| Common Name: | FROTH-PAK ISO INT AF HFC, FROTH-PAK CLASS A POLYOL INT BLEND |
| Manufacturer: | DOW CHEMICAL |
| SDS Revision Date: | 4/26/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 48WK27 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DOW(R*)
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
PRODUCT NAME: FROTH-PAK(TM) ISO INT AF HFC
ISSUE DATE: 04/26/2016
PRINT DATE: 11/02/2017
THE DOW CHEMICAL COMPANY ENCOURAGES AND EXPECTS YOU TO READ AND
UNDERSTAND THE ENTIRE (M)SDS, AS THERE IS IMPORTANT INFORMATION
THROUGHOUT THE DOCUMENT. WE EXPECT YOU TO FOLLOW THE PRECAUTIONS
IDENTIFIED IN THIS DOCUMENT UNLESS YOUR USE CONDITIONS WOULD
NECESSITATE OTHER APPROPRIATE METHODS OR ACTIONS.
| 1. IDENTIFICATION |  |
PRODUCT NAME: FROTH-PAK(TM) ISO INT AF HFC
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
IDENTIFIED USES:
FOR INDUSTRIAL USE. COMPONENT(S) FOR THE MANUFACTURE OF URETHANE POLYMERS.
WE RECOMMEND THAT YOU USE THIS PRODUCT IN A MANNER CONSISTENT WITH THE
LISTED USE. IF YOUR INTENDED USE IS NOT CONSISTENT WITH THE STATED USE,
PLEASE CONTACT YOUR SALES OR TECHNICAL SERVICE REPRESENTATIVE.
COMPANY IDENTIFICATION:
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
CUSTOMER INFORMATION NUMBER:
800-258-2436
SDSQUESTION@DOW.COM
EMERGENCY TELEPHONE NUMBER:
24-HOUR EMERGENCY CONTACT:
CHEMTREC: +1 800-424-9300
LOCAL EMERGENCY CONTACT: 800-424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
THIS MATERIAL IS HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD 29CFR 1910.1200.
GASES UNDER PRESSURE: LIQUEFIED GAS
ACUTE TOXICITY: CATEGORY 4 - INHALATION
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2B
RESPIRATORY SENSITISATION: CATEGORY 1
SKIN SENSITISATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CATEGORY 2 - INHALATION
LABEL ELEMENTS:
HAZARD PICTOGRAMS:
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MAR
SIGNAL WORD: DANGER!
HAZARDS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN AND EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HARMFUL IF INHALED.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DAMAGE TO ORGANS (RESPIRATORY TRACT) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/ FUME/ GAS/ MIST/ VAPOURS/ SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NO DATA AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT IS A MIXTURE.
COMPONENT CASRN CONCENTRATION
DIPHENYLMETHANE DIISOCYANATE, 9016-87-9 >=60.0 - <=100.0 %
ISOMERS AND HOMOLOGUES
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8 30.0 - 60.0 %
1,1,1,2-TETRAFLUOROETHANE 811-97-2 >=5.0 - <=10.0 %
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION AND USE
THE RECOMMENDED PROTECTIVE CLOTHING (CHEMICAL RESISTANT GLOVES, SPLASH
PROTECTION). IF POTENTIAL FOR EXPOSURE EXISTS REFER TO SECTION 8 FOR
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT.
INHALATION:
MOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION;
IF BY MOUTH TO MOUTH USE RESCUER PROTECTION (POCKET MASK, ETC). IF
BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. CALL A PHYSICIAN OR TRANSPORT TO A MEDICAL FACILITY.
SKIN CONTACT:
REMOVE MATERIAL FROM SKIN IMMEDIATELY BY WASHING WITH SOAP AND PLENTY OF
WATER. REMOVE CONTAMINATED CLOTHING AND SHOES WHILE WASHING. SEEK MEDICAL
ATTENTION IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. AN MDI SKIN
DECONTAMINATION STUDY DEMONSTRATED THAT CLEANING VERY SOON AFTER EXPOSURE
IS IMPORTANT, AND THAT A POLYGLYCOL-BASED SKIN CLEANSER OR CORN OIL MAY
BE MORE EFFECTIVE THAN SOAP AND WATER. DISCARD ITEMS WHICH CANNOT BE
DECONTAMINATED, INCLUDING LEATHER ARTICLES SUCH AS SHOES, BELTS AND
WATCHBANDS. SUITABLE EMERGENCY SAFETY SHOWER FACILITY SHOULD BE AVAILABLE
IN WORK AREA.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH WATER; REMOVE CONTACT LENSES, IF PRESENT,
AFTER THE FIRST 5 MINUTES, THEN CONTINUE FLUSHING EYES FOR AT LEAST
15 MINUTES. OBTAIN MEDICAL ATTENTION WITHOUT DELAY, PREFERABLY FROM
AN OPHTHALMOLOGIST. SUITABLE EMERGENCY EYE WASH FACILITY SHOULD BE
IMMEDIATELY AVAILABLE.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY MEDICAL PERSONNEL.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASIDE FROM THE INFORMATION FOUND UNDER DESCRIPTION OF FIRST AID
MEASURES (ABOVE) AND INDICATION OF IMMEDIATE MEDICAL ATTENTION
AND SPECIAL TREATMENT NEEDED (BELOW), ANY ADDITIONAL IMPORTANT
SYMPTOMS AND EFFECTS ARE DESCRIBED IN SECTION 11:
TOXICOLOGY INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
EXCESSIVE EXPOSURE MAY AGGRAVATE PREEXISTING ASTHMA AND OTHER RESPIRATORY
DISORDERS (E.G. EMPHYSEMA, BRONCHITIS, REACTIVE AIRWAYS DYSFUNCTION
SYNDROME). MAINTAIN ADEQUATE VENTILATION AND OXYGENATION OF THE
PATIENT. MAY CAUSE RESPIRATORY SENSITIZATION OR ASTHMA-LIKE SYMPTOMS.
BRONCHODILATORS, EXPECTORANTS AND ANTITUSSIVES MAY BE OF HELP. TREAT
BRONCHOSPASM WITH INHALED BETA2 AGONIST AND ORAL OR PARENTERAL
CORTICOSTEROIDS. RESPIRATORY SYMPTOMS, INCLUDING PULMONARY EDEMA,
MAY BE DELAYED. PERSONS RECEIVING SIGNIFICANT EXPOSURE SHOULD BE
OBSERVED 24-48 HOURS FOR SIGNS OF RESPIRATORY DISTRESS. IF YOU ARE
SENSITIZED TO DIISOCYANATES, CONSULT YOUR PHYSICIAN REGARDING WORKING
WITH OTHER RESPIRATORY IRRITANTS OR SENSITIZERS. EXPOSURE MAY INCREASE
"MYOCARDIAL IRRITABILITY". DO NOT ADMINISTER SYMPATHOMIMETIC DRUGS SUCH
AS EPINEPHRINE UNLESS ABSOLUTELY NECESSARY. TREATMENT OF EXPOSURE SHOULD
BE DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION OF THE
PATIENT.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG OR FINE SPRAY. DRY CHEMICAL FIRE EXTINGUISHERS. CARBON
DIOXIDE FIRE EXTINGUISHERS. FOAM. ALCOHOL RESISTANT FOAMS (ATC TYPE)
ARE PREFERRED. GENERAL PURPOSE SYNTHETIC FOAMS (INCLUDING AFFF) OR
PROTEIN FOAMS MAY FUNCTION, BUT WILL BE LESS EFFECTIVE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE DIRECT WATER STREAM. MAY SPREAD FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS COMBUSTION PRODUCTS:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR
IRRITATING. COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
NITROGEN OXIDES. ISOCYANATES. HYDROGEN CYANIDE. CARBON MONOXIDE.
CARBON DIOXIDE. HYDROGEN HALIDES. HALOGENATED HYDROCARBONS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
SOME COMPONENTS OF THIS PRODUCT WILL BURN IN A FIRE SITUATION. PRODUCT
REACTS WITH WATER. REACTION MAY PRODUCE HEAT AND/OR GASES. THIS REACTION
MAY BE VIOLENT. CONTAINER MAY RUPTURE FROM GAS GENERATION IN A FIRE
SITUATION. BLOWING AGENT VAPORIZES QUICKLY AT ROOM TEMPERATURE. VIOLENT
STEAM GENERATION OR ERUPTION MAY OCCUR UPON APPLICATION OF DIRECT WATER
STREAM TO HOT LIQUIDS. DENSE SMOKE IS PRODUCED WHEN PRODUCT BURNS.
ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
KEEP PEOPLE AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY. STAY UPWIND.
KEEP OUT OF LOW AREAS WHERE GASES (FUMES) CAN ACCUMULATE. WATER IS NOT
RECOMMENDED, BUT MAY BE APPLIED IN LARGE QUANTITIES AS A FINE SPRAY WHEN
OTHER EXTINGUISHING AGENTS ARE NOT AVAILABLE. DO NOT USE DIRECT WATER
STREAM. MAY SPREAD FIRE. FIGHT FIRE FROM PROTECTED LOCATION OR SAFE
DISTANCE. CONSIDER THE USE OF UNMANNED HOSE HOLDERS OR MONITOR NOZZLES.
IMMEDIATELY WITHDRAW ALL PERSONNEL FROM THE AREA IN CASE OF RISING
SOUND FROM VENTING SAFETY DEVICE OR DISCOLORATION OF THE CONTAINER.
MOVE CONTAINER FROM FIRE AREA IF THIS IS POSSIBLE WITHOUT HAZARD.
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND FIRE-AFFECTED
ZONE UNTIL FIRE IS OUT. CONTAIN FIRE WATER RUN-OFF IF POSSIBLE.
FIRE WATER RUNOFF, IF NOT CONTAINED, MAY CAUSE ENVIRONMENTAL DAMAGE.
REVIEW THE "ACCIDENTAL RELEASE MEASURES" AND THE "ECOLOGICAL
INFORMATION" SECTIONS OF THIS (M)SDS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT,
TROUSERS, BOOTS, AND GLOVES). AVOID CONTACT WITH THIS MATERIAL DURING
FIRE FIGHTING OPERATIONS. IF CONTACT IS LIKELY, CHANGE TO FULL CHEMICAL
RESISTANT FIRE FIGHTING CLOTHING WITH SELF-CONTAINED BREATHING APPARATUS.
IF THIS IS NOT AVAILABLE, WEAR FULL CHEMICAL RESISTANT CLOTHING WITH
SELF-CONTAINED BREATHING APPARATUS AND FIGHT FIRE FROM A REMOTE LOCATION.
FOR PROTECTIVE EQUIPMENT IN POST-FIRE OR NON-FIRE CLEAN-UP SITUATIONS,
REFER TO THE RELEVANT SECTIONS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ISOLATE AREA. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING THE
AREA. REFER TO SECTION 7, HANDLING, FOR ADDITIONAL PRECAUTIONARY MEASURES.
KEEP PERSONNEL OUT OF LOW AREAS. KEEP PERSONNEL OUT OF CONFINED OR POORLY
VENTILATED AREAS. KEEP UPWIND OF SPILL. VENTILATE AREA OF LEAK OR SPILL.
