| Common Name: | CREW BATHROOM CLEANER & SCALE REMOVER, UNDILUTED PRODUCT |
| Manufacturer: | DIVERSEY |
| SDS Revision Date: | 6/7/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 10C401, 11Y681, 20J844 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
DIVERSEY(TM)
CREW(R*) BATHROOM CLEANER & SCALE REMOVER
REVISION: 2019-06-07
VERSION: 02.0
| 1. IDENTIFICATION |  |
PRODUCT NAME: CREW(R*) BATHROOM CLEANER & SCALE REMOVER
PRODUCT CODE: 95271230, 93172650, 93145310
SDS #: MS0800505
RECOMMENDED USE:
RESTROOM CARE
THIS PRODUCT IS INTENDED TO BE DILUTED PRIOR TO USE
USES ADVISED AGAINST: USES OTHER THAN THOSE IDENTIFIED ARE NOT RECOMMENDED
MANUFACTURER, IMPORTER, SUPPLIER:
US HEADQUARTERS
DIVERSEY, INC.
1300 ALTURA RD., SUITE 125
FORT MILL, SC 29708
PHONE: 1-888-352-2249
SDS INTERNET ADDRESS: HTTPS://SDS.DIVERSEY.COM
CANADIAN HEADQUARTERS
DIVERSEY CANADA, INC.
3755 LAIRD ROAD UNITS 8-11
MISSISSAUGA, ONTARIO L5L 0B3
PHONE: 1-800-668-7171
EMERGENCY TELEPHONE NUMBER:
1-800-851-7145
1-651-917-6133 (INT'L)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION FOR THE UNDILUTED PRODUCT:
ACUTE ORAL TOXICITY: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
CORROSION
EXCLAMATION MARK
SIGNAL WORD: DANGER.
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE DAMAGE.
PRECAUTIONARY STATEMENTS:
CAUSES BURNS/SERIOUS DAMAGE TO MOUTH, THROAT AND STOMACH. KEEP CONTAINER
TIGHTLY CLOSED. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH AFFECTED
AREAS THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WEAR CHEMICAL-SPLASH GOGGLES AND CHEMICAL-RESISTANT GLOVES.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. DRINK A CUPFUL OF MILK OR WATER.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE OR ATTENTION.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING FOR AT LEAST 15 MINUTES.
IMMEDIATELY CALL A POISON CENTER (1-800-851-7145) OR PHYSICIAN. TAKE OFF
CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE. DISPOSE OF IN ACCORDANCE
WITH ALL FEDERAL, STATE AND LOCAL APPLICABLE REGULATIONS.
HEALTH HAZARDS NOT OTHERWISE CLASSIFIED (HHNOC): NOT APPLICABLE
PHYSICAL HAZARDS NOT OTHERWISE CLASSIFIED (PHNOC): NOT APPLICABLE
CLASSIFICATION FOR THE DILUTED PRODUCT @ 1:18
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
EXCLAMATION MARK
DILUTION SIGNAL WORD: WARNING.
HAZARD AND PRECAUTIONARY STATEMENTS: CAUSES SERIOUS EYE IRRITATION.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH AFFECTED AREAS THOROUGHLY
AFTER HANDLING. MAY CAUSE IRRITATION TO MOUTH, THROAT AND STOMACH. WEAR
CHEMICAL-SPLASH GOGGLES AND CHEMICAL-RESISTANT GLOVES.
IF SWALLOWED: RINSE MOUTH. DRINK A CUPFUL OF MILK OR WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING FOR AT LEAST 15 MINUTES.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE OR ATTENTION. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL,
STATE AND LOCAL APPLICABLE REGULATIONS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CLASSIFIED INGREDIENTS:
INGREDIENT(S) CAS # WEIGHT %
POTASSIUM ALKYL BENZENE SULFONATE 85480-57-5 10 - 30%
DIETHYLENE GLYCOL MONOETHYL ETHER 111-90-0 3 - 7%
BENZYL ALCOHOL 100-51-6 3 - 7%
ALCOHOL ETHOXYLATE 68002-97-1 3 - 7%
GLYCOLIC ACID POTASSIUM SALT 1932-50-9 1 - 5%
CITRIC ACID 77-92-9 0.5 - 1.5%
POTASSIUM CITRATE 866-84-2 >0.1 - <1%
*EXACT PERCENTAGES ARE BEING WITHHELD AS TRADE SECRET INFORMATION
| 4. FIRST AID MEASURES | |
UNDILUTED PRODUCT:
EYES:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING FOR AT LEAST 15 MINUTES.
