| Common Name: | REPEL PERMETHRIN CLOTHING & GEAR INSECT REPELLENT |
| Manufacturer: | CHEMSICO |
| SDS Revision Date: | 2/25/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 36WG49, 793G86 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
REPEL PERMETHRIN CLOTHING & GEAR INSECT REPELLENT
REVISION DATE: 2/25/2016
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIERS:
PRODUCT NAME: REPEL PERMETHRIN CLOTHING & GEAR INSECT REPELLENT
EPA REG. NUMBER: 305-55
RECOMMENDED PRODUCT USE: INSECTICIDE - FLEA & TICK, AEROSOL
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CHEMSICO
DIV. OF UNITED INDUSTRIES CORP.
P.O. BOX 142642
ST. LOUIS, MO 63114
FOR PRODUCT INFORMATION: 1-800-880-1181
FOR MEDICAL EMERGENCIES: 1-800-633-2873
| SECTION 2 - HAZARDS IDENTIFICATION | |
CONFORMS TO HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
GHS CLASSIFICATION OF SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOL: CATEGORY 2
GHS LABEL ELEMENTS:
HAZARD PICTOGRAM(S):
FLAME
GAS CYLINDER
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
FLAMMABLE AEROSOL
COMPRESSED GAS - CONTENTS UNDER PRESSURE; MAY BURST IF HEATED
CAUSES EYE IRRITATION
PRECAUTIONARY STATEMENTS:
CONTENTS UNDER PRESSURE.
DO NOT USE OR STORE NEAR HEAT OR OPEN FLAME.
DO NOT PUNCTURE OR INCINERATE CONTAINER.
EXPOSURE TO TEMPERATURES ABOVE 130 DEG. F MAY CAUSE BURSTING.
WASH HANDS THOROUGHLY WITH SOAP AND WATER AFTER HANDLING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS# WEIGHT PERCENT
PERMETHRIN 52645-53-1 0.50%
1-BUTOXY-2-PROPANOL 5131-66-8 0.50%
PETROLEUM DISTILLATES, HYDROTREATED LIGHT 64742-47-8 4.50%
ISOBUTANE 75-28-5 8.43%
PROPANE 74-98-6 6.57%
NOTE:
INGREDIENTS NOT IDENTIFIED ARE PROPRIETARY OR NON-HAZARDOUS. VALUES ARE
NOT PRODUCT SPECIFICATION(S).
| SECTION 4 - FIRST AID MEASURES | |
EYE CONTACT:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES, THEN CONTINUE
RINSING. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT ADVICE.
SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF WATER
FOR 15-20 MINUTES. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT
ADVICE.
INHALATION: NO SPECIAL REQUIREMENTS
INGESTION: NO SPECIAL REQUIREMENTS
NOTE TO PHYSICIAN: NONE
GENERAL ADVICE:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. KEEP OUT OF REACH OF CHILDREN.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES: PRESSURIZED AEROSOL CONTAINER
NFPA CLASSIFICATION: NFPA LEVEL 1 AEROSOL
SUITABLE EXTINGUISHING MEDIA: WATER FOG, FOAM, CO2, DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE - CONTAINER MAY BURST IN HEAT OF FIRE.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF-CONTAINED
BREATHING APPARATUS.
HAZARDOUS COMBUSTION PRODUCTS: NONE KNOWN
EXPLOSION DATA: NOT AVAILABLE
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONNEL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION. WEAR PERSONNEL PROTECTIVE EQUIPMENT AS
RECOMMENDED IN SECTION 8. WASH THOROUGHLY AFTER HANDLING.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS.