CONFINED SPACE ENTRY PROCEDURES MUST BE FOLLOWED BEFORE ENTERING THE AREA.
SEE SECTION 10 FOR MORE SPECIFIC INFORMATION. USE APPROPRIATE SAFETY
EQUIPMENT. FOR ADDITIONAL INFORMATION, REFER TO SECTION 8, EXPOSURE
CONTROLS AND PERSONAL PROTECTION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FROM ENTERING INTO SOIL, DITCHES, SEWERS, WATERWAYS AND/OR
GROUNDWATER. SEE SECTION 12, ECOLOGICAL INFORMATION.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLED MATERIAL IF POSSIBLE.
ABSORB WITH MATERIALS SUCH AS: DIRT. VERMICULITE. SAND. CLAY.
DO NOT USE ABSORBENT MATERIALS SUCH AS:
CEMENT POWDER (NOTE: MAY GENERATE HEAT). COLLECT IN SUITABLE AND PROPERLY
LABELED OPEN CONTAINERS. SEE SECTION 13, DISPOSAL CONSIDERATIONS, FOR
ADDITIONAL INFORMATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED OR REPEATED
CONTACT WITH SKIN. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING VAPOR.
USE WITH ADEQUATE VENTILATION. THIS MATERIAL IS HYGROSCOPIC IN NATURE.
KEEP CONTAINER CLOSED. DO NOT ENTER CONFINED SPACES UNLESS ADEQUATELY
VENTILATED. SEE SECTION 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
SPILLS OF THESE ORGANIC MATERIALS ON HOT FIBROUS INSULATIONS MAY LEAD
TO LOWERING OF THE AUTOIGNITION TEMPERATURES POSSIBLY RESULTING IN
SPONTANEOUS COMBUSTION.
CONDITIONS FOR SAFE STORAGE:
STORE IN A DRY PLACE. AVOID PROLONGED EXPOSURE TO HEAT AND AIR. PROTECT
FROM ATMOSPHERIC MOISTURE. BLOWING AGENT MAY MIGRATE FROM PRODUCT AND
ACCUMULATE IN SOME STORAGE SITUATIONS. ELEVATED TEMPERATURES CAN CAUSE
PRESSURE BUILDUP IN CLOSED CONTAINERS DUE TO THE RELEASE OF BLOWING
AGENTS. STORE IN THE FOLLOWING MATERIAL(S): CARBON STEEL. STAINLESS
STEEL. POLYPROPYLENE. POLYETHYLENE-LINED CONTAINER. TEFLON. GLASS-LINED
CONTAINER. ALUMINUM. PLASITE 3066 LINED CONTAINER. PLASITE 3070 LINED
CONTAINER. 316 STAINLESS STEEL. SEE SECTION 10 FOR MORE SPECIFIC
INFORMATION.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS ARE LISTED BELOW, IF THEY EXIST.
COMPONENT REGULATION TYPE OF LISTING VALUE/NOTATION
4,4' -METHYLENEDIPHENYL DOW IHG TWA 0.005 PPM
DIISOCYANATE
DOW IHG STEL 0.02 PPM
ACGIH TWA 0.005 PPM
OSHA Z-1 C 0.2 MG/M3
0.02 PPM
CAL PEL PEL 0.051 MG/M3
0.005 PPM
1,1,1,2-TETRAFLUOROETHANE US WEEL TWA 1,000 PPM
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION MAY BE
NECESSARY FOR SOME OPERATIONS. PROVIDE GENERAL AND/OR LOCAL EXHAUST
VENTILATION TO CONTROL AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
EXHAUST SYSTEMS SHOULD BE DESIGNED TO MOVE THE AIR AWAY FROM THE SOURCE
OF VAPOR/AEROSOL GENERATION AND PEOPLE WORKING AT THIS POINT. THE ODOR
AND IRRITANCY OF THIS MATERIAL ARE INADEQUATE TO WARN OF EXCESSIVE
EXPOSURE. LETHAL CONCENTRATIONS MAY EXIST IN AREAS WITH POOR VENTILATION.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION: USE CHEMICAL GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL. EXAMPLES OF
PREFERRED GLOVE BARRIER MATERIALS INCLUDE: BUTYL RUBBER. POLYETHYLENE.
CHLORINATED POLYETHYLENE. ETHYL VINYL ALCOHOL LAMINATE ("EVAL"). EXAMPLES
OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE: VITON. NEOPRENE. POLYVINYL
CHLORIDE ("PVC" OR "VINYL"). NITRILE/BUTADIENE RUBBER ("NITRILE" OR
"NBR"). NOTICE: THE SELECTION OF A SPECIFIC GLOVE FOR A PARTICULAR
APPLICATION AND DURATION OF USE IN A WORKPLACE SHOULD ALSO TAKE INTO
ACCOUNT ALL RELEVANT WORKPLACE FACTORS SUCH AS, BUT NOT LIMITED TO:
OTHER CHEMICALS WHICH MAY BE HANDLED, PHYSICAL REQUIREMENTS (CUT/PUNCTURE
PROTECTION, DEXTERITY, THERMAL PROTECTION), POTENTIAL BODY REACTIONS TO
GLOVE MATERIALS, AS WELL AS THE INSTRUCTIONS/SPECIFICATIONS PROVIDED BY
THE GLOVE SUPPLIER.
OTHER PROTECTION:
USE PROTECTIVE CLOTHING CHEMICALLY RESISTANT TO THIS MATERIAL. SELECTION
OF SPECIFIC ITEMS SUCH AS FACE SHIELD, BOOTS, APRON, OR FULL BODY SUIT
WILL DEPEND ON THE TASK.
RESPIRATORY PROTECTION:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE.
WHEN ATMOSPHERIC LEVELS MAY EXCEED THE EXPOSURE GUIDELINE, USE AN
APPROVED AIRPURIFYING RESPIRATOR EQUIPPED WITH AN ORGANIC VAPOR SORBENT
AND A PARTICLE FILTER. FOR SITUATIONS WHERE THE ATMOSPHERIC LEVELS MAY
EXCEED THE LEVEL FOR WHICH AN AIR-PURIFYING RESPIRATOR IS EFFECTIVE, USE
A POSITIVE-PRESSURE AIR-SUPPLYING RESPIRATOR (AIR LINE OR SELF-CONTAINED
BREATHING APPARATUS). FOR EMERGENCY RESPONSE OR FOR SITUATIONS WHERE THE
ATMOSPHERIC LEVEL IS UNKNOWN, USE AN APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS OR POSITIVEPRESSURE AIR LINE WITH
AUXILIARY SELF-CONTAINED AIR SUPPLY. IN CONFINED OR POORLY VENTILATED
AREAS, USE AN APPROVED SELF-CONTAINED BREATHING APPARATUS OR POSITIVE
PRESSURE AIR LINE WITH AUXILIARY SELF-CONTAINED AIR SUPPLY.
THE FOLLOWING SHOULD BE EFFECTIVE TYPES OF AIR-PURIFYING RESPIRATORS:
ORGANIC VAPOR CARTRIDGE WITH A PARTICULATE PRE-FILTER.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUEFIED GAS
COLOR: BROWN
ODOR: MUSTY
ODOR THRESHOLD: NO TEST DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/RANGE: NO TEST DATA AVAILABLE
FREEZING POINT: NO TEST DATA AVAILABLE
BOILING POINT (760 MMHg); NO TEST DATA AVAILABLE
FLASH POINT:
CLOSED CUP: GAS
EVAPORATION RATE (BUTYL ACETATE = 1): NO TEST DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
LOWER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
VAPOR PRESSURE:
1,551.3 KPA AT 54 DEG. C (129 DEG. F) CONTAINER IS UNDER PRESSURE.
RELATIVE VAPOR DENSITY (AIR = 1): NO TEST DATA AVAILABLE
RELATIVE DENSITY (WATER = 1):
1.24 AT 25 DEG. C (77 DEG. F) / 25 DEG. C ESTIMATED.
WATER SOLUBILITY: INSOLUBLE, REACTS, EVOLUTION OF CO2
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO TEST DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO TEST DATA AVAILABLE
KINEMATIC VISCOSITY: NO TEST DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES: NO
MOLECULAR WEIGHT: NO TEST DATA AVAILABLE
NOTE:
THE PHYSICAL DATA PRESENTED ABOVE ARE TYPICAL VALUES AND SHOULD NOT BE
CONSTRUED AS A SPECIFICATION.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS. SEE STORAGE, SECTION 7.
POSSIBILITY OF HAZARDOUS REACTIONS:
CAN OCCUR. ELEVATED TEMPERATURES CAN CAUSE HAZARDOUS POLYMERIZATION.
POLYMERIZATION CAN BE CATALYZED BY: STRONG BASES. WATER.
CONDITIONS TO AVOID:
EXPOSURE TO ELEVATED TEMPERATURES CAN CAUSE PRODUCT TO DECOMPOSE.
ELEVATED TEMPERATURES CAN CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS
DUE TO THE RELEASE OF BLOWING AGENTS. GENERATION OF GAS DURING
DECOMPOSITION CAN CAUSE PRESSURE IN CLOSED SYSTEMS. PRESSURE BUILD-UP
CAN BE RAPID. AVOID MOISTURE. MATERIAL REACTS SLOWLY WITH WATER, RELEASING
CARBON DIOXIDE WHICH CAN CAUSE PRESSURE BUILDUP AND RUPTURE OF CLOSED
CONTAINERS. ELEVATED TEMPERATURES ACCELERATE THIS REACTION.
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH: ACIDS. ALCOHOLS. AMINES. WATER. AMMONIA. BASES. METAL
COMPOUNDS. MOIST AIR. STRONG OXIDIZERS. DIISOCYANATES REACT WITH MANY
MATERIALS AND THE RATE OF REACTION INCREASES WITH TEMPERATURE AS WELL
AS INCREASED CONTACT; THESE REACTIONS CAN BECOME VIOLENT. CONTACT
IS INCREASED BY STIRRING OR IF THE OTHER MATERIAL MIXES WITH THE
DIISOCYANATE. DIISOCYANATES ARE NOT SOLUBLE IN WATER AND SINK TO THE
BOTTOM, BUT REACT SLOWLY AT THE INTERFACE. THE REACTION FORMS CARBON
DIOXIDE GAS AND A LAYER OF SOLID POLYUREA. REACTION WITH WATER WILL
GENERATE CARBON DIOXIDE AND HEAT. AVOID CONTACT WITH METALS SUCH AS:
ALUMINUM. ZINC. BRASS. TIN. COPPER. GALVANIZED METALS. AVOID CONTACT
WITH ABSORBENT MATERIALS SUCH AS: MOIST ORGANIC ABSORBENTS. AVOID
UNINTENDED CONTACT WITH POLYOLS. THE REACTION OF POLYOLS AND ISOCYANATES
GENERATE HEAT.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS DEPEND UPON TEMPERATURE, AIR SUPPLY AND THE
PRESENCE OF OTHER MATERIALS. GASES ARE RELEASED DURING DECOMPOSITION.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
ACUTE TOXICITY:
ACUTE ORAL TOXICITY:
LOW TOXICITY IF SWALLOWED. SMALL AMOUNTS SWALLOWED INCIDENTALLY AS A
RESULT OF NORMAL HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY;
HOWEVER, SWALLOWING LARGER AMOUNTS MAY CAUSE INJURY.
