| Common Name: | BRAKLEEN BRAKE PARTS CLEANER - 55 GAL NO. 05087 (ITEM 1003702) |
| Manufacturer: | CRC INDUSTRIES |
| SDS Revision Date: | 8/1/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: BRAKLEEN(R*) BRAKE PARTS CLEANER - 55 GAL
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: NO. 05087 (ITEM# 1003702)
RECOMMENDED USE: BRAKE PARTS CLEANER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC): 800-424-9300 (US)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 2
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 3
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
REPRODUCTIVE TOXICITY: CATEGORY 1A
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 1 (CENTRAL NERVOUS SYSTEM, EYES)
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 1
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
SKULLS AND CROSSBONES
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
HIGHLY FLAMMABLE LIQUID AND VAPOR. TOXIC IF SWALLOWED. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE
IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY DAMAGE FERTILITY OR
THE UNBORN CHILD. CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. TOXIC TO
AQUATIC LIFE. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM
HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP CONTAINER
TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE
EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT. USE ONLY
MOM-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE MIST OR VAPOR. USE ONLY WITH ADEQUATE VENTILATION;
MAINTAIN VENTILATION DURING USE AND UNTIL ALL VAPORS ARE GONE. OPEN DOORS
AND WIDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY DURING USE AND
WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS LISTED ON THIS
LABEL, INCREASE VENTILATION OR LEAVE THE AREA. WASH THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. RINSE MOUTH. DO NOT INDUCE
VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED: CALL A POISON CENTER/DOCTOR.
IN CASE OF FIRE:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
COLLECT SPILLAGE.
STORAGE:
KEEP COOL. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (ENOC):
STATIC ACCUMULATING FLAMMABLE LIQUID CAN BECOME ELECTROSTATICALLY CHARGED
EVEN IN BONDED AND GROUNDED EQUIPMENT. SPARKS MAY IGNITE LIQUID AND VAPOR.
MAY CAUSE FLASH FIRE OR EXPLOSION.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
METHANOL 67-56-1 40 - 50
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT 64742-49-0 10 - 20
TOLUENE 108-88-3 10 - 20
ACETONE 67-64-1 5 - 10
HEPTANE, BRANCHED, CYCLIC AND LINEAR 426260-76-6 5 - 10
SOLVENT NAPHTHA (PETROLEUM), LIGHT 64742-89-8 3 - 5
ALIPH.
3-METHYLHEXANE 589-34-4 1 - 3
N-HEPTANE 142-82-5 1 - 3
2-METHYLHEXANE 591-76-4 <1
2,3-DIMETHYLPEMTANE 565-59-3 <0.2
3-ETHYLPEMTANE 617-78-7 <0.2
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO
NOT INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH
CONTEMPT DOESN'T GET INTO THE LUNGS. DO NOT USE MOUTH-TO-MOUTH METHOD IF
VICTIM INGESTED THE SUBSTANCE. INDUCE ARTIFICIAL RESPIRATION WITH THE AID
OF A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PMEUMOMITIS. MAY CAUSE DROWSINESS
AND DIZZINESS. NARCOSIS. HEADACHE. NAUSEA, VOMITING. BEHAVIORAL CHANGES.
DECREASE IN MOTOR FUNCTIONS. SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE
STINGING, TEARING, REDNESS, SWELLING, AND BLURRED VISION. SKIN IRRITATION.
MAY CAUSE REDNESS AND PAIN. PROLONGED EXPOSURE MAY CAUSE CHROMIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
THERMAL BUMS:
FLUSH WITH WATER IMMEDIATELY. WHILE FLUSHING, REMOVE CLOTHES WHICH DO NOT
ADHERE TO AFFECTED AREA. CALL AM AMBULANCE. CONTINUE FLUSHING DURING
TRANSPORT TO HOSPITAL. KEEP VICTIM WARM. KEEP VICTIM UNDER OBSERVATION.
SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION: TAKE OFF ALL CONTAMINATED CLOTHING IMMEDIATELY.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF
THE MATERIAL(S) INVOLVED, AMD TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW
THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. ALCOHOL RESISTANT FOAM. CARBON DIOXIDE (CO2). DRY CHEMICAL
POWDER, CARBON DIOXIDE, SAND OR EARTH MAY BE USED FOR SMALL FIRES ONLY.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AM EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS MAY TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. THIS
PRODUCT IS A POOR CONDUCTOR OF ELECTRICITY AND CAM BECOME
ELECTROSTATICALLY CHARGED. IF SUFFICIENT CHARGE IS ACCUMULATED, IGNITION
OF FLAMMABLE MIXTURES CAM OCCUR. TO REDUCE POTENTIAL FOR STATIC
DISCHARGE, USE PROPER BONDING AND GROUNDING PROCEDURES. THIS LIQUID MAY
ACCUMULATE STATIC ELECTRICITY WHEN FILLING PROPERLY GROUNDED CONTAINERS.
STATIC ELECTRICITY ACCUMULATION MAY BE SIGNIFICANTLY INCREASED BY THE
PRESENCE OF SMALL QUANTITIES OF WATER OR OTHER CONTAMINANTS. MATERIAL
WILL FLOAT AND MAY IGNITE ON SURFACE OF WATER. DURING FIRE, GASES
HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORM IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS
FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. USE STANDARD FIREFIGHTING
PROCEDURES AND CONSIDER THE HAZARDS OF OTHER INVOLVED MATERIALS.
GENERAL FIRE HAZARDS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (MO SMOKING, FLARES, SPARKS,
OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. DO NOT BREATHE MIST OR VAPOR. DO NOT TOUCH
DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. TRANSFER BY
MECHANICAL MEANS SUCH AS VACUUM TRUCK TO A SALVAGE TANK OR OTHER SUITABLE
CONTAINER FOR RECOVERY OR SAFE DISPOSAL. LOCAL AUTHORITIES SHOULD BE
ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL
PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
USE ONLY NON-SPARKING TOOLS. PREVENT ENTRY INTO WATERWAYS, SEWER,
BASEMENTS OR CONFIRMED AREAS.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. USE A MOM-COMBUSTIBLE MATERIAL LIKE
VERMICULITE, SAND OR EARTH TO SOAK UP THE PRODUCT AND PLACE INTO A
CONTAINER FOR LATER DISPOSAL. FOLLOWING PRODUCT RECOVERY, FLUSH AREA
WITH WATER.
SMALL SPILLS:
ABSORB WITH EARTH, SAND OR OTHER MOM-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL. WIPE UP WITH ABSORBENT MATERIAL (E.G.
CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS,
WATER COURSES OR INTO THE GROUND. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT HANDLE, STORE OR OPEN
NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES OF IGNITION. PROTECT
MATERIAL FROM DIRECT SUNLIGHT. EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST
VENTILATION. MINIMIZE FIRE RISKS FROM FLAMMABLE AND COMBUSTIBLE MATERIALS
(INCLUDING COMBUSTIBLE DUST AND STATIC ACCUMULATING LIQUIDS) OR DANGEROUS
REACTIONS WITH INCOMPATIBLE MATERIALS.
HANDLING OPERATIONS THAT CAN PROMOTE ACCUMULATION OF STATIC CHARGES INCLUDE
BUT ARE NOT LIMITED TO:
MIXING, FILTERING, PUMPING AT HIGH FLOW RATES, SPLASH FILLING, CREATING
MISTS OR SPRAYS, TANK AND CONTAINER FILLING, TANK CLEANING, SAMPLING,
GAUGING, SWITCH LOADING, VACUUM TRUCK OPERATIONS. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGES. ALL EQUIPMENT USED WHEN HANDLING THE
PRODUCT MUST BE GROUNDED. USE MOM-SPARKING TOOLS AND EXPLOSION-PROOF
EQUIPMENT. DO NOT TASTE OR SWALLOW. AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING. AVOID PROLONGED EXPOSURE. WHEN USING, DO NOT EAT, DRINK OR
SMOKE. PREGNANT OR BREASTFEEDING WOMEN MUST NOT HANDLE THIS PRODUCT.
SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING.
AVOID RELEASE TO THE ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES. FOR PRODUCT USAGE INSTRUCTIONS, SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. PREVENT ELECTROSTATIC CHARGE
BUILD-UP BY USING COMMON BONDING AND GROUNDING TECHNIQUES. ELIMINATE
SOURCES OF IGNITION. AVOID SPARK PROMOTERS. GROUND/BOND CONTAINER AND
EQUIPMENT. THESE ALONE MAY BE INSUFFICIENT TO REMOVE STATIC ELECTRICITY.
STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. STORE IN TIGHTLY
CLOSED CONTAINER. STORE IN A WELL-VENTILATED PLACE. KEEP IN AM AREA
EQUIPPED WITH SPRINKLERS. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE
SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
METHANOL (CAS 67-56-1) PEL 260 MG/M3
200 PPM
NAPHTHA (PETROLEUM), PEL 400 MG/M3
HYDROTREATED LIGHT (CAS 100 PPM
64742-49-0)
N-HEPTANE (CAS 142-82-5) PEL 2000 MG/M3
500 PPM
SOLVENT NAPHTHA PEL 400 MG/M3
(PETROLEUM), LIGHT ALIPH. 100 PPM
(CAS 64742-89-8)
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
2,3-DIMETHYLPENTANE STEL 500 PPM
(CAS 565-59-3) TWA 400 PPM
2-METHYLHEXANE STEL 500 PPM
(CAS 591-76-4) TWA 400 PPM
3-ETHYLPENTANE STEL 500 PPM
(CAS 617-78-7) TWA 400 PPM
3-METHYLHEXANE STEL 500 PPM
(CAS 589-34-4) TWA 400 PPM
ACETONE STEL 500 PPM
(CAS 67-64-1) TWA 250 PPM
METHANOL STEL 250 PPM
(CAS 67-56-1) TWA 200 PPM
N-HEPTANE STEL 500 PPM
(CAS 142-82-5) TWA 400 PPM
TOLUENE TWA 20 PPM
(CAS 108-88-3)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
ACETONE TWA 590 MG/M3
(CAS 67-64-1) 250 PPM
METHANOL STEL 325 MG/M3
(CAS 67-56-1) 250 PPM
TWA 260 PPM
200 PPM
NAPHTHA (PETROLEUM), TWA 400 MG/M3
HYDROTREATED LIGHT 100 PPM
(CAS 64742-49-0)
N-HEPTANE CEILING 1800 MG/M3
(CAS 142-82-5) 440 PPM
TWA 350 MG/M3
85 PPM
SOLVENT NAPHTHA TWA 400 MG/M3
(PETROLEUM), LIGHT ALIPH.
(CAS 64742-89-8)
TOLUENE STEL 560 MG/M3
(CAS 108-88-3) 150 PPM
TWA 375 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
ACETONE (CAS 67-64-1) 25 MG/L ACETONE URINE *
METHANOL (CAS 67-56-1) 15 MG/L METHANOL URINE *
TOLUENE (CAS 108-88-3) 0.3 MG/G O-CRESOL, CREATININE *
WITH IN URINE
HYDROLYSIS
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
TOLUENE (CAS 108-88-3): CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS: SKIN DESIGNATION APPLIES
METHANOL (CAS 67-56-1): SKIN DESIGNATION APPLIES.
TOLUENE (CAS 108-88-3): SKIN DESIGNATION APPLIES.
US - TENNESSEE OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
US NIOSH POCKET GUIDE TO CHEMICAL HAZARDS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST VENTILATION. GOOD GENERAL
VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED.
VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO
AN ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER SHOULD BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. POLYVINYL ALCOHOL (PVA). NEOPRENE.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR
WITH AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS
IN CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO
DETERMINE ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. KEEP AWAY FROM FOOD AND DRINK. ALWAYS OBSERVE GOOD
PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND
BEFORE EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: CLEAR.