METHODS FOR CONTAINMENT AND CLEANING UP:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. BEFORE
ATTEMPTING CLEAN UP, REFER TO HAZARD DATA GIVEN ABOVE. SMALL SPILLS MAY BE
ABSORBED WITH EARTH, SAND OR ABSORBENT MATERIAL SWEPT UP AND PLACED IN
SUITABLE, COVERED, AND LABELED CONTAINERS. PREVENT LARGE SPILLS FROM
ENTERING SEWERS OR WATERWAYS. CONTACT EMERGENCY SERVICES AND SUPPLIER FOR
ADVICE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS RECOMMENDED IN
SECTION 8.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C
(122 DEG. F). DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT INGEST. AVOID
CONTACT WITH SKIN, EYES AND CLOTHING. AVOID BREATHING VAPOR OR MIST. USE
ONLY WITH ADEQUATE VENTILATION. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN
FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL
EQUIPMENT. USE ONLY NONSPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT
RESIDUE AND CAN BE HAZARDOUS.
STORAGE:
STORE IN A COOL, DRY AREA AWAY FROM OPEN FLAME. DO NOT STORE ABOVE
50 DEG. C (122 DEG. F).
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
CHEMICAL NAME EXPOSURE LIMITS
OSHA PEL ACGIH TLV SUPPLIER OEL
PPM MG/M3 PPM MG/M3 PPM MG/M3
PERMETHRIN TWA NONE NONE NONE
1-BUTOXY-2- TWA NOT LISTED NOT LISTED 50
PROPANOL
PETROLEUM TWA NONE LISTED 200 NONE LISTED
DISTILLATES,
LIGHT
ISOBUTANE TWA NOT ESTABLISHED 1000 NOT ESTABLISHED
PROPANE TWA 1000 1800 1000 NOT ESTABLISHED
ENGINEERING CONTROLS: GENERAL VENTILATION NORMALLY ADEQUATE.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
DURING APPLICATION, PREVENT ENTRY INTO EYES. WEAR SAFETY GLASSES WITH SIDE
SHIELDS IF USING IN LARGE APPLICATIONS.
SKIN AND BODY PROTECTION: WASH HANDS AFTER APPLICATION.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES.
WHEN USING, DO NOT EAT OR DRINK. WASH HANDS BEFORE BREAKS AND IMMEDIATELY
AFTER HANDLING THE PRODUCT.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: OPAQUE
COLOR: MILKY WHITE
PHYSICAL STATE: LIQUID
ODOR: ALIPHATIC SOLVENT
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7.4 (LIQUID PORTION)
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: 124 DEG. F (LIQUID PORTION)
FLAME EXTENSION: 0" (LEVEL 1 AEROSOL)
FLAMMABILITY LIMITS IN AIR, LOWER, % BY VOLUME: NO DATA AVAILABLE
FLAMMABILITY LIMITS IN AIR, UPPER, % BY VOLUME: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY @ 20 DEG. C: 0.982 (LIQUID PORTION)
OCTANOL/WATER COEFFICIENT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
SOLUBILITY: MISCIBLE IN WATER
EVAPORATION RATE: NO DATA AVAILABLE
% VOLATILE ORGANIC COMPOUNDS: 20.0
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
REACTIVITY:
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: AVOID STRONG OXIDIZERS.
CHEMICAL STABILITY:
PRODUCT STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
OTHER:
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRIMARY EYE IRRITATION:
CAUSES MODERATE EYE IRRITATION (EPA TOX. CATEGORY III)
PRIMARY SKIN IRRITATION: NON-IRRITATING (EPA TOX. CATEGORY IV)
ACUTE DERMAL:
LD50: >2000 MG/KG (EPA TOX. CATEGORY III)
ACUTE INHALATION:
LC50: >2 MG/L (EPA TOX. CATEGORY IV)
ACUTE ORAL:
LD50: >5000 MG/KG (EPA TOX. CATEGORY IV)
SENSITIZATION: NOT A SKIN SENSITIZER.
CHRONIC EFFECTS/CARCINOGENICITY: NO DATA AVAILABLE
MUTAGENICITY: NO DATA AVAILABLE
REPRODUCTIVE EFFECTS: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
ECOTOXICITY: NO DATA AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NO DATA AVAILABLE
AQUATIC TOXICITY: TOXIC TO AQUATIC ORGANISMS.