OBSERVATIONS IN ANIMALS INCLUDE: GASTROINTESTINAL IRRITATION.
AS PRODUCT: SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
LD50, RAT, >2,000 MG/KG ESTIMATED.
ACUTE DERMAL TOXICITY:
PROLONGED SKIN CONTACT IS UNLIKELY TO RESULT IN ABSORPTION OF HARMFUL
AMOUNTS.
AS PRODUCT: THE DERMAL LD50 HAS NOT BEEN DETERMINED.
LD50, RABBIT, >2,000 MG/KG ESTIMATED.
ACUTE INHALATION TOXICITY:
IN CONFINED OR POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE
AND CAN CAUSE UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN.
EXCESSIVE EXPOSURE MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT
(NOSE AND THROAT) AND LUNGS. MAY CAUSE PULMONARY EDEMA (FLUID IN THE
LUNGS.) EFFECTS MAY BE DELAYED. DECREASED LUNG FUNCTION HAS BEEN
ASSOCIATED WITH OVEREXPOSURE TO ISOCYANATES. EXCESSIVE EXPOSURE MAY
INCREASE SENSITIVITY TO EPINEPHRINE AND INCREASE MYOCARDIAL IRRITABILITY
(IRREGULAR HEARTBEATS). MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. SYMPTOMS
OF EXCESSIVE EXPOSURE MAY BE ANESTHETIC OR NARCOTIC EFFECTS; DIZZINESS AND
DROWSINESS MAY BE OBSERVED.
AS PRODUCT: THE LC50 HAS NOT BEEN DETERMINED.
SKIN CORROSION/IRRITATION:
PROLONGED CONTACT MAY CAUSE SKIN IRRITATION WITH LOCAL REDNESS.
MAY STAIN SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE MODERATE EYE IRRITATION.
MAY CAUSE SLIGHT TEMPORARY CORNEAL INJURY.
SENSITIZATION:
SKIN CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION.
ANIMAL STUDIES HAVE SHOWN THAT SKIN CONTACT WITH ISOCYANATES MAY PLAY A
ROLE IN RESPIRATORY SENSITIZATION.
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
MDI CONCENTRATIONS BELOW THE EXPOSURE GUIDELINES MAY CAUSE ALLERGIC
RESPIRATORY REACTIONS IN INDIVIDUALS ALREADY SENSITIZED.
ASTHMA-LIKE SYMPTOMS MAY INCLUDE COUGHING, DIFFICULT BREATHING AND A
FEELING OF TIGHTNESS IN THE CHEST.
OCCASIONALLY, BREATHING DIFFICULTIES MAY BE LIFE THREATENING.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ROUTE OF EXPOSURE: INHALATION
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
TISSUE INJURY IN THE UPPER RESPIRATORY TRACT AND LUNGS HAS BEEN OBSERVED
IN LABORATORY ANIMALS AFTER REPEATED EXCESSIVE EXPOSURES TO MDI/POLYMERIC
MDI AEROSOLS.
CARCINOGENICITY:
LUNG TUMORS HAVE BEEN OBSERVED IN LABORATORY ANIMALS EXPOSED TO RESPIRABLE
AEROSOL DROPLETS OF MDI/POLYMERIC MDI (6 MG/M3) FOR THEIR LIFETIME. TUMORS
OCCURRED CONCURRENTLY WITH RESPIRATORY IRRITATION AND LUNG INJURY. CURRENT
EXPOSURE GUIDELINES ARE EXPECTED TO PROTECT AGAINST THESE EFFECTS REPORTED
FOR MDI.
TERATOGENICITY:
IN LABORATORY ANIMALS, MDI/POLYMERIC MDI DID NOT CAUSE BIRTH DEFECTS;
OTHER FETAL EFFECTS OCCURRED ONLY AT HIGH DOSES WHICH WERE TOXIC TO
THE MOTHER. CONTAINS COMPONENT(S) WHICH DID NOT CAUSE BIRTH DEFECTS
IN ANIMALS; OTHER FETAL EFFECTS OCCURRED ONLY AT DOSES TOXIC TO THE
MOTHER.
REPRODUCTIVE TOXICITY: NO RELEVANT DATA FOUND.
MUTAGENICITY:
GENETIC TOXICITY DATA ON MDI ARE INCONCLUSIVE. MDI WAS WEAKLY POSITIVE
IN SOME IN VITRO STUDIES; OTHER IN VITRO STUDIES WERE NEGATIVE. ANIMAL
MUTAGENICITY STUDIES WERE PREDOMINANTLY NEGATIVE.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
COMPONENTS INFLUENCING TOXICOLOGY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
ACUTE INHALATION TOXICITY:
LC50, RAT, 4 HOUR, DUST/MIST, 0.49 MG/L
FOR SIMILAR MATERIAL(S):
2,4'-DIPHENYLMETHANE DIISOCYANATE (CAS 5873-54-1).
LC50, RAT, 4 HOUR, AEROSOL, 0.31 MG/L
FOR SIMILAR MATERIAL(S):
4,4'-METHYLENEDIPHENYL DIISOCYANATE (CAS 101-68-8).
LC50, RAT, 1 HOUR, AEROSOL, 2.24 MG/L
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
ACUTE INHALATION TOXICITY:
LC50, RAT, 1 HOUR, DUST/MIST, 2.24 MG/L
1,1,1,2-TETRAFLUOROETHANE:
ACUTE INHALATION TOXICITY:
LC50, RAT, 4 HOUR, VAPOUR, >1,500 MG/L
MDI BASED URETHANE POLYMER P83-1015:
ACUTE INHALATION TOXICITY: THE LC50 HAS NOT BEEN DETERMINED.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
TOXICITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY
UNDER CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L,
OECD TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR, GROWTH
RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES., >100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL: 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY
UNDER CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L,
OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L,
OECD TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR,
GROWTH RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES., >100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL: 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
1,1,1,2-TETRAFLUOROETHANE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), SEMI-STATIC TEST, 96 HOUR,
450 MG/L
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, 980 MG/L
TOXICITY TO BACTERIA:
EC50, PSEUDOMONAS PUTIDA, STATIC TEST, 6 HOUR, GROWTH INHIBITION,
>730 MG/L
MDI BASED URETHANE POLYMER P83-1015:
ACUTE TOXICITY TO FISH:
NOT EXPECTED TO BE ACUTELY TOXIC TO AQUATIC ORGANISMS.
PERSISTENCE AND DEGRADABILITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH WATER
FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE STABLE.
IN THE ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE A SHORT
TROPOSPHERIC HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY WITH
RELATED DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH WATER
FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE STABLE.
IN THE ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE A SHORT
TROPOSPHERIC HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY WITH
RELATED DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
1,1,1,2-TETRAFLUOROETHANE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT).
FAILS TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 4 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301D OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 0.47 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 1,700 D
METHOD: ESTIMATED.
MDI BASED URETHANE POLYMER P83-1015:
BIODEGRADABILITY:
SURFACE PHOTODEGRADATION IS EXPECTED WITH EXPOSURE TO SUNLIGHT.
NO APPRECIABLE BIODEGRADATION IS EXPECTED.
BIOACCUMULATIVE POTENTIAL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS WITH
WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED
TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS WITH
WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED
TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
1,1,1,2-TETRAFLUOROETHANE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 1.68 ESTIMATED.
MDI BASED URETHANE POLYMER P83-1015:
BIOACCUMULATION:
NO BIOCONCENTRATION IS EXPECTED BECAUSE OF THE RELATIVELY HIGH MOLECULAR
WEIGHT (MW GREATER THAN 1000).
MOBILITY IN SOIL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
1,1,1,2-TETRAFLUOROETHANE:
POTENTIAL FOR MOBILITY IN SOIL IS HIGH (KOC BETWEEN 50 AND 150).
PARTITION COEFFICIENT (KOC): 97 ESTIMATED.
MDI BASED URETHANE POLYMER P83-1015: NO RELEVANT DATA FOUND.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
ALL DISPOSAL PRACTICES MUST BE IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY
IN DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH
APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR.
AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED
IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: COMPOSITION
INFORMATION. FOR UNUSED & UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS
INCLUDE SENDING TO A LICENSED, PERMITTED:
RECYCLER. RECLAIMER. INCINERATOR OR OTHER THERMAL DESTRUCTION DEVICE.
FOR ADDITIONAL INFORMATION, REFER TO:
HANDLING & STORAGE INFORMATION, MSDS SECTION 7 STABILITY & REACTIVITY
INFORMATION, MSDS SECTION10 REGULATORY INFORMATION, MSDS SECTION 15
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER UN: 3500
CLASS: 2.2
PACKING GROUP:
REPORTABLE QUANTITY: MDI
CLASSIFICATION FOR SEA TRANSPORT (IMO-IMDG):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX I OR II OF MARPOL 73/78 AND THE IBC
OR IGC CODE:
CONSULT IMO REGULATIONS BEFORE TRANSPORTING OCEAN BULK
CLASSIFICATION FOR AIR TRANSPORT (IATA/ICAO):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
THIS INFORMATION IS NOT INTENDED TO CONVEY ALL SPECIFIC REGULATORY
OR OPERATIONAL REQUIREMENTS/INFORMATION RELATING TO THIS PRODUCT.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND
MAY BE INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS.
ADDITIONAL TRANSPORTATION SYSTEM INFORMATION CAN BE OBTAINED THROUGH
AN AUTHORIZED SALES OR CUSTOMER SERVICE REPRESENTATIVE. IT IS THE
RESPONSIBILITY OF THE TRANSPORTING ORGANIZATION TO FOLLOW ALL
APPLICABLE LAWS, REGULATIONS AND RULES RELATING TO THE TRANSPORTATION
OF THE MATERIAL.
| 15. REGULATORY INFORMATION | |
OSHA HAZARD COMMUNICATION STANDARD:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTIONS 311 AND 312:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SUDDEN RELEASE OF PRESSURE HAZARD
REACTIVITY HAZARD
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND WHICH ARE LISTED IN
40 CFR 372.
COMPONENTS CASRN
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES 9016-87-9
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8
PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
TO THE BEST OF OUR KNOWLEDGE, THIS PRODUCT DOES NOT CONTAIN CHEMICALS AT
LEVELS WHICH REQUIRE REPORTING UNDER THIS STATUTE.
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT
OF 1986):
THIS PRODUCT CONTAINS NO LISTED SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM, AT LEVELS WHICH WOULD REQUIRE A WARNING UNDER THE STATUTE.
UNITED STATES TSCA INVENTORY (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY
LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA)
CHEMICAL SUBSTANCE INVENTORY.
| 16. OTHER INFORMATION | |
REVISION:
IDENTIFICATION NUMBER: 102984406 / A001
ISSUE DATE: 04/26/2016
VERSION: 1.0
MOST RECENT REVISION(S) ARE NOTED BY THE BOLD, DOUBLE BARS IN LEFT-HAND
MARGIN THROUGHOUT THIS DOCUMENT.