ODOR: SOLVENT.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -144 DEG. F (-97 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
132.9 DEG. F (56.1 DEG. C) ESTIMATED
FLASH POINT: -0.00004 DEG. F (-17.8 DEG. C)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 1% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 36% ESTIMATED
VAPOR PRESSURE: 107.9 HPA ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 0.78
SOLUBILITY(IES):
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 539.6 DEG. F (282 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 99.9% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. CONTACT WITH
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
ACIDS. ALKALIES. REDUCING AGENTS. STRONG OXIDIZING AGENTS. HYPOCHLORITES.
PEROXIDES. ALUMINUM. MAGNESIUM. SODIUM. ZINC.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES. FORMALDEHYDE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DAMAGE TO ORGANS BY INHALATION. MAY CAUSE DROWSINESS AND
DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED INHALATION MAY
BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
TOXIC IF SWALLOWED. DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS
THROUGH INGESTION OR VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PMEUMOMITIS. MAY CAUSE
DROWSINESS AND DIZZINESS. NARCOSIS. HEADACHE. NAUSEA, VOMITING.
BEHAVIORAL CHANGES. DECREASE IN MOTOR FUNCTIONS. SEVERE EYE IRRITATION.
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
COMPONENTS SPECIES TEST RESULTS
3-METHYLHEXANE (CAS 589-34-4):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
INHALATION:
LC50 RAT >20 MG/L, 4 HOURS
ORAL:
LD50 RAT >2000 MG/KG
ACETONE (CAS 67-64-1):
ACUTE:
DERMAL:
LD50 RABBIT > 15800 MG/KG
20000 MG/KG
INHALATION:
LC50 RAT 76 MG/L, 4 HOURS
ORAL:
LD50 RAT >5800 MG/KG
HEPTANE, BRANCHED, CYCLIC AND LINEAR (CAS 426260-76-6):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
INHALATION:
LC50 RAT >60 MG/L, 4 HOURS
ORAL:
LD50 RAT >5000 MG/KG
METHANOL (CAS 67-56-1):
ACUTE:
DERMAL:
LD50 RABBIT 12800 MG/KG
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
INHALATION:
LC50 RAT 61 MG/L, 4 HOURS
ORAL:
LD50 RAT >5000 MG/KG
N-HEPTANE (CAS 142-82-5):
ACUTE:
DERMAL:
LD50 RABBIT 3000 MG/KG
INHALATION:
VAPOR:
LC50 RAT >73.5 MG/L, 4 HOURS
ORAL:
LD50 RAT 25000 MG/KG
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. (CAS 64742-89-8):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
INHALATION:
LC50 RAT 61 MG/L, 4 HOURS
ORAL:
LD50 RAT >3000 MG/KG
TOLUENE (CAS 108-88-3):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
INHALATION:
LC50 RAT 12.5 MG/L, 4 HOURS
ORAL:
LD50 RAT 5580 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TOLUENE (CAS 108-88-3): 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES). MAY CAUSE
DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. PROLONGED
INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON TROUT 4740 - 6330 MG/L,
(ONCORHYNCHUS MYKISS) 96 HOURS
ACUTE:
CRUSTACEA EC50 DAPHNIA MAGNA 10294 - 17704 MG/L,
48 HOURS
HEPTANES, BRANCHED, CYCLIC AND LINEAR (CAS 426260-76-6):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >10000 MG/L, 48 HOURS
METHANOL (CAS 67-56-1):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >10000 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES >100 MG/L, 96 HOURS
PROMELAS)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0):
AQUATIC:
ACUTE:
CRUSTACEA EC50 DAPHNIA 1 - 10 MG/L, 48 HOURS
FISH LC50 FISH 1 - 10 MG/L, 48 HOURS
N-HEPTANE (CAS 142-82-5):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 1.5 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 2.1 - 2.98 MG/L, 96 HOURS
PROMELAS)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. (CAS 64742-89-8):
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON TROUT 8.8 MG/L, 96 HOURS
(ONCORHYNCHUS MYKISS)
8.8 MG/L, 96 HOURS
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 1.5 MG/L, 48 HOURS
TOLUENE (CAS 108-88-3):
ACUTE:
OTHER EC50 PSEUDOKIRCHNERELLA SUBCAPITATA 433 MG/L, 96 HOURS
12.5 MG/L, 72 HOURS
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 6 MG/L, 48 HOURS
FISH LC50 COHO SALMON, SILVER SALMON 5.5 MG/L, 96 HOURS
(ONCORHYNCHUS KISUTCH)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
ACETONE -0.24
METHANOL -0.77
N-HEPTANE 4.66
TOLUENE 2.73
BIOCONCENTRATION FACTOR (BCF):
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT 10 - 25000
TOLUENE 90
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
F003: WASTE NON-HALOGENATED SOLVENT - SPENT NON-HALOGENATED SOLVENT
F005: WASTE NON-HALOGENATED SOLVENT - SPENT NON-HALOGENATED SOLVENT
DISPOSAL INSTRUCTIONS:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER
SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL
OR USED CONTAINER. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT
RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1992
UN PROPER SHIPPING NAME:
FLAMMABLE LIQUIDS, TOXIC, N.O.S. (METHANOL RQ = 11785 LBS, TOLUENE
RQ = 5515 LBS), MARINE POLLUTANT (HEPTANES)
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK: 6.1
LABEL(S): 3, 6.1
PACKING GROUP: II
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
SPECIAL PRECAUTIONS FOR USER: NOT AVAILABLE.
