| Common Name: | SAFEGUARD LIQUID ANTIBACTERIAL HAND SOAP |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 5/14/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 43PG35, 44F742 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G PROFESSIONAL(TM)
SAFETY DATA SHEET
ISSUING DATE: 08-JAN-2016
REVISION DATE: 14-MAY-2018
VERSION 1.02
| 1. IDENTIFICATION |  |
PRODUCT NAME: SAFEGUARD(R*) LIQUID ANTIBACTERIAL HAND SOAP
PRODUCT CODE(S): 2-10
PRODUCT IDENTIFIER: 97284925_PROF_NG
PRODUCT TYPE: FINISHED PRODUCT - PROFESSIONAL USE ONLY
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
PROCTER & GAMBLE PROFESSIONAL
1 P&G PLAZA
CINCINNATI, OHIO 45202
PROCTER & GAMBLE INC.
P.O. BOX 355, STATION A
TORONTO, ON M5W 1C5
1-800-332-7787
E-MAIL ADDRESS: PGSDS.IM@PG.COM
EMERGENCY TELEPHONE:
TRANSPORTATION (24 HR):
CHEMTREC: 1-800-424-9300
(U.S./ CANADA) OR: 1-703-527-3887
MEXICO TOLL FREE IN COUNTRY: 800-681-9531
| 2. HAZARD IDENTIFICATION | |
THIS PRODUCT IS CLASSIFIED UNDER 29CFR 1910.1200(D) AND THE CANADIAN
HAZARDOUS PRODUCTS REGULATION AS FOLLOWS: NOT CLASSIFIED.
HAZARD STATEMENTS: NONE
HAZARD PICTOGRAMS: NONE
PRECAUTIONARY STATEMENTS: NONE
PRECAUTIONARY STATEMENTS - RESPONSE: NONE
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL REGULATION
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS ARE LISTED ACCORDING TO 29CFR 1910.1200 APPENDIX D
AND THE CANADIAN HAZARDOUS PRODUCTS REGULATION
CHEMICAL NAME SYNONYMS TRADE CAS-NO WEIGHT-%
SECRET
SULFURIC ACID SULFURIC ACID YES 151-21-3 3 - 7
MONODODECYL ESTER MONODODECYL ESTER
SODIUM SALT (1:1) SODIUM SALT (1:1)
POLY(OXY-1,2- POLY(OXY-1,2- YES 9004-82-4 1 - 5
ETHANEDIYL), ETHANEDIYL),
ALPHA-SULFO-OMEGA- ALPHA-SULFO-
(DODECYLOXY)-, OMEGA-(DODE
SODIUM SALT (1:1) CYLOXY)-, SODIUM
SALT (1:1)
DODECANAMIDE, DODECANAMIDE, YES 120-40-1 1 - 5
N,N-BIS(2- N,N-BIS(2-
HYDROXYETHYL)- HYDROXYETHYL)-
1-PROPANAMINIUM, 1-PROPANAMINIUM, YES 61789-40-0 0.5 - 1.5
3-AMINO-N- 3-AMINO-N-
(CARBOXYMETHYL)- (CARBOXYMETHYL)-
N,N-DIMETHYL-, N,N-DIMETHYL-,
N-COCO ACYL N-COCOACYL DERIVS.,
DERIVS., INNER INNER SALTS
SALTS
CHLOROXYLENOL PHENOL, 4-CHLORO- YES 88-04-0 0.1 - 1
3,5-DIMETHYL-
ADDITIONAL INFORMATION:
ACTUAL CONCENTRATIONS WITHHELD AS TRADE SECRET IN ACCORDANCE WITH
CANADIAN HPR
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IMMEDIATELY IF
IRRITATION PERSISTS. SKIN CONTACT RINSE WITH PLENTY OF WATER. GET
MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED: NONE UNDER NORMAL
USE CONDITIONS.
F. INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED, IF NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO 2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY. DRY
CHEMICAL. ALCOHOL RESISTANT FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIAL HAZARD: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. DO NOT GET IN EYES, ON SKIN, OR
ON CLOTHING.
ADVICE FOR EMERGENCY RESPONDERS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
KEEP OUT OF WATERWAYS
DO NOT DISCHARGE PRODUCT INTO NATURAL WATERS WITHOUT PRE-TREATMENT OR
ADEQUATE DILUTION
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND
TRANSFER TO CONTAINERS FOR LATER DISPOSAL. PREVENT PRODUCT FROM
ENTERING DRAINS. PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT
MATERIAL, (E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND
PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL
REGULATIONS (SEE SECTION 13).
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED
WHEN NOT IN USE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE.
KEEP OUT OF THE REACH OF CHILDREN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME CAS-NO ALBERTA QUEBEC ONTARIO TWAEV BRITISH
COLUMBIA
PHENOXYETHANOL 122-99-6 TWA: 25 PPM
TWA: 141 MG/M3
SKIN
NO RELEVANT EXPOSURE GUIDELINES FOR OTHER INGREDIENTS
EXPOSURE CONTROLS:
ENGINEERING MEASURES:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS: ENSURE ADEQUATE VENTILATION
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
USE APPROPRIATE EYE PROTECTION
HAND PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
PROTECTIVE GLOVES
SKIN AND BODY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE @20 DEG. C: LIQUID
APPEARANCE: PEACH OPAQUE
ODOR: SWEET
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES NOTE
PH VALUE 6.2 10% AQUEOUS
SOLUTION
MELTING POINT / FREEZING POINT 100 DEG. C / 212 DEG. F
BOILING POINT / BOILING RANGE NO INFORMATION AVAILABLE
FLASH POINT 93.4 DEG. C / >200 DEG. F.