LEGEND:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
C: CEILING
CAL PEL:
CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
DOW IHG: DOW INDUSTRIAL HYGIENE GUIDELINE
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
PEL: PERMISSIBLE EXPOSURE LIMIT
STEL: SHORT TERM EXPOSURE LIMIT
TWA: TIME WEIGHTED AVERAGE
US WEEL: USA. WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS (WEEL)
INFORMATION SOURCE AND REFERENCES:
THIS SDS IS PREPARED BY PRODUCT REGULATORY SERVICES AND HAZARD
COMMUNICATIONS GROUPS FROM INFORMATION SUPPLIED BY INTERNAL REFERENCES
WITHIN OUR COMPANY.
THE DOW CHEMICAL COMPANY URGES EACH CUSTOMER OR RECIPIENT OF THIS (M)SDS
TO STUDY IT CAREFULLY AND CONSULT APPROPRIATE EXPERTISE, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
(M)SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THE INFORMATION HEREIN
IS PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS. IT IS THE BUYER'S/USER'S RESPONSIBILITY TO ENSURE
THAT HIS ACTIVITIES COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL OR LOCAL
LAWS. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS
SHIPPED. SINCE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE
CONTROL OF THE MANUFACTURER, IT IS THE BUYER'S/USER'S DUTY TO DETERMINE
THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS PRODUCT. DUE TO THE
PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS MANUFACTURERSPECIFIC
(M)SDSS, WE ARE NOT AND CANNOT BE RESPONSIBLE FOR (M)SDSS OBTAINED FROM
ANY SOURCE OTHER THAN OURSELVES. IF YOU HAVE OBTAINED AN (M)SDS FROM
ANOTHER SOURCE OR IF YOU ARE NOT SURE THAT THE (M)SDS YOU HAVE IS CURRENT,
PLEASE CONTACT US FOR THE MOST CURRENT VERSION.
(R*) (TM) TRADEMARK OF THE DOW CHEMICAL COMPANY ("DOW") OR AN AFFILIATED
COMPANY OF DOW
DOW(R*)
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
PRODUCT NAME: FROTH-PAK(TM) CLASS A POLYOL INT BLEND
ISSUE DATE: 05/24/2016
PRINT DATE: 11/02/2017
THE DOW CHEMICAL COMPANY ENCOURAGES AND EXPECTS YOU TO READ AND UNDERSTAND
THE ENTIRE (M)SDS, AS THERE IS IMPORTANT INFORMATION THROUGHOUT THE
DOCUMENT. WE EXPECT YOU TO FOLLOW THE PRECAUTIONS IDENTIFIED IN THIS
DOCUMENT UNLESS YOUR USE CONDITIONS WOULD NECESSITATE OTHER APPROPRIATE
METHODS OR ACTIONS.
| 1. IDENTIFICATION | |
PRODUCT NAME: FROTH-PAK(TM) CLASS A POLYOL INT BLEND
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
IDENTIFIED USES:
FOR INDUSTRIAL USE. COMPONENT(S) FOR THE MANUFACTURE OF URETHANE POLYMERS.
WE RECOMMEND THAT YOU USE THIS PRODUCT IN A MANNER CONSISTENT WITH THE
LISTED USE. IF YOUR INTENDED USE IS NOT CONSISTENT WITH THE STATED USE,
PLEASE CONTACT YOUR SALES OR TECHNICAL SERVICE REPRESENTATIVE.
COMPANY IDENTIFICATION:
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
CUSTOMER INFORMATION NUMBER:
800-258-2436
SDSQUESTION@DOW.COM
EMERGENCY TELEPHONE NUMBER:
24-HOUR EMERGENCY CONTACT:
CHEMTREC: +1 800-424-9300
LOCAL EMERGENCY CONTACT: 800-424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
THIS MATERIAL IS HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD 29CFR 1910.1200.
GASES UNDER PRESSURE - LIQUEFIED GAS
REPRODUCTIVE TOXICITY - CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - CATEGORY 2 - ORAL
LABEL ELEMENTS:
HAZARD PICTOGRAMS:
GAS CYLINDER
HEALTH HAZARD
SIGNAL WORD: WARNING!
HAZARDS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS (KIDNEY) THROUGH PROLONGED OR REPEATED EXPOSURE
IF SWALLOWED.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/ FUME/ GAS/ MIST/ VAPOURS/ SPRAY.
WEAR PROTECTIVE GLOVES/ PROTECTIVE CLOTHING/ EYE PROTECTION/ FACE
PROTECTION.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ ATTENTION.
STORAGE:
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NO DATA AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT IS A MIXTURE.
COMPONENT CASRN CONCENTRATION
SUCROSE , PROPYLENE OXIDE 9049-71-2 <=25.0 %
TEREPHTHALIC ACID-DEG-PEG-GLYCERINE 1221716-56-8 <=20.0 %
POLYESTER POLYOL
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE 13674-84-5 <=20.0 %
1,1,1,3,3-PENTAFLUOROPROPANE 460-73-1 <=15.0 %
1,2-BENZENEDICARBOXYLIC ACID, 3,4,5,6- 77098-07-8 <=10.0 %
TETRABROMO-, MIXED ESTERS WITH
DIETHYLENE GLYCOL AND PROPYLENE GLYCOL
TRIETHYL PHOSPHATE 78-40-0 <=10.0 %
POLYETHYLENE GLYCOL 25322-68-3 <=5.0 %
2-ETHYLHEXANOIC ACID POTASSIUM SALT 3164-85-0 <=5.0 %
GLYCEROL PROPYLENE OXIDE 25791-96-2 <=5.0 %
DIETHYLENE GLYCOL 111-46-6 <=5.0 %
DIMETHYL SILOXANES AND SILICONES, 3- 68937-54-2 <=5.0 %
HYDROXYPROPYL METHYL, ETHOXYLATED
1,1,1,2-TETRAFLUOROETHANE 811-97-2 <=20.0 %
DIMETHYLBIS((1-OXONEODECYL)OXY)STANNANE 68928-76-7 >=0.1 - <1.0 %
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION AND USE
THE RECOMMENDED PROTECTIVE CLOTHING (CHEMICAL RESISTANT GLOVES, SPLASH
PROTECTION). IF POTENTIAL FOR EXPOSURE EXISTS REFER TO SECTION 8 FOR
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT.
INHALATION:
MOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION;
IF BY MOUTH TO MOUTH USE RESCUER PROTECTION (POCKET MASK, ETC). IF
BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. CALL A PHYSICIAN OR TRANSPORT TO A MEDICAL FACILITY.
SKIN CONTACT: WASH OFF WITH PLENTY OF WATER.
EYE CONTACT:
FLUSH EYES THOROUGHLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT
LENSES AFTER THE INITIAL 1-2 MINUTES AND CONTINUE FLUSHING FOR SEVERAL
ADDITIONAL MINUTES. IF EFFECTS OCCUR, CONSULT A PHYSICIAN, PREFERABLY AN
OPHTHALMOLOGIST. SUITABLE EMERGENCY EYE WASH FACILITY SHOULD BE AVAILABLE
IN WORK AREA.
INGESTION:
DO NOT INDUCE VOMITING. CALL A PHYSICIAN AND/OR TRANSPORT TO EMERGENCY
FACILITY IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASIDE FROM THE INFORMATION FOUND UNDER DESCRIPTION OF FIRST AID MEASURES
(ABOVE) AND INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL
TREATMENT NEEDED (BELOW), ANY ADDITIONAL IMPORTANT SYMPTOMS AND EFFECTS
ARE DESCRIBED IN SECTION 11: TOXICOLOGY INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
DUE TO STRUCTURAL ANALOGY AND CLINICAL DATA, THIS MATERIAL MAY HAVE A
MECHANISM OF INTOXICATION SIMILAR TO ETHYLENE GLYCOL. ON THAT BASIS,
TREATMENT SIMILAR TO ETHYLENE GLYCOL INTOXICATION MAY BE OF BENEFIT. IN
CASES WHERE SEVERAL OUNCES (60 - 100 ML) HAVE BEEN INGESTED, CONSIDER THE
USE OF ETHANOL AND HEMODIALYSIS IN THE TREATMENT. CONSULT STANDARD
LITERATURE FOR DETAILS OF TREATMENT. IF ETHANOL IS USED, A THERAPEUTICALLY
EFFECTIVE BLOOD CONCENTRATION IN THE RANGE OF 100 - 150 MG/DL MAY BE
ACHIEVED BY A RAPID LOADING DOSE FOLLOWED BY A CONTINUOUS INTRAVENOUS
INFUSION. CONSULT STANDARD LITERATURE FOR DETAILS OF TREATMENT. 4-METHYL
PYRAZOLE (ANTIZOL(R*)) IS AN EFFECTIVE BLOCKER OF ALCOHOL DEHYDROGENASE
AND SHOULD BE USED IN THE TREATMENT OF ETHYLENE GLYCOL (EG), DI- OR
TRIETHYLENE GLYCOL (DEG, TEG), ETHYLENE GLYCOL BUTYL ETHER (EGBE), OR
METHANOL INTOXICATION IF AVAILABLE. FOMEPIZOLE PROTOCOL (BRENT, J. ET AL.,
NEW ENGLAND JOURNAL OF MEDICINE, FEB. 8, 2001, 344:6, P. 424-9):
LOADING DOSE 15 MG/KG INTRAVENOUSLY, FOLLOW BY BOLUS DOSE OF 10 MG/KG
EVERY 12 HOURS; AFTER 48 HOURS, INCREASE BOLUS DOSE TO 15 MG/KG EVERY 12
HOURS. CONTINUE FOMEPIZOLE UNTIL SERUM METHANOL, EG, DEG, TEG OR EGBE ARE
UNDETECTABLE. THE SIGNS AND SYMPTOMS OF POISONING INCLUDE ANION GAP
METABOLIC ACIDOSIS, CNS DEPRESSION, RENAL TUBULAR INJURY, AND POSSIBLE
LATE STAGE CRANIAL NERVE INVOLVEMENT. RESPIRATORY SYMPTOMS, INCLUDING
PULMONARY EDEMA, MAY BE DELAYED. PERSONS RECEIVING SIGNIFICANT EXPOSURE
SHOULD BE OBSERVED 24-48 HOURS FOR SIGNS OF RESPIRATORY DISTRESS. IN
SEVERE POISONING, RESPIRATORY SUPPORT WITH MECHANICAL VENTILATION AND
POSITIVE END EXPIRATORY PRESSURE MAY BE REQUIRED. MAINTAIN ADEQUATE
VENTILATION AND OXYGENATION OF THE PATIENT. ATTEMPT SEIZURE CONTROL WITH
DIAZEPAM 5-10 MG (ADULTS) INTRAVENOUS OVER 2-3 MINUTES. REPEAT EVERY 5-10
MINUTES AS NEEDED. MONITOR FOR HYPOTENSION, RESPIRATORY DEPRESSION, AND
NEED FOR INTUBATION. CONSIDER SECOND AGENT IF SEIZURES PERSIST AFTER 30
MG. IF SEIZURES PERSIST OR RECUR ADMINISTER PHENOBARBITAL 600-1200 MG
(ADULTS) INTRAVENOUS DILUTED IN 60 ML 0.9% SALINE GIVEN AT 25-50
MG/MINUTE. EVALUATE FOR HYPOXIA, DYSRHYTHMIA, ELECTROLYTE DISTURBANCE,
HYPOGLYCEMIA (TREAT ADULTS WITH DEXTROSE 100 MG INTRAVENOUS). IF LAVAGE IS
PERFORMED, SUGGEST ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL. DANGER FROM
LUNG ASPIRATION MUST BE WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING
THE STOMACH. EXPOSURE MAY INCREASE "MYOCARDIAL IRRITABILITY". DO NOT
ADMINISTER SYMPATHOMIMETIC DRUGS SUCH AS EPINEPHRINE UNLESS ABSOLUTELY
NECESSARY. TREATMENT OF EXPOSURE SHOULD BE DIRECTED AT THE CONTROL OF
SYMPTOMS AND THE CLINICAL CONDITION OF THE PATIENT.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG OR FINE SPRAY. DRY CHEMICAL FIRE EXTINGUISHERS. CARBON DIOXIDE
FIRE EXTINGUISHERS. FOAM. ALCOHOL RESISTANT FOAMS (ATC TYPE) ARE
PREFERRED. GENERAL PURPOSE SYNTHETIC FOAMS (INCLUDING AFFF) OR PROTEIN
FOAMS MAY FUNCTION, BUT WILL BE LESS EFFECTIVE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE DIRECT WATER STREAM. MAY SPREAD FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS COMBUSTION PRODUCTS:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR
IRRITATING. COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
CARBON MONOXIDE. CARBON DIOXIDE. HYDROGEN HALIDES.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINER MAY RUPTURE FROM GAS GENERATION IN A FIRE SITUATION. BLOWING
AGENT VAPORIZES QUICKLY AT ROOM TEMPERATURE. VIOLENT STEAM GENERATION OR
ERUPTION MAY OCCUR UPON APPLICATION OF DIRECT WATER STREAM TO HOT LIQUIDS.
ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
KEEP PEOPLE AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY. USE WATER SPRAY
TO COOL FIRE EXPOSED CONTAINERS AND FIRE AFFECTED ZONE UNTIL FIRE IS OUT
AND DANGER OF REIGNITION HAS PASSED. FIGHT FIRE FROM PROTECTED LOCATION OR
SAFE DISTANCE. CONSIDER THE USE OF UNMANNED HOSE HOLDERS OR MONITOR
NOZZLES. IMMEDIATELY WITHDRAW ALL PERSONNEL FROM THE AREA IN CASE OF
RISING SOUND FROM VENTING SAFETY DEVICE OR DISCOLORATION OF THE CONTAINER.
DO NOT USE DIRECT WATER STREAM. MAY SPREAD FIRE. MOVE CONTAINER FROM FIRE
AREA IF THIS IS POSSIBLE WITHOUT HAZARD. BURNING LIQUIDS MAY BE MOVED BY
FLUSHING WITH WATER TO PROTECT PERSONNEL AND MINIMIZE PROPERTY DAMAGE.
CONTAIN FIRE WATER RUN-OFF IF POSSIBLE. FIRE WATER RUN-OFF, IF NOT
CONTAINED, MAY CAUSE ENVIRONMENTAL DAMAGE. REVIEW THE "ACCIDENTAL RELEASE
MEASURES" AND THE "ECOLOGICAL INFORMATION" SECTIONS OF THIS (M)SDS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT,
TROUSERS, BOOTS, AND GLOVES). AVOID CONTACT WITH THIS MATERIAL DURING
FIRE FIGHTING OPERATIONS. IF CONTACT IS LIKELY, CHANGE TO FULL CHEMICAL
RESISTANT FIRE FIGHTING CLOTHING WITH SELF-CONTAINED BREATHING APPARATUS.
IF THIS IS NOT AVAILABLE, WEAR FULL CHEMICAL RESISTANT CLOTHING WITH
SELF-CONTAINED BREATHING APPARATUS AND FIGHT FIRE FROM A REMOTE LOCATION.
FOR PROTECTIVE EQUIPMENT IN POST-FIRE OR NON-FIRE CLEAN-UP SITUATIONS,
REFER TO THE RELEVANT SECTIONS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ISOLATE AREA. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING
THE AREA. KEEP PERSONNEL OUT OF CONFINED OR POORLY VENTILATED AREAS. KEEP
UPWIND OF SPILL. SPILLED MATERIAL MAY CAUSE A SLIPPING HAZARD. VENTILATE
AREA OF LEAK OR SPILL. CONFINED SPACE ENTRY PROCEDURES MUST BE FOLLOWED
BEFORE ENTERING THE AREA. REFER TO SECTION 7, HANDLING, FOR ADDITIONAL
PRECAUTIONARY MEASURES. USE APPROPRIATE SAFETY EQUIPMENT. FOR ADDITIONAL
INFORMATION, REFER TO SECTION 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FROM ENTERING INTO SOIL, DITCHES, SEWERS, WATERWAYS AND/OR
GROUNDWATER. SEE SECTION 12, ECOLOGICAL INFORMATION.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLED MATERIAL IF POSSIBLE. ABSORB WITH MATERIALS SUCH AS:
DIRT. SAND. SAWDUST. COLLECT IN SUITABLE AND PROPERLY LABELED CONTAINERS.
WASH THE SPILL SITE WITH WATER. SEE SECTION 13, DISPOSAL CONSIDERATIONS,
FOR ADDITIONAL INFORMATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES. AVOID BREATHING VAPOR. DO NOT ENTER CONFINED
SPACES UNLESS ADEQUATELY VENTILATED. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. THIS MATERIAL IS
HYGROSCOPIC IN NATURE. SEE SECTION 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.
SPILLS OF THESE ORGANIC MATERIALS ON HOT FIBROUS INSULATIONS MAY LEAD
TO LOWERING OF THE AUTOIGNITION TEMPERATURES POSSIBLY RESULTING IN
SPONTANEOUS COMBUSTION.
CONDITIONS FOR SAFE STORAGE:
MINIMIZE SOURCES OF IGNITION, SUCH AS STATIC BUILD-UP, HEAT, SPARK OR
FLAME. FLAMMABLE VAPORS MAY ACCUMULATE IN SOME STORAGE SITUATIONS.
PROTECT FROM ATMOSPHERIC MOISTURE. STORE IN A DRY PLACE. AVOID PROLONGED
EXPOSURE TO HEAT AND AIR. AVOID TEMPERATURES ABOVE 50 DEG. C (122 DEG. F)
SEE SECTION 10 FOR MORE SPECIFIC INFORMATION.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS: EXPOSURE LIMITS ARE LISTED BELOW, IF THEY EXIST.
COMPONENT REGULATION TYPE OF LISTING VALUE/NOTATION
1,1,1,3,3- US WEEL TWA 300 PPM
PENTAFLUOROPROPANE
TRIETHYL PHOSPHATE US WEEL TWA 7.45 MG/M3
POLYETHYLENE GLYCOL US WEEL TWA AEROSOL 10 MG/M3
DIETHYLENE GLYCOL US WEEL TWA 10 MG/M3
1,1,1,2- US WEEL TWA 1,000 PPM
TETRAFLUOROETHANE
DIMETHYLBIS((1- ACGIH TWA SKIN
OXONEODECYL)OXY)
STANNANE
ACGIH STEL SKIN
OSHA Z-1 TWA 0.1 MG/M3, TIN
ACGIH TWA 0.1 MG/M3, TIN
ACGIH STEL 0.2 MG/M3, TIN
OSHA P0 TWA 0.1 MG/M3, TIN
NIOSH REL TWA 0.1 MG/M3, TIN
CAL PEL PEL 0.1 MG/M3, TIN
CAL PEL STEL 0.2 MG/M3, TIN
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVEL BELOW EXPOSURE LIMIT
REQUIREMENTS OR GUIDELINES. IF THERE ARE NO APPLICABLE EXPOSURE LIMIT
REQUIREMENTS OR GUIDELINES, USE ONLY IN ENCLOSED SYSTEMS OR WITH LOCAL
EXHAUST VENTILATION. EXHAUST SYSTEMS SHOULD BE DESIGNED TO MOVE THE AIR
AWAY FROM THE SOURCE OF VAPOR/AEROSOL GENERATION AND PEOPLE WORKING AT
THIS POINT. LETHAL CONCENTRATIONS MAY EXIST IN AREAS WITH POOR
VENTILATION.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION: USE CHEMICAL GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL. EXAMPLES OF PREFERRED
GLOVE BARRIER MATERIALS INCLUDE:
CHLORINATED POLYETHYLENE. POLYETHYLENE. ETHYL VINYL ALCOHOL LAMINATE
("EVAL"). POLYVINYL ALCOHOL ("PVA"). STYRENE/BUTADIENE RUBBER. VITON.
EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE:
BUTYL RUBBER. NATURAL RUBBER ("LATEX"). POLYVINYL CHLORIDE ("PVC" OR
"VINYL").
NOTICE:
THE SELECTION OF A SPECIFIC GLOVE FOR A PARTICULAR APPLICATION AND
DURATION OF USE IN A WORKPLACE SHOULD ALSO TAKE INTO ACCOUNT ALL
RELEVANT WORKPLACE FACTORS SUCH AS, BUT NOT LIMITED TO:
OTHER CHEMICALS WHICH MAY BE HANDLED, PHYSICAL REQUIREMENTS (CUT/PUNCTURE
PROTECTION, DEXTERITY, THERMAL PROTECTION), POTENTIAL BODY REACTIONS TO
GLOVE MATERIALS, AS WELL AS THE INSTRUCTIONS/SPECIFICATIONS PROVIDED BY
THE GLOVE SUPPLIER.
OTHER PROTECTION:
USE PROTECTIVE CLOTHING CHEMICALLY RESISTANT TO THIS MATERIAL. SELECTION
OF SPECIFIC ITEMS SUCH AS FACE SHIELD, BOOTS, APRON, OR FULL BODY SUIT
WILL DEPEND ON THE TASK.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION SHOULD BE WORN WHEN THERE IS A POTENTIAL TO EXCEED
THE EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES. IF THERE ARE NO APPLICABLE
EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES, USE AN APPROVED RESPIRATOR.
WHEN RESPIRATORY PROTECTION IS REQUIRED, USE AN APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS OR POSITIVEPRESSURE AIRLINE WITH
AUXILIARY SELF-CONTAINED AIR SUPPLY. FOR EMERGENCY CONDITIONS, USE AN
APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CONFINED
OR POORLY VENTILATED AREAS, USE AN APPROVED SELF-CONTAINED BREATHING
APPARATUS OR POSITIVE PRESSURE AIR LINE WITH AUXILIARY SELF-CONTAINED AIR
SUPPLY.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUEFIED GAS
COLOR: BROWN
ODOR: SHARP
ODOR THRESHOLD: NO TEST DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/RANGE: NOT APPLICABLE TO LIQUIDS
FREEZING POINT: NO TEST DATA AVAILABLE
BOILING POINT (760 MMHg):
>100 DEG. C (>212 DEG. F) ESTIMATED. (BASED ON MAJOR COMPONENT)
FLASH POINT:
CLOSED CUP: 100 DEG. C (212 DEG. F) ESTIMATED. (BASED ON MAJOR COMPONENT)
EVAPORATION RATE (BUTYL ACETATE = 1): NO TEST DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
LOWER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
VAPOR PRESSURE: VERY LOW
RELATIVE VAPOR DENSITY (AIR = 1): NO TEST DATA AVAILABLE
RELATIVE DENSITY (WATER = 1): 1.18 ESTIMATED.