SPECIAL PROVISIONS: IB2, T7, TP2, TP13
PACKAGING EXCEPTIONS: 150
PACKAGING NON BULK: 202
PACKAGING BULK: 243
IATA:
UN NUMBER: UN1992
UN PROPER SHIPPING NAME:
FLAMMABLE LIQUID, TOXIC, N.O.S. (METHANOL, TOLUENE)
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
ERG CODE: 3HP
SPECIAL PRECAUTIONS FOR USER: NOT AVAILABLE.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1992
UN PROPER SHIPPING NAME:
FLAMMABLE LIQUID, TOXIC, N.O.S. (METHANOL, TOLUENE), MARINE POLLUTANT
(HEPTANES)
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: F-E, S-D
SPECIAL PRECAUTIONS FOR USER: NOT AVAILABLE.
DOT:
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
POISION, CLASS/DIVISION 6.1 PACKING GROUP I OR II
IATA; IMDG:
CLASS 3, FLAMMABLE LIQUIDS
CLASS 6.2, INFECTIOUS SUBSTANCES
MARINE POLLUTANT: ENVIRONMENT
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFAMED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL: LISTED SUBSTANCE
METHANOL (CAS 67-56-1)
TOLUENE (CAS 108-88-3)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETONE (CAS 67-64-1)
METHANOL (CAS 67-56-1)
TOLUENE (CAS 108-88-3)
CERCLA HAZARDOUS SUBSTANCES: REPORTABLE QUANTITY
ACETONE (CAS 67-64-1): 5000 LBS
METHANOL (CAS 67-56-1): 5000 LBS
TOLUENE (CAS 108-88-3): 1000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR
ABOVE ITS RQ REQUIRE IMMEDIATE MORTIFICATION TO THE NATIONAL RESPONSE
CENTER (800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (EAPS) LIST:
METHANOL (CAS 67-56-1)
TOLUENE (CAS 108-88-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS
(21 CFR 1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
ACETONE (CAS 67-64-1) 6532
TOLUENE (CAS 108-88-3) 6594
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL
MIXTURES (21 CFR 1310.12(C)):
ACETONE (CAS 67-64-1) 35 %WV
TOLUENE (CAS 108-88-3) 35 %WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
ACETONE (CAS 67-64-1) 6532
TOLUENE (CAS 108-88-3) 594
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE
FLAVOR MANUFACTURING WORKPLACE:
ACETONE (CAS 67-64-1) LOW PRIORITY
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
CLASSIFIED HAZARD CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
REPRODUCTIVE TOXICITY
SPECIFIC TARGET ORGASM TOXICITY (SINGLE OR REPEATED EXPOSURE)
ASPIRATION HAZARD
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
METHANOL 67-56-1 40 - 50
TOLUENE 108-88-3 10 - 20
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
2,3-DIMETHYLPEMTAME (CAS 565-59-3)
3-METHYLHEXAME (CAS 589-34-4)
ACETONE (CAS 67-64-1)
METHANOL (CAS 67-56-1)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
N-HEPTANE (CAS 142-82-5)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. (CAS 64742-89-8)
TOLUENE (CAS 108-88-3)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
2,3-DIMETHYLPEMTAME (CAS 565-59-3)
2-METHYLHEXAME (CAS 591-76-4)
3-METHYLHEXAME (CAS 589-34-4)
ACETONE (CAS 67-64-1)
METHANOL (CAS 67-56-1)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
N-HEPTANE (CAS 142-82-5)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. (CAS 64742-89-8)
TOLUENE (CAS 108-88-3)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