SKIN:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
INHALATION:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
INGESTION:
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. DRINK A CUPFUL OF MILK OR WATER.
MOST IMPORTANT SYMPTOMS/EFFECTS: NO INFORMATION AVAILABLE.
IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: NOT APPLICABLE.
DILUTED PRODUCT:
EYES:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING FOR AT LEAST 15 MINUTES.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
SKIN: NO SPECIFIC FIRST AID MEASURES ARE REQUIRED
INHALATION: NO SPECIFIC FIRST AID MEASURES ARE REQUIRED
INGESTION:
IF SWALLOWED: RINSE MOUTH. DRINK A CUPFUL OF MILK OR WATER.
| 5. FIRE-FIGHTING MEASURES | |
SPECIFIC METHODS: NO SPECIAL METHODS REQUIRED
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. EXTINGUISH FIRE USING AGENT SUITABLE FOR
SURROUNDING FIRE.
SPECIFIC HAZARDS: CORROSIVE MATERIAL (SEE SECTIONS 8 AND 10).
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
EXTINGUISHING MEDIA WHICH MUST NOT BE USED FOR SAFETY REASONS:
NO INFORMATION AVAILABLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8.).
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP METHODS:
CLEAN-UP METHODS - LARGE SPILLAGE. ABSORB SPILL WITH INERT MATERIAL (E.G.
DRY SAND OR EARTH), THEN PLACE IN A CHEMICAL WASTE CONTAINER. USE A WATER
RINSE FOR FINAL CLEAN-UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.
DO NOT TASTE OR SWALLOW. PRODUCT RESIDUE MAY REMAIN ON/IN EMPTY CONTAINERS.
ALL PRECAUTIONS FOR HANDLING THE PRODUCT MUST BE USED IN HANDLING THE EMPTY
CONTAINER AND RESIDUE. AVOID BREATHING VAPORS OR MISTS. USE ONLY WITH
ADEQUATE VENTILATION. REMOVE AND WASH CONTAMINATED CLOTHING AND FOOTWEAR
BEFORE RE-USE. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
STORAGE: KEEP TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
AEROSOL LEVEL (IF APPLICABLE): NOT APPLICABLE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
THIS PRODUCT, AS SUPPLIED, DOES NOT CONTAIN ANY HAZARDOUS MATERIALS WITH
OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY THE REGION SPECIFIC REGULATORY
BODIES.
UNDILUTED PRODUCT:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS.
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: CHEMICAL-SPLASH GOGGLES.
HAND PROTECTION: CHEMICAL-RESISTANT GLOVES.
SKIN AND BODY PROTECTION:
NO PERSONAL PROTECTIVE EQUIPMENT REQUIRED UNDER NORMAL USE CONDITIONS.
RESPIRATORY PROTECTION:
NO PERSONAL PROTECTIVE EQUIPMENT REQUIRED UNDER NORMAL USE CONDITIONS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
DILUTED PRODUCT:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS.
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: CHEMICAL-SPLASH GOGGLES.
HAND PROTECTION: CHEMICAL-RESISTANT GLOVES.
SKIN AND BODY PROTECTION:
NO PERSONAL PROTECTIVE EQUIPMENT REQUIRED UNDER NORMAL USE CONDITIONS.
RESPIRATORY PROTECTION:
NO PERSONAL PROTECTIVE EQUIPMENT REQUIRED UNDER NORMAL USE CONDITIONS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: CLEAR DARK PURPLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
ODOR: SURFACTANT
ODOR THRESHOLD: NO INFORMATION AVAILABLE.
BOILING POINT/RANGE: NOT DETERMINED
MELTING POINT/RANGE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NO INFORMATION AVAILABLE
SOLUBILITY: COMPLETELY SOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NO INFORMATION AVAILABLE
RELATIVE DENSITY (RELATIVE TO WATER): 1.072
DENSITY:
8.94 LBS/GAL
1.072 KG/L
VAPOR DENSITY: NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
VAPOR PRESSURE: NO INFORMATION AVAILABLE.
FLASH POINT (DEG. F):
>200 DEG. F
>93 DEG. C
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
ELEMENTAL PHOSPHORUS: 0.00% BY WT.
VOC: 0% *
PH: 4.38
FLAMMABILITY (SOLID OR GAS): NOT APPLICABLE
CORROSION TO METALS: NOT CORROSIVE TO METALS
SUSTAINED COMBUSTION: NOT APPLICABLE
EXPLOSION LIMITS:
UPPER: NOT DETERMINED
LOWER: NOT DETERMINED
DILUTION PH: 3.79
DILUTION FLASH POINT (DEG. F):
>200 DEG. F
>93.4 DEG. C
VOC % BY WT. AT USE DILUTION: 0.001%
* - TITLE 17, CALIFORNIA CODE OF REGULATIONS, DIVISION 3, CHAPTER 1,
SUBCHAPTER 8.5, ARTICLE 2, CONSUMER PRODUCTS, SECTIONS 94508
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT APPLICABLE
STABILITY: THE PRODUCT IS STABLE
HAZARDOUS DECOMPOSITION PRODUCTS: NONE REASONABLY FORESEEABLE.
MATERIALS TO AVOID:
DO NOT MIX WITH ANY OTHER PRODUCT OR CHEMICAL UNLESS SPECIFIED IN THE USE
DIRECTIONS.
CONDITIONS TO AVOID: NO INFORMATION AVAILABLE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
SKIN CONTACT, INHALATION, INGESTION, EYE CONTACT
DELAYED, IMMEDIATE, OR CHRONIC EFFECTS AND SYMPTOMS FROM SHORT AND
LONG-TERM EXPOSURE:
SKIN CONTACT:
CAUSES SKIN IRRITATION. SYMPTOMS MAY INCLUDE PAIN (WHICH MAY BE DELAYED),
REDNESS, AND/OR DISCOMFORT.
EYE CONTACT:
CORROSIVE. CAUSES SERIOUS EYE DAMAGE. SYMPTOMS MAY INCLUDE PAIN, BURNING
SENSATION, REDNESS, WATERING, BLURRED VISION OR LOSS OF VISION.
INGESTION:
CAUSES BURNS/SERIOUS DAMAGE TO MOUTH, THROAT AND STOMACH. SYMPTOMS MAY
INCLUDE STOMACH PAIN AND NAUSEA. HARMFUL IF SWALLOWED. SYMPTOMS MAY INCLUDE
VOMITING, NAUSEA, AND/OR FEELING OF GENERAL UNWELLNESS.
INHALATION:
MAY CAUSE IRRITATION AND CORROSIVE EFFECTS TO NOSE, THROAT AND RESPIRATORY
TRACT. SYMPTOMS MAY INCLUDE COUGHING AND DIFFICULTY BREATHING.
SENSITIZATION: NO KNOWN EFFECTS.
TARGET ORGANS (SE): NONE KNOWN
TARGET ORGANS (RE): NONE KNOWN
NUMERICAL MEASURES OF TOXICITY:
ATE - ORAL (MG/KG): 2000
ATE - DERMAL (MG/KG): >5000
ATE - INHALATORY, MISTS (MG/L): >20
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE FROM RESIDUES / UNUSED PRODUCTS (UNDILUTED PRODUCT):
THIS PRODUCT, AS SOLD, IF DISCARDED OR DISPOSED, IS NOT A HAZARDOUS WASTE
ACCORDING TO FEDERAL REGULATIONS (40 CFR 261.4 (B)(4)). UNDER RCRA, IT IS
THE RESPONSIBILITY OF THE USER OF THE PRODUCT TO DETERMINE, AT THE TIME OF
DISPOSAL, WHETHER THE WASTE SOLUTION MEETS RCRA CRITERIA FOR HAZARDOUS
WASTE. DISPOSE IN COMPLIANCE WITH ALL FEDERAL, STATE, PROVINCIAL, AND LOCAL
LAWS AND REGULATIONS.