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO TEST DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO TEST DATA AVAILABLE
KINEMATIC VISCOSITY: NO TEST DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES: NO
MOLECULAR WEIGHT: NO TEST DATA AVAILABLE
NOTE:
THE PHYSICAL DATA PRESENTED ABOVE ARE TYPICAL VALUES AND SHOULD
NOT BE CONSTRUED AS A SPECIFICATION.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS. SEE STORAGE, SECTION 7.
POSSIBILITY OF HAZARDOUS REACTIONS: WILL NOT OCCUR BY ITSELF.
CONDITIONS TO AVOID:
PRODUCT CAN OXIDIZE AT ELEVATED TEMPERATURES. ELEVATED TEMPERATURES CAN
CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS DUE TO THE RELEASE OF BLOWING
AGENTS. GENERATION OF GAS DURING DECOMPOSITION CAN CAUSE PRESSURE IN
CLOSED SYSTEMS.
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH OXIDIZING MATERIALS. AVOID CONTACT WITH:
STRONG ACIDS. STRONG BASES. AVOID UNINTENDED CONTACT WITH ISOCYANATES.
THE REACTION OF POLYOLS AND ISOCYANATES GENERATES HEAT.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS DEPEND UPON TEMPERATURE, AIR SUPPLY AND THE
PRESENCE OF OTHER MATERIALS. DECOMPOSITION PRODUCTS CAN INCLUDE AND
ARE NOT LIMITED TO:
CARBON DIOXIDE. ALCOHOLS. ETHERS. HYDROCARBONS. HYDROGEN HALIDES. KETONES.
POLYMER FRAGMENTS.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
ACUTE TOXICITY:
ACUTE ORAL TOXICITY:
LOW TOXICITY IF SWALLOWED. SMALL AMOUNTS SWALLOWED INCIDENTALLY AS A
RESULT OF NORMAL HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY;
HOWEVER, SWALLOWING LARGER AMOUNTS MAY CAUSE INJURY. SIGNS AND SYMPTOMS
OF EXCESSIVE EXPOSURE MAY INCLUDE:
MAY CAUSE LACRIMATION (TEARS). SALIVATION. CONVULSIONS. TREMORS. INCREASED
ACTIVITY (HYPERACTIVITY).
AS PRODUCT: SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
BASED ON INFORMATION FOR COMPONENT(S):
LD50, RAT, >2,000 MG/KG ESTIMATED.
ACUTE DERMAL TOXICITY:
PROLONGED SKIN CONTACT IS UNLIKELY TO RESULT IN ABSORPTION OF HARMFUL
AMOUNTS.
AS PRODUCT: THE DERMAL LD50 HAS NOT BEEN DETERMINED.
BASED ON INFORMATION FOR COMPONENT(S):
LD50, RABBIT, >2,000 MG/KG ESTIMATED.
ACUTE INHALATION TOXICITY:
PROLONGED EXCESSIVE EXPOSURE MAY CAUSE ADVERSE EFFECTS. IN CONFINED OR
POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE AND CAN CAUSE
UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN. MAY CAUSE
RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM DEPRESSION. EXCESSIVE
EXPOSURE MAY INCREASE SENSITIVITY TO EPINEPHRINE AND INCREASE MYOCARDIAL
IRRITABILITY (IRREGULAR HEARTBEATS). SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE
ANESTHETIC OR NARCOTIC EFFECTS; DIZZINESS AND DROWSINESS MAY BE OBSERVED.
AS PRODUCT: THE LC50 HAS NOT BEEN DETERMINED.
SKIN CORROSION/IRRITATION:
BRIEF CONTACT MAY CAUSE SLIGHT SKIN IRRITATION WITH LOCAL REDNESS.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE MODERATE EYE IRRITATION.
MAY CAUSE SLIGHT CORNEAL INJURY.
SENSITIZATION:
BASED ON INFORMATION FOR COMPONENT(S):
DID NOT CAUSE ALLERGIC SKIN REACTIONS WHEN TESTED IN GUINEA PIGS.
FOR RESPIRATORY SENSITIZATION: NO RELEVANT DATA FOUND.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS SPECIFIC TARGET ORGAN
TOXICANT, SINGLE EXPOSURE.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
CONTAINS COMPONENT(S) WHICH HAVE BEEN REPORTED TO CAUSE EFFECTS ON THE
FOLLOWING ORGANS IN HUMANS:
GASTROINTESTINAL TRACT.
KIDNEY.
CONTAINS A COMPONENT WHICH IS REPORTED TO BE A WEAK ORGANOPHOSPHATE-TYPE
CHOLINESTERASE INHIBITOR.
EXCESSIVE EXPOSURE MAY PRODUCE ORGANOPHOSPHATE TYPE CHOLINESTERASE
INHIBITION.
SIGNS AND SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE HEADACHE, DIZZINESS,
INCOORDINATION, MUSCLE TWITCHING, TREMORS, NAUSEA, ABDOMINAL CRAMPS,
DIARRHEA, SWEATING, PINPOINT PUPILS, BLURRED VISION, SALIVATION, TEARING,
TIGHTNESS IN CHEST, EXCESSIVE URINATION, CONVULSIONS.
CONTAINS COMPONENT(S) WHICH HAVE BEEN REPORTED TO CAUSE EFFECTS ON THE
FOLLOWING ORGANS IN ANIMALS:
LIVER.
CARCINOGENICITY: NO RELEVANT DATA FOUND.
TERATOGENICITY:
DIETHYLENE GLYCOL HAS CAUSED TOXICITY TO THE FETUS AND SOME BIRTH DEFECTS
AT MATERNALLY TOXIC, HIGH DOSES IN ANIMALS. OTHER ANIMAL STUDIES HAVE NOT
REPRODUCED BIRTH DEFECTS EVEN AT MUCH HIGHER DOSES THAT CAUSED SEVERE
MATERNAL TOXICITY. CONTAINS COMPONENT(S) WHICH DID NOT CAUSE BIRTH DEFECTS
IN ANIMALS; OTHER FETAL EFFECTS OCCURRED ONLY AT DOSES TOXIC TO THE
MOTHER.
REPRODUCTIVE TOXICITY:
IN ANIMAL STUDIES ON COMPONENT(S), EFFECTS ON REPRODUCTION WERE SEEN ONLY
AT DOSES THAT PRODUCED SIGNIFICANT TOXICITY TO THE PARENT ANIMALS.
DIETHYLENE GLYCOL DID NOT INTERFERE WITH REPRODUCTION IN ANIMAL STUDIES
EXCEPT AT VERY HIGH DOSES.
MUTAGENICITY:
CONTAINS COMPONENT(S) WHICH WERE NEGATIVE IN SOME IN VITRO GENETIC
TOXICITY STUDIES AND POSITIVE IN OTHERS. CONTAINS COMPONENT(S) WHICH WERE
NEGATIVE IN SOME ANIMAL GENETIC TOXICITY STUDIES AND POSITIVE IN OTHERS.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
COMPONENTS INFLUENCING TOXICOLOGY:
SUCROSE , PROPYLENE OXIDE:
ACUTE INHALATION TOXICITY:
AT ROOM TEMPERATURE, EXPOSURE TO VAPOR IS MINIMAL DUE TO LOW VOLATILITY;
SINGLE EXPOSURE IS NOT LIKELY TO BE HAZARDOUS. VAPOR FROM HEATED MATERIAL
OR MIST MAY CAUSE RESPIRATORY IRRITATION.
TYPICAL FOR THIS FAMILY OF MATERIALS. NO DEATHS OCCURRED FOLLOWING
EXPOSURE TO A SATURATED ATMOSPHERE.
TEREPHTHALIC ACID-DEG-PEG-GLYCERINE POLYESTER POLYOL:
ACUTE INHALATION TOXICITY:
AS PRODUCT: THE LC50 HAS NOT BEEN DETERMINED.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
ACUTE INHALATION TOXICITY:
NO DEATHS OCCURRED AT THIS CONCENTRATION.
LC50, RAT, 4 HOUR, DUST/MIST, >7 MG/L
1,1,1,3,3-PENTAFLUOROPROPANE:
ACUTE INHALATION TOXICITY:
PROLONGED EXCESSIVE EXPOSURE MAY CAUSE ADVERSE EFFECTS. IN CONFINED OR
POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE AND CAN CAUSE
UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN. MAY CAUSE
RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM DEPRESSION. SYMPTOMS
MAY INCLUDE HEADACHE, DIZZINESS AND DROWSINESS, PROGRESSING TO
INCOORDINATION AND UNCONSCIOUSNESS. SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE
ANESTHETIC OR NARCOTIC EFFECTS; DIZZINESS AND DROWSINESS MAY BE OBSERVED.
EXCESSIVE EXPOSURE MAY INCREASE SENSITIVITY TO EPINEPHRINE AND INCREASE
MYOCARDIAL IRRITABILITY (IRREGULAR HEARTBEATS).
LC50, RAT, 4 HOUR, VAPOUR, 1,096 MG/L
1,2-BENZENEDICARBOXYLIC ACID, 3,4,5,6-TETRABROMO-, MIXED ESTERS WITH
DIETHYLENE GLYCOL AND PROPYLENE GLYCOL:
ACUTE INHALATION TOXICITY:
LC0, 1 HOUR, VAPOUR, >0.008 MG/L OTHER GUIDELINES THE LC50 VALUE IS
GREATER THAN THE MAXIMUM ATTAINABLE CONCENTRATION. NO DEATHS OCCURRED
FOLLOWING EXPOSURE TO A SATURATED ATMOSPHERE.
TRIETHYL PHOSPHATE:
ACUTE INHALATION TOXICITY:
LC50, RAT, 4 HOUR, DUST/MIST, >2.35 MG/L NO DEATHS OCCURRED AT THIS
CONCENTRATION.
POLYETHYLENE GLYCOL:
ACUTE INHALATION TOXICITY:
TYPICAL FOR THIS FAMILY OF MATERIALS. LC50, RAT, 6 HOUR, DUST/MIST,
>2.5 MG/L NO DEATHS OCCURRED AT THIS CONCENTRATION.
2-ETHYLHEXANOIC ACID POTASSIUM SALT:
ACUTE INHALATION TOXICITY:
AT ROOM TEMPERATURE, EXPOSURE TO VAPOR IS MINIMAL DUE TO LOW VOLATILITY;
VAPOR FROM HEATED MATERIAL MAY CAUSE RESPIRATORY IRRITATION. PROLONGED
EXCESSIVE EXPOSURE TO MIST MAY CAUSE ADVERSE EFFECTS.
LC50, RAT, 4 HOUR, VAPOUR, >0.14 MG/L NO DEATHS OCCURRED FOLLOWING
EXPOSURE TO A SATURATED ATMOSPHERE.
GLYCEROL PROPYLENE OXIDE:
ACUTE INHALATION TOXICITY:
AT ROOM TEMPERATURE, EXPOSURE TO VAPOR IS MINIMAL DUE TO LOW VOLATILITY;
SINGLE EXPOSURE IS NOT LIKELY TO BE HAZARDOUS. VAPOR FROM HEATED MATERIAL
OR MIST MAY CAUSE RESPIRATORY IRRITATION.
THE LC50 HAS NOT BEEN DETERMINED.
DIETHYLENE GLYCOL:
ACUTE INHALATION TOXICITY:
LC50, RAT, 4 HOUR, DUST/MIST, >4.6 MG/L THE LC50 VALUE IS GREATER THAN
THE MAXIMUM ATTAINABLE CONCENTRATION. NO DEATHS OCCURRED AT THIS
CONCENTRATION.
DIMETHYL SILOXANES AND SILICONES, 3-HYDROXYPROPYL METHYL, ETHOXYLATED:
ACUTE INHALATION TOXICITY: THE LC50 HAS NOT BEEN DETERMINED.
1,1,1,2-TETRAFLUOROETHANE:
ACUTE INHALATION TOXICITY: LC50, RAT, 4 HOUR, VAPOUR, >1,500 MG/L
DIMETHYLBIS((1-OXONEODECYL)OXY)STANNANE:
ACUTE INHALATION TOXICITY:
PROLONGED EXCESSIVE EXPOSURE TO MIST MAY CAUSE ADVERSE EFFECTS. MIST MAY
CAUSE IRRITATION OF UPPER RESPIRATORY TRACT (NOSE AND THROAT).
THE LC50 HAS NOT BEEN DETERMINED.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
TOXICITY:
SUCROSE , PROPYLENE OXIDE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, 6,310 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, 9,890 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, MORTALITY,
>=10 MG/L
LOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, MORTALITY,
>10 MG/L
TEREPHTHALIC ACID-DEG-PEG-GLYCERINE POLYESTER POLYOL:
ACUTE TOXICITY TO FISH:
FOR SIMILAR MATERIAL(S):
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
ACUTE TOXICITY TO FISH:
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH), STATIC TEST, 96 HOUR,
84 MG/L, OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, 131 MG/L
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
ERC50, PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE), STATIC TEST,
96 HOUR, GROWTH RATE INHIBITION, 82 MG/L, OECD TEST GUIDELINE 201
OR EQUIVALENT
TOXICITY TO BACTERIA:
EC50, ACTIVATED SLUDGE, RESPIRATION INHIBITION, 3 HOUR, 784 MG/L,
OECD 209 TEST
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, NUMBER OF
OFFSPRING, 32 MG/L MATC (MAXIMUM ACCEPTABLE TOXICANT LEVEL), DAPHNIA
MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, NUMBER OF OFFSPRING,
>32 MG/L
1,1,1,3,3-PENTAFLUOROPROPANE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), SEMI-STATIC TEST, 96 HOUR,
>100 MG/L
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, >100 MG/L
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
ERC50, SELENASTRUM CAPRICORNUTUM (GREEN ALGAE), STATIC TEST, 72 HOUR,
GROWTH RATE, >118 MG/L
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 14 D, MORTALITY,
29 MG/L
1,2-BENZENEDICARBOXYLIC ACID, 3,4,5,6-TETRABROMO-, MIXED ESTERS WITH
DIETHYLENE GLYCOL AND PROPYLENE GLYCOL:
ACUTE TOXICITY TO FISH:
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
TOXICITY TO AQUATIC SPECIES OCCURS AT CONCENTRATIONS ABOVE MATERIAL'S
WATER SOLUBILITY.
LC50, LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH), 96 HOUR, 12 MG/L, OECD TEST
GUIDELINE 203 OR EQUIVALENT
TRIETHYL PHOSPHATE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, LEUCISCUS IDUS (GOLDEN ORFE), STATIC TEST, 48 HOUR, 2,140 MG/L,
OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, 350 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
EC50, DESMODESMUS SUBSPICATUS (GREEN ALGAE), 72 HOUR, GROWTH RATE
INHIBITION, 900 MG/L, OECD TEST GUIDELINE 201
TOXICITY TO BACTERIA:
EC50, ACTIVATED SLUDGE, RESPIRATION INHIBITION, 30 MIN, >2,985 MG/L,
OECD 209 TEST
POLYETHYLENE GLYCOL:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, PIMEPHALES PROMELAS (FATHEAD MINNOW), STATIC TEST, 96 HOUR,
>10,000 MG/L, OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
LC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, >10,000 MG/L
2-ETHYLHEXANOIC ACID POTASSIUM SALT:
ACUTE TOXICITY TO FISH:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
ACUTE TOXICITY TO AQUATIC INVERTEBRATES: EC50, DAPHNIA MAGNA, 60 MG/L
GLYCEROL PROPYLENE OXIDE:
ACUTE TOXICITY TO FISH:
FOR THIS FAMILY OF MATERIALS:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
FOR THIS FAMILY OF MATERIALS:
LC50, LEUCISCUS IDUS (GOLDEN ORFE), SEMI-STATIC TEST, 96 HOUR,
>1,000 MG/L, OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
FOR THIS FAMILY OF MATERIALS:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 48 HOUR, >100 MG/L,
OECD TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
FOR THIS FAMILY OF MATERIALS:
EC50, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR,
GROWTH RATE INHIBITION, >100 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D,
MORTALITY, >=10 MG/L
LOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D,
MORTALITY, >10 MG/L
DIETHYLENE GLYCOL:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, PIMEPHALES PROMELAS (FATHEAD MINNOW), FLOW-THROUGH TEST, 96 HOUR,
75,200 MG/L, OECD TEST GUIDELINE 203 OR EQUIVALENT
TOXICITY TO BACTERIA:
EC50, ACTIVATED SLUDGE, 3 HOUR, >1,000 MG/L, OECD 209 TEST
DIMETHYL SILOXANES AND SILICONES, 3-HYDROXYPROPYL METHYL, ETHOXYLATED:
ACUTE TOXICITY TO FISH: NO RELEVANT DATA FOUND.
1,1,1,2-TETRAFLUOROETHANE:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), SEMI-STATIC TEST, 96 HOUR,
450 MG/L
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, 980 MG/L
TOXICITY TO BACTERIA:
EC50, PSEUDOMONAS PUTIDA, STATIC TEST, 6 HOUR, GROWTH INHIBITION,
>730 MG/L
DIMETHYLBIS((1-OXONEODECYL)OXY)STANNANE:
ACUTE TOXICITY TO FISH:
FOR SIMILAR MATERIAL(S):
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
FOR SIMILAR MATERIAL(S):
LC50, ZEBRA FISH (DANIO/BRACHYDANIO RERIO), SEMI-STATIC TEST,
96 HOUR, >100 MG/L, OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
FOR SIMILAR MATERIAL(S):
EC50, DAPHNIA MAGNA, STATIC TEST, 48 HOUR, 17 MG/L,
OECD TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
FOR SIMILAR MATERIAL(S):
ERC50, ALGAE (SCENEDESMUS SUBSPICATUS), GROWTH RATE, 72 HOUR,
GROWTH RATE, 37 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
FOR SIMILAR MATERIAL(S):
NOEC, ALGAE (SCENEDESMUS SUBSPICATUS), GROWTH RATE, 72 HOUR,
GROWTH RATE, 1.1 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
FOR SIMILAR MATERIAL(S):
EC50, BACTERIA, 3 HOUR, RESPIRATION RATES., 14 MG/L
PERSISTENCE AND DEGRADABILITY:
SUCROSE , PROPYLENE OXIDE:
BIODEGRADABILITY:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
MATERIAL IS INHERENTLY BIODEGRADABLE (REACHES >20% BIODEGRADATION IN
OECD TEST(S) FOR INHERENT BIODEGRADABILITY).
TEREPHTHALIC ACID-DEG-PEG-GLYCERINE POLYESTER POLYOL:
BIODEGRADABILITY: NO RELEVANT DATA FOUND.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT).
FAILS TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 14 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301E OR EQUIVALENT
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 95 %
EXPOSURE TIME: 64 D
METHOD: OECD TEST GUIDELINE 302A OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.17 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 0.24 D
METHOD: ESTIMATED.
1,1,1,3,3-PENTAFLUOROPROPANE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT). FAILS
TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 8 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301D OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 0.60 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 360 D
METHOD: ESTIMATED.
1,2-BENZENEDICARBOXYLIC ACID, 3,4,5,6-TETRABROMO-, MIXED ESTERS WITH
DIETHYLENE GLYCOL AND PROPYLENE GLYCOL:
BIODEGRADABILITY: EXPECTED TO DEGRADE SLOWLY IN THE ENVIRONMENT.
THEORETICAL OXYGEN DEMAND: 0.74 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 0.351 D
METHOD: ESTIMATED.
TRIETHYL PHOSPHATE:
BIODEGRADABILITY:
MATERIAL IS ULTIMATELY BIODEGRADABLE (REACHES >70% MINERALIZATION IN
OECD TEST(S) FOR INHERENT BIODEGRADABILITY).
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: >90 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302B OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.58 MG/MG
POLYETHYLENE GLYCOL:
BIODEGRADABILITY:
MATERIAL IS READILY BIODEGRADABLE. PASSES OECD TEST(S) FOR READY
BIODEGRADABILITY.
10-DAY WINDOW: PASS
BIODEGRADATION: 85 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301F OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.67 MG/MG
2-ETHYLHEXANOIC ACID POTASSIUM SALT:
BIODEGRADABILITY:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
MATERIAL IS EXPECTED TO BE READILY BIODEGRADABLE. MATERIAL IS ULTIMATELY
BIODEGRADABLE (REACHES >70% MINERALIZATION IN OECD TEST(S) FOR INHERENT
BIODEGRADABILITY).
GLYCEROL PROPYLENE OXIDE:
BIODEGRADABILITY:
FOR THIS FAMILY OF MATERIALS:
BASED ON STRINGENT OECD TEST GUIDELINES, THIS MATERIAL CANNOT BE
CONSIDERED AS READILY BIODEGRADABLE; HOWEVER, THESE RESULTS DO NOT
NECESSARILY MEAN THAT THE MATERIAL IS NOT BIODEGRADABLE UNDER
ENVIRONMENTAL CONDITIONS. MATERIAL IS ULTIMATELY BIODEGRADABLE
(REACHES >70% MINERALIZATION IN OECD TEST(S) FOR INHERENT
BIODEGRADABILITY).
10-DAY WINDOW: FAIL
BIODEGRADATION: 40 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301B OR EQUIVALENT
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 99 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302B OR EQUIVALENT
DIETHYLENE GLYCOL:
BIODEGRADABILITY:
MATERIAL IS READILY BIODEGRADABLE. PASSES OECD TEST(S) FOR READY
BIODEGRADABILITY. MATERIAL IS ULTIMATELY BIODEGRADABLE (REACHES
>70% MINERALIZATION IN OECD TEST(S) FOR INHERENT BIODEGRADABILITY).
10-DAY WINDOW: PASS
BIODEGRADATION: 90 - 100 %
EXPOSURE TIME: 20 D
METHOD: OECD TEST GUIDELINE 301A OR EQUIVALENT
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 82 - 98 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.51 MG/MG ESTIMATED.
DIMETHYL SILOXANES AND SILICONES, 3-HYDROXYPROPYL METHYL, ETHOXYLATED:
BIODEGRADABILITY: NO RELEVANT DATA FOUND.
1,1,1,2-TETRAFLUOROETHANE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT).
FAILS TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 4 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301D OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 0.47 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 1,700 D
METHOD: ESTIMATED.
DIMETHYLBIS((1-OXONEODECYL)OXY)STANNANE:
BIODEGRADABILITY:
FOR SIMILAR MATERIAL(S):
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT).
FAILS TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
FOR SIMILAR MATERIAL(S): 10-DAY
WINDOW: FAIL
BIODEGRADATION: 3 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301F OR EQUIVALENT
BIOACCUMULATIVE POTENTIAL:
SUCROSE , PROPYLENE OXIDE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): -3.38 - -3.25 ESTIMATED.
TEREPHTHALIC ACID-DEG-PEG-GLYCERINE POLYESTER POLYOL:
BIOACCUMULATION:
NO BIOCONCENTRATION IS EXPECTED BECAUSE OF THE RELATIVELY HIGH MOLECULAR
WEIGHT (MW GREATER THAN 1000).
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT:
N-OCTANOL/WATER(LOG POW): 2.59 MEASURED
BIOCONCENTRATION FACTOR (BCF):
0.8 - 4.6 CYPRINUS CARPIO (CARP) 42 D MEASURED
1,1,1,3,3-PENTAFLUOROPROPANE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT:
N-OCTANOL/WATER(LOG POW): 1.35 MEASURED
1,2-BENZENEDICARBOXYLIC ACID, 3,4,5,6-TETRABROMO-, MIXED ESTERS WITH
DIETHYLENE GLYCOL AND PROPYLENE GLYCOL:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT:
N-OCTANOL/WATER(LOG POW): 3.83 ESTIMATED.
BIOCONCENTRATION FACTOR (BCF): 39 FISH ESTIMATED.
TRIETHYL PHOSPHATE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT:
N-OCTANOL/WATER(LOG POW): 0.80 MEASURED
POLYETHYLENE GLYCOL:
BIOACCUMULATION:
NO BIOCONCENTRATION IS EXPECTED BECAUSE OF THE RELATIVELY HIGH WATER
SOLUBILITY.
2-ETHYLHEXANOIC ACID POTASSIUM SALT:
BIOACCUMULATION:
BASED ON INFORMATION FOR A SIMILAR MATERIAL: BIOCONCENTRATION POTENTIAL IS
LOW (BCF <100 OR LOG POW <3).
GLYCEROL PROPYLENE OXIDE:
BIOACCUMULATION:
NO BIOCONCENTRATION IS EXPECTED BECAUSE OF THE RELATIVELY HIGH WATER
SOLUBILITY.
DIETHYLENE GLYCOL:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT:
N-OCTANOL/WATER(LOG POW): -1.98 AT 20 DEG. C ESTIMATED.
BIOCONCENTRATION FACTOR (BCF): 100 FISH MEASURED
DIMETHYL SILOXANES AND SILICONES, 3-HYDROXYPROPYL METHYL, ETHOXYLATED:
BIOACCUMULATION: NO RELEVANT DATA FOUND.
1,1,1,2-TETRAFLUOROETHANE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT:
N-OCTANOL/WATER(LOG POW): 1.68 ESTIMATED.
DIMETHYLBIS((1-OXONEODECYL)OXY)STANNANE:
BIOACCUMULATION: NO RELEVANT DATA FOUND.
MOBILITY IN SOIL:
SUCROSE , PROPYLENE OXIDE: NO RELEVANT DATA FOUND.
TEREPHTHALIC ACID-DEG-PEG-GLYCERINE POLYESTER POLYOL:
NO RELEVANT DATA FOUND.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
POTENTIAL FOR MOBILITY IN SOIL IS SLIGHT (KOC BETWEEN 2000 AND 5000).
PARTITION COEFFICIENT (KOC): 1300 ESTIMATED.
1,1,1,3,3-PENTAFLUOROPROPANE:
POTENTIAL FOR MOBILITY IN SOIL IS MEDIUM (KOC BETWEEN 150 AND 500).
PARTITION COEFFICIENT (KOC): 280 ESTIMATED.
1,2-BENZENEDICARBOXYLIC ACID, 3,4,5,6-TETRABROMO-, MIXED ESTERS WITH
DIETHYLENE GLYCOL AND PROPYLENE GLYCOL:
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
GIVEN ITS VERY LOW HENRY'S CONSTANT, VOLATILIZATION FROM NATURAL BODIES
OF WATER OR MOIST SOIL IS NOT EXPECTED TO BE AN IMPORTANT FATE PROCESS.
PARTITION COEFFICIENT (KOC): 10 ESTIMATED.
TRIETHYL PHOSPHATE:
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
GIVEN ITS VERY LOW HENRY'S CONSTANT, VOLATILIZATION FROM NATURAL BODIES
OF WATER OR MOIST SOIL IS NOT EXPECTED TO BE AN IMPORTANT FATE PROCESS.
PARTITION COEFFICIENT (KOC): 48 ESTIMATED.
POLYETHYLENE GLYCOL: NO RELEVANT DATA FOUND.
2-ETHYLHEXANOIC ACID POTASSIUM SALT:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
GLYCEROL PROPYLENE OXIDE: NO RELEVANT DATA FOUND.
DIETHYLENE GLYCOL:
GIVEN ITS VERY LOW HENRY'S CONSTANT, VOLATILIZATION FROM NATURAL BODIES
OF WATER OR MOIST SOIL IS NOT EXPECTED TO BE AN IMPORTANT FATE PROCESS.
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
PARTITION COEFFICIENT (KOC): <1 ESTIMATED.
DIMETHYL SILOXANES AND SILICONES, 3-HYDROXYPROPYL METHYL, ETHOXYLATED:
NO RELEVANT DATA FOUND.
1,1,1,2-TETRAFLUOROETHANE:
POTENTIAL FOR MOBILITY IN SOIL IS HIGH (KOC BETWEEN 50 AND 150).
PARTITION COEFFICIENT (KOC): 97 ESTIMATED.
DIMETHYLBIS((1-OXONEODECYL)OXY)STANNANE: NO RELEVANT DATA FOUND.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
ALL DISPOSAL PRACTICES MUST BE IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY IN
DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH
APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR. AS
YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: COMPOSITION INFORMATION.
FOR UNUSED & UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS INCLUDE
SENDING TO A LICENSED, PERMITTED:
RECYCLER. RECLAIMER. INCINERATOR OR OTHER THERMAL DESTRUCTION DEVICE. FOR
ADDITIONAL INFORMATION, REFER TO:
HANDLING & STORAGE INFORMATION, MSDS SECTION 7 STABILITY & REACTIVITY
INFORMATION, MSDS SECTION10 REGULATORY INFORMATION, MSDS SECTION 15
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
CLASSIFICATION FOR SEA TRANSPORT (IMO-IMDG):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX I OR II OF MARPOL 73/78 AND THE IBC
OR IGC CODE:
CONSULT IMO REGULATIONS BEFORE TRANSPORTING OCEAN BULK
CLASSIFICATION FOR AIR TRANSPORT (IATA/ICAO):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2-TETRAFLUOROETHANE)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
THIS INFORMATION IS NOT INTENDED TO CONVEY ALL SPECIFIC REGULATORY OR
OPERATIONAL REQUIREMENTS/INFORMATION RELATING TO THIS PRODUCT.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND MAY BE
INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS. ADDITIONAL
TRANSPORTATION SYSTEM INFORMATION CAN BE OBTAINED THROUGH AN AUTHORIZED
SALES OR CUSTOMER SERVICE REPRESENTATIVE. IT IS THE RESPONSIBILITY OF THE
TRANSPORTING ORGANIZATION TO FOLLOW ALL APPLICABLE LAWS, REGULATIONS AND
RULES RELATING TO THE TRANSPORTATION OF THE MATERIAL.
| 15. REGULATORY INFORMATION | |
OSHA HAZARD COMMUNICATION STANDARD:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III
(EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTIONS 311
AND 312:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SUDDEN RELEASE OF PRESSURE HAZARD
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS
ESTABLISHED BY SARA TITLE III, SECTION 313.
PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
THE FOLLOWING CHEMICALS ARE LISTED BECAUSE OF THE ADDITIONAL REQUIREMENTS
OF PENNSYLVANIA LAW:
COMPONENTS CASRN
DIETHYLENE GLYCOL 111-46-6
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT
OF 1986):
THIS PRODUCT CONTAINS NO LISTED SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM,
AT LEVELS WHICH WOULD REQUIRE A WARNING UNDER THE STATUTE.
UNITED STATES TSCA INVENTORY (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY
LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA)
CHEMICAL SUBSTANCE INVENTORY.
| 16. OTHER INFORMATION | |
REVISION:
IDENTIFICATION NUMBER: 102984522 / A001
ISSUE DATE: 05/24/2016
VERSION: 2.0
MOST RECENT REVISION(S) ARE NOTED BY THE BOLD, DOUBLE BARS IN LEFT-HAND
MARGIN THROUGHOUT THIS DOCUMENT.
LEGEND:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
CAL PEL:
CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
NIOSH REL: USA. NIOSH RECOMMENDED EXPOSURE LIMITS
OSHA P0: USA. OSHA - TABLE Z-1 LIMITS FOR AIR CONTAMINANTS - 1910.1000
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
PEL: PERMISSIBLE EXPOSURE LIMIT
SKIN: ABSORBED VIA SKIN
STEL: SHORT TERM EXPOSURE LIMIT
TWA: 8-HOUR, TIME-WEIGHTED AVERAGE
US WEEL: USA. WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS (WEEL)
INFORMATION SOURCE AND REFERENCES:
THIS SDS IS PREPARED BY PRODUCT REGULATORY SERVICES AND HAZARD
COMMUNICATIONS GROUPS FROM INFORMATION SUPPLIED BY INTERNAL REFERENCES
WITHIN OUR COMPANY.
THE DOW CHEMICAL COMPANY URGES EACH CUSTOMER OR RECIPIENT OF THIS (M)SDS
TO STUDY IT CAREFULLY AND CONSULT APPROPRIATE EXPERTISE, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
(M)SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THE INFORMATION HEREIN
IS PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS. IT IS THE BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED.
SINCE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF THE
MANUFACTURER, IT IS THE BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS
NECESSARY FOR THE SAFE USE OF THIS PRODUCT. DUE TO THE PROLIFERATION OF
SOURCES FOR INFORMATION SUCH AS MANUFACTURERSPECIFIC (M)SDSS, WE ARE NOT
AND CANNOT BE RESPONSIBLE FOR (M)SDSS OBTAINED FROM ANY SOURCE OTHER THAN
OURSELVES. IF YOU HAVE OBTAINED AN (M)SDS FROM ANOTHER SOURCE OR IF YOU
ARE NOT SURE THAT THE (M)SDS YOU HAVE IS CURRENT, PLEASE CONTACT US FOR
THE MOST CURRENT VERSION.
(R*) (TM) TRADEMARK OF THE DOW CHEMICAL COMPANY ("DOW") OR AN AFFILIATED
COMPANY OF DOW