2,3-DIMETHYLPEMTAME (CAS 565-59-3)
3-METHYLHEXAME (CAS 589-34-4)
ACETONE (CAS 67-64-1)
METHANOL (CAS 67-56-1)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
N-HEPTANE (CAS 142-82-5)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. (CAS 64742-89-8)
TOLUENE (CAS 108-88-3)
US. RHODE ISLAND RTK:
ACETONE (CAS 67-64-1)
METHANOL (CAS 67-56-1)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
N-HEPTANE (CAS 142-82-5)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. (CAS 64742-89-8)
TOLUENE (CAS 108-88-3)
CALIFORNIA PROPOSITION 65:
WARNING: CANCER AND REPRODUCTIVE HARM - WWW.P65WARMIMGS.CA.GOV
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
ACETALDEHYDE (CAS 75-07-0) LISTED: APRIL 1, 1988
BENZENE (CAS 71-43-2) LISTED: FEBRUARY 27, 1987
CUMENE (CAS 98-82-8) LISTED: APRIL 6, 2010
ETHYLBENZENE (CAS 100-41-4) LISTED: JUNE 11, 2004
NAPHTHALENE (CAS 91-20-3) LISTED: APRIL 19, 2002
CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
BENZENE (CAS 71-43-2) LISTED: DECEMBER 26, 1997
METHANOL (CAS 67-56-1) LISTED: MARCH 16, 2012
TOLUENE (CAS 108-88-3) LISTED: JANUARY 1, 1991
CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/MALE REPRODUCTIVE TOXIN
BENZENE (CAS 71-43-2) LISTED: DECEMBER 26, 1997
N-HEXANE (CAS 110-54-3) LISTED: DECEMBER 15, 2017
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
ACETONE (CAS 67-64-1)
METHANOL (CAS 67-56-1)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
M-HEPTANE (CAS 142-82-5)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. (CAS 64742-89-8)
TOLUENE (CAS 108-88-3)
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 90 %
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A BRAKE CLEANER. THIS PRODUCT IS NOT
COMPLIANT TO BE SOLD FOR USE IN CALIFORNIA, CONNECTICUT, DELAWARE, THE
DISTRICT OF COLUMBIA, ILLINOIS, INDIANA, MAINE, MARYLAND, MASSACHUSETTS,
MICHIGAN, NEW HAMPSHIRE, NEW JERSEY, NEW YORK, OHIO, PENNSYLVANIA, RHODE
ISLAND AND PARTS OF UTAH AND VIRGINIA. THIS PRODUCT IS COMPLIANT IN ALL
OTHER STATES.
VOC CONTENT (CA): 90 %
VOC CONTENT (OTC): 90 %
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON SUBSTANCES
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) YES
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL NO
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN CHEMICAL SUBSTANCE INVENTORY (TCSI) YES
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH
THE INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 08-01-2019
PREPARED BY: ALLISON YOON
VERSION #: 01
FURTHER INFORMATION: CRC # 483A/1002477
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC'S KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC TO
BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS
ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON
THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR
CRC INDUSTRIES, INC..
REVISION INFORMATION:
PRODUCT AND COMPANY IDENTIFICATION: PRODUCT CODES
ECOLOGICAL INFORMATION: ECOTOXICITY
TRANSPORT INFORMATION: MATERIAL TRANSPORTATION INFORMATION
MATERIAL NAME: BRAKLEEN(R*) BRAKE PARTS CLEANER - 55 GAL
SDS US