHYLENE GLYCOL RAT NOAEL: 1.008 MG/L 2 WEEKS
POLYETHYLENE GLYCOL RAT NOAEL: 13 WEEKS
5,640 MG/KG/DAY
OXIDE GLASS HUMAN NOAEL: OCCUPATIONAL EXPOSURE
CHEMICALS NOT AVAILABLE
QUARTZ SILICA HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
TEST ORGANISM TEST TYPE RESULT
WATER FLEA, DAPHNIA MAGNA 48 HOURS AQUATIC TOXICITY - ACUTE 27 MG/L
GREEN ALGAE, 72 HOURS AQUATIC TOXICITY - CHRONIC 2.6 MG/L
PSEUDOKIRCHNERIELLA
SUBCAPITATA
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY.
AS A DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL
DURING INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED
FOR TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
SERIOUS EYE DAMAGE OR EYE IRRITATION
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC BORATE 2335 (ZINC COMPOUNDS) 138265-88-0 10 - 30
15.2. STATE REGULATIONS:
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
15.4. INTERNATIONAL REGULATIONS:
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 09-5451-1
VERSION NUMBER: 26.06
ISSUE DATE: 10/03/19
SUPERCEDES DATE: 02/22/19
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE
OF TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT
IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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