WASTE FROM RESIDUES / UNUSED PRODUCTS (DILUTED PRODUCT):
THIS PRODUCT, WHEN DILUTED AS STATED ON THIS SDS, IS NOT A HAZARDOUS WASTE
ACCORDING TO FEDERAL REGULATIONS (40 CFR 261.4 (B)(4)). UNDER RCRA, IT IS
THE RESPONSIBILITY OF THE USER OF THE PRODUCT TO DETERMINE, AT THE TIME OF
DISPOSAL, WHETHER THE WASTE SOLUTION MEETS RCRA CRITERIA FOR HAZARDOUS
WASTE. DISPOSE IN COMPLIANCE WITH ALL FEDERAL, STATE, PROVINCIAL, AND LOCAL
LAWS AND REGULATIONS.
RCRA HAZARD CLASS (UNDILUTED PRODUCT): NOT REGULATED
RCRA HAZARD CLASS (DILUTED PRODUCT): NOT REGULATED
CONTAMINATED PACKAGING: DO NOT RE-USE EMPTY CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT/TDG/IMDG:
THE INFORMATION PROVIDED BELOW IS THE FULL TRANSPORTATION CLASSIFICATION
FOR THIS PRODUCT. THIS DESCRIPTION DOES NOT ACCOUNT FOR THE PACKAGE SIZE(S)
OF THIS PRODUCT, THAT MAY FALL UNDER A QUANTITY EXCEPTION, ACCORDING TO THE
APPLICABLE TRANSPORTATION REGULATIONS. WHEN SHIPPING DANGEROUS GOODS,
PLEASE CONSULT WITH YOUR INTERNAL, CERTIFIED HAZARDOUS MATERIALS SPECIALIST
TO DETERMINE IF ANY EXCEPTIONS CAN BE APPLIED TO YOUR SHIPMENT.
DOT (GROUND) BILL OF LADING DESCRIPTION: NOT REGULATED
IMDG (OCEAN) BILL OF LADING DESCRIPTION: NOT REGULATED
INTERNATIONAL INVENTORIES AT CAS# LEVEL:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE FOLLOWING INVENTORIES:
U.S.A. (TSCA), CANADA (DSL/NDSL).
RIGHT TO KNOW (RTK):
INGREDIENT(S) CAS # MARTK NJRTK PARTK RIRTK
WATER 7732-18-5
POTASSIUM ALKYL BENZENE SULFONATE 85480-57-5
BENZYL ALCOHOL 100-51-6 X X
DIETHYLENE GLYCOL MONOETHYL ETHER 111-90-0 X
ALCOHOL ETHOXYLATE 68002-97-1
GLYCOLIC ACID POTASSIUM SALT 1932-50-9
CITRIC ACID 77-92-9
POTASSIUM CITRATE 866-84-2
CERCLA/SARA:
INGREDIENT(S) CAS # WEIGHT % CERCLA/SARA SECTION 302 SECTION
RQ (LBS) TPQ (LBS) 313
DIETHYLENE GLYCOL 111-90-0 3 - 7% X
MONOETHYL ETHER
INGREDIENT(S) CAA HAP CAA ODS CWA PRIORITY
POLLUTANTS
DIETHYLENE GLYCOL MONOETHYL ETHER X
CANADIAN REGULATIONS:
| 16. OTHER INFORMATION | |
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION):
RATING SCALE: (LOW HAZARD) 0 - 4 (EXTREME HAZARD)
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS
DILUTED PRODUCT:
HEALTH 2
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS
REVISION: 2019-06-07
VERSION: 02.0
REASON FOR REVISION: NOT APPLICABLE
PREPARED BY: NORTH AMERICAN REGULATORY AFFAIRS
ADDITIONAL ADVICE:
DOES NOT CONTAIN AN ADDED FRAGRANCE
WHEN USED THROUGH DISPENSING/AUTODOSE EQUIPMENT, THIS PRODUCT MEETS GREEN
SEAL'S REQUIREMENTS FOR SKIN AND EYE IRRITATION AND ACUTE TOXICITY AT THE
AS-USED DILUTION
NOTICE TO READER:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESS OR
IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED WITHIN. ACTUAL
CONDITIONS OF USE AND HANDLING ARE BEYOND SELLER'S CONTROL. USER IS
RESPONSIBLE TO EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR
ANY PARTICULAR USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND
LOCAL LAWS AND REGULATIONS.