PERSISTENCE / DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATION / ACCUMULATION: NO DATA AVAILABLE
PARTITION COEFFICIENT: NO DATA AVAILABLE
MOBILITY IN ENVIRONMENTAL MEDIA: NO DATA AVAILABLE
CHEMICAL FATE INFORMATION: NO DATA AVAILABLE
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE CODES: NOT AVAILABLE
DISPOSAL INSTRUCTIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
WASTE FROM RESIDUES / UNUSED PRODUCTS: NOT AVAILABLE
CONTAMINATED PACKAGING: NOT AVAILABLE
| SECTION 14 - TRANSPORTATION INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION:
(DOT): UN-1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY
IATA: UN-1950, AEROSOLS, 2.1
IMDG: UN-1950, AEROSOLS, FLAMMABLE, 2, LIMITED QUANTITY
| SECTION 15 - REGULATORY INFORMATION | |
29 CFR 1910.1200 HAZARDOUS CHEMICAL OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NO
CERCLA (SUPERFUND) REPORTABLE QUANTITY: NOT AVAILABLE
HAZARD CATEGORIES:
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
IMMEDIATE HAZARD: NO
DELAYED HAZARD: NO
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: NO
CLEAN AIR ACT (CAA): NOT AVAILABLE
CLEAN WATER ACT (CWA): NOT AVAILABLE
STATE REGULATIONS:
FIFRA LABELING:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS, AND FOR
WORKPLACE NON-PESTICIDE CHEMICALS. FOLLOWING IS THE HAZARD INFORMATION AS
REQUIRED ON THE PESTICIDE LABEL:
SIGNAL WORD: CAUTION
PRECAUTIONARY STATEMENTS:
HARMFUL IF ABSORBED THROUGH SKIN. CAUSES MODERATE EYE IRRITATION. AVOID
CONTACT WITH SKIN, EYES OR CLOTHING. WASH THOROUGHLY WITH SOAP AND WATER
AFTER HANDLING AND BEFORE EATING, DRINKING, CHEWING GUM, USING TOBACCO OR
USING THE TOILET. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
DO NOT USE ON CATS. MAY BE TOXIC OR POTENTIALLY FATAL IF APPLIED TO OR
INGESTED BY CATS. ACCIDENTAL APPLICATION TO CATS AND/OR GROOMING A RECENTLY
TREATED DO MAY RESULT IN TREMORS AND/OR UNCOORDINATED MUSCLE MOVEMENTS.
IF THIS OCCURS, IMMEDIATE VETERINARY CARE SHOULD BE PROVIDED.
THIS PESTICIDE IS EXTREMELY TOXIC TO AQUATIC ORGANISMS, INCLUDING FISH AND
INVERTEBRATES. DO NOT APPLY DIRECTLY TO OR NEAR WATER. DRIFT AND RUNOFF MAY
BE HAZARDOUS TO FISH IN WATER ADJACENT TO TREATED AREAS. THIS PESTICIDE IS
HIGHLY TOXIC TO BEES EXPOSED TO DIRECT TREATMENT ON BLOOMING CROPS OR
WEEDS. DO NOT APPLY THIS PRODUCT OR ALLOW IT TO DRIFT TO BLOOMING CROPS OR
WEEDS WHILE BEES ARE ACTIVELY VISITING THE TREATMENT AREA.
CONTENTS UNDER PRESSURE. DO NOT USE OR STORE NEAR HEAT OR OPEN FLAME.
EXPOSURE TO TEMPERATURES ABOVE 130 DEG. F MAY CAUSE BURSTING.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR ANY OTHER REPRODUCTIVE HARM.
DISCLAIMER:
INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED
TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO
ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT
AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE
BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS MATERIAL
HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE
LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED OR IMPLIED,
IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR
CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON ANY
INFORMATION CONTAINED IN THIS DOCUMENT.
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH HAZARD 1
FLAMMABILITY 2
PHYSICAL HAZARD 1
ITEM NUMBERS: HG-94127
FORMULA NUMBER(S): 21-1096
ISSUE DATE: 2/25/2016
PREPARED BY:
WPC BRANDS, INC.
P.O. BOX 4406
BRIDGETON, MO 63044-0406
(800) 242-1166