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
RELATIVE DENSITY NO INFORMATION AVAILABLE
WATER SOLUBILITY NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
VISCOSITY NO INFORMATION AVAILABLE
VOC CONTENT (%):
PRODUCTS COMPLY WITH US STATE AND FEDERAL REGULATIONS FOR VOC CONTENT
IN CONSUMER PRODUCTS.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
STABILITY: STABLE UNDER NORMAL CONDITIONS.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE UNDER NORMAL PROCESSING.
INCOMPATIBLE MATERIALS: NONE IN PARTICULAR.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL USE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO KNOWN EFFECT.
SKIN CONTACT: NO KNOWN EFFECT.
INGESTION: NO KNOWN EFFECT.
EYE CONTACT: NO KNOWN EFFECT.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
ACUTE TOXICITY: NO KNOWN EFFECT.
SKIN CORROSION/IRRITATION: NO KNOWN EFFECT.
SERIOUS EYE DAMAGE/EYE IRRITATION: NO KNOWN EFFECT.
SKIN SENSITIZATION: NO KNOWN EFFECT.
RESPIRATORY SENSITIZATION: NO KNOWN EFFECT.
GERM CELL MUTAGENICITY: NO KNOWN EFFECT.
NEUROLOGICAL EFFECTS: NO KNOWN EFFECT.
REPRODUCTIVE TOXICITY: NO KNOWN EFFECT.
DEVELOPMENTAL TOXICITY: NO KNOWN EFFECT.
TERATOGENICITY: NO KNOWN EFFECT.
STOT - SINGLE EXPOSURE: NO KNOWN EFFECT.
STOT - REPEATED EXPOSURE: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: NO KNOWN EFFECT.
ASPIRATION HAZARD: NO KNOWN EFFECT.
CARCINOGENICITY: NO KNOWN EFFECT.
COMPONENT INFORMATION:
CHEMICAL NAME CAS-NO ORAL LD50 DERMAL LD50 INHALATION LC50
SULFURIC ACID 151-21-3 977 MG/KG >2000 MG/KG
MONODODECYL ESTER BW (OECD 401) BW (OECD 402)
SODIUM SALT (1:1)
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
WASTE FROM RESIDUES/UNUSED PRODUCTS:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL
AND LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL
AND LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES (NON-HOUSEHOLD SETTING): 331
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
IMDG: NOT REGULATED
IATA: NOT REGULATED
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED AS
A HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302):
CHEMICAL NAME CAS-NO HAZARDOUS EXTREMELY CERCLA/SARA
SUBSTANCES HAZARDOUS 302 TPQ
RQS SUBSTANCES
RQS
2,2'-IMINODIETHANOL 111-42-2 100 LB
FORMALDEHYDE ...% 50-00-0 100 LB 100 LB 500 LB
METHANOL 67-56-1 5000 LB
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCE(S) WHICH ARE EITHER LISTED
AS HAZARDOUS AIR POLLUTANTS (HAPS) OR VOC'S PER THE CLEAN AIR ACT:
CHEMICAL NAME CAS-NO CAA (CLEAN AIR ACT) - 1990
HAZARDOUS AIR POLLUTANTS
2,2'-IMINODIETHANOL 111-42-2 X
FORMALDEHYDE ...% 50-00-0 X
METHANOL 67-56-1 X
CLEAN WATER ACT:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE REGULATED
POLLUTANTS PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40
CFR 122.42):
CHEMICAL NAME CAS-NO CWA - CWA - TOXIC CWA - CWA -
REPORTABLE POLLUTANTS PRIORITY HAZARDOUS
QUANTITIES POLLUTANTS SUBSTANCES
FORMALDEHYDE ...% 50-00-0 100 LB X
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
ETHANOL IS ONLY A CONSIDERED A PROPOSITION 65 DEVELOPMENTAL HAZARD
WHEN IT IS INGESTED AS AN ALCOHOLIC BEVERAGE.
U.S. STATE REGULATIONS (RTK):
CHEMICAL NAME CAS-NO PENNSYLVANIA
GLYCERIN 56-81-5 X
2,2'-IMINODIETHANOL 111-42-2 X
INTERNATIONAL INVENTORIES:
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT(S) ARE LISTED ON THE
US TSCA INVENTORY.
CANADA: THIS PRODUCT IS IN COMPLIANCE WITH CEPA FOR IMPORT BY P&G.
LEGEND:
UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY (TSCA)
CEPA - CANADIAN ENVIRONMENTAL PROTECTION ACT
| 16. OTHER INFORMATION | |
ISSUING DATE: 08-JAN-2016
REVISION DATE: 14-MAY-2018
DISCLAIMER.:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE
BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR
SAFE HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND
RELEASE AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION.
THE INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY
NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER
MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT